EA-60-RI-00176.01
Varanus Island Hub Operations Environment Plan Summary (State Waters)
PROJECT / FACILITY Varanus Island Hub
REVIEW INTERVAL (MONTHS) No Review Required
SAFETY CRITICAL DOCUMENT NO
Any hard copy of this document, other than those identified above, are uncontrolled. Please refer to the Santos Offshore Business Document Management System for the latest revision.
Rev Rev Date Author / Editor Amendment
0 11/09/2019 Santos Issued to DMIRS
A 21/8/19 CDM Smith Draft for Santos review
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Contents 1 Introduction 5 1.1 Operator 5 1.2 Compliance 6 1.3 Schedule 7 2 Activity Location 8 2.1 Operational Area 8 3 Description of Activity 12 3.1 Varanus Island 12 3.2 Airlie Island 14 3.3 Activities not included under this EP 14 4 Description of the Environment 15 4.1 Regional Setting 15 4.2 Benthic Habitats 15 4.3 Protected/Significant Areas 19 4.4 Threatened and Migratory Fauna 22 4.5 Socio-Economic Receptors 23 5 Stakeholder Consultation 27 5.1 Addressing consultation feedback 29 6 Environmental Hazards and Controls 29 6.1 Overview of process 29 6.2 ALARP and Acceptability Evaluation 31 6.3 Summary of Risks 32 7 Management Approach 46 8 Hydrocarbon Spill Response Arrangements 47 9 Contact Details 48 10 References 49
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List of Figures Figure 2-1: Operational boundary for VI Hub and Airlie Island Operations 9 Figure 2-2: VI Hub and Airlie Islands Offshore Facilities 10 Figure 2-3: VI Hub Onshore Facilities 11 Figure 4-1: Benthic Habitats within the EMBA and Operational Area 18 Figure 4-2: Protected areas within and near the EMBA and Operational Area 21 Figure 6-1: Environmental impact and risk assessment process 29 Figure 6-2: Santos WA Risk Matrix 31
List of Tables Table 1-1: Joint Venture Participants in the VI Hub Operations 5 Table 2-1: Key Coastal or Mainland Features in Proximity to Varanus and Airlie Islands 8 Table 3-1: Activities that Support Varanus Island Operations 12 Table 4-1: Overview of Key Habitat Values Relevant to VI Hub Operations 16 Table 4-2: Marine Protected Areas Present within the Operational Area and EMBA 20 Table 4-1: Summary of Protected Species and Communities within the Operational Area and EMBA 22 Table 4-4: Socio-economic activities in the vicinity of the operational area and EMBA 24 Table 5-1: Summary of stakeholders engaged for VI Hub Operations EP 28 Table 6-1: Consequence level description 30 Table 6-2: Likelihood description 30 Table 6-3: Summary of the residual risk rankings associated with planned events 32 Table 6-4: Summary of the environmental risks for events associated with unplanned events 33 Table 6-5: Potential Impacts, Risks and Control Measures for Planned Events 34 Table 6-6: Environmental Impact Summary for Unplanned Events 39 Table 8-1: Summary of Maximum Credible Spill (MCS) Scenarios 47
Appendices Appendix A: Chemical Disclosure & Safety Data Sheets
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1 Introduction On 27 November 2018, Santos completed its acquisition of Quadrant Energy. This has the effect that Santos Limited is now the ultimate holding company of Quadrant Energy Holdings Pty Ltd and its subsidiaries. It has also resulted in most of the Quadrant group of entities changing their name. For example, Quadrant Energy Australia Limited has changed its name to Santos WA Energy Limited and Quadrant Northwest Pty Ltd has changed its name to Santos WA Northwest Pty Ltd. Each entity’s ABN has remained the same. Santos WA Energy Limited on behalf of Santos WA Northwest Pty Ltd and Santos WA Southwest Pty Limited (hereafter referred to as Santos WA or Company) will be responsible for all commitments and obligations in this EP.
Santos WA operates the Varanus Island Hub (VI Hub), located on the North West Shelf of Western Australia (WA). The scope of this EP comprises all infrastructure and operational activities associated with the VI Hub within State waters, including: All infrastructure located on VI; The associated offshore platforms/monopods and subsea tie-backs; Vessel based activities; The subsea pipelines, flowlines and umbilicals (within State waters) between VI and the offshore facilities; The pipelines between VI and the mainland metering station and the pipeline from VI to the marine load-out terminal; Maintenance and environment monitoring on Airlie Island; and Monitoring and maintenance activities on Airlie Island (AI).
1.1 Operator
Santos WA is the operator of the activity described within this EP. Table 1-1 lists Production Licences, the operators and JV partners. Table 1-1: Joint Venture Participants in the VI Hub Operations Production Permits/Pipeline Licences Operations (including non- Joint Venture Partners (% Share) (Associated producing) Operator in Bold licences are listed in Appendix A_3) TL/1, 5, 6, 8 & 9 Harriet (Alpha, Bravo, Charlie, Gipsy Santos WA Northwest Pty Ltd (87.7771%) and Bambra subsea), Sinbad, Harriet (Onyx) Pty Ltd (12.2229%) Access Campbell, Tanami, Rosette, Authorities Agincourt, Wonnich, Simpson, - ADW 12/91-2 Gibson / South Plato, Victoria, Double Island, Twickenham, Linda - ADW 10/92-3 PL 29 East Spar Gas Plants Trains 1 and 2 Santos WA Southwest Pty Limited (25%) (VI), Amine (CO2 Removal) Plants Santos WA East Spar Pty Limited (25%) Train 1 and 2, East Spar Ground and Santos WA Kersail Pty Ltd (5%) Elevated Flares Santos (BOL) Pty Ltd (45%) PL 12 Harriet LTS Gas Plants Trains 1, 2 Santos WA Northwest Pty Ltd (87.7771%) and 3 (VI), Liquids Separation Plant Harriet (Onyx) Pty Ltd (12.2229%) (VI), Harriet Ground and Elevated Flares, Bulk Crude and Condensate
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Production Permits/Pipeline Licences Operations (including non- Joint Venture Partners (% Share) (Associated producing) Operator in Bold licences are listed in Appendix A_3) Storage Tanks (VI), Marine Export Terminal, Produced Formation Water Treatment System including Rosette, Alkimos and Simpson depleted gas/oil reservoirs PL 30 John Brookes and East Spar Santos WA Southwest Pty Limited (25%) Pipelines which feed into East Spar Santos WA East Spar Pty Limited (25%) Gas Plant Santos WA Kersail Pty Ltd (5%) Santos (BOL) Pty Ltd (45%) TL/2 Airlie Santos WA Southwest Pty Limited Chervil (well head platform removed (66.834%) but subsea infrastructure remains) Hydra Energy (WA) Pty Ltd (23.166%) South Pepper Tanami Energy Pty Ltd (10.000%) North Herald Santos (BOL) Pty Ltd (0%) PL 14 Airlie Island Licence Area
1.2 Compliance
P(SL)(E)R 2012 Requirements
Regulation 11 (3) & (4) (3) Within 10 days after receiving notice that the Regulator has accepted an environment plan (whether in full, in part or subject to limitations or conditions), the titleholder must submit a summary of the accepted plan to the Regulator for public disclosure. (4) The summary: (a) must include the following material from the environment plan: (i) the location of the activity; (ii) a description of the receiving environment; (iii) a description of the activity; (iv) details of environmental impacts and risks; (v) a summary of the control measures for the activity; (vi) a summary of the arrangements for ongoing monitoring of the titleholder’s environmental performance; (vii) a summary of the response arrangements in the oil pollution emergency plan; (viii) details of consultation already undertaken, and plans for ongoing consultation; (ix) details of the titleholder’s nominated liaison person for the activity; and (b) must be to the satisfaction of the Regulator. PP(E)R 2012 Requirements
Regulation 11 (7) & (8)
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(7) Within 10 days after receiving a notification that the Minister has approved an environment plan under subregulation (5)(a) the operator must submit to the Minister for public disclosure a summary of the plan. Penalty: a fine of $5,500. (8) A summary submitted under subregulation (7) must include the following: (a) the contact details of the operator of the pipeline activity or the operator’s agent; (b) the location of locations of the pipeline activity; (c) a general description of the existing environment that may be affects by the pipeline activity; (c) a summary of; (i) the details of the construction and layout of any pipeline; and (ii) the operational details of the pipeline activity and proposed timetables; and (iii) the environmental impacts and environmental risks of the pipeline activity; (iv) the implementation strategy included in the environment plan; and (v) the consultation that has been undertaken during the development of the environment plan that is to be undertaken in accordance with the implementation strategy.
Santos WA has revised the associated EP in accordance with the Petroleum (Submerged Lands) (Environment) Regulations 2012 (P(SL)(E)R 2012) and Petroleum Pipelines (Environment) Regulations 2012 (PP(E)R 2012), requiring a revision of an accepted EP every 5 years. This EP has also considered the ‘Guidelines for the Preparation and Submission of an Environment Plan’ released by the DMIRS in November 2016 (DMP, 2016). The EP was submitted to the WA Department of Mines, Industry Regulations and Safety (DMIRS) for assessment on 11 September 2019. The operation of the Varanus Island Hub has been managed under the Varanus Island Hub Operations Environment Plan (EA-60-RI-186) Revision 6. The EP was accepted by DMIRS on 25 September 2014 and the VI Oil Pollution Emergency Plan (OPEP) (EA-60-RI- 186.2, Revision 6) was accepted by DMIRS on 21 July 2017. 1.3 Schedule The VI Hub operates 24 hours a day, 7 days a week, and routine activities may occur at any time during any season. The EP’s proposed validity is 5 years, as per regulatory approvals.
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2 Activity Location Varanus Island Hub (and Airlie Island) are located on the North West Shelf of Western Australia, in the Shire of Ashburton, off the Pilbara Coast. Figure 2-1 shows the location of the operational area, while Figure 2-2 and Figure 2-3 show the location of infrastructure associated with the VI Hub. The proximity of the islands to other key costal or mainland features are provided in Table 2-1. Table 2-1: Key Coastal or Mainland Features in Proximity to Varanus and Airlie Islands Features Varanus Island Airlie Island State/Commonwealth waters boundary 20 km west 21 km west Montebello Commonwealth Marine Reserve boundary 20 km west 55 km north Montebello Islands Marine Conservation Reserve 10 km north 89 km north Barrow Island 11 km southwest 50 km north Barrow Island Marine Management Area 25 km south 28 km north Barrow Island Marine Park 23 km southwest 61 km north Mainland 58 km southeast 35 km east
2.1 Operational Area The operational area is defined as the area shown in Figure 2-1, comprising 250 m either side of pipelines, 500 m radius around platforms and subsea infrastructure and a 500 m radius around Varanus Island and Airlie Island.
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Figure 2-1: Operational boundary for VI Hub and Airlie Island Operations
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Figure 2-2: VI Hub and Airlie Islands Offshore Facilities
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Figure 2-3: VI Hub Onshore Facilities
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3 Description of Activity
3.1 Varanus Island
Varanus Island (VI) forms the central gathering and processing hub for the Santos WA oil and gas production facilities in the area. Gas and liquids from the offshore facilities are processed on the island (refer Figure 2-3). The onshore facilities include the control centre and systems to remotely control and monitor the normally unmanned offshore facilities. The accommodation, administration and operating centre for the various production facilities are also located on VI. All facilities that form part of the Varanus Island Hub are operated and maintained from VI. Personnel reside on VI and travel to and from the offshore facilities on a regular basis via helicopter or support vessel. An overview of the types of activities that support operations at the VI Hub facilities, and covered by this EP, are briefly described in Table 3-1. Table 3-1: Activities that Support Varanus Island Operations Activity Brief Description Routine operations and maintenance (onshore and offshore) Daily inspections/ checks Vessels, instruments, valving, sumps and drains Hydrotesting and isolation Pipelines and production equipment Critical function testing Including systems such as the firewater deluge system Intervention activities/ Isolations Valves, rotating equipment, instrumentation, vessels and topsides flowlines for maintenance / project / drilling activities Inspection/Maintenance/Monitoring Cutting, grinding, welding, testing, paint removal (water/grit blasting) and Repair activities and painting activities Inspection and maintenance of wellheads; storage tanks, pressure equipment and piping (including hydrocarbon freeing) and infrastructure in sub-tidal zone (e.g. pipelines and wharfs) Bund liner inspection and repairs Civil works To support ongoing repair, maintenance and brownfield modifications Transport Support vessel and helicopter operations between the mainland, VI, AI and the offshore facilities Transport of personnel and equipment/goods by helicopter, vessel or vehicles to onshore and offshore locations Flushing, cleaning, purging and Undertaken on process vessels and pipelines (flowlines), including pipeline pigging facilities topside cleaning Well suspension and intervention Including coil tubing, wireline (e.g. eline & Slickline), hydraulic work activities over (e.g. snubbing) and pumping Brownfield modifications and To static / rotating equipment, process, electrical, instrumentation and upgrades utility systems Marine Activities Unloading / back loading support Activities at the Varanus Island wharves and offshore facilities (e.g. vessels transport of chemicals and fuel on platforms), clearance of sediment/debris build up around wharves and ramps to maintain safe vessel/roll on roll off access.
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Activity Brief Description Facilities and subsea infrastructure Including activities such as: inspection, maintenance, monitoring diving operations, remotely operated vehicle (ROV) surveys, and repair automatous underwater vehicle (AUV) surveys, side scan sonar (SSS), wave glider surveys, drones Pipeline and well inspection and intervention work Freespan rectification Platform recertification Well services activities including pumping, well top up or kill, cementing, acidising and pressure testing from the rear of the vessel Routine maintenance and replacement of marine buoys/ clump weights/chain Fabric and equipment maintenance on offshore facilities. Onshore Activities Rock crushing operations and Of redundant concrete/ rock, or crushing for road/access repairs so storage safe for use, and temporary storage Inspection/Maintenance/Monitoring Includes Lease boundary; monitoring transects; concrete batching and Repair activities and as required to existing infrastructure Includes pipeline inspection, maintenance, monitoring and repairs to pipelines, as well as civil remediation activities as required to prevent soil erosion and stabilise the land surface under/ around the plant, pipelines within pipeline easement. Environmental monitoring program Various environmental monitoring programs undertaken onshore and offshore typically on a scheduled basis Use of mobile equipment Cleaning and maintaining of mobile equipment Refuelling of mobile equipment Crane and mobile vehicle operations and maintenance. Maintaining/ operating and repairs Warehouse, workshops, offices, accommodation blocks and mess facilities Sewage plant and other sewage treatment facilities Production, storage of fresh water and maintenance of fresh water making equipment Clean out of sumps/bunds Maintaining of roads and tracks Maintaining and repairing of roads and tracks so they are safe for use and access, vegetation removed. Minor soil excavation works Trenching for underground services, road or access grading, maintenance of drainage channels Firefighting System Commissioning, firewater and foam discharge testing Management, storage and transport Includes collection of waste material; segregation of solids and of wastes liquids, hazardous and non-hazardous wastes; disposal of wastes; storage and sampling; classification of the waste; and shipping and transportation of the waste.
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Activity Brief Description Contaminated Sites Remediation Contaminated site investigation and remediation activities include Activities construction, installation and commissioning of equipment and infrastructure for the purpose of recovery of contamination and monitoring and sampling/taking of groundwater, vapour and soil, to be conducted in both on-lease and off-lease areas.
