DOCSLIB.ORG

Specially Denatured Alcohol

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Specially Denatured Alcohol Bureau of Alcohol, Tobacco and Firearms, Treasury Pt. 21 and which forms a durable medium for 21.39 Formula No. 6–B. reproducing and preserving the original 21.40 Formula No. 12–A. record. 21.41 Formula No. 13–A. (b) Copies of records treated as original 21.42 Formula No. 17. 21.43 Formula No. 18. records. Whenever records are repro- 21.44 Formula No. 19. duced under this section, the repro- 21.45 Formula No. 20. duced records will be preserved in con- 21.46 Formula No. 22. veniently accessible files, and provi- 21.47 Formula No. 23–A. sions will be made for examining, view- 21.48 Formula No. 23–F. ing, and using the reproduced records 21.49 Formula No. 23–H. the same as if they were the original 21.50 Formula No. 25. 21.51 Formula No. 25–A. record, and they will be treated and 21.52 Formula No. 27. considered for all purposes as though 21.53 Formula No. 27–A. they were the original record. All pro- 21.54 Formula No. 27–B. visions of law and regulations applica- 21.55 Formula No. 28–A. ble to the original are applicable to the 21.56 Formula No. 29. reproduced record. As used in this sec- 21.57 Formula No. 30. tion, ‘‘original record’’ means the 21.58 Formula No. 31–A. 21.59 Formula No. 32. record required by this part to be 21.60 Formula No. 33. maintained or preserved by the per- 21.61 Formula No. 35. mittee, even though it may be an exe- 21.62 Formula No. 35–A. cuted duplicate or other copy of the 21.63 Formula No. 36. document. 21.64 Formula No. 37. 21.65 Formula No. 38–B. (Sec. 201, Pub. L. 85–859, 72 Stat. 1395, as 21.66 Formula No. 38–C. amended (26 U.S.C. 5555)) 21.67 Formula No. 38–D. 21.68 Formula No. 38–F. PART 21—FORMULAS FOR 21.69 Formula No. 39. 21.70 Formula No. 39–A. DENATURED ALCOHOL AND RUM 21.71 Formula No. 39–B. 21.72 Formula No. 39–C. Subpart A—General Provisions 21.73 Formula No. 39–D. 21.74 Formula No. 40. Sec. 21.75 Formula No. 40–A. 21.1 Scope of regulations. 21.76 Formula No. 40–B. 21.2 Forms prescribed. 21.77 Formula No. 40–C. 21.3 Stocks of discontinued formulas. 21.78 Formula No. 42. 21.4 Related regulations. 21.79 Formula No. 44. 21.5 Denatured spirits for export. 21.80 Formula No. 45. 21.6 Incorporations by reference. 21.81 Formula No. 46. 21.7 Delegations of the Director. Subpart B—Definitions Subpart E—Specifications for Denaturants 21.11 Meaning of terms. 21.91 General. 21.92 Denaturants listed as U.S.P. or N.F. Subpart C—Completely Denatured 21.93 Acetaldehyde. 21.94 Acetaldol. Alcohol Formulas 21.95 Alpha terpineol. 21.21 General. 21.96 Ammonia, aqueous. 21.22 Formula No. 18. 21.97 Benzene. 21.23 Formula No. 19. 21.98 Bone oil (Dipple’s oil). 21.24 Formula No. 20. 21.99 Brucine alkaloid. 21.100 n-Butyl alcohol. Subpart D—Specially Denatured Spirits 21.101 tert-Butyl alcohol. Formulas and Authorized Uses 21.102 Caustic soda, liquid. 21.103 Chloroform. 21.31 General. 21.104 Cinchonidine. 21.32 Formula No. 1. 21.105 Citronella oil, natural. 21.33 Formula No. 2–B. 21.106 Diethyl phthalate. 21.34 Formula No. 2–C. 21.107 Ethyl acetate. 21.35 Formula No. 3–A. 21.108 Ethyl ether. 21.36 Formula No. 3–B. 21.109 Gasoline. 21.37 Formula No. 3–C. 21.110 Gasoline, unleaded. 21.38 Formula No. 4. 21.111 Gentian violet. 467 VerDate Apr<18>2002 11:33 May 15, 2002 Jkt 197099 PO 00000 Frm 00467 Fmt 8010 Sfmt 8010 Y:\SGML\197099T.XXX pfrm15 PsN: 197099T § 21.1 27 CFR Ch. I (4–1–02 Edition) 21.112 Heptane. mation called for in each form shall be 21.113 Isopropyl alcohol. furnished as indicated by the headings 21.114 Kerosene. on the form and the instructions on or 21.115 Kerosene (deodorized). 