Basic Chemicals Production 2030
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Safe Hydroformylation of Aliphatic Alkene in a Flow Reactor
International Journal of Organic Chemistry, 2018, 8, 135-141 http://www.scirp.org/journal/ijoc ISSN Online: 2161-4695 ISSN Print: 2161-4687 Safe Hydroformylation of Aliphatic Alkene in a Flow Reactor Hisashi Masui, Eiki Honda, Sakura Niitsu, Mitsuru Shoji, Takashi Takahashi* Department of Pharmaceutical Sciences, Yokohama University of Pharmacy, Yokohama, Japan How to cite this paper: Masui, H., Honda, Abstract E., Niitsu, S., Shoji, M. and Takahashi, T. (2018) Safe Hydroformylation of Aliphatic Despite hydroformylation being a very efficient method for the transforma- Alkene in a Flow Reactor. International tion of alkenes, it is not commonly employed in laboratories owing to the Journal of Organic Chemistry, 8, 135-141. flammable/toxic nature of hydrogen and carbon monoxide gases and the ne- https://doi.org/10.4236/ijoc.2018.81009 cessity of high-pressure equipment in a batch system. Flow chemistry often Received: November 30, 2017 raises the safety profiles against high-pressure and toxic gases because the Accepted: March 6, 2018 diameter of the flow reactor is small. Herein, we show that aliphatic alkenes Published: March 9, 2018 can be safely hydroformylated in a flow reactor. In our flow method, although Copyright © 2018 by authors and the target hydroformylated product was obtained in a low yield (19%), toxic Scientific Research Publishing Inc. gases were safely treated using a flow reactor. Better yields could possibly be This work is licensed under the Creative achieved by recycling of the unreacted alkene. Commons Attribution International License (CC BY 4.0). http://creativecommons.org/licenses/by/4.0/ Keywords Open Access Hydroformylation, Flow Synthesis, Alkene, Carbon Monoxide, Aldehyde 1. -
Catalytic Systems Based on Cp2zrx2 (X = Cl, H), Organoaluminum
catalysts Article Catalytic Systems Based on Cp2ZrX2 (X = Cl, H), Organoaluminum Compounds and Perfluorophenylboranes: Role of Zr,Zr- and Zr,Al-Hydride Intermediates in Alkene Dimerization and Oligomerization Lyudmila V. Parfenova 1,* , Pavel V. Kovyazin 1, Almira Kh. Bikmeeva 1 and Eldar R. Palatov 2 1 Institute of Petrochemistry and Catalysis of Russian Academy of Sciences, Prospekt Oktyabrya, 141, 450075 Ufa, Russia; [email protected] (P.V.K.); [email protected] (A.K.B.) 2 Bashkir State University, st. Zaki Validi, 32, 450076 Ufa, Russia; [email protected] * Correspondence: [email protected]; Tel.: +7-347-284-3527 i i Abstract: The activity and chemoselectivity of the Cp2ZrCl2-XAlBu 2 (X = H, Bu ) and [Cp2ZrH2]2- ClAlEt2 catalytic systems activated by (Ph3C)[B(C6F5)4] or B(C6F5)3 were studied in reactions with 1-hexene. The activation of the systems by B(C6F5)3 resulted in the selective formation of head- to-tail alkene dimers in up to 93% yields. NMR studies of the reactions of Zr complexes with organoaluminum compounds (OACs) and boron activators showed the formation of Zr,Zr- and Zr,Al-hydride intermediates, for which diffusion coefficients, hydrodynamic radii, and volumes were estimated using the diffusion ordered spectroscopy DOSY. Bis-zirconium hydride clusters of type x[Cp ZrH ·Cp ZrHCl·ClAlR ]·yRnAl(C F ) − were found to be the key intermediates of alkene 2 2 2 2 6 5 3 n dimerization, whereas cationic Zr,Al-hydrides led to the formation of oligomers. Citation: Parfenova, L.V.; Kovyazin, P.V.; Bikmeeva, A.K.; Palatov, E.R. -
Petrochemistry and Chemical Engineering November 18-20, 2013 Hilton San Antonio Airport, TX, USA