3.2 Airlie Island
The facilities on AI are drained of any hydrocarbons. The type of care and maintenance activities that take place at the AI facilities include:
+ Transport of personnel and equipment/goods by vessel to the island; + Visual inspection of Chervil pipeline; + Inspection of communication equipment on Airlie Island; + Inspection and removal of weather damaged facilities/equipment; and + Environmental monitoring. At AI a dingy is deployed from the support vessel to access the island, if required, as there is no wharf to accommodate larger vessels. If a barge is used to transport equipment to AI for maintenance activities, the barge may be stranded on the beach for offloading and onloading of personnel and equipment.
There are four subsea pipelines associated with Airlie Island (these are all suspended and flooded with seawater):
+ A 200mm NB production flowline from the Chervil monopod to AI; + An 80mm NB gas-lift line to the Chervil monopod from AI; + A 500mm NB crude oil export pipeline from AI to the tanker mooring; and + The 200mm NB South Pepper pipeline.
3.3 Activities not included under this EP
Decommissioning will be carried out at the end of the Facility life, in accordance with relevant legislation at that time. Decommissioning activities will be the subject of separate approval processes and are not part of the scope of this EP. The platforms, subsea installations and pipelines located in Commonwealth waters are covered by the Varanus Island Hub Commonwealth EP, and are outside of the scope of this EP.
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4 Description of the Environment While the area impacted by the planned activity is limited to the immediate vicinity of the facilities, an unplanned worse case credible hydrocarbon release has been modelled to illustrate potential impacts to a wider area. The wider environment that may be affected (EMBA) by the potential spill is the spatial extent considered when discussing the sensitivities and receptors of the existing environment.
4.1 Regional Setting
The operational area is located within the Northwest Shelf Province, as defined under the Integrated Marine and Coastal Regionalisation of Australia (IMCRA) Version 4.0. The operational area occurs in shallow-water tropical marine ecosystems with high species richness. Most of the region’s species are tropical and are also found in other parts of the Indian and western Pacific oceans. The EMBA overlaps five IMCA provincial bioregions including the Northwest Transition, Northwest Province, Northwest Shelf Province, Central Western Transition and Central Western Shelf Transition. The southern part of the EMBA is a transition zone between tropical and temperate waters and includes the northern extent of the ranges of some temperate species that are more typical of the South-west Marine Region. High diversity is partly driven by the interaction between seafloor features and the currents of the region. The interaction of seafloor features and oceanographic processes also supports unique ecosystems and associated trophic interactions and communities (DSEWPaC, 2012). Key features of the EMBA are the Ningaloo Reef and North West Cape to the southwest of the monopod, the Montebello/Barrow/Lowendal Islands to the north east of the monopod and the Dampier Archipelago/Burrup Peninsula to the north east of the monopod. Barrow Island, the Montebello Islands, Lowendal Islands including VI, Airlie Island are part of a shallow submarine ridge, which extends north from the mainland near Onslow. The ridge contains extensive areas of intertidal and shallow subtidal limestone pavement surrounding the numerous, mostly small islands which are found in the region. The seabed is primarily less than 5 m deep and consists of sand veneered limestone pavement with patches of fringing coral reef. In addition to the mainland area surrounding Cape Range, key values of this subregion include Exmouth Gulf Islands, Muiron Islands, Lowendal Islands, Montebello Islands and Barrow Island.
4.2 Benthic Habitats
The benthic habitats within waters in the operational area lie at depths ranging from shoreline to 40 m. Benthic habitats within the operational area consist of coral reefs, seagrasses and macroalgae, which are associated with hard substrate around the Montebello and Lowendal Islands, as well as the mainland shore (Cardno 2011, Chevron 2005). However, the majority of the seabed habitat within the operational area is relatively devoid of hard corals, with coral outcrops being sparsely distributed (Cardno 2011). Seagrasses within the operational area are small ephemeral species, sparsely interspersed between macroalgae, that grow on soft sediments, subtidal sands and in intertidal pools (Chevron 2005). The seafloor along the sales gas pipeline between Varanus Island and the mainland comprises calcareous sandy sediments with scattered sponges, algae, sea whips, soft corals and occasionally hard corals (LEC 1990). The habitat of the sales gas pipeline is widely distributed throughout the region. Saline mudflats occur where the sales gas pipeline occurs on-shore.
Dominant shoreline habitats within the remainder of the operational area include widely spread mangroves, and sandy beaches interspersed with hard substrate and intertidal platforms, which provide breeding and nesting grounds for marine turtles and seabirds (Astron 2012, Garnet and Crowley 2000).
Mangroves occur as discrete patches within the tidal and supratidal (immediately above the high tide mark) zone on the west coast of VI at South Mangrove Beach and in a small embayment directly adjacent to West Wharf (Astron 2012).
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The terrestrial habitats within the operational area include Varanus Island, Airlie Island and the onshore pipeline. The vegetation on Varanus Island and Airlie Island is broadly described as ‘desertic’ dominated by hummock grasslands, with much of the vegetation disturbed to some degree (weeds) (Astron 2013). The mainland portion of the sales gas pipeline is dominated by sand dunes and grass savannas (Dames and Moore 1998). Table 4-1 and Figure 4-1 provide an overview of the benthic habitats surrounding the operational area and within the EMBA.
Table 4-1: Overview of Key Habitat Values Relevant to VI Hub Operations Presence Relevant events that may impact on the Value Operational EMBA receptors area Coral Reefs Unplanned: Introduction of IMS Hydrocarbon release due to subsea /surface well release Hydrocarbon release from vessel collision Hydrocarbon release from pipeline. Seagrass Unplanned: Hydrocarbon release due to subsea /surface well release Hydrocarbon release from vessel collision Hydrocarbon release from pipeline. Macroalgae Unplanned: Introduction of IMS Hydrocarbon release due to subsea /surface well release Hydrocarbon release from vessel collision Hydrocarbon release from pipeline. Non-coral Planned: benthic Seabed disturbance invertebrates Planned operational discharges Unplanned: Introduction of IMS Hydrocarbon release due to subsea /surface well release Hydrocarbon release from vessel collision Hydrocarbon release from pipeline Non-hydrocarbon release (surface) – solid. Mangroves Planned: Intertidal Atmospheric emissions platforms
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Presence Relevant events that may impact on the Value Operational EMBA receptors area Sandy Unplanned: beaches Hydrocarbon release due to subsea /surface well release Rocky shorelines Hydrocarbon release from vessel collision Saline Hydrocarbon release from pipeline. mudflats Terrestrial Planned: habitat - VI, AI Atmospheric emissions and mainland Remediation activities – soil and groundwater Planned water management on Varanus Island Disturbance of land and native vegetation Unplanned: Unplanned release onshore Accidental discharge (terrestrial) – non- hydrocarbon release of solids and liquids Introduction of non-indigenous flora and fauna Accidental fire.
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Figure 4-1: Benthic Habitats within the EMBA and Operational Area
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4.3 Protected/Significant Areas
Protected/significant areas identified in the operational area and EMBA are detailed in
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Table 4-2 and shown in Error! Reference source not found.. Part of the operational area intersects the Montebello Australian Marine Park (AMP). AMPs are recognised under the Environment Protection and Biodiversity Conservation Act 1999 (EPBC Act) for protecting and maintaining biological diversity and contributing to a national representative network of marine protected areas. Management plans for AMPs have been developed and came into force on 1 July 2018. Under these plans AMPs are allocated conservation objectives (International Union for Conservation of Nature (IUCN) Protected Area Category) based on the Australian IUCN reserve management principles in Schedule 8 of the EPBC Regulations 2000. The operational area also intersects the Montebello Islands Marine Park (State waters) and Barrow Island Marine Management Area, which also represent a National Heritage Area (Barrow Island and the Montebello-Barrow Island Marine Conservation Reserves). There is a management plan in place for the Montebello/Barrow Islands (DEC, 2007). Socio-economic values of the Montebello and Barrow Islands MCR include hydrocarbon exploration and production, pearling, nature-based tourism, commercial and recreational fishing, water sports, European history and maritime heritage and scientific research (DEC, 2007).
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Table 4-2: Marine Protected Areas Present within the Operational Area and EMBA Operational Area Marine Protected Area EMBA Presence Presence Australian Marine Parks Montebello AMP (IUCN Category I, IV & VI) Dampier AMP (IUCN Category I, IV & VI) x Ningaloo AMP (IUCN IV) x Gascoyne AMP (IUCN IV) x Argo-Rowley Terrace AMP (IUCN VI) x Shark Bay AMP (IUCN VI) x Carnarvon Canyon AMP (IUCN IV) x State Marine Parks and Management Areas Montebello Islands Marine Park Barrow Island Marine Management Area Barrow Island Marine Park x Muiron Islands Marine Management Area x Ningaloo Marine Park x World Heritage Areas The Ningaloo Coast x National Heritage Areas Barrow Island and the Montebello-Barrow Island Marine Conservation Reserves Dampier Archipelago (including Burrup Peninsula) x The Ningaloo Coast x Commonwealth Heritage Areas Ningaloo Marine Area – Commonwealth Waters x Naval Communication Station Harold E Holt x Learmonth Air Weapons Range Facility x Key Ecological Features Ancient Coastline at 125 m Depth Contour x Continental Slope Demersal Fish Communities x Canyons linking the Cuvier Abyssal Plain and the Cape x Range Peninsula Glomar Shoals x Exmouth Plateau x Commonwealth waters adjacent to Ningaloo Reef x
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Figure 4-2: Protected areas within and near the EMBA and Operational Area
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4.4 Threatened and Migratory Fauna
The EPBC Act lists threatened and migratory fauna species that are protected under Commonwealth legislation and various international conventions and treaties. A search of the EPBC Act Protected Matters Database was conducted using the coordinates of the EMBA to identify these species. Table 4-3: Summary of Protected Species and Communities within the Operational Area and EMBA Value Description Fish and sharks 14 species of fish and sharks listed as threatened and/or migratory under the EPBC Act could occur within the EMBA (9 of which could occur within the operational area) Marine Reptiles 6 marine reptile species could occur within the operational area and EMBA (5 turtle species, 1 seasnake) that are listed as threatened and/or migratory under the EPBC Act The following Biologically Important Areas (BIAs) intersect the operational area: - Internesting (interesting buffer) (loggerhead, green, hawksbill and flatback turtles) - Basking (green turtle) - Foraging (hawksbill, green, loggerhead and flatback turtles) - Nesting (hawksbill, green, loggerhead and flatback turtles) - Mating (green, hawksbill and flatback turtles). Habitat mapped as ‘habitat critical (nesting)’ for green, hawksbill and flatback turtles also occur within the operation area. Nesting is also known to occur on Varanus and Airlie Islands. Marine Mammals 12 species of marine mammals listed as threatened and/or migratory under the EPBC Act could occur within the EMBA (8 of which could occur within the operational area) The following BIAs intersect the operational area: - Migration (humpback whale) - Distribution (pygmy blue whale). A number of marine mammals are known to occur in the local region around the EMBA, including dolphins, whales and the dugong. Some species are seasonal visitors, migrating through NWS waters, while others occur all year round. Seabirds 58 species of birds listed as threatened and/or migratory under the EPBC Act could occur within the EMBA (25 of which could occur within the operational area). Breeding BIAs intersect the operational area for the following species; wedge-tailed shearwater, Australian fairy tern, lesser crested tern, white- tailed tropicbird and roseate tern. Seabird colonies and nesting sites (primarily for the wedge-tailed shearwater) occur on Varanus and Airlie Islands. Terrestrial / 8 fauna listed as threatened and/or migratory under the EPBC Act could Subterranean occur within the terrestrial environments of the operational area and/or Fauna EMBA, and have the potential to be impacted by planned or unplanned activities (2 subterranean fish, 3 mammals and 3 reptiles).
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4.5 Socio-Economic Receptors
Socio-economic activities that may occur within the operational area and surrounds include commercial fishing, oil and gas exploration and production; and to a lesser extent, recreational fishing and tourism, are summarised below in Table 4-4.
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Table 4-4: Socio-economic activities in the vicinity of the operational area and EMBA Relevant events within the Operational EMBA Value/ Sensitivity Description Operational Area and Area Presence Presence EMBA Commercial Three Commonwealth fisheries overlap the operational area: the Planned fisheries - Western Tuna and Billfish Fishery, Southern Bluefin Tuna Fishery, Interaction with other marine Commonwealth and the Western Skipjack Tuna Fishery. users Since 2005, there has been fewer than five vessels active in the Unplanned Western Tuna and Billfish Fishery, down from 50 active vessels in Unplanned hydrocarbon 2000 (ABARES Fishery Status Reports, 2010). spills Southern Bluefin Tuna Fishery is only active in waters offshore South and South Eastern Australia, confirmed in consultation with the Australia Southern Bluefin Tuna Association in consultation for previous company offshore activities (ABARES Fishery Status Reports, 2018). There has been no fishing effort in the Skipjack Tuna Fishery since the 2009 season, and in that season activity concentrated off South Australia (ABARES Fishery Status Reports, 2018). Commercial State fisheries active within the operational area are the Pilbara Planned fisheries - State Trap, Line, Developmental Crab and Fish Trawl Managed Interaction with other marine Fisheries, the Mackerel Managed Fishery Area 2 and the Onslow users Prawn Limited Entry Fishery. A number of fisheries are open within Unplanned the operational area and EMBA, however do not have activity in this area. These are the Marine Aquarium Fish Managed Fishery, Unplanned hydrocarbon Western Australian Pearl Oyster Fishery, WA Sea Cucumber spills Fishery and Specimen Shell Managed Fishery. Shipping Shipping using NWS waters includes iron ore carriers, oil tankers Planned and other vessels proceeding to or from the ports of Dampier, Port Interaction with other marine Walcott and Port Hedland; however, these are predominantly users heading north from these ports. Unplanned The proposed operational area does not overlap any major shipping Unplanned hydrocarbon lanes (>10 km away), although vessel traffic may be encountered spills throughout the operational area as commercial vessels transit
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Relevant events within the Operational EMBA Value/ Sensitivity Description Operational Area and Area Presence Presence EMBA around the Montebello Islands and support vessel(s) conduct operations with the offshore infrastructure. Recreational fishing Within the operational area there are no known natural seabed - N/A Unplanned features that would aggregate fishes and which are typically Unplanned hydrocarbon targeted by recreational fishers. It is unlikely recreational fishing spills would occur in the operational area, but may occur in around the nearby Montebello Islands. Recreational fishing does occur within the EMBA, and therefore could be impacted by a LOWC. Defence In consultation Defence has advised no concerns with this - N/A N/A proposed activity. Shipwrecks Sixty-three (63) historic shipwrecks (>75 years) old are found within - Unplanned the EMBA. Unplanned hydrocarbon One shipwreck intersects the operational area near the mainland spills coast; Macey’s Wreck Unidentified. The year the shipwreck was stranded is not recorded. Oil and gas Various petroleum exploration and production activities have been - Planned undertaken within the northwest shelf, however there are none in Interaction with other marine the vicinity of the operational area. Vessels servicing oil and gas users operations in the region may pass through the area en route to Unplanned facilities, which is discussed under ‘Shipping’ above. Unplanned hydrocarbon Oil and gas facilities occur within the EMBA as do permits operated spills by other titleholders. As such, oil and gas activities could be impacted by unplanned events. Tourism Aquatic recreational activities such as boating, diving and fishing - - Unplanned occur near the coast and Montebello Islands. These activities are Unplanned hydrocarbon concentrated in the vicinity of the population centres such as spills Exmouth, Dampier and Onslow.