21.116 Methyl alcohol. pertaining to the form. In addition, in- 21.117 Methyl isobutyl ketone. formation called for in each form shall 21.118 Methyl n-butyl ketone. be furnished as required by this part. 21.119 Nicotine solution. The form will be filed in accordance 21.120 Nitropropane, mixed isomers of. with the instructions for the form. 21.121 Phenyl mercuric benzoate. 21.122 Pyridine bases. (b) Forms may be requested from the 21.123 Pyronate. ATF Distribution Center, P.O. Box 21.124 Quassin. 5950, Springfield, Virginia 22150–5950, or 21.125 Rubber hydrocarbon solvent. by accessing the ATF web site (http:// 21.126 Safrole. www.atf.treas.gov/). 21.127 Shellac (refined). 21.128 Sodium (metallic). [T.D. ATF–133, 48 FR 24673, June 2, 1983, as 21.129 Spearmint oil, terpeneless. amended by T.D. ATF–249, 52 FR 5961, Feb. 21.130 Spike lavender oil, natural. 27, 1987; T.D. 372, 61 FR 20724, May 8, 1996; 21.131 Sucrose octaacetate. T.D. ATF–435, 66 FR 5475, Jan. 19, 2001] 21.132 Toluene. 21.133 Vinegar. § 21.3 Stocks of discontinued formulas. Subpart F—Uses of Specially Denatured Denaturers, or specially denatured Alcohol and Specially Denatured Rum spirits dealers or users, having on hand stocks of denaturants or formulas of 21.141 List of products and processes using specially denatured spirits no longer specially denatured alcohol and rum, and formulas authorized therefor. authorized by this part may— (a) Continue to supply or use those Subpart G—Denaturants Authorized for stocks in accordance with existing per- Denatured Spirits mits until the stocks are exhausted; 21.151 List of denaturants authorized for de- (b) Use up those stocks in any manu- natured spirits. facturing process approved by the ap- propriate ATF officer, pursuant to an Subpart H—Weights and Specific Gravities application filed with him on ATF of Specially Denatured Alcohol Form 5150.19, Formula for Articles made with Specially Denatured Alco- 21.161 Weights and specific gravities of spe- cially denatured alcohol. hol and Rum; (c) On approval of an application, AUTHORITY: 5 U.S.C. 552(a); 26 U.S.C. 5242, filed with the appropriate ATF officer 7805. and approved by such officer, destroy SOURCE: T.D. ATF–133, 48 FR 24673, June 2, those stocks under whatever super- 1983, unless otherwise noted. vision the appropriate ATF officer re- EDITORIAL NOTE: Nomenclature changes to quires; or part 21 appear by T.D. ATF–435, 66 FR 5475, (d) Otherwise dispose of those stocks Jan. 19, 2001. in a manner satisfactory to the appro- priate ATF officer, pursuant to ap- Subpart A—General Provisions proval of an application. § 21.1 Scope of regulations. [T.D. ATF–133, 487 FR 24673, June 2, 1983, as The regulations in this part relate to amended by T.D. ATF–435, 66 FR 5475, Jan. the formulation of completely dena- 19, 2001] tured alcohol, specially denatured alco- § 21.4 Related regulations. hol, and specially denatured rum; to the specifications for denaturants; and The procedural and substantive re- to the uses of denatured spirits. quirements relative to the production of denatured alcohol and specially de- § 21.2 Forms prescribed. natured rum are prescribed in Part 19 (a) General. The appropriate ATF offi- of this chapter, and those relative to cer is authorized to prescribe all forms the distribution and use of denatured required by this part. All of the infor- alcohol and specially denatured rum 468 VerDate Apr<18>2002 11:33 May 15, 2002 Jkt 197099 PO 00000 Frm 00468 Fmt 8010 Sfmt 8010 Y:\SGML\197099T.XXX pfrm15 PsN: 197099T Bureau of