Gordadze G. N et al., J Pet Environ Biotechnol 2013, 4:6 http://dx.doi.org/10.4172/2157-7463.S1.002 World Congress on Petrochemistry and Chemical Engineering November 18-20, 2013 Hilton San Antonio Airport, TX, USA Formation of n-alkanes by bacteria Arthrobacter sp. RV and Pseudomonas aeruginosa RM Gordadze G. N and Stroeva A.R Gubkin Russian State University of Oil and Gas, Russia rocesses of petroleum hydrocarbons (HC) formation in literature have been discussing for 200 years. At present time there Pare two main theories of oil formation: organic (sedimentary-migration) and inorganic (abiotic). It is believed that n-alkanes formed from n-saturated fatty acids by decarboxylation. It is known that in the original organic matter (OM) fatty acids with an even number of carbon atoms in the molecule are prevail. In case sapropelic OM, low molecular weight acids (n-C16, n-C18 and n-C20) are mainly produced and if OM is humus higher molecular (n-C26, n-C28 and n-C30) are produced. It is important to note there are high molecular n-alkanes C23, C25, C27, C29, C31 and C33 in soil OM. Bacterial synthesis of n-alkanes could be accounted by decarboxylation with relatively high temperatures. However, this phenomenon doesn’t support by experiment. In this work we studied, if n-alkanes with an odd number of carbon atoms in the molecule formed by bacteria. The objects of study were the hydrocarbon aerobic bacteria Arthrobacter sp. RV and the bacteria Pseudomonas aeruginosa RM, that are able to both aerobic and anaerobic growth in the process of denitrification. -
Petrochemistry April 25-27, 2018 Rome, Italy
J-M. Basset et al., Int J Petrochem Res. 2018 http://dx.doi.org/10.18689/2638-1974.a2.002 2nd International Conference on Petrochemistry April 25-27, 2018 Rome, Italy Predictive Heterogeneous Catalysis by Design: Well-Defined Single-Site Catalysts J-M. Basset1*, M. K. Samantaray1, S. Barman1, S. Kavitake1, N. Morlanes1, L Cavallo1, A. Hamieh1, R. Dey1, Abou Hamad1, J. Pelletier1, S. Ould-Chikh1, A. Bendjeriou-Sedjerari1, Eva B. Pump1, N. Merle2, F. Le Quemener2, K. C. Szeto2, A. De Mallmann2, Laurent Delevoye3, R. Gauvin3 and Mostafa Taoufik3 1KAUST Catalysis Center, King Abdullah University of Science and Technology, Saudi Arabia 2Laboratoire de Chimie, Catalyse, Polymères et Procédés, France 3Univ. Lille, CNRS, Centrale Lille, ENSCL, Univ. Artois, Unité de Catalyse et Chimie du Solide, France redictive catalysis” or “catalysis by design” in heterogeneous catalysis has recently benefited from using “surface “Porganometallic fragments” (SOMF) or Surface Coordination fragments (SCF) to enter any presumed catalytic cycle. These conceptual tools in which one or several fragments of the molecule are linked to metal grafted on the surface (M-H, M-R, M=CR2, M≡CR, M=O, M=NR) became the logical continuation of the abundant work published in the field of Surface Organometallic Chemistry (SOMC). To note, SOMC has produced new catalytic reactions (e.g. Ziegler Natta depolymerisation, alkane metathesis, non-oxidative methane coupling etc…) and had improved the activity or selectivity or life time of known ones. The catalytic mechanisms employs the concepts of molecular chemistry (organic, organometallic, coordination chemistry) to explain how bonds can be broken and reformed. In this context, the reactivity of “surface organometallic fragments” (SOMF) or Surface Coordination fragments (SCF) is pivotal to the outcome of the catalysis. -
A DFT Study of Synthesis of Acetic Acid from Methane and Carbon Dioxide
_______________________________________________________________________________www.paper.edu.cn Chemical Physics Letters 368 (2003) 313–318 www.elsevier.com/locate/cplett A DFT study of synthesis of acetic acid from methane and carbon dioxide Jian-guo Wang a, Chang-jun Liu a,*, Yue-ping Zhang b, Baldur Eliasson c a State Key Laboratory of C1 Chemistry and Technology, ABB Plasma Greenhouse Gas Chemistry Laboratory and School of Chemical Engineering, Tianjin University, Tianjin 300072, PR China b Department of Chemistry, Tianjin University, Tianjin 300072, PR China c ABB Switzerland Ltd., CH5405, Baden, Switzerland Received 2 October 2002; in final form 20 November 2002 Abstract We have previously reported an experimental investigation on synthesis of acetic acid directly from CH4 and CO2 via dielectric-barrier discharge. In this work, a DFT study was conducted using three hybrid DFT methods in order to À understand the mechanism of such direct synthesis. It suggests that the synthesis is via two pathways with CO2 and CO À as key intermediates. The energy requirement with CO2 pathway is much less than that with CO. The methyl radical formation and the dissociation of CO2 are two limiting steps for the synthesis of acetic acid directly from CH4 and CO2. Ó 2002 Elsevier Science B.V. All rights reserved. 1. Introduction [1,2]. But methane utilization still remains as a big challenge to chemists all over the world. Methane is the principal component of natural One of the important target molecules of direct gas, coalbed methane, associated gas of oil fields methane conversion is acetic acid [5–9] and some by-product gases of chemical plants. -
C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen