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Relevant events within the Operational EMBA Value/ Sensitivity Description Operational Area and Area Presence Presence EMBA Planned events are not predicted to have a significant impact on tourism given that the majority of operational activities occur at a greater water depth that aquatic recreational activities. The EMBA overlaps a portion with the Montebello Marine Park and also the Barrow Island Marine Park, as such eco-tourism based on specific local values (whale sharks, game fish, nearshore reef snorkelling and diving) could be impacted by unplanned events Cultural Heritage No known sites of Aboriginal Heritage significance occur within the - N/A N/A operational area or EMBA. No known sites of Cultural Heritage significance or National Heritage places exist within the EMBA.
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5 Stakeholder Consultation Stakeholders, identified in Table 5-1, were provided a VI Hub Operations Consultation Package via email in June 2018 to ensure they were aware the EP was being revised. In addition, Santos WA’s wider stakeholder group is regularly updated on Santos’ activities through Quarterly Consultation Update documents, which list the VI Hub as a key operating facility for Santos WA. Outside of the regulatory approval process, Santos WA continuously engages with regional stakeholders to maintain a social licence to operate. Santos WA maintains relationships with community partners, focussing on the Karratha and Exmouth communities, allowing the business to align community investments with the strategic objectives of the communities in which Santos WA operates. Other interested stakeholders are able to find information regarding the VI Hub in a fact sheet published on Santos WA’s external website. Santos WA considers that consultation with regulators and key stakeholders has been adequate for activities covered under this EP. No stakeholder has objected to activities covered under this EP nor claimed that the environmental impacts or risks are unacceptable. Given the long term presence at VI, Santos WA anticipates all relevant stakeholders are familiar with the facility. For the activities undertaken under this EP, a standardised approach is applied to identify key stakeholders for the activity in question, beginning with a review of Santos’ stakeholder list, and of the stakeholders consulted over other recent activities in the area. In particular, the operational area for the activity is used to identify relevant persons and will be used throughout the duration of this EP.
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Table 5-1: Summary of stakeholders engaged for VI Hub Operations EP Group Stakeholder Fishers and representative Austral Fisheries bodies Australian Southern Bluefin Tuna Association (ASBTIA) Fat Marine Marine Tourism WA MG Kailis Old Brown Dog Pearl Producers Association Quest Maritime Recfishwest Western Australian Fishing Industry Council (WAFIC) Marine conservation Department of Primary Industries and Regional Development (DPIRD) Department of Biodiversity, Conservation and Attractions (DBCA) Department of Water and Environmental Regulation (DWER) Shipping safety and security Australian Marine Oil Spill Centre (AMOSC) Australian Maritime Safety Authority (AMSA) Department of Defence (DoD) Department of Transport (DoT) Pilbara Port Authority Indigenous stakeholder Buurabalayji Thalanyji Aboriginal Corporation (BTAC) groups Kuruma Marthudhunera Aboriginal Corporation (KMAC) Yaburara and Coastal Mardudhunera Aboriginal Corporation (YACMAC) Regional Stakeholders City of Karratha Karratha Chamber of Commerce and Industry Kings Bay Fishing Club Pilbara Development Commission Tourism Operators Apache Charters Blue Horizon Charters Keshimer Expeditions Kimberley Expeditions Kings Ningaloo Reef Tours Lady M Cruising Montebello Tours Odyssey Expeditions Pelican Charters Sail Leeuwin Sail Ningaloo Top Gun Charters Neighbouring operators Chevron Eni Australia Woodside
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5.1 Addressing consultation feedback
Santos WA’s Consultation Coordinator is available before, during and after the activity to ensure opportunities for stakeholders to provide feedback are available. Consultation material is provided to relevant internal, activity personnel to ensure the Santos WA business has a thorough understanding of how the activity is being received by relevant persons. If in stakeholder consultation a change to any control measure or activity outlined in this EP is required, Santos WA would undertake an internal assessment using the management of change (MoC) process.
6 Environmental Hazards and Controls
6.1 Overview of process
Santos WA operates under an overarching risk management policy (QE-91-IF-10050). The company risk management framework (QE-91-IF-10051) underpins the risk management policy and is consistent with the requirements of AS/NZS ISO 31000:2018 Risk Management – Guidelines (ISO, 2018).
The key steps to risk management are illustrated in Figure 6-1.
Describe the activity and identiy the hazards (planned and unplanned events) arising from the activity
Identify receptors in the environment that will, or may be impacted by the event and determine the nature and scale of impacts
Apply standard control measures
Assess impacts (planned events (based on consequences only)) and risks (unplanned events (based on likelihood and consequence)) with standard controls applied
Treat risks and impacts by implementing additional controls as needed
Determine residual impact and risk ranking and ensure activity is ALARP and Acceptable.
Figure 6-1: Environmental impact and risk assessment process
Santos WA has undertaken environmental impact and risk assessments for the operational activities planned events (including any routine, non-routine and contingency activities) and unplanned events in accordance with the P(SL)(E)R 2012. The extent of actual or potential impacts from each planned or unplanned event is assessed using, where required, modelling (e.g., hydrocarbon spills) and scientific reports. The duration of the event is
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also described, including the potential duration of any impacts should they occur. For each planned and unplanned event, a set of Environmental Performance Objective(s), Control Measures, Environmental Performance Standards and Measurement Criteria are identified. The definitions of the performance objectives, environmental performance standards and measurement criteria are consistent with PSL(E)R 2012.
Impact mechanisms and any thresholds for impacts are determined and described, using scientific literature and modelling where required. Impact thresholds for different critical life stages are also identified where relevant. The consequence level of the impact is then determined for each planned and unplanned event based on the severity of the impact to relevant receptors.
This process determines a consequence level based on set criteria for each receptor category and takes into consideration the duration and extent of the impact, receptor recovery time and the effect of the impact at a population, ecosystem or industry level. The consequence definitions are outlined in Table 6-1.
Table 6-1: Consequence level description Consequence Consequence Level Description Level A Negligible No impact or negligible impact. Environmental impact lasting days up to 1 week. B Minor Detectable but insignificant change to local population, industry or ecosystem factors. Environmental impact lasting weeks up to 12 months. C Moderate Significant impact to local population, industry or ecosystem factors. Environmental impact lasting 1 to 10 years. D Major Major long-term effect on local population, industry or ecosystem factors. Environmental impact lasting 10 to 20 years. E Critical Complete loss of local population, industry or ecosystem factors AND/ OR major wide-spread regional impacts with slow recovery to no full recovery. Environmental impact lasting more than 20 years to no recovery. Note: Injury or mortality to a protected species is included as a moderate consequence level
For unplanned events, in addition to the consequence level of the impact, a risk ranking is also determined using an assessment of the likelihood (likelihood ranking) of the impact occurring from an unplanned event. For oil spill events, potential impacts to environmental receptors are assessed where they occur within the EMBA using results from modelling. The Santos WA risk matrix is provided in Table 6-2.
Table 6-2: Likelihood description No. Matrix Description 1. Event has occurred frequently within the Company. 5 Probable 2. Between 1 and 10 incidents every 10 years (i.e. up to a frequency of 1/year). 1. Event has occurred frequently within the Industry. 4 Likely 2. Between 1 and 10 incidents every 100 years (i.e. up to a frequency of 10- 1/year). 3 Unlikely 1. Event has occurred occasionally within the Company.
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No. Matrix Description 2. Between 1 and 10 incidents every 1000 years (i.e. up to a frequency of 10- 2/year). 1. Event has occasionally occurred within the Industry. Very 2 Unlikely 2. Between 1 and 10 incidents every 10,000 years (i.e. up to a frequency of 10-3/year). 1. Event could happen under exceptional circumstances only. 1 Rare 2. Between 1 and 10 incidents every 100,000 years (i.e. up to a frequency of 10-4/year).
SEVERITY
Negligible Minor Moderate Major Critical A B C D E
5. Probable
4. Likely
3. Unlikely
2. Very
LIKELIHOOD Unlikely
1. Rare
High Risk Reduction of risk required Medium Risk Reduction of risk required based on ALARP principle Low Risk Deemed acceptable based on standard risk controls in place Figure 6-2: Santos WA Risk Matrix
6.2 ALARP and Acceptability Evaluation
For planned and unplanned events, an ALARP assessment is undertaken to demonstrate that the standard control measures adopted reduce the impact (consequence level) or risk to as low as reasonably practicable (ALARP). This process relies on demonstrating that further potential control measures would require a disproportionate level of cost/effort in order to reduce the level of impact or risk. If this cannot be demonstrated, then further control measures are adopted. The level of detail included within the ALARP assessment is based upon the nature and scale of the potential impact or risk. For example, more detail is required for a risk ranked as ˋMedium’ compared to a risk ranked as ˋLow’.
Santos WA considers an impact or risk associated with the proposed activity to be acceptable if the following criteria are met:
+ The consequence of a planned event is ranked as A or B; or a risk of impact from an unplanned event is ranked low to medium;
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+ An assessment has been completed to determine if further information/studies are required to support or validate the consequence assessment; + Assessment and management of risks has addressed the principles of ecologically sustainable development (ESD); + That the acceptable levels of impact and risks have been informed by relevant species recovery plans, threat abatement plans and conservation advice can be demonstrated; + Performance standards are consistent with legal and regulatory requirements; + Performance standards are consistent with the Santos WA’s Environmental Management Policy; + Performance standards are consistent with industry standards and best practice guidance (e.g., National Biofouling Management Guidelines for the Petroleum Production and Exploration Industry (Marine Pest Sectoral Committee, 2018)); + Performance outcomes and standards are consistent with stakeholder expectations; and + Performance standards have been demonstrated to reduce the impact or risk to ALARP.
6.3 Summary of Risks
Table 6-3 and Table 6-4 summarise the identified hazards and the final consequence ranking (for planned events) and residual risk ranking (for unplanned events) respectively. Planned and unplanned events are all considered acceptable using Santos consequence ranking process. Table 6-5 summarises the potential impacts, risks and control measures for planned events and Table 6-6 summarises the potential impacts, risks and control measures for unplanned events. Table 6-3: Summary of the residual risk rankings associated with planned events
Hazard Final Consequence level Acoustic disturbance to marine fauna A – Negligible Light Emissions A – Negligible Atmospheric Emissions A – Negligible Seabed and benthic habitat disturbance A – Negligible Interaction with other marine users A – Negligible Operational discharges A – Negligible Spill response operations B – Minor Water management on Varanus Island A – Negligible Disturbance of land and native vegetation B – Minor Disturbance to terrestrial fauna B – Minor Remediation activities (soil and groundwater) A – Negligible
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Table 6-4: Summary of the environmental risks for events associated with unplanned events Consequence Likelihood Residual Hazard/Risk risk ranking Introduction of invasive marine D – Major 1 – Rare Medium species Interaction with marine fauna C – Moderate 2 – Very Unlikely Medium Release of solid objects to the A – Negligible 4 – Likely Low environment Hazardous liquid release to the A – Negligible 3 – Unlikely Low marine environment Release from vessel collision D – Major 2 – Very Unlikely Medium (diesel/VI crude blend/HFO) Release from loss of well control C – Moderate 1 – Rare Low Release from pipeline C – Moderate 3 – Unlikely Medium
Release onshore D – Major 2 – Very Unlikely Medium
Accidental discharge (terrestrial) – C – Moderate 3 – Unlikely Medium non-hydrocarbon release
Air emissions A – Negligible 4 – Likely Low
Introduction of non-indigenous flora C – Moderate 2 – Very Unlikely Medium and fauna
Accidental fire C – Moderate 2 – Very Unlikely Medium
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Table 6-5: Potential Impacts, Risks and Control Measures for Planned Events Event Potential Impacts Management Controls/ Performance Standards Marine Underwater Noise generated from vessels Noise and helicopters may result in physiological or behavioural Procedure for interacting with marine fauna – reduces risk of physical and behavioural impacts to marine impacts to marine fauna, fauna from vessels because if they are sighted, then vessels can slow down, or move away, and helicopters especially to cetacean species and UAV’s can increase distances from sighted fauna if required. that use sound for navigation and communication. Light Emissions Artificial lighting has the potential to affect marine fauna Lighting management for onshore facilities and activities and support vessels – external lights to adhere to that use visual cues for minimum lighting levels to reduce light spill to the surrounding environment. A Lighting Management Plan orientation, navigation, or other will provide a coordinated approach to the management of potential impacts from light on marine fauna. purposes, resulting in Manage the timing of activities to avoid peak turtle and Wedge-tailed Shearwater nesting season (1 behavioural responses which October – 30 April) – minimise the potential risk of light spill disturbing shearwater nesting. that can alter foraging and Management of vessel lighting during turtle nesting season (1 October to 30 April) – minimise the potential breeding activity in marine risk of light spill disturbing turtle nesting. reptiles, seabirds, fish and zooplankton; create competitive Vessel loading / unloading is carried out during daylight hours unless in an emergency – reduce risk of advantage to some species; impacts from light emissions on listed marine fauna and reduce reproductive Monitoring of nesting fauna – enables potential impacts to the species to be identified and drives success and/or survival in compliance with regulatory commitments. others. Atmospheric The release of air emissions Facilities planned maintenance system – reduces emissions from the facilities because equipment is Emissions resulting in deterioration of local maintained within its design parameters. and regional air quality and Vessels planned maintenance system – reduce emissions from vessels because equipment is operating contribution to regional, national within its parameters. and global greenhouse gas Fuel oil quality – reduces emissions through use of low sulphur fuel in accordance with Marine Order 97. emissions. International Air Pollution Prevention Certification (IAPP) – reduces probability of potential impacts to air quality due to ODS emissions and high nitrogen oxide, sulphur oxide and incineration emissions. Ozone-depleting substance handling procedures – reduces probability of potential impacts to air quality due to ODS emissions.
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Event Potential Impacts Management Controls/ Performance Standards Waste incineration management – reduces the potential for emissions or particulates by ensuring only permissible waste is incinerated as per Marine Order 97. Manage flaring on VI to meet Santos WA flaring annual target – reduces emissions from flaring. Dust Management Procedures – manages all sources of dust to avoid deterioration in air quality. Monitoring, recording and reporting of gas flows and emissions – enables tracking and quantification of emissions to air. Seabed and Direct physical disturbance of Planned subsea and offshore maintenance – preplanning of subsea and offshore maintenance activities Benthic Habitat benthic and seabed habitat, reduces the risk of impacts to the seabed. Disturbance Indirect disturbance to benthic Anchoring and equipment deployment management – requires using existing moorings or Santos WA habitats and associated marine approved anchor locations within operational area, unless in case of an emergency, to prevent further fauna by sedimentation, seabed disturbance. Increased turbidity of the near- Dropped object prevention procedures (lifting equipment management system (LEMS)) – implementation seabed water column and of a dropped object prevention procedure for equipment deployment, helps to protect the integrity of introduction of marine pest infrastructure on the seabed and equipment being lowered. This in turn minimises impacts and extent of species. seabed disturbance through standards for lifting equipment inspection and maintenance and procedures for lifting. Interaction with The presence of the activity Well head platform (WHP) Petroleum Safety – Petroleum Safety and Cautionary Zones applies around the other marine could potentially inhibit marine offshore platforms and is gazetted on Australian Nautical Charts. users user groups, tourism, Navigational charting of infrastructure – ensure other marine users are aware of the presence of the commercial shipping, fishing pipeline. and other oil and gas activities. Navigation lighting and aids – reduces risk of environmental impact from vessel collisions due to ensuring safety requirements are fulfilled. Seafarer competency and certification – requires appropriately trained and competent personnel to navigate vessels to reduce interaction with other marine users. Constant bridge watch on support vessels – monitoring of surrounding marine environment to identify potential collision risks with other marine users. Stakeholder consultation – Santos WA will update relevant stakeholders on a quarterly basis. Operational Reduction of marine water VI Hub sewage and wastewater management – reduces potential impacts of inappropriate discharge of Discharges quality from planned sewage and wastewater from VI Hub. (operational) discharges Vessel sewage system – reduces potential impacts of inappropriate discharge of sewage.