Alcohol, Tobacco and Firearms, Treasury § 21.11 are prescribed in Part 20 of this chap- Society for Testing and Materials, 1916 ter. Race Street, Philadelphia, Pennsyl- vania 19103. [T.D. ATF–133, 48 FR 24673, June 2, 1983, as amended by T.D. ATF–199, 50 FR 9183 Mar. 6, (c) Material from the ‘‘Official Meth- 1985] ods of Analysis of the Association of Official Analytical Chemists (13th Edi- § 21.5 Denatured spirits for export. tion 1980)’’ (AOAC) is incorporated by Spirits may be denatured in accord- reference in this part. This incorpora- ance with formulas prescribed by the tion by reference was approved by the government of a foreign country to Director of the Federal Register. This which the denatured spirits will be ex- publication may be inspected at the Of- ported. However, the denaturer must fice of the Federal Register, 800 North first apply for and obtain written per- Capitol Street, NW., suite 700, Wash- mission from the appropriate ATF offi- ington, DC, and is available from the cer. The application shall be submitted Association of Official Analytical to the appropriate ATF officer and Chemists, 11 North 19th Street, Suite shall contain the following informa- 210, Arlington, Virginia 22209. tion: (a) A complete list of ingredients for (Pub. L. 89–554, 80 Stat. 383 as amended (5 U.S.C. 552(a))) the spirits to be denatured. (b) The exact amount of each ingre- § 21.7 Delegations of the Director. dient to be used in denaturing the spir- its. All of the regulatory authorities of (c) A copy (accompanied by an the Director contained Part 21 of the English translation as necessary) of regulations are delegated to appro- the law or regulations of the foreign priate ATF officers.
Load more

Recommended publications
  • 2354 Metabolism and Ecology of Purine Alkaloids Ana Luisa Anaya 1
    [Frontiers in Bioscience 11, 2354-2370, September 1, 2006] Metabolism and Ecology of Purine Alkaloids Ana Luisa Anaya 1, Rocio Cruz-Ortega 1 and George R. Waller 2 1Departamento de Ecologia Funcional, Instituto de Ecologia, Universidad Nacional Autonoma de Mexico. Mexico DF 04510, 2Department of Biochemistry and Molecular Biology, Oklahoma State University. Stillwater, OK 74078, USA TABLE OF CONTENTS 1. Abstract 2. Introduction 3. Classification of alkaloids 4. The importance of purine in natural compounds 5. Purine alkaloids 5.1. Distribution of purine alkaloids in plants 5.2. Metabolism of purine alkaloids 6. Biosynthesis of caffeine 6.1. Purine ring methylation 6.2. Cultured cells 7. Catabolism of caffeine 8. Caffeine-free and low caffeine varieties of coffee 8.1. Patents 9. Ecological role of alkaloids 9.1. Herbivory 9.2. Allelopathy 9.2.1. Mechanism of action of caffeine and other purine alkaloids in plants 10. Perspective 11. Acknowledgements 12. References 1. ABSTRACT 2. INTRODUCTION In this review, the biosynthesis, catabolism, Alkaloids are one of the most diverse groups of ecological significance, and modes of action of purine secondary metabolites found in living organisms. They alkaloids particularly, caffeine, theobromine and have many distinct types of structure, metabolic pathways, theophylline in plants are discussed. In the biosynthesis of and ecological and pharmacological activities. Many caffeine, progress has been made in enzymology, the amino alkaloids have been used in medicine for centuries, and acid sequence of the enzymes, and in the genes encoding some are still important drugs. Alkaloids have, therefore, N-methyltransferases. In addition, caffeine-deficient plants been prominent in many scientific fields for years, and have been produced.
