Petrology, Zircon and Monazite Geochronology

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Petrology, Zircon and Monazite Geochronology Eburnian, Kibaran and Pan-African metamorphic events in the Ubendian belt of Tanzania: Petrology, zircon and monazite geochronology Dissertation zur Erlangung des Doktorgrades an der Mathematisch{Naturwissenschaftlichen Fakult¨at der Christian{Albrechts{Universit¨at zu Kiel vorgelegt von Nelson Boniface Kiel 2009 Eburnian, Kibaran and Pan-African metamorphic events in the Ubendian belt of Tanzania: Petrology, zircon and monazite geochronology Dissertation zur Erlangung des Doktorgrades an der Mathematisch{Naturwissenschaftlichen Fakult¨at der Christian{Albrechts{Universit¨at zu Kiel vorgelegt von Nelson Boniface Kiel 2009 Gedruckt mit Unterst¨utzungdes Deutschen Akademischen Austauschdienstes Referent: Prof. Dr. Volker Schenk Korreferentin: Prof. Dr. Astrid Holzheid Tag der m¨undlichen Pr¨ufung: 29. Januar 2009 Zum Druck genehmigt: Der Dekan Erkl¨arung Hiermit erkl¨areich, Nelson Boniface, dass die vorgelegte Abhandlung, abgesehen von der Beratung durch meinen akademischen Lehrer Professor Dr. Volker Schenk, nach Inhalt und Form meine Arbeit ist und ausschließlich unter Verwendung der angegebenen Hilfsmittel entstanden ist. Des Weiteren erkl¨areich, dass ich weder diese noch eine ¨ahnliche Arbeit an dieser oder einer anderen Hochschule im Rahmen eines Pr¨ufungsverfahrens vorgelegt oder ver¨offentlicht habe. Kiel, den ................................ ....................................... vi Acknowledgment I am greatly indebted to my academic advisor Prof. Dr. Volker Schenk who planned this project. His supervision, advices, guidances and constructive criticism are lifeblood of my achievement. Our relationship was not strictly academic, he always treated me as a good friend, I immensely value this! It was a great honor to get the financial support for the project from DAAD (Deutscher Akademischer Austausch Dienst) and the DFG (Deutsche Forschungsgemeinschaft). The permits to research in the Ubendian belt, issued by the Mpanda district commissioner (2004) and by the director for Tanzania geological survey, Dodoma (2006) are appreciated. Many thanks to Prof. Dr. Astrid Holzheid for her enthusiastic participations in seminars and for always giving positive recommendations and constructive comments. A lot of thanks to Prof. Abdul Mruma of the geological survey of Tanzania for the guidance in the field during a second field trip in 2006. It was much easier with him to locate useful outcrops. Special thanks go to my lovely wife Flora Stephano and to our wonderful kids, Kennedy and Elizabeth, for patience and prayers. The kids missed very much the paternal care as most of the time I was away. I highly appreciate the contributions of Dr. Peter Appel in dating monazite, discussing the results and the guides on how to use Electron Probe Microanalyser (EPMA). Thanks to Dr. Timm John for his guides in handling samples with acids in a clean geochemical laboratory. A lot of thanks to Dr. Peter Raase as he was available whenever I need help to read thin sections. Dr. S¨onke Brandt is appreciated for reading chapter four and giving constructive comments. My colleagues, Dr. Niels J¨ons,Dr. Denny Loose, Dr. Fran¸coisvan der Straaten and Dr. Christoph Beier who pursued doctoral degrees during my stay in Kiel were academically co-operative and not to mention the social activities we did together. By sharing with me whatever they knew facilitated my world of using many computer programs like LATEX and others. The contributions of the technical stuffs of the Petrology division were of significant importance. Mrs. Barbara Mader apart from being helpful in the EPMA laboratory always provided social help at any time of need. Mr. Andreas Fehler prepared all the thin sections I needed on time. Mrs. Astrid Weinkauf helped me a lot in preparing glass disks for XRF and ICP-MS. I wish to thank the ICP-MS laboratory team at the University of Kiel. Dr. Dieter Garbe- Sch¨onberg made useful comments whenever I approached him, Mrs. Petra Fiedler and viii Mrs. Ulrike Westernstr¨oerwere always available to help me to use the ICP-MS laboratories in a proper way. Many thanks to a team of technical staffs of the SHRIMP laboratory in St. Petersburg, Russia. Just to name few of them; A. Larionov, I. Paderin, S. Presniakov and N. Rodionov were very kind and co-operative. Other members in our institute of geosciences provided me with academic or social support in one way or another. Dr. Ralf Halama, Dr. Petra Herms, Dr. Wolf-Achim Kahl, Dr. Philip Kegler, Mrs. Maike Zakrotzky and Ms. Katja Beier. Last but not least thanks to Mr. Nambunga, now a retired driver from the University of Dar es Salaam, for driving our car during a field trip in the Ubendian belt in 2004. Contents Declaration v Acknowledgment vi Einf¨uhrungund Zusammenfassung xvii Introduction and outline of the thesis xix 1 Paleoproterozoic and Neoproterozoic sutures in the Ubendian belt 1 Abstract . 