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Event Potential Impacts Management Controls/ Performance Standards Vessel oily mixtures system – reduces potential impacts of planned discharge of oily water to the environment. Provides compliance with Marine Order 91 Marine Pollution Prevention – Oil. Offshore platform deck drainage sump – reduces potential for oily residue within deck drainage to reach the marine environment. Garbage management procedure – reduces probability of garbage being discharged to sea, reducing potential impacts to marine fauna. Stipulates putrescible waste disposal conditions and limitations. Garbage management placards – provides a visual message to personnel about what wastes can be discharged where. Pipeline/flowline flushing for leak detection and/or breaking containment – reduces potential impacts of poorly managed discharges. Deck cleaning product selection procedure – improves water quality discharge (reduces toxicity) to the marine environment. Domestic and deck cleaning products are biodegradable. Only environmentally acceptable chemicals would be released overboard. Chemical selection procedure – improves water quality discharge (reduces toxicity) to the marine environment. Only environmentally acceptable chemicals would be released overboard (Chemical Disclosure is provided in Appendix A). Spill Response In the event of a hydrocarbon Competent Incident Management Team (IMT) and oil spill responder personnel – ensures that spill Operations spill, response strategies will be response strategy selection and operational activities consider the potential for additional environmental implemented where possible to impacts. reduce environmental impacts Use of competent vessel crew and personnel – reduces potential for environmental impacts from vessel to ALARP. The selection of usage. strategies will be undertaken Vessels and aircraft compliant with Santos WA’s Protected Marine Fauna Interaction and Sighting through the Net Environmental Procedure – reduces potential for behavioural disturbance to cetaceans. Benefit Analysis (NEBA) Select temporary base camps in consultation with DoT and DBCA – reduce coastal habitat and fauna process, outlined in the OPEP. disturbance. Given spill response operations International Air pollution prevention certificate – reduces level of air quality impacts. will be within offshore waters Stakeholder consultation – promotes awareness and reduces potential impacts from response to socio- using vessels and aircraft, the economic activities. types of impact are consistent with vessel and aircraft Vessel sewage system – reduces potential for water quality impacts. operations described within this Oily mixture system – reduces potential for water quality impacts. EP for routine operations. Approved oily water decanting - Reduces impact from discharge of oily water from storage. Frees up space in liquid waste containers to allow further waste collection.
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Event Potential Impacts Management Controls/ Performance Standards Compliance with controlled waste, unauthorised discharge and landfill regulations – ensures correct handling and disposal of oily wastes. Use of shallow draft vessels for shoreline and nearshore operations – reduce seabed and shoreline disturbance. OSR Team Leader assesses and selects vehicles appropriate to shoreline conditions – reduce coastal habitat and fauna disturbance. Conduct shoreline, nearshore habitat, bathymetry assessment – reduce shoreline habitat disturbance. Establish demarcation zones for vehicle and personnel movement considering sensitive vegetation, bird nesting and roosting areas and turtle nesting habitat – reduce coastal habitat and fauna disturbance. Operational restriction of vehicle and personnel movement to limit erosion and compaction – reduce coastal habitat erosion and compaction. Prioritise use of existing roads and tracks – reduce coastal habitat and fauna disturbance. Soil profile assessment prior to earthworks – reduce habitat disruption and erosion. Use of Heritage Advisor if spill response activities overlap with potential areas of cultural significance – reduce disturbance to culturally significant sites. Pre-cleaning and inspection of equipment (quarantine) - Reduces potential for invasive species to offshore islands. Water Planned water management Drainage management and water disposal systems and procedures – reduces risk of environmental impact Management activities may cause local from contaminated water. on Varanus contamination of soil, Chemical selection procedure – aids in the process of chemical management that reduces the risk of Island vegetation and groundwater environmental impact of water discharges including firefighting foam. Only environmentally acceptable from contaminated water/foam products are used. discharge/disposal, soil erosion PFW management and monitoring – the treatment of PFW prior to reinjection reduces risk of environmental from rain and stormwater run- impact from PFW discharges. off and localised turbidity in the Fire water and foam system management and monitoring – discharges from the firewater and foam marine environment from soil monitors/hydrants will occur within the lease to have minimal off-lease impacts. erosion. Disturbance of Operational activities (including Vegetation clearing permitting and management – reduces potential for accidental clearing. Land and remediation) on Varanus Island Quarantine management and weed control – reduces potential for bushfires and impacts to native Native will lead to loss of and/or vegetation. Vegetation disturbance to native vegetation Fire management – ignition sources are controlled to minimise the potential for fire and explosion hazards. and flora species, and may lead
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Event Potential Impacts Management Controls/ Performance Standards to smothering and potential loss Vehicle movement and speed restrictions – minimises the potential for dust to adversely impact native of vegetation from dust, soil vegetation. erosion and the introduction Clearly mark lease boundaries and sensitive environments which have access restrictions – reduces and/or spread of non- potential for accidental clearing and unauthorised disturbance outside of the lease areas. indigenous species. Access restrictions outside lease areas – reduces potential for accidental clearing and unauthorised disturbance outside of the lease areas. Management of Sales Gas Pipelines – drives regulatory compliance and reduces the risk of impacting environmentally significant areas. Monitoring of mangroves and vegetation – enables timely identification of potential mangrove and vegetation mortality. Permit to Work System – reduces potential for indirect impacts to environmentally sensitive areas through increased awareness and consideration of need for additional controls. Varanus Island Site Management Plan – provides an overarching management framework document for the management and ongoing measures with respect to contaminated sites on VI. Disturbance to Operational (including Management of ground disturbance activities (e.g. earthworks) – the preferential scheduling of ground Terrestrial remediation) activities on VI disturbing activities outside the turtle nesting and Wedge-tailed Shearwater nesting season if within 50 m Fauna resulting in behavioural and of rookery / nesting areas will reduces potential disturbance impacts to these conservation significant fauna physiological impacts to species. The provision of fauna escape/exclusion means for excavations reduces the risk of fauna threatened and/or migratory entrapment and injury/death. fauna. Traffic management – reduces potential impacts to conservation significant fauna species. Nearshore activities scheduled around sensitive environmental periods – reduces risk of physical and behavioural impacts from activities to turtles and the Wedge-tailed Shearwater during a period where abundance of the species nearshore will be higher. Environmental monitoring – enables potential impacts to the species to be identified. Shielded ground flares – the HJV and ESJV low pressure ground flares are shielded avoiding the possibility of any impact or disturbance to seabirds and nesting turtles. Varanus Island Site Management Plan – provides an overarching management framework document for the management and ongoing measures with respect to contaminated sites on VI.
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Table 6-6: Environmental Impact Summary for Unplanned Events Event Potential Impacts Management Controls / Performance Standards Introduction of Invasive Unplanned introduction of Implementation of the management controls within the Santos WA Invasive Marine Species Marine Species (IMS) IMS posing a significant Management Plan – the risk of introducing IMS is reduced due to the assessment procedure. risk to environmental Current anti-foulant system – the risk of introducing IMS is reduced due to anti-foulant values, biodiversity, systems. ecosystem health, human Ballast water management plan – the risk of introducing IMS is reduced through procedures health, fisheries, managing ballast water exchange and identifying high risk ballast water. aquaculture, shipping, ports and tourism. Interaction with Marine Vessels or equipment Procedures for interacting with marine fauna – reduces risk of physical and behavioural Fauna involved in operational impacts to marine fauna from vessels, helicopters and UAVs because if they are sighted, activities interacting with vessels can slow down, or move away, and helicopters and UAVs can increase distances marine fauna, including from sighted fauna if required. potential strike or Constant bridge watch on support vessels – monitoring of surrounding marine environment collision, potentially to identify potential collision risks (and reducing harm) to cetaceans and other marine fauna. resulting in severe injury or mortality. Release of Solid Objects to Release of solid objects Garbage management plan – reduces probability of garbage (waste) being accidentally the Marine Environment such as packaging and discharged to sea, reducing potential impacts to marine fauna. Stipulates putrescible (food) hazardous fluorescent waste disposal conditions and limitations. Complies with Marine Order 95: Marine Pollution tubes, medical wastes, Prevention – Garbage. and aerosol cans can be Facilities Planned Maintenance System – requires that lifting equipment is maintained and accidentally released to certified, and that lifting procedures are followed reducing probability of dropped objects the marine environment. occurring. Vessels planned maintenance system – requires that lifting equipment is maintained and certified and that lifting procedures are followed, reducing probability of dropped objects occurring. Dropped object prevention procedure (LEMS) – impacts to environment are reduced by preventing dropped objects. Dropped object recovery – required dropped objects are recovered (where safe and practicable to do so unless the environmental consequences are negligible).
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Event Potential Impacts Management Controls / Performance Standards Hazardous Liquid Release Minor hydrocarbon spill Dropped object prevention procedure (LEMS) – minimises dropped object risk during vessel to the Marine Environment including miscellaneous lifting operations that may cause secondary spill (discharges) resulting in reduction in water chemicals and waste quality. streams which are used Inspection of platform structures and hydrocarbon containing equipment – reduces or stored on facilities, likelihood of leaks from equipment on offshore platforms reaching the marine environment. onboard support vessels Offshore platform deck drain system and bunding – reduces the likelihood of any and onshore. oily/chemical content reaching the marine environment, from the offshore platform. Facilities Planned Maintenance System – inspection and maintenance of equipment provides for safe and efficiently operating equipment less likely to leak/spill. Hazardous chemical management procedures – reduced the risk of spills and leaks (discharges) to sea by controlling the storage, handling and clean-up of hazardous chemicals. General chemical management procedures – potential impacts to the environment are reduced through following correct procedures for the safe handling and storage of chemicals. Spill Response Equipment on producing offshore platforms – provides a means to prevent any deck spills of hazardous liquids reaching the sea. Vessel spill response plan (SOPEP/SMPEP) – implements response plans on board vessels to deal with unplanned hydrocarbon releases and spills quickly and efficiently in order to reduce impacts to the marine environment. Remotely operated vehicle (ROV) inspection and maintenance procedures – maintenance and pre-deployment inspection on ROV completed as scheduled to reduce the risk of hydraulic fluid releases to the marine environment. Hydrocarbon Release from 24-hour surface release of Seafarer competency and certification – requires appropriately trained and competent Vessel Collision (Diesel/VI 8,629 m3 of VI Crude personnel, in accordance with Marine Order 70, to navigate vessels to reduce interaction Crude Blend/HFO) Blend from a vessel to with other marine users. vessel collision in the Navigation lighting and aids – ensures vessels meet minimum safety standards therefore operational area. reducing potential for vessel collision events with associated diesel spill to the environment. Surface release of 1,900 Navigational charting of infrastructure – provides a means for other marine users to be aware m3 HFO from an offtake of the presence of the platforms. tanker collision in the Support vessel positioning – requires vessel to maintain accurate positioning and reduce operational area. potential to impact the platforms.
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Event Potential Impacts Management Controls / Performance Standards Surface release of 329 m3 WHP petroleum safety zone and cautionary zone – petroleum safety zone applies around of diesel from a vessel the offshore platforms and on Australian Nautical Charts to prevent vessel collision with an collision with the Wonnich offshore platform. platform. Dropped object prevention procedures (LEMS) – impacts to the environment are reduced by preventing dropped objects during unloading to platforms that may result in fuel tank rupture. Ensures lifting equipment is certified and inspected. Vessel spill response (SOPEP/SMPEP) – implements response plans on board vessels to deal with unplanned hydrocarbon releases and spills quickly and efficiently in order to reduce impacts to the marine environment. Accepted OPEP – implements response plan to deal with an unplanned hydrocarbon release quickly and efficiently in order to reduce impacts to the marine environment. Refuelling and chemical transfer procedure – minimises the risk of vessel collision during refuelling processes from an offshore support vessel to an offshore facility. Implementation of the Procedure for Port of Varanus Island Marine Operations – covers approval, arrival, mooring, loading and departure of offtake tankers so that offtakes are properly controlled to avoid spill scenario occurring. Tanker mooring and mooring subsea systems are inspected and maintained – inspection, maintenance and repair of the tanker mooring and associated above water and subsea mooring systems reduces the potential for the tanker to lose its moored position (i.e. remains properly controlled). Hydrocarbon Release from Release of Linda, Lee or Approved WMP in place – includes control measures for well integrity and well control. a Loss of Well Control Rose condensate and gas Emergency power equipment is provided on offshore producing platforms to secure could occur from a secondary power source for safety integrity system (SIS) – provides backup power for the production well at the offshore SIS for control of emergency shutdowns in abnormal operation situations. 3 Linda platform (521 m ) or Inspection of platform structures and hydrocarbon containing equipment – regular a release of Bambra inspections reduce the risk of leaks from platform structures/ hydrocarbon containing crude from the Harriet equipment by confirming appropriate integrity. 3 Bravo platform (121 m ). Planned subsea and offshore maintenance – pre-planning of subsea and offshore maintenance activities reduces the risk of impacts to the seabed. Testing and maintenance of emergency shutdown systems and shutdown/safety valves – maintenance and testing of emergency systems and shutdown valves ensures potential spill volumes can be minimised.
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Event Potential Impacts Management Controls / Performance Standards Navigation lighting and aids – reduces risk of environmental impact from vessel collisions due to ensuring safety requirements are fulfilled. Navigational charting of infrastructure – ensures other marine users are aware of the presence of the platform and vessels. Dropped object prevention procedure (LEMS) – impacts to the environment are reduced by preventing dropped objects. Ensures lifting equipment is certified and inspected. Accepted Oil pollution emergency plan (OPEP) – implements response plans to deal with an unplanned hydrocarbon release quickly and efficiently in order to reduce impacts to the marine environment. Well services procedures and criteria – includes control measures for well integrity, well operations and well control. Dropped object recovery – requires dropped objects are recovered (where safe and practicable to do so unless the environmental consequences are negligible). Support vessel positioning – ensures vessel maintain accurate positioning and reduce potential to impact the platform. Hydrocarbon Release from Dropped objects, anchor DMIRS Accepted Operational Pipeline Management Plan (OPMP)/Safety Case – includes Pipeline drag or loss of pipeline control measures for pipeline integrity and management controls. integrity causing a subsea Inspection and corrosion monitoring of pipeline (offshore and onshore) – regular inspections release of: reduce the risk of leaks from subsea pipelines by confirming appropriate integrity. John Brookes Testing and maintenance of emergency shutdown systems and shutdown/safety valves – condensate (210 maintenance and testing of emergency systems and shutdown valves ensures potential spill m3); volumes can be minimised. John Brookes Navigational charting of infrastructure – ensures other marine users are aware of the condensate presence of the platform and vessels. shoreline crossing Dropped object prevention procedures (LEMS) – impacts to the environment are reduced (56 m3); by preventing dropped objects. Ensures lifting equipment is certified and inspected. Halyard Anchoring, mooring and equipment deployment management – anchoring and placement of equipment is controlled through ensuring that any anchoring occurs at pre-approved condensate (16 locations, therefore reducing potential environmental impacts. m3); Accepted Oil pollution emergency plan (OPEP) – implements response plans to deal with Harriet crude (13 an unplanned hydrocarbon release quickly and efficiently in order to reduce impacts to the m3); or marine environment.