C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen Annual report Research conducted October 1, 2003-September 30, 2004 U.S. Department of Energy Contract No. DE-FC26-02NT41594 Prepared by the Consortium for Fossil Fuel Science Gerald P. Huffman, Director University of Kentucky/CFFS 533 S. Limestone Street, Suite 107 Lexington, KY 40506-0043 Phone: (859) 257-4027 FAX: (859) 257-7215 E-mail: [email protected] Consortium for Fossil Fuel Science University of Kentucky West Virginia University University of Pittsburgh University of Utah Auburn University Consortium for Fossil Fuel Science 1 This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. 2 C1 Chemistry for the Production of Clean Liquid Transportation Fuels and Hydrogen U.S. DOE Contract No. DE-FC26-02NT41594 ABSTRACT: The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. -
Alkyne Selective Hydrogenation with Mono- and Bimetallic-Anchored Catalysts Bimetallic-Anchored Catalysts
Provisional chapter Chapter 2 Alkyne Selective Hydrogenation with Mono- and Alkyne Selective Hydrogenation with Mono- and Bimetallic-Anchored Catalysts Bimetallic-Anchored Catalysts Cecilia Lederhos, Carolina Betti, Domingo Liprandi, EdgardoCecilia Lederhos, Cagnola Carolina and Mónica Betti, Quiroga Domingo Liprandi, Edgardo Cagnola and Mónica Quiroga Additional information is available at the end of the chapter Additional information is available at the end of the chapter http://dx.doi.org/10.5772/64866 Abstract Partial hydrogenation of alkynes has industrial and academic relevance on a large scale; industries such as petrochemical, pharmacological and agrochemical use these compounds as raw material. Finding an economic, active and selective catalyst for the production of alkenes through partial hydrogenation of alkynes is thus an important challenge. Mono- and bimetallic catalysts (palladium, ruthenium and nickel) were synthetized by the incipient wetness technique using gamma alumina and an activated carbon as supports. The catalysts were characterized by inductively coupled plasma, hydrogen chemisorption, temperature-programmed reduction and X-ray photoelec- tronic spectroscopy (XPS). The objective of this work is to study 1-heptyne-selective hydrogenation using supported catalysts influenced by different factors: (a) pretreat- ment reduction temperature, (b) reaction temperature, (c) type of support, (d) metal loading, (e) precursor salt and (f) addition of a second metal to monometallic palladium catalyst. The Lindlar commercial catalyst, commonly used in these types of reactions, was used for comparative purposes. XPS technique allowed verifying that the presence of electron-deficient species on the catalyst surface with high metal loading affects the conversion and selectivity to the desired product. Nevertheless, the influence of geometrical effects and/or mixed active sites in the catalysts, as well as metal-metal and metal-support interactions, cannot be neglected. -
A Heat Exchanger Reactor Equipped with Membranes to Produce Dimethyl Ether from Syngas and Methyl Formate and Hydrogen from Methanol