1 1.1 Introduction . 2 1.2 Geological settings . 2 1.3 Analytical techniques . 4 1.4 Metamorphic events . 4 1.4.1 Ubende terrane . 4 1.4.2 Ufipa terrane . 5 1.4.3 Wakole and Katuma terranes . 6 1.4.4 Mbozi terrane . 6 1.5 Discussion and conclusions . 9 1.6 Acknowledgment . 10 References . 10 2 Paleoproterozoic eclogites of the Ubendian belt 13 Abstract . 13 2.1 Introduction . 13 2.2 Geological settings . 15 2.3 Analytical techniques . 17 2.4 Petrology, geochemistry and geochronology of eclogites . 19 2.4.1 Petrography and mineral chemistry . 19 2.4.2 P-T conditions . 22 2.4.3 Geochemistry . 25 2.4.4 U-Pb SHRIMP zircon ages . 29 2.5 Geochronology of metapelites and mafic granulites . 32 2.5.1 Sample localities . 33 x Contents 2.5.2 U-Pb SHRIMP zircon ages . 34 2.5.3 Th-U-total Pb CHIME monazite ages . 37 2.6 Conclusions . 45 2.6.1 Paleoproterozoic subduction of oceanic crust . 45 2.6.2 Relationships between subduction and regional metamorphism . 45 2.6.3 Kibaran and Pan-African orogenic impacts in the Ubendian belt . 46 2.7 Acknowledgment . 46 References . 46 3 Kibaran age metamorphism in NW Ubendian belt of Tanzania 53 Abstract . 53 3.1 Introduction . 53 3.2 Geological settings . 54 3.3 Analytical techniques . 56 3.4 Petrography and mineral chemistry . 57 3.4.1 Wakole terrane . 57 3.4.2 Ubende terrane . 58 3.5 Mineral reactions . 59 3.6 Geothermobarometry . 62 3.7 U-Pb SHRIMP zircon dating . 64 3.7.1 Zircon textures and U-Th contents . 64 3.7.2 Zircon ages . 64 3.8 Th-U-total Pb monazite dating . 66 3.8.1 Monazite composition and textures . 66 3.8.2 Monazite isochron ages . 68 3.9 Discussion and conclusions . 71 3.10 Acknowledgment . 72 References . 72 4 Neoproterozoic eclogites in the Ubendian belt 77 Abstract . 77 4.1 Introduction . 78 4.2 Analytical techniques . 79 4.3 Geological setting . 79 4.4 Petrography and mineral chemistry . 83 4.4.1 Kyanite-free eclogites . 83 4.4.2 Kyanite-bearing eclogites . 83 4.5 Mineral reaction history . 86 4.5.1 Kyanite-free eclogites . 86 4.5.2 Kyanite-bearing eclogites . 86 4.6 Geothermobarometry . 93 4.7 Geochemistry of kyanite-free eclogites . 96 4.8 Geochronology . 100 Contents xi 4.8.1 Textures and U-Th-Pb compositions of zircons . 100 4.8.2 Results of the U-Pb dating . 101 4.9 Discussion . 103 4.9.1 Geochronological and geochemical results . 103 4.9.2 Neoproterozoic eclogite formation in the Ubendian belt and geody- namic consequences . 103 4.10 Conclusions . 105 4.11 Acknowledgment . 106 References . 106 Curriculum vitae 111 xii Contents List of Figures 1.1 Locations of Kibaran orogenic system in southern Africa . 3 1.2 REE patterns of the Eclogites . 5 1.3 Monazite BSE images for the Ubendian belt metapelites . 7 1.4 Simplified geological map of central Gondwana with Pan-African sutures and eclogites . 10 2.1 The 2.1-1.8 Ga collisional orogens of the World . 14 2.2 Location of the Ubendian belt . 15 2.3 Textures of mylonitic eclogites of the Ubende terrane . 19 2.4 Grt and Cpx composition of the Ubende terrane eclogites. 20 2.5 BSE image of rutile and calculated temperatures . 22 2.6 P-T conditions in mylonitic eclogites . 24 2.7 Classification of mylonitic eclogites on magma discrimination diagrams . 25 2.8 REE and trace element patterns of the Ubende terrane eclogites . 26 2.9 Plot of Nb=La vs (La=Sm)N for Ubende terrane eclogites . 26 2.10 Zircon textures, Ubende terrane eclogites . 29 2.11 Concordia diagrams with U-Pb zircon ages of eclogites . 30 2.12 Map of the Ubendian belt showing ages distribution . 32 2.13 Textures of zircon of metapelites and mafic granulites . 35 2.14 Concordia diagrams with U-Pb zircon ages of metapelites and mafic granulite 36 2.15 Textures in monazite showing ages in cores and rims . 38 2.16 Monazite composition, Ufipa terrane . 39 2.17 Monazite isochron ages . 40 2.18 Textures in monazite showing ages in cores and rims . 41 2.19 Monazite composition sample T21-1-04 . 42 2.20 Monazite isochron ages, Mbozi terrane . ..
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