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Event Potential Impacts Management Controls / Performance Standards Agincourt crude Dropped object recovery – requires dropped objects are recovered (where safe and (10 m3). practicable to do so unless the environmental consequences are negligible). Hydrocarbon Release Loss of containment from Testing and maintenance of emergency shutdown systems and shutdown/safety valves – Onshore onshore hydrocarbon maintenance and testing of emergency systems and shutdown valves ensures potential spill containing equipment volumes can be minimised. including storage tanks Inspection and corrosion monitoring of pipeline (offshore and onshore) – regular inspections (39,750 m3 VI crude reduce the risk of leaks from subsea pipelines by confirming appropriate integrity. blend, 2 m3 diesel, 115 m3 Dropped object prevention procedures (LEMS) – impacts to the environment are reduced crude oil), onshore by preventing dropped objects. Ensures lifting equipment is certified and inspected. pipelines and processing Accepted Oil Pollution Emergency Plan (OPEP) – implements response plans to deal with equipment could occur an unplanned hydrocarbon release quickly and efficiently in order to reduce impacts to the due to external marine environment. interference. All bunded areas designed, inspected and maintained in accordance with PS-14 Bunding and Open Drains – all bunded areas have been designed to be of sufficient capacity, reducing the risk of unplanned releases. Spill kits and spill response equipment (sorbents, booms, skimmers, clean-up equipment etc.) – the availability of spill response equipment and spill kits on VI enable a timely response to be implemented in the event of a spill to the environment. Groundwater monitoring – Santos WA undertakes routine groundwater monitoring at VI as a lease condition which helps to identify any environment trend in relation to ground water contamination. Accidental Discharge Non-hazardous solid Garbage Management Plan – reduces probability of waste being inappropriately managed (Terrestrial) – Non- wastes including paper, and therefore reducing potential impacts to terrestrial fauna. hydrocarbon Release plastics and packaging, Facilities Planned Maintenance System – inspection and maintenance of equipment and hazardous solid ensures safe and efficiently operating equipment less likely to leak/spill. wastes such as batteries, Dedicated lined chemical laydown areas – captures any spills preventing impacts to fluorescent tubes, medical groundwater. wastes, and aerosol cans Dropped object prevention procedures (LEMS) – impacts to the environment are reduced may be dropped by preventing dropped objects. Ensures lifting equipment is certified and inspected. unintentionally to the Chemical selection procedure – reduced toxicity to the terrestrial environment. receiving environment, Incident Response Plan – reduces escalation of the spread of an unplanned spill.
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Event Potential Impacts Management Controls / Performance Standards potentially impacting on Incident response equipment – access to spill kits will reduce the quantity of chemicals sensitive receptors. potentially entering the environment. Air Emissions Unplanned air emission Facilities Planned Maintenance System – inspection and maintenance of equipment events resulting in short- ensures safe and efficiently operating equipment less likely to leak/spill. term deterioration of local Permit to work system – work and isolation activities are controlled and risk assessed to and regional air quality, reduce the likelihood of unplanned releases. exceedance of one or Flare system – gaseous hydrocarbons released to flare for safe disposal to prevent potential more allowable pollutant explosive atmosphere leading to increased environmental impacts. concentrations under the VI process control system (DCS) – reduces likelihood of gaseous hydrocarbon releases National Environment through use of a DCS. Protection Measure for ambient air quality (Air NEPM) or the National Environment Protection (Air Toxics) Measure (Air Toxics NEPM), and fire and/or explosion. Introduction of Non- Introduction of non- Quarantine management plan – all goods, materials, and equipment destined for VI or AI indigenous Flora and Fauna indigenous flora and are inspected for the presence of soil, vegetative matter and non-indigenous fauna (and fauna species from a treated as required) prior to being shipped to the islands. Monitoring of the presence of mainland or overseas vermin on support vessels to reduce likelihood for introduction to the islands. location to the islands that Environmental monitoring program – environmental monitoring undertaken for non- may allow vermin, weeds indigenous species. The monitoring program includes method statements for weeds and or non-indigenous plants vermin to enable detection and inform the requirement for any control measures. to establish on the islands. Accidental Fire Fire may cause mortality Fire management – ignition sources are controlled to minimise the potential for fire and or injury to fauna, explosion hazards. vegetation and habitat Fire and gas detection systems maintained – provides early detection and warning of fires damage. or accumulation of flammable gas. Permit to Work System – ensure appropriate controls for hot work are in place to manage potential environmental impact from accidental fire.
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Event Potential Impacts Management Controls / Performance Standards Change management procedure –ensures that any changes or new information/ hazards are identified and appropriately managed. Fire and Petroleum Spillage Management Plan – ensures appropriate controls are in place to manage potential incidences. Plant shutdown, isolation and blowdown – provides the means for pipeline isolation remote from the plant preventing gaseous hydrocarbon releases that could lead to explosive atmosphere and fires. All vehicles and equipment shall remain on marked tracks and within designated works areas – reduces potential source of ignition in vegetated areas. Firefighting equipment including fixed and mobile fire water and foam system, and extinguishers available for use – the availability of firefighting equipment will reduce the potential for fires to spread and result in damage. Facilities Planned Maintenance System – inspection and maintenance of equipment ensures safe and efficiently operating equipment less likely to leak/spill. Incident Response Plan – reduce potential escalation of fire.
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7 Management Approach The VI Hub operations activities will be managed in accordance with the Santos WA Environmental Management Policy and with all measures and controls detailed within the EP accepted by DMIRS.
The objective of the EP is to ensure that potential adverse environmental impacts from planned and unplanned events associated with the activity are identified and assessed, and to stipulate mitigation measures to avoid and/or reduce any adverse impacts to the environment to ALARP and acceptable levels.
The EP details specific performance objectives, standards and procedures, and identifies the range of controls to be implemented (consistent with the standards) to achieve the performance outcomes. The EP also identifies the specific measurement criteria and records to be kept to demonstrate the achievement of each performance outcome.
As described in the EP, the implementation strategy includes the relevant details of the following:
Environmental Management System; Environmental Management Policy; Hazard identification, risk and impact assessment and controls; Environmental performance objectives, control measures and performance standards; Leadership, accountability and responsibility; Workforce training and competency; Maintenance management system; Emergency preparedness and response; Incident reporting, investigation and follow-ups; Document management; and Audits and inspections. During the period of the activity described in the EP being undertaken, Santos will ensure environmental performance is monitored and managed through an inspection and monitoring regime undertaken by Santos representatives or delegates. During an activity, frequent HSE inspections will be conducted to verify compliance against selected environmental performance objectives and standards of the EP. Any in-field opportunities for improvement or corrective actions will be discussed during the inspection with the work area supervisor and/or crew and may also be entered into the action tracking management system until closed out, as for non-conformance actions. Inspection reports will be distributed to Santos WA’s relevant personnel (e.g. operations superintendent, Santos WA on-board representatives), and HSE Department representatives, for review. EP non-conformances will be addressed and resolved by a systematic corrective action process as outlined in Santos WA’s Assurance Standard. Non-conformances arising from audits and inspections will be entered into Santos WA’s incident and action tracking management system (i.e. ‘Enablon’). Once entered, corrective actions, time frames and responsible persons (including action owners and event validators) will be assigned. Corrective action ‘close out’ will be monitored using a management escalation process.
Environmental recordable and reportable incidents will be reported to DMIRS, and other regulators as required. The incident reporting requirements will be provided to all crew on board the facilities and support vessels with special attention to the reporting time-frames to provide for accurate and timely reporting. Santos Ltd | EA-60-RI-00176.01 Page 47 of 97
8 Hydrocarbon Spill Response Arrangements The risk assessment for the activity has identified credible spill scenarios as provided in Table 8-1 below. The worst-case spill, requiring the greatest potential level of response in an offshore/nearshore environment is a surface release from a vessel collision (8,629 m3 of VI crude blend) and in an onshore environment is a loss of containment from storage tanks (39,750 m3). Table 8-1: Summary of Maximum Credible Spill (MCS) Scenarios Maximum MCS Scenario Hydrocarbon Types Credible Volume Diesel 329 m3 Surface release from vessel collision HFO 1,900 m3 VI crude blend 8,629 m3 Surface release of diesel from bunker transfer Diesel 15 m3 Linda, Lee and Rose 521 m3 Loss of well control producing assets condensate Bambra crude* 121 m3 Wonnich condensate 270 m3 Harriet crude* 121 m3 Loss of well control non-producing assets Simpson crude* 41 m3 Agincourt crude 109 m3 Double Island crude* 46 m3 John Brookes 210 m3 condensate Loss of integrity/damage resulting in pipeline release* John Brookes 56 m3 condensate – *Wonnich, Campbell/Sinbad, Gypsy, Simpson, Victoria, shoreline crossing Double Island and Gibson pipelines have been flushed 3 with treated seawater therefore no credible hydrocarbon Halyard condensate 16 m spill scenario. Harriet crude 13 m3 Agincourt crude 10 m3 VI crude blend 39,750 m3 Onshore release from storage tanks/pipelines and Diesel 2 m3 hydrocarbon processing VI crude blend 115 m3
The VI OPEP (EA-60-RI-00186.02) was last accepted by DMIRS on 21 July 2017, is due for resubmission and reassessment prior by 21 January 2020. It is considered fit for purpose for the activity and will be referred to in response to accidental hydrocarbon spills, providing guidance on notification and spill response requirements. The response strategies and support arrangements included within the VI OPEP are appropriate for the worst scale spill associated with VI Hub activities. Given that the activity is contained within State waters, any spill requiring Level 2/3 activation will require notification to DoT as the relevant Controlling Agency. Santos WA will provide initial control of the incident and then necessary resources and assistant to support DoT once DoT assumes control of the incident as defined in the OPEP.
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9 Contact Details Details for Santos WA’s Nominated Liaison Person for the activity is as follows:
Name: G. Bamford (Manager – Gas Assets)
Business address: Level 7, 100 St Georges Terrace, Perth, WA 6000
Telephone number: (08) 6218 7100
Email address: [email protected]
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10 References ABARES (Australian Bureau of Agricultural and Resource Economics and Sciences) (2010). Fisheries Status Reports 2010. Australian Government.
ABARES (2018). Fisheries Status Reports 2018. Australian Government. Available from: [http://www.agriculture.gov.au/SiteCollectionDocuments/abares/publications/fsr2018.pdf].
Astron (2012). Varanus and Bridled Islands Mangrove Monitoring Annual Report 2011. Prepared for Apache Energy Limited. Astron Environmental Services, Perth.
Astron (2013). Varanus and Bridled Islands Annual Vegetation Monitoring Report. September 2012. Prepared for Apache Energy. Astron Environmental Services, Perth, WA.
Cardno (2011). Airlie Island and Taunton Reef Habitat Survey. Report prepared for Apache Energy Ltd by Cardno Ecology Lab, Perth, Western Australia, October 2011.
Chevron (2005). Gorgon Development on Barrow Island Technical Report Intertidal Habitats. Technical Appendix C9 prepared by RPS Bowman Bishaw Gorham April 2005 for Chevron Texaco Australia, Perth, Western Australia.
Dames & Moore (1998). Second Sales Gas Pipeline Environmental Assessment and Management Document. Report completed for Apache Energy.
DEC (2007). Management Plan for the Montebello/Barrow Islands Marine Conservation Reserves 2007–2017: Management Plan No. 55. Department of Environment and Conservation, Perth, Western Australia.
DMP (Department of Mines and Petroleum) (2016). Guideline for the Development of Petroleum and Geothermal Environment Plans in Western Australia. Government of Western Australia. DSEWPaC (Department of Sustainability, Environment, Water, Population and Communities) (2012). Marine bioregional plan for the North-west Marine Region, Prepared under the Environment Protection and Biodiversity Conservation Act 1999. Garnett, ST & Crowley, GM (2000). The action plan for Australian birds 2000, recovery outline, lesser noddy (Australian), Environment Australia, Canberra.
ISO (International Organisation for Standardisation) (2018). AS/NZS ISO 31000:2018 Risk Management – Guidelines. Available online: https://www.iso.org/iso-31000-risk-management.html. LEC (1990). Seafloor and Habitat Description Proposed Gas Pipeline Routes. Unpublished report to Hadson Energy by Le Provost Environmental Consultants, October 1990.
Marine Pest Sectoral Committee (2018). National Biofouling Management Guidelines for the Petroleum Production and Exploration Industry. Available online: https://www.marinepests.gov.au.
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Appendix A: Chemical Disclosure & Safety Data Sheets
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A. SYSTEM DETAILS
OPERATOR: SANTOS WA PROJECT / WELL: VARANUS ISLAND HUB SYSTEM: PRODUCED WATER RE-INJECTION SYSTEM TOTAL VOLUME OF SYSTEM: 2,950,000 L/d
B. PRODUCT LIST Produced Formation Water Chemicals NOTE: Specific Ecotox Reports have been provided by the supplier. The data supplied is a more accurate representation of toxicity than the data supplied on the SDSs. Therefore, where reports have been provided, the mammalian and aquatic toxicity from the SDSs have not been included in the Toxicity/Ecotoxicity column. Some chemicals in this disclosure document are listed as contingency and may not be used during the activity NOTE: Other products exempt from Chemical Disclosure: Degreasers (e.g. Caltex Kwik, Simple Green), diesel engine oil (e.g. Delvac 1640), hydraulic fluid (e.g. Mobil DTE 25) and cooking oils may be added to the Produced Formation Water Injection stream in trace quantities.
Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) PFW Not applicable Injection fluid 99.9842 N/A – as per components below N/A 2,949,534 SRN6023 Nalco Champion Corrosion 0.003813 Acute Mammalian Toxicity Yes 112 Inhibitor Component 1 (30-60%) (Data only available for this component) LD50 (Oral) Rat: 7712 mg/kg LC50 (Inhalation) Rat: >2.5 mg/L air LD50 (Dermal) Mouse: >3500 mg/kg Skin irritation Rabbit: Not irritating Eye irritation Rabbit: Not irritating Sensitisation Guinea pig: Not sensitising
Aquatic Toxicity Component 1 (30-60%) OSPAR PLONOR Listed Fish LC50 (96h): 72,860 mg/L (Pimephales promelas) Crustacean LC50(48h): >100 mg/L (Daphnia magna Algae EC50 (96h): 6500 mg/L (Selenastrum capricornutum)
Component 2 (1-10%) Fish LC50 (96h):1.34mg/L (Scophthalmus maximus) Crustacean LC50 (48h):0.21 mg/L (Acartia tonsa) Algae EC50 (72h):0.0009 mg/L (Skeletonema costatum)
*Component 3 (1-10%) Fish LC50 (96h): 1-10 mg/L* Crustacean LC50 (48hr): <1 mg/L*
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Algae EC50(72hr): <1 mg/L* *Estimated data based on structural analogue
Component 4 (1-10%) Fish LC50 (96hr):>0.2 mg/L (Limit test, Sheepshead minnow) Crustacean LC50 (48h): 1.23 mg/L (Acartia tonsa) Algae EC50 (72h): 0.19 mg/L (Skeletonema costatum)
Component 5 (1-10%) Fish LC50 (96h): 4.35 mg/L Crustacean LC50 (48h): 43.51 mg/L Algae EC50 (72h): 4.36 mg/L (Component 5 data based on WAF test)
Component 6 (1-10%) Fish LC50 (96h): :>18 mg/L (Limit test, Sheepshead minnow) Crustacean LC50 (48h): 32.6 mg/L (Acartia tonsa) Algae EC50 (72h): 98.58 mg/L (Skeletonema costatum)
Component 7 (1-10%) Fish LC50 (96h): 6.1 mg/L (Zebra fish)* *Based on supplier data, no other data available.
Component 8 (1-10%) Fish LC50 (96h): 2100 mg/L (Sheepshead minnow) Crustacean LC50 (48h): 1195 mg/L (Acartia tonsa) Algae EC50 (72h): 1100 mg/L (Skeletonema costatum)
Component 9 (<1%) OSPAR PLONOR Listed Component 10 (<0.1%) Fish LC50 (96h): 52 mg/L Crustacean LC50 (48h): 439 mg/L Algae EC50 (72h): 375 mg/L (Component 10 data based on WAF test)
Component 11 (<0.01%) Fish LC50 (96h): 174 mg/L Crustacean LC50 (48h): 562 mg/L Algae EC50 (72h): 710 mg/L (Component 11 data based on WAF test)
Component 12 (<0.01%) Fish LC50 (96h): 7.72 mg/L (Fathead minnow) Crustacean LC50 (48h): 17 mg/L ((Cancer magister, Dungeness or edible crab) Algae EC50 (72h): Not available
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) (Literature data from NZ HSNO CCID)
Component 13 (<0.01%) Fish LC50 (96h): 1.2 mg/L (Pink salmon) Crustacean LC50 (48h): 2.16 mg/L (Daphnia magna) Algae EC50 (72h): ~0.4 mg/L (Skeletonema costatum) (Literature data from NZ HSNO CCID)
Component 14 (<0.01%) Fish LC50 (96h): 4.2 mg/L (Oncorhynchus mykiss) Crustacean LC50 (48h): 2.16 mg/L (Daphnia magna) Algae EC50 (72h): 4.6 mg/L (Selenastrum capricornutum) (Literature data from NZ HSNO CCID)
Chronic Toxicity Risk of cancer and heritable genetic damage. Sensitization due to skin contact. Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (30-60%) OSPAR PLONOR Listed
Component 2 (1-10%) Biodegradation (28d): 38% (Marine BODIS)
Component 3 (1-10%) Biodegradation (28d): ~40% (Estimate based on structural analogue)
Component 4 (1-10%) Biodegradation (28d): 41% (OECD 306)
Component 5 (1-10%) Biodegradation (28d): 23% (OECD 306)
Component 6 (1-10%) Biodegradation (28d): 21% (OECD 306)
Component 7 (1-10%) Biodegradation (28d): 56.6% *Based on supplier data
Component 8 (1-10%) Biodegradation (28d): 68% (OECD 306)
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Component 9 (<1%) OSPAR PLONOR Listed
Component 10 (<0.1%) Biodegradation (28d): 86% (OECD 306)
Component 11 (<0.01%) Biodegradation (28d): 71% (OECD 306)
Component 12 (<0.01%) Biodegradation (28d): <60 (Literature data from NZ HSNO CCID)
Component 13 (<0.01%) Biodegradation (28d): >60 (Literature data from NZ HSNO CCID)
Component 14 (<0.01%) Biodegradation (28d): >60 (Literature data from NZ HSNO CCID)
Octanol/Water Partition Coefficient Component 1 (30-60%) OSPAR PLONOR Listed
Component 2 (1-10%) Log Pow:6.0
Component 3 (1-10%) Log Pow:6.0 (Estimate based on structural analogue)
Component 4 (1-10%) Log Pow: Not applicable, surface active
Component 5 (1-10%) Log Pow: Not applicable, surface active Component 6 (1-10%) Log Pow: -0.8
Component 7 (1-10%) Log Pow: 2.67 *Based on supplier data
Component 8 (1-10%) Log Pow: 1.6
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded)
Component 9 (<1%) PLONOR
Component 10 (<0.1%) Log Pow: 4.6
Component 11 (<0.01%) Log Pow: 3.4
Component 12 (<0.01%) Log Pow: <3 (Literature data from NZ HSNO CCID)
Component 13 (<0.01%) Log Pow: >3 (Literature data from NZ HSNO CCID)
Component 14 (<0.01%) Log Pow: <3 (Literature data from NZ HSNO CCID) WCW24160 Baker Hughes Corrosion/ 0.00407 Acute Mammalian Toxicity Yes 120 Scale Inhibitor Component 1 (30-60%) Natural product – exempted under Chemical Disclosure Guidelines
Component 2 (10-30%) Specie: Mouse LD50 (Dermal): > 3500 mg/kg
Component 3 (10-30%) Specie: Rat LD50 (Oral): 4500 mg/kg
Component 4 (5-10%) No scientific data or research is available for this component.
Component 5 (5-10%) No scientific data or research is available for this component
Component 6 (5-10%) Specie: Rat LD50 (Intraperitoneal): 4420 mg/kg
Component 7 (1-5%) Specie: Rat LD50 (Oral): > 5000 mg/kg
Component 8 (1-5%) Specie: Rat LD50 (Oral): 304.5 mg/kg
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded)
Component 9 (1-5%) No scientific data or research is available for this component.
Chronic Toxicity No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects for this product.
Aquatic Toxicity Component 1 (30-60%) Natural product – exempted under Chemical Disclosure Guidelines Component 2 (10-30%) Specie: Skeletonema costatum (marine algae) EC50 (96h): 1000 - 5000 mg/L Specie: Daphnia magna (freshwater invertebrate) EC50 (48h):47 400 mg/L Specie: Pimephales promelas (freshwater fish) LC50 (96h):69 518 mg/L
Component 3 (10-30%) Specie: Skeletonema costatum (marine algae) EC50 (72h):2700 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h):3200 mg/L Specie Cyprinodon variegatus (marine fish) LC50 (96h):2828 mg/L
Component 4 (5-10%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 0.23 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 0.55 mg/L Specie Scophthalmus maximus (marine fish) LC50 (96h):1.16 mg/L
Component 5 (5-10%) Specie: Selenastrum capricornutum (freshwater algae) EC50 (96h): 3 mg/L Specie: Ceriodaphnia dubia (freshwater invertebrate) LC50, 48(h): 509 mg/L Specie: Pimephales promelas (freshwater fish) LC50 (96h): 42 mg/L
Component 6 (5-10%) Specie: Scenedesmus quadricauda (freshwater algae) EC50 (8 days): > 10,000 mg/L Specie: Daphnia magna (freshwater invertebrate) EC50 (24h): > 10,000 mg/L Specie: Carassius auratus (freshwater fish) LC50 (24h): > 5 000 mg/L
Component 7 (1-5%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 58 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h) = 6.2 mg/L Specie: Cyprinodon variegatus (marine fish) LC50 (96h) >1000 mg/L
Component 8 (1-5%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 58 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 6.2 mg/L Specie: Cyprinodon variegatus (marine fish) LC50 (96h): 1000 mg/L
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Component 9 (<1%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 3200 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 3200 mg/L Specie: Scophthalmus maximus (marine fish) LC50 (96h): 3212 mg/L
Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Method OECD 306 Biodegradability 28 days: 81%
Component 3 (10-30%) Method: OECD 306 Biodegradability 28 days: 85%
Component 4 (5-10%) Method: OECD 306 Biodegradability 30 days: 62%
Component 5 (5-10%) Method: 306 Biodegradability 28 days: 5% Component 6 (5-10%) Method: OECD 306 Biodegradability 30 days: 92%
Component 7 (1-5%) Method: OECD 306 Biodegradability 28 days: 52%
Component 8 (1-5%) No scientific data or research is available for this component
Component 9 (1-5%) Not applicable to inorganic substances
Octanol/Water Partition Coefficient Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Method: OECD 117 (HPLC) Log (Pow): < 0
Component 3 (10-30%) Method: OECD 117 (HPLC) Log (Pow): -1.40 to 1.31
Component 4 (5-10%) Not applicable to surfactants
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded)
Component 5 (5-10%) Method: Calculation Log (Pow): -1.76
Component 6 (5-10%) Method: OECD 117 (HPLC) Log (Pow): -1.76
Component 7 (1-5%) Not applicable to Surfactants Component 8 (1-5%) No scientific data or research is available for this component
Component 9 (1-5%) Not applicable to inorganic TRETOLITETM Baker Hughes Water Clarifier 0.00180 Acute Mammalian Toxicity Yes 53 RBW24136 Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) No scientific data or research is available for this component.
Component 3 (1-5%) Specie: Rat (oral): 273 mg/kg
Chronic Toxicity No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects for this product.
Aquatic Toxicity Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guideline
Component 2 (10-30%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 0.64 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 0.68 mg/L Specie: Scaphthalmus maximus (marine fish) LC50 (96h): 143.8 mg/L
Component 3 (1-5%) Specie: Ceriodaphnia dubia (freshwater invertebrate) EC50 (48h): 56 mg/L Specie: Gambusia affinis (freshwater fish) LC50 (96h): 80 mg/L Specie: Freshwater algae EC50 (72h): No relevant data available due to known pH effects.
Biodegradation / bioaccumulation Ready Biodegradability Test
Component 1 (60-100%)
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Method: OECD 306 Biodegradability 28 days; 29%
Component 3 (1-5%) Not applicable to inorganic substances
Octanol/Water Partition Coefficient Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Method: OECD 117 (HPLC) Log (Pow): 2.6
Component 3 (1-5%) Not applicable to inorganic substances
TRETOLITETM Baker Hughes Water Clarifier 0.00180 Acute Mammalian Toxicity Yes 53 RBW24362 Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (30-60%) No scientific data or research is available for this component
Chronic Toxicity No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects are associated with this product.
Aquatic Toxicity Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (30-60%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 203.4 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 259.2 mg/L Specie: Scaphthalmus maximus (marine fish) LC50 (96h): 205.02 mg/L
Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure
Component 2 (30-60%) Method: OECD 306: Biodegradability 28 days: 34%
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded)
Octanol/Water Partition Coefficient Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure
Component 2 (30-60%) Method: OECD 117 (HPLC) Log (Pow): < 0 XC24117 Baker Hughes Biocide 0.00132 Acute Mammalian Toxicity Yes 39 Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Specie: Rat LD50 (oral): 200 mg/kg
Component 3 (1-5%) Specie: Rat LD50 (oral): 426 mg/kg
Component 4 (0.1-1%) Specie: Rat LD50 (oral): 2528 mg/kg
No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects for this product.
Aquatic Toxicity Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 0.35 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 3.6 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): 25 mg/L
Component 3 (1-5%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 0.1 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 0.3 mg/L Specie: Sheephead minnow (marine fish) LC50 (96h): 1.3 mg/L Component 4 (0.1-1%) Specie: Chlorella pyrenoidosa (freshwater algae) EC50 (72h): 36 000 mg/L Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 3 289 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): 15 500 mg/L
Biodegradation / Bioaccumulation
Ready Biodegradability Test
Component 1 (60-100%)
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Natural product – exempted under the Chemical Disclosure Guidelines.
Component 2 (10-30%) Method: OECD 306 Biodegradability 28 days: 73%
Component 3 (1-5%) Method: OECD 306 Biodegradability 28 days: 95%
Component 4 (0.1-1%) Method: APHA Biodegradability 20 days: 95%
Octanol/Water Partition Coefficient Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Method: OECD 117 (HPLC) Log (Pow): < 0
Component 3 (1-5%) Not applicable to surfactants
Component 4 (0.1-1%) Method: OECD 117 (HPLC) Log (Pow): < 0 CRW24006 Baker Hughes Corrosion 0.00071 Acute Mammalian Toxicity* Yes 21 Inhibitor Component 1 (10-30%)
LC50 (14 days) >4000 mg/kg bw (Rat)
Component 2 (10-30%)
LC50 (14 days) 2410 mg/kg bw (Mouse)
Component 3 (5-10%)
LC50 3530 mg/kg bw (Rat)
Component 4 (1-5%) No scientific data or research is available for this component
Component 5 (1-5%)
LC50 (14 days) 73 mg/kg bw (Rat)
Component 6 (0.1-1%)
LC50 (14 days) 5840 mg/kg bw (Rat)
Component 7 (0.1-1%)
LC50 (14 days) 1553 mg/kg bw (Rat)
Component 8 (30-60%)
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Not applicable - exempted under the Chemical Disclosure Guidelines
*All mammalian toxicity values are based upon 100% active material
Chronic Toxicity No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects for this product.
Aquatic Toxicity Component 1 (10-30%)
LC50 (48h): 0.67 mg/L (Acartia tonsa) NOEC (48h): 0.12 mg/L (Acartia tonsa)
EC50 (72h): 0.17 mg/L (Skeletonema costatum) NOEC (72h): 0.10 mg/L (Skeletonema costatum)
LC50 (96h): 1.27 mg/L (Sheepshead minnow) NOEC (96h): 0.96 mg/L (Sheepshead minnow)
Component 2 (10-30%)
LC50 (48h): 2850 mg/L (Daphnia magna)
EC50 (72h): 500 to 5000 mg/L (Skeletonema costatum)
LC50 (96h): 1300 mg/L (Bluegill sunfish)
Component 3 (5-10%) OSPAR PLONOR Listed
Component 4 (1-5%)
LC50 (48h): 0.3 mg/L (Acartia tonsa) NOEC (48h): 0.05 mg/L (Acartia tonsa)
EC50 (72h): 0.1 mg/L (Skeletonema costatum) NOEC (72h): 0.03 mg/L(Skeletonema costatum)
LC50 (10d): 38 mg/kg (Corophium volutator) NOEC (10d): 25 mg/kg (Corophium volutator)
LC50 (96h): 1.1 mg/L (Sheepshead minnow) NOEC (96h): 0.5 mg/L (Sheepshead minnow)
Component 5 (1-5%) EC50 (96h): 30 mg/L Fathead minnow
Component 6 (0.1-1.0%) OSPAR PLONOR listed
Component 7 (0.1-1%) EC50 (72h): >20 mg/L (Skeletonema costatum)
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Component 8 (30-60%) Not applicable - exempted under the Chemical Disclosure Guidelines
Biodegradation / Bioaccumulation
Ready Biodegradability Test
Biodegradability 28 days (Component 1) 47% Biodegradability 28 days (Component 2) 69% Biodegradability 28 days (Component 3) PLONOR Biodegradability 28 days (Component 4) 100% Biodegradability 28 days (Component 5) Not available Biodegradability 28 days (Component 6) PLONOR Biodegradability 28 days (Component 7) Not available Biodegradability 28 days (Component 8) Not applicable - exempted under the Chemical Disclosure Guidelines
Octanol/Water Partition Coefficient Log Pow (Component 1) 2.29 Log Pow (Component 2) 0.20 Log Pow (Component 3) PLONOR Log Pow (Component 4) Surfactant Log Pow (Component 5) 0.09 Log Pow (Component 6) PLONOR Log Pow (Component 7) -2.13 Log Pow (Component 8) Not applicable - exempted under the Chemical Disclosure Guidelines XC24380 Baker Hughes Biocide 0.00047 Acute Mammalian Toxicity Yes 14 Component 1 (60-100%) LD50 (oral): 575 mg/kg
Component 2 (10-30%) Natural product – exempted under the Chemical Disclosure Guidelines Aquatic Toxicity Component 1 (60-100%)
LC50 (96h): 72.5 mg/L Scophthalmus maximus
EC50 (72h): 0.16 mg/L Skeletonema costatum
LC50 (48h): 0.60 mg/L Acartia tonsa
Component 2 (10-30%) Natural product – exempted under the Chemical Disclosure Guidelines Chronic Toxicity No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H40) or reproductive (H360, H362) effects for this product. A component of this product does carry the following Hazard statement: H3161 – Suspected of damaging the unborn child. Biodegradation / Bioaccumulation
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded)
Ready Biodegradability Test Component 1 (60-100%) Ready Biodegradability (Method OPPTS 835.4300) Biodegradability, 7 days 60%
Component 2 (10-30%) Natural product – exempted under the Chemical Disclosure Guidelines Octanol/Water Partition Coefficient Component 1 (60-100%) Method: OECD 117 (HPLC)
Log Pow < 0
Component 2 (10-30%) Natural product – exempted under the Chemical Disclosure Guidelines. CRW24830 Baker Hughes Corrosion 0.00034 Acute Mammalian Toxicity Yes 10 Inhibitor Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines.