    [Show full text]
  • Retention Indices for Frequently Reported Compounds of Plant Essential Oils
    Retention Indices for Frequently Reported Compounds of Plant Essential Oils V. I. Babushok,a) P. J. Linstrom, and I. G. Zenkevichb) National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA (Received 1 August 2011; accepted 27 September 2011; published online 29 November 2011) Gas chromatographic retention indices were evaluated for 505 frequently reported plant essential oil components using a large retention index database. Retention data are presented for three types of commonly used stationary phases: dimethyl silicone (nonpolar), dimethyl sili- cone with 5% phenyl groups (slightly polar), and polyethylene glycol (polar) stationary phases. The evaluations are based on the treatment of multiple measurements with the number of data records ranging from about 5 to 800 per compound. Data analysis was limited to temperature programmed conditions. The data reported include the average and median values of retention index with standard deviations and confidence intervals. VC 2011 by the U.S. Secretary of Commerce on behalf of the United States. All rights reserved. [doi:10.1063/1.3653552] Key words: essential oils; gas chromatography; Kova´ts indices; linear indices; retention indices; identification; flavor; olfaction. CONTENTS 1. Introduction The practical applications of plant essential oils are very 1. Introduction................................ 1 diverse. They are used for the production of food, drugs, per- fumes, aromatherapy, and many other applications.1–4 The 2. Retention Indices ........................... 2 need for identification of essential oil components ranges 3. Retention Data Presentation and Discussion . 2 from product quality control to basic research. The identifi- 4. Summary.................................. 45 cation of unknown compounds remains a complex problem, in spite of great progress made in analytical techniques over 5.
    [Show full text]
  • Borneol - Camphor - Isoborneol
    EXP. 35 A & B OXIDATION-REDUCTION SCHEME: BORNEOL - CAMPHOR - ISOBORNEOL LEARNING OBJECTIVES: To illustrate the concepts of oxidation and reduction in organic chemistry, to illustrate the stereochemical effects of these reactions in certain systems, to use IR spectroscopy to characterize diastereomers and monitor reactions. QUIZ PREPARATION: Recitation notes and readings assigned in the syllabus. OXIDATION AND REDUCTION IN ORGANIC CHEMISTRY The concepts of oxidation and reduction in chemistry are fundamentally related to the loss and gain of electrons, respectively. For a specific atom, oxidation brings about an increase in the oxidation number, whereas reduction does the opposite. This is of course true in organic reactions as well, but it is frequently less clear where the gain or loss of electrons is taking place. For this reason, the concepts of oxidation and reduction are addressed from a different perspective in organic chemistry. Since carbon is the most important element in organic chemistry, we can define oxidation as a process whereby carbon gains bonds to more electronegative atoms. These can be any atoms more electronegative than carbon, such as chlorine or sulphur, but the most commonly seen in organic oxidations is oxygen. The more bonds to oxygen, the higher the oxidation state of the carbon involved. Examples of oxidation reactions are those that convert alkanes into alcohols, or alcohols into carbonyl compounds. The functional groups that contain the most highly oxidized form of carbon in organic compounds are the carboxylic acids and their derivatives. Reduction is the opposite of oxidation. We can define reduction as a process whereby carbon adds bonds to less electronegative atoms.
    [Show full text]
  • A New Source of Natural D-Borneol and Its Characteristic
    Journal of Medicinal Plants Research Vol. 5(15), pp. 3440-3447, 4 August, 2011 Available online at http://www.academicjournals.org/JMPR ISSN 1996-0875 ©2011 Academic Journals Full Length Research Paper A new source of natural D-borneol and its characteristic Lei Chen 1, Jianyu Su 1*, Lin Li 1, Bing Li 1 and Wang Li 2 1Department of Food Science and Technology, South China University of Technology, 510642 Guangzhou, Peoples Republic of China. 2Food Safety Key Laboratory of Guangdong Province, College of Food Science, South China Agricultural University, 510642 Guangzhou, Peoples Republic of China. Accepted 28 February, 2011 The essential oils from leaves of Mei Pian tree (a Cinnamomun burmannii physiological type), were obtained by hydro-distillation and analyzed by gas chromatography and mass spectrometry (GC/MS). Forty compounds representing 99.61% of the total oil containing D-borneol (78.6%) as the major component were obtained. D-borneol was purified by sublimation, and the characteristic of the refined D-borneol was compared with standard D-borneol and synthetic borneol by infrared spectra analysis and optical activity analysis. The chemical composition and the optical rotation of refined D-borneol from leaves of Mei Pian tree were extremely similar to the standard D-borneol and materially surpass synthetic borneol. Antioxidant activities of the refined D-borneol and standard D-borneol were determined by testing their DPPH and hydroxyl radicals scavenging activities and the reducing power. The refined D-borneol and standard D-borneol had the same antioxidant activity. They exhibited higher hydroxyl radicals scavenging activity, but weaker reducing power, compared with the synthetic borneol.