64 International Journal of Membrane Science and Technology, 2016, 3, 64-84 A Heat Exchanger Reactor Equipped with Membranes to Produce Dimethyl Ether from Syngas and Methyl Formate and Hydrogen from Methanol A. Bakhtyari, A. Darvishi, and M.R. Rahimpour* Department of Chemical Engineering, School of Chemical and Petroleum Engineering, Shiraz University, Shiraz 71345, Iran Abstract: The energy crisis of the century is a motivation to present processes with higher energy efficiency for production of clean and renewable resources of energy. Hence, a catalytic heat exchanger reactor for production of dimethyl ether (DME) from syngas, and hydrogen and methyl formate (MF) from methanol is investigated in the present study. The proposed configuration is equipped with two different membranes for in-situ separation of products. Syngas is converted to DME through an exothermic reaction and it supplies a part of required energy for the methanol dehydrogenation reaction. Produced water in the exothermic side and produced hydrogen in the endothermic side are separated by using appropriate perm-selective membranes. In-situ separation of products makes the equilibrium reactions proceed toward higher conversion of reactants. A mathematical model based on reasonable assumptions is developed to evaluate molar and thermal behavior of the configuration. Performance of the system is aimed to enhance by obtaining optimum operating conditions. In this regard, Genetic Algorithm is applied. Performance of the heat exchanger double membrane reactor working under optimum conditions (OTMHR) is compared with a heat exchanger reactor without membrane (THR). OTMHR promotes methanol conversion to MF to %87.2, carbon monoxide conversion to %95.8 and hydrogen conversion to %64.6. -
General and Prospective Views on Oxidation Reactions in Heterogeneous Catalysis
Preprints (www.preprints.org) | NOT PEER-REVIEWED | Posted: 13 September 2018 doi:10.20944/preprints201809.0225.v1 Peer-reviewed version available at Catalysts 2018, 8, 483; doi:10.3390/catal8100483 Review General and Prospective Views on Oxidation Reactions in Heterogeneous Catalysis Sabine Valange 1,* and Jacques C. Védrine2,* 1 Institut de Chimie, des Milieux et Matériaux de Poitiers (IC2MP), UMR CNRS 7285, Université de Poitiers, ENSI Poitiers, B1, 1 rue Marcel Doré, TSA41105, F-86073, Poitiers Cedex 9, France 2 Sorbonne Université, Faculté des Sciences et Ingénierie, Laboratoire de Réactivité de Surface, UMR-CNRS 7197, 4 place Jussieu, F-75252 Paris, France * Correspondence: [email protected]; [email protected]; Tel.: +33-5-49454048 (S.V.); +33-1-44275560 (J.C.V.) Abstract: In this short review paper we have assembled the main characteristics of partial oxidation reactions (oxidative dehydrogenation and selective oxidation to olefins or oxygenates, as aldehydes and carboxylic acids and nitriles), as well as total oxidation, particularly for depollution, environmental issues and wastewater treatments. Both gas-solid and liquid-solid media have been considered with recent and representative examples within these fields. We have also discussed about their potential and prospective industrial applications. Particular attention has been brought to new raw materials stemming from biomass and to liquid-solid catalysts cases. This review paper also summarizes the progresses made in the use of unconventional activation methods for performing oxidation reactions, highlighting the synergy of these technologies with heterogeneous catalysis. Focus has been centered on usual catalysts activation methods but also on less usual ones, such as the use of ultrasounds, microwaves, grinding (mechanochemistry) and photo-activated processes, as well as their combined use. -
User:Smallman12q/Articles/Chemistry 1 User:Smallman12q/Articles/Chemistry
User:Smallman12q/articles/Chemistry 1 User:Smallman12q/articles/Chemistry Chemistry (from Egyptian kēme (chem), meaning "earth"[1] ) is the science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions.[2] It is a physical science for studies of various atoms, molecules, crystals and other aggregates of matter whether in isolation or combination, which incorporates the concepts of energy and entropy in relation to the spontaneity of chemical processes. Modern chemistry evolved out of alchemy following the chemical revolution (1773). Disciplines within chemistry are traditionally grouped by the type of matter being studied or the kind of study. These include inorganic chemistry, the study of inorganic matter; organic chemistry, the study Chemistry is the science concerned with the composition, structure, and properties of matter, of organic matter; biochemistry, the study of substances found in as well as the changes it undergoes during biological organisms; physical chemistry, the energy related studies of chemical reactions. chemical systems at macro, molecular and submolecular scales; analytical chemistry, the analysis of material samples to gain an understanding of their chemical composition and structure. Many more specialized disciplines have emerged in recent years, e.g. neurochemistry the chemical study of the nervous system (see subdisciplines). Summary Chemistry is the scientific study of interaction of chemical [3] substances that are constituted of -
Recycling of Carbone Oxides (Co, Co ) Conversion Into
Reports on research (2016), «EUREKA: Physics and Engineering» projects Number 6 RECYCLING OF CARBONE OXIDES (CO, CO2) CONVERSION INTO METHANOL AT ATMOSPHERIC PRESSURE OVER MECHANOCHEMICAL ACHTIVATED U N L C O-Z O-A 2O3 CATALYST Nataliia Khimach Department of Homogeneous Catalysis and Additives to Oil Products Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine 1 Murmanska str., Kyiv, Ukraine, 02660 [email protected] Vitaly Yevdokymenko Department of Organic and Petrochemical Synthesis Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine 1 Murmanska str., Kyiv, Ukraine, 02660 [email protected] Ievgen Polunkin Department of Homogeneous Catalysis and Additives to Oil Products Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine 1 Murmanska str., Kyiv, Ukraine, 02660 [email protected] Abstract The catalytic process for methanol production by synthesis gas conversion under the conditions of mechanochemical activa- tion (MCA) of copper-zinc-aluminum oxide catalyst in the temperature range 160–280 °C at a pressure of 0.1 MPa are investigated. The use of mechanical action force is one of the promising ways to improve the activity of heterogeneous catalysts designed to simplify the manufacturing process lines, improving the efficiency of catalytic processes and reduce the cost of the target product. Given the importance of technology for methanol production on copper-zinc-aluminum oxide catalysts and high demand for metha- nol in the world [1–3], clarification of the peculiarities of the process of methanol production by synthesis gas conversion in terms of mechanical load on the catalyst is important in scientific and applied ways. -
Conversion of Green Methanol to Methyl Formate
catalysts Review Conversion of Green Methanol to Methyl Formate Doreen Kaiser, Luise Beckmann, Jan Walter and Martin Bertau * Institute of Chemical Technology, TU Bergakademie Freiberg, Leipziger Straße 29, 09599 Freiberg, Germany; [email protected] (D.K.); [email protected] (L.B.); [email protected] (J.W.) * Correspondence: [email protected]; Tel.: +49-3731-392384 Abstract: Methyl formate is a key component for both defossilized industry and mobility. The current industrial production via carbonylation of methanol has various disadvantages such as high requirements on reactant purity and low methanol conversion rates. In addition, there is a great interest in replacing the conventional homogeneous catalyst with a heterogeneous one, among other things to improve the downstream processing. This is why new approaches for methyl formate are sought. This review summarizes promising approaches for methyl formate production using methanol as a reactant. Keywords: carbonylation; green chemistry; methanol; methyl formate; synfuel 1. Introduction Methyl formate (MF) is one of the most important building blocks in C1 chemistry and it is of great interest as an emission reducing fuel additive. MF can be synthesized from CO and methanol and can be understood as chemical storage for CO. If methanol is produced Citation: Kaiser, D.; Beckmann, L.; from CO2 and hydrogen, which is generated through water electrolysis by renewable Walter, J.; Bertau, M. Conversion of energy, an access to green MF is created. This way a (partial) substitution for classical i.e., Green Methanol to Methyl Formate. fossil feedstock borne petrochemicals can be realized while reducing CO2 emissions.