Component 2 (10-30%) No scientific data or research is available for this component.
Component 3 (10-30%) OSPAR PLONOR Listed
Component 4 (5-10%) Specie Rat (Oral) LD50: 4500 mg/kg
Component 5 (5-10%) Specie Rat (Oral): 426 mg/kg
Component 6 (5-10%) OSPAR PLONOR Listed
Component 7 (<1%) Specie: Rat (Oral) LD50: 6720 mg/kg
Aquatic Toxicity Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Specie: Skeletonema costatum (marine algae) EC50 (72h).: 0.15 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 1.1 mg/L Specie: Cyprinodon variegatus (marine fish) LC50 (96h): >0.1 mg/L
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Component 3 (10-30%) OSPAR PLONOR Listed
Component 4 (5-10%) Specie: Skeletonema costatum (marine algae) EC50 (48h): 500 – 5000 mg/L Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 2850 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): 1300 mg/L
Component 5 (5-10%) Specie: Algae: No scientific data or research is available for this component at this trophic level. Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 0.08 mg/L Specie: Pimephales promelas (freshwater fish) LC50 (96h): 0.66 mg/L
Component 6 (5-10%) OSPAR PLONOR Listed
Component 7 (<1%) Specie: Chlorella sp. (freshwater algae) EC50 (48h): >10 mg/L Specie: Daphnia pulex (freshwater invertebrate) LC50 (48h): 337 mg/L Specie: Scophthalmus maximus (marine fish) LC50 (96h): 423 mg/L
Chronic Toxicity No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects for this product.
Biodegradation / Bioaccumulation
Readily Biodegradability Test Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Method: OECD 306 Biodegradability 28 days: 39%
Component 3 (10-30%) OSPAR PLONOR Listed
Component 4 (5-10%) Method: OECD 306 Biodegradability 28 days: 75%
Component 5 (5-10%) No scientific data or research is available for this component.
Component 6 (5-10%) OSPAR PLONOR Listed
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Component 7 (<1%) No scientific data or research is available for this component.
Octanol/Water Partition Coefficient Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Not accumulative, molecular weight (MW) > 700
Component 3 (10-30%) OSPAR PLONOR Listed
Component 4 (5-10%) Method: OECD 177 (HPLC) Log (Pow): 0.2
Component 5 (5-10%) Not applicable to surfactants
Component 6 (5-10%) OSPAR PLONOR Listed
Component 7 (<1%) Method” OECD 117 (HPLC) Log (Pow): 3.35 CRW24200 Baker Hughes Packing Fluid 0.00060 Acute Mammalian Toxicity Yes 18 Corrosion Component 1 (60-100%) Inhibitor Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (5-10%) Specie: Mouse LD50 (oral): 2410 mg/kg
Component 3 (5-10%) No scientific data or research is available for this component. Data are presented for a similar ingredient. Specie: Rat LD50 (oral): >500 mg/kg Component 4 (5-10%) Specie: Rat LD50 (oral): 156 mg/kg
Component 5 (1-5%) Specie: Rat LD50 (oral): 344 mg/kg
Component 6 (1-5%) Specie: Rat LD50 (oral): > 2000 mg/kg
Component 7 (1-5%) Specie: Rat LD50 (oral): > 6000 mg/kg
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded)
Component 8 (1-5%) Specie: Rat LD50 (oral): > 5000 mg/kg
Component 9 (<0.1%) Specie: Rat LC50 (oral): 5840 mg/kg
Chronic Toxicity A component of this product is suspected of damaging fertility (R61). There are no known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects for this product.
Aquatic Toxicity Component 1 (60-100%) Natural product – exempted under Chemical Disclosure Guidelines
Component 2 (1-5%) Specie: Scenedesmus subspicatus (freshwater algae) EC50: (96h) > 100 mg/L Specie: Daphnia magna (freshwater invertebrate) EC50 (48h): > 100 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): > 1300 mg/L
Component 3 (5-10%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 0.2 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h):1.1 mg/L Specie: Cyprinodon variegatus (marine fish) LC 50 (96h): > 0.1 mg/L
Component 4 (5-10%) Specie: Pseudokirchneriella subcapitata (freshwater algae) EC50 (72h): 29.3 mg/L
Component 5 (1-5%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 0.089 mg/L
Component 6 (1-5%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 267.8 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 94.25 mg/L Specie: Cyprinodon variegatus (marine fish) LC50 (96h): 230.1 mg/L
Component 7 (1-5%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 97.9 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 94.25 mg/L Specie: Cyprinodon variegatus (marine fish) LC50 (96h): 230.1 mg/L
Component 8 (<0.1%) Specie: Scenedesmus subspicatus (freshwater algae) EC50 (96h): 0.205 mg/L Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 95 mg/L Specie: Oncorhynhcus mykiss (freshwater fish) LC50 (96h): 27 mg/L)
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded)
Component 9 (<0.1%) Specie: Scenedesmus quadricauda (freshwater algae) EC50 (8d): 1800 mg/L Specie: Daphnia magna (freshwater invertebrate) LC50 (24h): > 10 000 mg/L Specie: Pimpephales promelas (freshwater fish) LC50 (96h): 9640 mg/L
Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (60-100%) Natural product – exempted under Chemical Disclosure Guidelines
Component 2 (5-10%) Method: OECD 301C Biodegradability 28 days: > 85%
Component 3 (5-10%) Method: OECD 306 Biodegradability 28 days: 39%
Component 4 (5-10%) Method: OECD 301D Biodegradability 20 days: > 92%
Component 5 (1-5%) Method: OECD 301B Biodegradability 28 days: > 95.5%
Component 6 (1-5%) Not applicable to inorganic compounds
Component 7 (1-5%) Method: OECD 301D Biodegradability 28 days: 80-90%
Component 8 (<0.1%) Method: OECD 301D Biodegradability 28 days: 76%
Component 9 (<0.1%) Method : OECD 301D Biodegradability 28 days: 76% Octanol/Water Partition Coefficient
Component 1 (60-100%) Natural product – exempted under Chemical Disclosure Guidelines
Component 2 (5-10%) Method: OECD 117 (HPLC) Log (Pow): 1.40 to 1.31 (Wt. avg = 0.2)
Component 3 (5-10%) Not applicable to surfactants
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Component 4 (5-10%) Method: OECD 117 (HPLC) Log (Pow): 1.9
Component 5 (1-5%) Not applicable to Surfactants
Component 6 (1-5%) Not applicable to inorganic substances
Component 7 (1-5%) Method: OECD 117 (HPLC) Log (Pow): <0
Component 8 (<0.1%) Method: Calculated (EPA Epi-Suite KOWWIN) Log (Kow): <0
Component 9 (<0.1%) Method: Calculated (EPA EPI-Suite KOWWIN) Log (Kow): 0.28 CRO24009 Baker Hughes Corrosion 0.00031 Acute Mammalian Toxicity Yes 9 Inhibitor Component 1 (60-100%) No scientific data or research is available for this component. Data are presented for a similar ingredient. Specie: Rat LD50 (Oral): > 5000 mg/kg
Component 2 (10-30%) No scientific data or research is available for this component. Data are presented for similar ingredient. Specie: Mouse LD50 (Oral): 2410 mg/kg
Component 3 (1-5%) Specie: Rat LD50 (Oral): 2410 mg/kg
Component 4 (0.1-1%) No scientific or research is available for this component. Data are presented for a similar ingredient. Specie: Rat (Oral): 1080 mg/kg
Component 5 (0.1-1%) No scientific or research is available for this component OSPAR PLONOR Listed
Component 6 (<0.1%) No scientific data or research is available for this component. Data are presented for a similar ingredient. Specie: Rat LD50 (Oral): 1553 mg/kg
Chronic Toxicity
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects for this product.
Aquatic Toxicity Component 1 (60-100%) Specie: Pseudokirchneriella subcapita (freshwater algae) EC50 (72 h).: 1.0 mg/L o Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 1.4 mg/L o Specie: Oncorhynchus mykiss (freshwater fish) LC50 (96h): 2 - 5 mg/L
Component 2 (10-30%) Specie: Scenedesmus subspicatus (freshwater algae) EC50, 72 hours.: >100 mg/L Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): >100 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): 1300 mg/L
Component 3 (1-5%) Specie: Skeletonema costatum (marine algae) EC50 (72h).: 0.08 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 5.0 mg/L Specie: Sheepshead minnow (marine fish) LC50 (96h): 2.3 mg/L
Component 4 (0.1-1%) Specie: Pseudokirchneriella subcapita (freshwater algae) EC50 (72 h): 112 mg/L Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 38.5 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): 6.5 mg/L
Component 5 (0.1-1%) OSPAR PLONOR Listed
Component 6 (<0.1%) No scientific data or research is available for this component. Data are presented for a similar ingredient. Specie: Pseudokirchneriella subcapita (freshwater algae) EC50 (72 h): 345 mg/L Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 64.6 mg/L Specie: Poecilia reticulata (freshwater fish) LC50 (96h): 0.43 mg/L Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (60-100%) No scientific data or research is available for this component. Data are presented for a similar ingredient. Method: OECD 306 Biodegradability 28 days: 32%
Component 2 (10-30%) Method: OECD 301C Biodegradability 28 days: >80%
Component 3 (1-5%) Method: OECD 306 Biodegradability 28 days: 45%
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded)
Component 4 (0.1-1%) Method: OECD 301B Biodegradability 28 days: 85%
Component 5 (0.1-1%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 6 (<0.1%) Method: OECD 301D Biodegradability 28 days: 87%
Octanol/Water Partition Coefficient Component 1 (60-100%) Method: OECD 117 (HPLC) Log (Pow): 6.16-6.45
Component 2 (10-30%) Method: OECD 117 (HPLC) Log (Pow): 0.2
Component 3 (1-5%) Method: OECD 117 (HPLC) :Log (Pow): 4.27 Component 4 (0.1-1%) Method: EPA EPI Win software estimate (Log (pow): 2.997
Component 5 (0.1-1%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 6 (<0.1%) Method: EPA EPI Win software estimate (Log (pow): -2.13 WAO24026 Baker Hughes Antifoulant 0.00027 Acute Mammalian Toxicity Yes 8 Component 1 (60-100%) Specie: Rat LD50 (oral): > 2000 mg/kg
Component 2 (10-30%) No scientific data or research is available for this component. Data are presented for similar ingredient. Specie: Rat (oral): 4500 mg/kg
Component 3 (1-5%) Specie: Rat LD50 (oral): 4290 mg/kg
Chronic Toxicity A component of this product does carry the following Hazard Statement: H351 - Suspected of causing cancer There are no known carcinogenic (H350), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects for this product.
Aquatic Toxicity
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Component 1 (30-60%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 13.5 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h):1264.9 mg/L Specie: Cyprinodon variegatus (marine fish) LC50 (96h): 11.3 mg/L
Component 2 (10-30%) Specie: Skeletonema costatum (marine algae) EC50 (96h): 2700 mg/L Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 2850 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): 1300 mg/L
Component 3 (1-5%) Specie: Pseudokirchneriella subcapitata (freshwater algae) LC50 (96h): 12 mg/L Specie: Daphnia magna (freshwater invertebrate) EC50 (48h): 14 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (24h): 15 mg/L
Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (30-60%) Method: OECD 306 Biodegradability 28 days: 71%
Component 2 (10-30%) Method: OECD 306 Biodegradability 28 days: 85%
Component 3 (1-5%) Method: OECD 306 Biodegradability 28 days: 28 days: 82%
Octanol/Water Partition Coefficient Component 1 (60-100%) Method: OECD 117 (HPLC) Log (Pow): 3.33 to 5.29
Component 2 (10-30%) Method: OECD 117 (HPLC) Log (Pow): -1.40 to 1.31
Component 3 (1-5%) Not applicable to surfactants MEG Water Baker Hughes Hydrate 0.00019 Aquatic Mammalian Toxicity Yes 6 (90:10) Inhibitor Ethanediol (60-100%) OSPAR PLONOR Listed
LD50 Dermal 9530 µL/kg
LD50 Oral Rat 4700 mg/kg
Chronic Toxicity No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects for this product.
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Aquatic Toxicity Ethanediol (60-100%) OSPAR PLONOR Listed
LC50 (96 hours) >18500 mg/L (Oncorhynchus mykiss)
Biodegradation / Bioaccumulation Ethanediol (60-100%) OSPAR PLONOR Listed DFO24986 Baker Hughes Defoamer 0.00005 Acute Mammalian Toxicity Yes 1.5 Component 1 (60-100%) Specie: Rat LD50 (oral): 5840 mg/kg
Chronic Toxicity No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects are associated with this product.
Aquatic Toxicity Component 1 (60-100%) Specie: Daphnia magna (Freshwater invertebrate) EC50 (48h): 95 mg/L mg/L Specie: Selenastrum capricornutum EC50(h): 112 mg/L Specie: Pimephales promelas (freshwater fish) LC50 (96h): 50 mg/L
Biodegradation / Bioaccumulation Component 1 (60-100%) Method: EPA Suite Ready Biodegradability Prediction: Yes
Octanol/Water Partition Coefficient (Method OECD 117 (HPLC))
Log Pow = 1.18 to 4.37 Jefftreat MP Huntsman Gas treatment 0.00001 Acute Mammalian Toxicity Yes 0.3 Amine agent Amine compound
LD50 Dermal 11336 mg/kg (Rabbit – female)
LD50 Dermal 10244 mg/kg (Rabbit – male)
LC50 Oral 4680 mg/kg (Rat – male & female) 3 LC50 Inhalation dusts and mists >6.5 mg/m (Rat – male & female)
Piperzine
LD50 Dermal 8300 mg/kg (Rabbit – male & female)
LD50 Oral 2600 mg/kg (Rat – male & female)
Chronic Mammalian Toxicity Amine compound Sub-chronic NOAEL Dermal (90 days; 5 days per week) 750 mg/kg (Rat – male & female)
Piperzine
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Sub-chronic NOAEL Oral (90 days; 7 days per week) 627 mg/kg/d (Rat – male & female) Sub-acute LOAEL Oral (7 days) 30 mg/kg/d (Human) No carcinogenic (R40, R45, R49) or mutagenic (R46) effects are known.