    [Show full text]
  • Natural Borneol Recycling from Cinnamomum Camphor Chvar
    Chen et al Tropical Journal of Pharmaceutical Research September 2014; 13 (9): 1463-1470 ISSN: 1596-5996 (print); 1596-9827 (electronic) © Pharmacotherapy Group, Faculty of Pharmacy, University of Benin, Benin City, 300001 Nigeria. All rights reserved . Available online at http://www.tjpr.org http://dx.doi.org/10.4314/tjpr.v13i9.12 Original Research Article Natural Borneol Recycling from Cinnamomum camphor chvar. Borneol Oil Residue by Fractional Distillation and Recrystallization Xiao Ying Chen 1, Xiao Ning Zhao 2, Hui Fang Zeng 2, Jian Hui Xie 1,3 , Xiao Lu Chen 2, Yong Zhuo Liang 1, Qi Duan Wu 2, Zi Ren Su 1,5 , Hong Feng Wang 4* and Xiao Ping Lai 1,5 * 1School of Chinese Materia Medica, Guangzhou University of Chinese Medicine, Guangzhou 510006, 2The First Affiliated Hospital of Chinese Medicine, Guangzhou University of Chinese Medicine, Guangzhou 510405, 3The Second Affiliated Hospital of Chinese Medicine, Guangzhou University of Chinese Medicine, Guangzhou 510405, 4Biotechnology Division, Guangdong Academy of Forestry, Guangzhou, 5Dongguan Mathematical Engineering Academy of Chinese Medicine, Guangzhou University of Chinese Medicine, Dongguan, 523808, China *For correspondence: Email: [email protected], [email protected]; Tel: +86-20-39358517; Fax: +86-20-39358390 Received: 10 May 2014 Revised accepted: 7 August 2014 Abstract Purpose: To establish an efficient method to recycle natural borneol from Cinnamomum camphor chvar. Borneol oil residue. Methods: The fractions and raffinate of the oil residue of Cinnamomum camphor chvar. Borneol were obtained by fractional distillation, and analyzed by gas chromatography with flame ionization detector (GC-FID) and gas chromatography- mass spectrometry (GC-MS). Natural borneol was purified by recrystallization and suction filtration.
    [Show full text]
  • Parks Denatured Alcohol
    Material Safety Data Sheet Section 1 General Information Manufacturer: Zinsser Company, Inc. 173 Belmont Drive Somerset, NJ 08875 (732) 469-8100 Emergency Telephone: Chemtrec (800) 424-9300 Date: December 1, 2006 Product Name: Parks Denatured Alcohol Codes: 002121 002122 002123 002125 Section 2 Hazardous Ingredients OSHA ACGIH Hazardous Component CAS# PEL TLV Ethanol 64-17-5 1000 ppm 1000 ppm Methanol 67-56-1 200 ppm 200 ppm 250 ppm STEL Methyl Isobutyl Ketone 108-10-1 100 ppm 50 ppm 75 ppm STEL Ethyl Acetate 141-78-6 400 ppm 400 ppm Rubber Solvent 64742-89-8 500 ppm 400 ppm Section 3 Hazard Identification Emergency Overview: This product is a clear liquid with a characteristic smell and flash point of 41oF. Primary Routes of Exposure: Skin Contact Eye Contact Inhalation Potential Acute Health Effects: Eye: Contact may cause eye irritation. N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated Parks Denatured Alcohol (12-01-06) Page 1 of 6 pages. Skin: May cause skin irritation. Repeated or prolonged contact with skin may cause dermatitis. Ingestion: May be fatal or cause blindness if swallowed. Inhalation: May cause respiratory tract irritation. Potential Chronic Health Effects: Signs and Symptoms: Prolonged exposure to excessive concentrations of ethanol may result in irritation of mucous membranes, headache, drowsiness, fatigue and narcosis. Methanol is also narcotic in effect and its effects are cumulative. Overexposure to methanol can result in acidosis and visual disturbances which may progress to permanent loss of vision. (See also Sections 4, 8, and 11for related information) Section 4 First Aid Measures Eye contact: Immediately flush eyes with water for at least 15 minutes.
