Chapter 5
Elements of quantum electrodynamics
5.1 Quantum mechanical equations of motion
In quantum mechanics I & II, the correspondence principle played a central role. It is in a sense the recipe to quantize a system whose Hamiltonian is known. It consists in the following two substitution rules : #» p i (momentum), (5.1) �−→ − ∇ E i∂ (energy). (5.2) �−→ t
For nonrelativistic quantum mechanics we get the celebrated Schr¨odinger equation,
1 #» i∂ ψ=Hψ, withH= +V( x), (5.3) t − 2m� #» whose free solution (V( x) 0) is, ≡ #» #» #» 2 #» i(Et p x) p ψ( x , t)=Ce − · withE= . 2m
The relativistic version of the energy-momentum relationship is however, #» E2 = p 2 +m 2, (5.4) from which we get, using again the correspondence principle Eq. (5.1),
∂2ψ=( +m 2)ψ. (5.5) − t −�
55 56 CHAPTER 5. ELEMENTS OF QUANTUM ELECTRODYNAMICS
At this point we define some important symbols which will follow us troughout the rest of this lecture,
∂ := (∂ , ), (5.6) µ t ∇ ∂µ :=g µν∂ = (∂ , ), (5.7) ν t −∇ :=∂ ∂µ =∂ 2 . (5.8) � µ t − � With this notation we can then reformulate Eq. (5.5) to get the Klein-Gordon equation,
2 �+m ψ=0 , (5.9)
with solutions, � � #» #» #» i(Et p x) #»2 2 ψ( x , t)=Ce − · withE= p +m . ± � We see that in this case it is possible to have negative energy eigenvalues, a fact not arising with the nonrelativistic case. As in the case of the Schr¨odinger equation (5.3) we can formulate a continuity equation. To do so we multiply the Klein-Gordon equation (5.9) by the left withψ ∗ and its conjugate, 2 (�+m )ψ ∗ = 0, byψ and then subtract both equations to get,
µ µ 0 =ψ ∗∂ ∂µψ ψ∂ ∂µψ∗ µ − =∂ (ψ∗∂ ψ ψ∂ ψ∗) µ − µ ∂ (ψ∗∂ ψ ψ∂ ψ∗) + (ψ ∗ ψ ψ ψ ∗) = 0. (5.10) ⇒ t t − t ∇· ∇ − ∇
We would like to interpretψ ∗∂tψ ψ∂ tψ∗ in Eq. (5.10) as a probability density, or more exactly, −
ρ=i(ψ ∗∂ ψ ψ∂ ψ∗), t − t which is not a positive definite quantity (as we can convince ourselves by computingρ for the plane wave solution), and hence cannot be interpreted as a probability density as it was the case in QM. When computing the continuity equation for the Schr¨odinger equation, where such a problem does not arise, we see that the problem lies essentially in the presence of a second order time derivative in the Klein-Gordon equation. We now make a big step, by imposing that our equation of motion only contains a first order time derivative. Since we want a Lorentz invariant equation of motion, we conclude that only a linear dependence on is allowed. Following D irac’s intuition, we make the ansatz, ∇ #» (iγµ∂ m)ψ=(iγ 0∂ +i γ m)ψ=0. (5.11) µ − t ·∇− 5.1. QUANTUM MECHANICAL EQUATIONS OF MOTION5 7
Turning back to the correspondence principle we remark that, #» #» (γ0E γ p m)ψ=0 (5.12) − · − #» #» (γ 0E γ p m) 2ψ=0, ⇒ − · − #» which must stay compatible with the mass-shell relation,E 2 = p 2 +m 2. This implies that theγ µ’s cannot be numbers since it would then be impossible to satisfy,
3 2 #» #» ! #» ( γ p) 2 = γip p 2, · i ∝ � i=1 � � so we let them ben n matrices, for ann which is still to be dete rmined. × We now derive relations that theγ µ’s must fullfill, so that the mass-shell relation remains true. From Eq. (5.12), and again with the correspondence principle, we must have,
0 1 #» 0 1 i∂t =(γ )− γ ( i ) +(γ )− m · − ∇#» E p 3 ����2 1 � ��0 �1 i 0 1 j 0 1 j 0 1 i ∂ = (γ )− γ (γ )− γ + (γ )− γ (γ )− γ ∂ ∂ (5.13) ⇒ − t − 2 i j i,j=1 E2 � � � 3 ���� 0 1 i 0 1 0 1 0 1 i i m (γ )− γ (γ )− + (γ )− (γ )− γ ∂ (5.14) − · i i=1 2 �0 1� 0 1 � +m (γ )− (γ )− (5.15) ! 2 =(∂i∂i +m ) (5.16) =( +m2). −�#» p 2 ���� Comparing Eqs. (5.16) and (5.15) we conclude that,
0 1 0 1 ! 0 1 0 (γ )− (γ )− = (γ )− =γ . (5.17) ⇒
Defining a, b := ab+ ba and comparing Eq. (5.1 6) and Eq. (5.14) we get { }
0 i 0 1 ! i 0 γ γ (γ )− = 0 γ , γ =0.( 5.18) ⇒{ }
Finally, comparing Eq. (5.16) and Eq. (5.13), we have,
1 0 1 i 0 1 j 0 1 j 0 1 i ! i j (γ )− γ (γ )− γ + (γ )− γ (γ )− γ =δ γ , γ = 2δ . (5.19) −2 ij ⇒ { } − ij � � 58 CHAPTER 5. ELEMENTS OF QUANTUM ELECTRODYNAMICS
We can summarize Eqs. (5.17), (5.18) and (5.19) in the Clifford algebra of theγ- matrices,
γµ, γν =2g µν , (5.20) { } whereg 00 = 1,g ii = 1 and all the other elem ents vanish. − Important facts : The eigenvalues ofγ 0 can only be 1 and those ofγ i i and the γ-matrices have vanishing trace : ± ±
Trγ i = Tr (γ0γ0γi) = Tr (γ 0γiγ0) = Trγ i Trγ i = 0, − − ⇒ 0 0 i i 1 i 0 i 1 0 0 Trγ = Tr (γ γ (γ )− ) = Tr (γ γ (γ )− ) = Tr (γ ) Trγ = 0. − − ⇒ The eigenvalue property ofγ 0 implies with the last equation that the dimensionn of the γ-matrices must be even. Forn = 2 there are no matric es satisfying Eq. (5.20), as can be checked by direct compu- tation. Forn = 4 there are many p ossibilities. The most common choice in textbooks is the Dirac-Pauli representation :