    [Show full text]
  • Non-Beverage Alcohol Consumption & Harm Reduction Trends
    Non-beverage Alcohol Consumption & Harm Reduction Trends A Report for the Thunder Bay Drug Strategy Prepared by Kim Ongaro HBSW Placement Lakehead University June 15, 2017 Non-beverage Alcohol Consumption & Harm Reduction Trends What is non-beverage alcohol? Non-beverage alcohol can go by many names in the literature. Broadly, it is understood to be liquids containing a form of alcohol that is not intended for human consumption (e.g., mouthwash, hand sanitizer, etc.) that are consumed instead of beverage alcohol for the purposes of intoxication or a “high” (Crabtree, Latham, Bird, & Buxton, 2016; Egbert, Reed, Powell, Liskow, & Liese, 1985). Within the literature, there are different definitions for non- beverage alcohols, including surrogate alcohol, illicit alcohol and unrecorded alcohol. Unrecorded alcohol, as defined by the World Health Organization, is untaxed alcohol outside of government regulation including legal or illegal homemade alcohol, alcohol that is smuggled from an outside country (and therefore is not tracked by its sale within the country of consumption), and alcohol of the “surrogate” nature (World Health Organization Indicator and Measurement Registry, 2011). Surrogate alcohol is alcohol that is not meant for human consumption, and is generally apparent as high concentrations of ethanol in mouthwash, hand sanitizers, and other household products (Lachenmeier, Rehm, & Gmel, 2007; World Health Organization Indicator and Measurement Registry, 2011). Surrogate alcohols also include substances containing methanol, isopropyl alcohol, and ethylene glycol (Lachenmeier et al., 2007). Nonbeverage alcohol and surrogate alcohol can be used interchangeably, but Lachenmeier et al., (2007), goes even further to include alcohol that is homemade in their definition of surrogate alcohol, as they stated that this alcohol is sometimes created using some form of non-beverage alcohol.
    [Show full text]
  • Kinetics and Mechanism of Oxidation of Borneol (Cyclic Secondary Alcohol) by Trichloroisocyanuric Acid in Acidic Medium
    Jr. of Industrial Pollution Control 25 (1) (2009) pp 1-8 © Enviromedia Printed in India. All rights reserved KINETICS AND MECHANISM OF OXIDATION OF BORNEOL (CYCLIC SECONDARY ALCOHOL) BY TRICHLOROISOCYANURIC ACID IN ACIDIC MEDIUM NAVNEET SHARMA* AND MAMTA GOEL** * Department of Chemistry, H.R. Institute of Technology, Ghaziabad, U.P., India **Department of Chemistry, SGIT, Ghaziabad, U.P., India Key words : Kinetics, Oxidation, Borneol, Trichloroisocyanuric acid, Perchloric acid. ABSTRACT The kinetics of Oxidation of borneol (C10H18O) [endo-1, 7, 7-Trimethyl bicyclo (2, 2, 1) heptan-2-ol] by aqueous perchloric system, yields of ketone in the presence of Trichloroisocyanuric acid at 300C. The stoichiometry is (1:1) and the main oxidation product is Camphor which is studied by TLC using benzene as a solvent and by spraying with 2, 4-dinitrophenyl hydrazine reagent. The observed rate of oxidation shows a first order dependence on both borneol and TCICA (Oxidant). INTRODUCTION have been studied by various oxidants such as N- Bromo-acetamide8, N-Bromoseccharin9, N-Chloro R- Oxidation of organic compounds is one of the most 2, C-6 Diphenyl-t-3 Methyl piperedin-4-on (NCP)10, important reaction in organic synthesis. For this pur- Cerium (IV) Catalysed by chromium (III)11,Cromium pose, some new oxidizing reagents have been pre- (VI) in presence of oxalic acid12, by aqueous chlorine13 pared1-3. In the recent years, studies of oxidation of and oxidation of organic alcohol by pyrazinium various organic compounds in presence of perchlo- dichromate14. The Oxidation of Borneol has been stud- ric acid by halo-compounds4. Borneol is a white crys- ied by chlorine15 and copper (II)-ß-cyclodextrin in py- talline bicyclic terpene alcohol and a component of ridine acetic acid-hydrogen peroxide system16, but many essential oils 5 and it is natural insect repel- there is no references in the literature on the oxida- lent.6 Borneol is easily oxidized to ketone and occurs tion of borneol by TCICA.
    [Show full text]
  • Hazard Communication Chemical Inventory Form
    Hazard Communication Chemical Inventory Form ESTIM. CAS STATE QTY. USAGE ROOM SDS DATE OF CHEMICAL NAME COMMON NAME MANUFACTURER NUMBER S,L,G ON HAND PER YEAR CAMPUS NO. DEPARTMENT ? INV. Chromogenic Substrate (p-nitrophenyl phosphate liquid substrate) Sigma 4264-83-9 L 24mL 33mL STC D129B Science SDS 3/7/2018 1,3-Diphenylacetone 1,3-Diphenol-2-propanone ACROS 102-04-5 S 75mg 5g STC D126A Science SDS 3/5/2018 Butyl Alcohol, n- 1-butanol, n-butyl alcohol Flinn 71-36-3 L 400mL 50mL STC D126A Science SDS 3/5/2018 Hexyl Alcohol 1-hexanol Flinn 111-27-3 L 500ml 10mL STC D126A Science SDS 3/5/2018 Octanol, 1- 1-octanol, caprylic or n-octyl alcohol Flinn 111-87-5 L 470mL 25mL STC D126A Science SDS 3/5/2018 tert-Butyl Chloride 2-chloro-2-methylpropane Flinn 507-20-0 L 25mL 25mL STC D126A Science SDS 3/5/2018 Citric Acid, Anhydrous 2-hydroxy-1,2,3-propanetricarboxylic acid, anhydrous Flinn 77-92-9 S 500g 50g STC D126A Science SDS 3/5/2018 Citric Acid, Monohydrate 2-hydroxy-1,2,3-propanetricarboxylic acid, monohydrate Flinn 5959-29-1 S 2g 50g STC D126A Science SDS 3/5/2018 tert-Pentyl Alcohol 2-Methyl-2-butanol; tert-Amyl alcohol Flinn 75-85-4 L 400mL 25mL STC D126A Science SDS 3/5/2018 3-in-1 lock dry lube WD-40 company N/A L 2 4 STC E104A Facilities Y 3/1/2018 3-in1 Multipurpose Oil WD-40 company N/A L 1 2 STC E104A Facilities Y 3/1/2018 3M Dust Remover 3M Stationary Products 75-37-6 1 STC B147 Student Affairs Y 1/29/2018 3M Hi Power Brake Cleaner 3M N/A L 2 4 STC E104A Facilities Y 3/1/2018 3M HI-Strength Spray Adhesive 90 (aerosol)3M N/A L
    [Show full text]
  • Safety Data Sheet Denatured Alcohol
    Safety Data Sheet Denatured Alcohol SECTION I - IDENTIFICATION PRODUCT NAME: Denatured Alcohol PRODUCT CODE: 6210 PRODUCT USE: Industrial Cleaner COMPANY NAME: QuestVapco Corporation COMPANY ADDRESS: PO Box 624 Brenham, TX 77834 COMPANY PHONE: 1-800-231-0454 EMERGENCY PHONE: 800-255-3924 SECTION II – HAZARDS IDENTIFICATION CLASSIFICATION: Flammable Liquid: Category 2 Skin Irritant: Category 2 Eye Irritant: Category 2A HAZARD STATEMENT(S): Danger: Highly flammable liquid and vapor Causes skin and serious eye irritation. This product contains the following percentage of chemicals of unknown toxicity: 0% PRECAUTIONARY STATEMENTS: Keep away from heat, sparks, open flames, and hot surfaces. -No smoking. Keep container tightly closed. Wear protective gloves and eye protection. If on skin (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water or shower. If skin irritation occurs: Get medical advice or attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. In case of fire use dry chemical, foam, or carbon dioxide. Store in a well- ventilated place. Keep cool. Dispose of contents and container in accordance with local, state, and national regulations. Wash hands thoroughly after handling. For large quantities: Ground or bond container and receiving equipment. Use explosion-proof electrical, ventilating, and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. SYMBOL: HAZARDS NOT OTHERWISE CLASSIFIED: N/A SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER PERCENT Ethyl Alcohol 64-17-5 60%-100% Isopropyl Alcohol 67-63-0 3-7% SECTION IV - FIRST AID MEASURES EYES: If in eyes: Rinse cautiously with water for several minutes.
    [Show full text]
  • Surrogate Alcohol: What Do We Know and Where Do We Go?
    Alcoholism: Clinical and Experimental Research Vol. 31, No. 10 October 2007 Surrogate Alcohol: What Do We Know and Where Do We Go? Dirk W. Lachenmeier, Ju¨rgen Rehm, and Gerhard Gmel Background: Consumption of surrogate alcohols (i.e., nonbeverage alcohols and illegally pro- duced alcohols) was shown to impact on different causes of death, not only poisoning or liver dis- ease, and appears to be a major public health problem in Russia and elsewhere. Methods: A computer-assisted literature review on chemical composition and health conse- quences of ‘‘surrogate alcohol’’ was conducted and more than 70 references were identified. A wider definition of the term ‘‘surrogate alcohol’’ was derived, including both nonbeverage alcohols and illegally produced alcohols that contain nonbeverage alcohols. Results: Surrogate alcohol may contain substances that cause severe health consequences including death. Known toxic constituents include lead, which may lead to chronic toxicity, and methanol, which leads to acute poisoning. On the other hand, the role of higher alcohols (e.g., propanol, isobutanol, and isoamyl alcohol) in the etiology of surrogate-associated diseases is cur- rently unclear. Whether other constituents of surrogates have contributed to the high all-cause mortality over and above the effect of ethanol in recent studies also remains unclear. Conclusions: Given the high public health importance associated with the consumption of sur- rogate alcohols, further knowledge on its chemical composition is required as well as research on its links to various disease endpoints should be undertaken with priority. Some interventions to reduce the harm resulting from surrogate alcohol could be undertaken already at this point.
    [Show full text]
  • Resolution of Racemic 5-Phenyl-2-Pentanol
    Patentamt JEuropaischesEuropean Patent Office 11) Publication number: 0 078 145 Office europeen des brevets A1 © EUROPEAN PATENT APPLICATION © Int. ci * C 07 B 19/00 C 07 C 33/20, C 07 D 491/22 C 07 C 69/80 //C07D215/22, C07D221/12, (C07D491/22, 313/00, 221/00, 221/00, 209/00, 209/00) @ Priority: 22.10.81 US 313560 © Applicant: PFIZER INC. 235 East 42nd Street New York, N.Y.10017(US) © Date of publication of application: 04.05.83 Bulletin 83/18 © Inventor: Moore, Bernard Shields 39 Savi Avenue © Designated Contracting States: Waterford Connecticut(US) AT BE CH DE FR GB IT U LU NL SE © Representative: Graham, Philip Colin Christison et al, Pfizer Limited Ramsgate Road Sandwich, Kent CT13 9NJIGB) © Resolution of racemic 5-phenyl-2-pentanol. Racemic 5-phenyl-2-pentanol is resolved via its hemiph- thalate ester, followed by diastereomer salt formation with (+)-brucine, separation of the brucine salt of (S)-5-phenyl-2- pentylhemi-phthalate and recovery of the (S)-alcohol there- from. The (S)-5-phenyl-2-pentanol is a valuable intermediate for organic synthesis. The separated (+)-brucine salt of (S)-5-phenyl-2-pentylhemiphthalate is a novel and useful intermediate. This invention relates to a process for resolution of racemic 5-phenyl-2-pentanol to (S)-5-phenyl-2- pentanol, a valuable intermediate in the synthesis of analgesic agents. More specifically, the process comprises esterifying racemic 5-phenyl-2-pentanol to form the hemiphthalate ester, followed by treating said ester with (+)-brucine, separating (S)-5-phenyl- 2-pentylhemiphthalate(+)-brucine salt, decomposing said salt to regenerate (S)-5-phenyl-2-pentylhemiphthalate, and hydrolyzing said ester to (S)-5-phenyl-2-pentanol.
    [Show full text]