Teratogenicity toxicity – May cause birth defects, based on animal data. Amine compound NOAEL Negative - Dermal >1000 mg/kg (9 days; 6 hours per day) (Rat – Male & Female)
Piperazine NOAEL Negative – Oral 2100 mg/kg (10 days; 7days per week) (Rat – Male & Female) Reproductive toxicity – Oral 125 mg/kg NOAEL Rat male, female May impair fertility, based on animal data. R62 – Possible risk of impaired fertility R63 – Possible risk of harm to the unborn child.
Aquatic Toxicity Amine compound
EC50 (17h) Bacteria: 413.8 mg/L
EC50 (48) Daphnia: 233 mg/L
ErC50 (72h) Algae: 176 mg/L
LC50 (96h) Fish: 1000 to 2200 mg/L
Piperazine
EC50 (48h) Daphnia: 21 mg/L
LC50 (96h): > 1800 mg/L Fish
Chronic Aquatic Toxicity Piperazine NOEC (30 min)_: 540 mg/L Bacteria NOEC (21d): 12.5 mg/L Daphnia NOECr (72h) Algae: >1000 mg/L
Biodegradation / Bioaccumulation
Ready Biodegradability Test Amine compound Method: OECD 301A 96% Readily biodegradable in 18 days (41 mg/L DOC)
Piperazine Ready Biodegradability (Method OECD 301F) 70.2% Readily biodegradable in 28 days
Octanol/Water Partition Coefficient Amine compound
Log Pow -1.08 BCF 3.16
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Product in Volume (L) Product Name Supplier Purpose Toxicity & Ecotoxicity Information SDS Attached System (%) (Note. These volumes are rounded) Piperazine
Log Pow -1.24 Triethylene Huntsman Gas Treatment 0.00001 Acute Mammalian Toxicity Yes 0.3 Glycol (TEG) Agent Whole Product LC50 Oral: 18 000 mg/kg (Rat)
Chronic Toxicity No known carcinogenic (R40, R45, R49), chronic (R33, R39, R48, R68), mutagenic (R46) or reproductive (R60, R61, R62, R63, R64) effects for this product.
Aquatic Toxicity Whole Product LC50 (96h): > 10 000 mg/L Fish
Triethylene glycol EC50 (48h): 39 305 mg/L
Biodegradation / Bioaccumulation Whole Product Ready Biodegradability Test Biodegradation: > 70% (28 days)
Octanol/Water Partition Coefficient No scientific data or research is available.
Contingency Products:
Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Water Not Applicable Base Fluid 99.8292 Not applicable – exempt under the ‘Chemical Disclosure Guidelines’ N/A EC1477A NALCO Champion Corrosion 0.00078 Acute Mammalian Toxicity Yes Inhibitor No scientific data or research is available for this component.
Aquatic Toxicity Component 1 (0-1%) OSPAR PLONOR Listed
Component 2 (1-10%)
LC50 (96h): 252 mg/L (Scophthalmus maximus)
LC50 (48h): 70 mg/L (Acartia tonsa)
EC50 (72h): 93 mg/L (Skeletonema costatum)
Component 3 (1-10%)
LC50 (96h): 1.7 mg/L (Scophthalmus maximus)
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%)
LC50 (48h): 0.4 mg/L (Acartia tonsa)
EC50 (72h): 0.26 mg/L (Skeletonema costatum)
Component 4 (1-10%)
LC50 (96h): 3.4 mg/L (Scophthalmus maximus)
LC50 (48h): 1.2 mg/L (Acartia tonsa)
EC50 (72h): 0.5 mg/L (Skeletonema costatum)
Component 5 (60-90%) Natural product – exempted under Chemical Disclosure Guidelines
Chronic Toxicity No known carcinogenic (R40, R25, R49), chronic (R33, R39, R48, R68), mutagenic (R46) or reproductive (R60, R61, R62, R64) effects are associated with this product
Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (0-1%) OSPAR PLONOR Listed
Component 2 (1-10%) Biodegradation in 28 days, 64% (OECD 306)
Component 3 (1-10%) Biodegradation in 28 days, 94% (OECD 306)
Component 4 (1-10%) Biodegradation in 28 days, 35% (OECD 306)
Component 5 (60-90%) Natural product – exempted under Chemical Disclosure Guidelines
Octanol/Water Partition Coefficient Component 1 (0-1%) OSPAR PLONOR Listed
Component 2 (1-10%)
Log Pow: 0.059
Component 3 (1-10%)
Log Pow: -1.4 to 3.5
Component 4 (1-10%)
Log Pow: 0 to 4.7
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Component 5 (60-90%) Natural product – exempted under Chemical Disclosure Guidelines XC24359 Baker Hughes Biocide 0.00040 Aquatic Mammalian Toxicity Yes Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines Component 2 (10-30%) Specie: Rat LD50 (oral): 575 mg/kg Component 3 (1-5%) Specie: Rat LD50 (oral): 1002 mg/kg
Chronic Toxicity This product does carry the following H phrase: H361 – Suspected of damaging unborn child. This product does not carry any of the following H phrases for carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) reproductive (H360, H362) effects.
Aquatic Toxicity Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Specie: Skeletonema costatum (marine algae) EC50 (72h): 0.16 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 0.60 mg/L Specie: Cyprinodon variegatus (marine fish) LC50 (96h): 72 mg/L
Component 3 (1-5%) Specie: Selenastrum capricarnutum (freshwater algae) EC50 (72h): 0.019 mg/L Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 0.025 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): 0.059 mg/L
Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Method: USEPA 164-2. Biodegradability 30 days: 67%
Component 3 (1-5%) Method: Die-away test with radiolabelled. Biodegradability 7 days: > 98%
Octanol/Water Partition Coefficient Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%)
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Method: OECD 117 (HPLC). Log (Pow): <0
Component 3 (1-5%) Method: OECD 107 (Shake Flask Method). Log (Pow) 2.45 Hydrosure O- Nalco Champion Hydrotest 0.05023 Acute Mammalian Toxicity Yes 3670R Chemical No scientific data or research is available for this component.
Acute toxicity Component 1 (10-30%) OSPAR PLONOR Listed
Component 2 (10-30%) Crustacean LC50(48h):3.0 mg/L (Acartia tonsa) Algae EC50(72h):0.04 mg/L (Skeletonema costatum)
Component 3 (1-10%) Fish LC50(96h): 0.19 mg/L (Sheepshead minnow) Crustacean LC50(48h): 1.23 mg/L (Acartia tonsa) Algae EC50(72h):0.19 mg/L (Skeletonema costatum)
Component 4 (1-10%) OSPAR PLONOR Listed
Component 5 (1-10%) Fish LC50(96h): 178.89 mg/L (Scophtalmus maximus) Crustacean LC50(48h):266 mg/L (Acartia tonsa) Algae EC50(72h): 205.7 mg/L (Skeletonema costatum)
Component 6 (60-90%) Natural product – exempted under Chemical Disclosure Guidelines
Chronic Toxicity No known carcinogenic (R40, R25, R49), chronic (R33, R39, R48, R68), mutagenic (R46) or reproductive (R60, R61, R62, R64) effects are associated with this product
Biodegradation / Bioaccumulation
Ready Biodegradability Test
Component 1 (10-30%) OSPAR PLONOR Listed
Component 2 (10-30%) Biodegradation (28d): 39.9% (OECD 306)
Component 3 (1-10%)
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Biodegradation (28d): 41% (OECD 306)
Component 4 (1-10%) OSPAR PLONOR Listed
Component 5 (1-10%) Biodegradation (28d): 0% (OECD 306)
Component 6 (60-90%) Natural product – exempted under Chemical Disclosure Guidelines
Octanol/Water Partition Coefficient Component 1 (10-30%) OSPAR PLONOR Listed
Component 2 (10-30%) Log Pow: Not applicable, surface active
Component 3 (1-10%) Log Pow: Not applicable, surface active
Component 4 (1-10%) OSPAR PLONOR Listed
Component 5 (1-10%) Log Pow:<1
Component 6 (60-90%) Natural product – exempted under Chemical Disclosure Guidelines Fluoroscein Baker Hughes Leak Detection 0.01535 Acute Mammalian Toxicity Yes Liquid Dye Component 1 (60-100%) (HDW24838) Natural product – exempted under chemical Disclosure Guidelines
Component 2 (1-5%) Specie: Rat LD50 (oral): 2800 mg/kg
Component 3 (0.1-1%) Specie: Mice LD50 (oral): 4738 mg/kg
Chronic Toxicity No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or other reproductive (H360, H361, H362) effects for this product.
Aquatic Toxicity Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%)
Component 2 (1-5%) Specie: Navicula seminulum (freshwater algae) EC50 (96hr): 242 mg/L Specie: Ceriodaphnia dubia (freshwater invertebrate) LC50 (48hr): 199.82 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96hr): 300 mg/L
Component 3 (0.1-1%) Specie: Chlorella sp. (freshwater algae) EC50 (7 days): >10 mg/L Specie Daphnia pulex (freshwater invertebrate) LC50 (48hr): 337 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96hr): 3433 mg/L
Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (1-5%) Not applicable to inorganic compounds
Component 3 (0.1-1%) Method: EPA EPI Suite Prediction for Ready Biodegradability: <60%
Octanol/Water Partition Coefficient Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (1-5%) Not applicable to inorganic compounds
Component 3 (0.1-1%) Method: EPA EPI Suite KOWWIN v1.68 estimate log(KoW):-0.67 Fluoroscein Baker Hughes Leak Detection 0.01535 Acute Mammalian Toxicity Yes Liquid Dye Component 1 (60-100%) (HDW24106) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Specie: Rat LD50 (oral): 2800 mg/kg
Component 3 (10-30%) Specie: Mice LD50 (oral): 4738 mg/kg
Chronic Toxicity No known carcinogenic (H530, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or other reproductive (H360, H361, H362) effects for this product.
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Aquatic Toxicity Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Specie: Navicula seminulum (freshwater algae) EC50 (96h): 242 mg/L Specie: Ceriodaphnia dubia (freshwater invertebrate) EC50 (48h): 199.82 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): 300 mg/L
Component 3 (10-30%) Specie: Chorella sp. (freshwater algae) EC50 (7d): > 10 mg/L Specie: Daphnia pulex (freshwater invertebrate) LC50 (48h): 337 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): 3433 mg/L Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Not applicable to inorganic compounds
Component 3 (10-30%) Method: EPA EPI Suite Prediction for Ready Biodegradability: < 60%
Octanol/Water Partition Coefficient Component 1 (60-100%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Not applicable to inorganic compounds
Component 3 (10-30%) Method: EPA EPI Suite Kowwin v1.68 estimate log (Kow): -0.67 Hydrosure Nalco Champion Oxygen 0.00001 Acute Mammalian Toxicity Yes Oxygen Scavenger Whole Product Scavenger E2 Acute toxicity estimate: > 2000 mg/kg Sticks
Sodium Metabisulfite Specie: Rat LC50 (4hr): 5.5 mg/L
Chronic Toxicity No known carcinogenic (R40, R45), chronic (R33, R39, R48, R68), mutagenic (R46) or reproductive (R60, R61, R62, R63, R64) effects are associated with this product. Aquatic Toxicity Whole Product
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Specie: Skeletonema costatum (marine algae) EC50 (72h): <100 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): >100 mg/L Specie: Scophthalmus maximus LC50 (96h) >100 mg/L
Sodium Metabisulfite Fish LC50 (96hr): 150 mg/L OSPAR PLONOR Listed
Biodegradation / Bioaccumulation Not applicable for inorganic substances Hydrosure Nalco Champion Biocide for 0.00001 Acute Mammalian Toxicity Yes Biocide Stick water Whole Product treatment Specie: Rat (oral) LD50: 180 mg/kg Specie Rat (dermal) LD50: 1600 mg/L Specie Rat LC50 (6hr): >5000 mg/m3
Aquatic Toxicity Whole Product Specie: Skeletonema costatum (marine algae) EC50 (72h): <1mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): <10 mg/L Specie: Scophthalmus maximus LC50 (96h) >40 mg/L
Chronic Toxicity No known carcinogenic (R40, R45, R49), chronic (R33, R39, R48, R68), mutagenic (R46) or reproductive (R60, R61, R62, R63, R64) effects are associated with this product.
Biodegradation / Bioaccumulation Whole Product
Ready Biodegradability Test Method: OECD306. Biodegradability 28 days: 0%
Octanol/Water Partition Coefficient
Method: OECD 117 (HPLC). Log (Pow) <1 Hydrosure NALCO Champion Hydrotest 0.00001 Acute Mammalian Toxicity Yes Fluorescein chemical No scientific data or research is available. Dye Stick Aquatic Toxicity Whole Product Specie: Skeletonema costatum (marine algae) EC50 (72h): >100 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): >100 mg/L Specie: Scophthalmus maximus LC50 (96h): >1000 mg/L Specie: Corophium volutator LC50 (10d): > 1000 mg/L
Sodium Carbonate Lepomis macrochirus LC50 (96h): 300 mg/L
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Ceriodaphnia EC50 (48h): 213.5 mg/L
Chronic Toxicity No known carcinogenic (R40, R45, R49), chronic (R33, R39, R48, R68), mutagenic (R46) or reproductive (R60, R61, R62, R63, R64) effects are associated with this product.
Biodegradation / Bioaccumulation Whole Product
Ready Biodegradability Test Method: OECD306. Biodegradability 28 days: 0%
Octanol/Water Partition Coefficient Method: OECD 117 (HPLC). Log(Pow) <1 OSW24514 Baker Hughes Oxygen 0.00209 Acute Mammalian Toxicity Yes Scavenger Component 1 (60-100%) Specie: Rat (Oral) LC50: > 2g/kg
Component 2 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines
Chronic toxicity: No known carcinogenic (H530, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or other reproductive (H360, H361, H362) effects for this product.
Aquatic toxicity Component 1 (60-100%) Ceriodaphnia dubia LC50(48h): 177.0 mg/L Daphnia magna LC50(48h): 161.0 mg/L Fathead minnow LC50 (48h): 683 mg/L Threespine Stickleback LC50 (96h): 220 mg/L OSPAR PLONOR Listed
Component 2 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines
Biodegradation / Bioaccumulation
Ready Biodegradability Test Component 1 (60-100%) Not applicable to inorganic compounds
Component 2 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines Octanol/Water Partition Coefficient Component 1 (60-100%)
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Not applicable to inorganic compounds
Component 2 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines Oceanic MacDermid Hydraulic Fluid 0.00698 Acute Mammalian Toxicity Yes HW525 Ethylene Glycol LD50 (Rat): 4700 mg/kg LD50 (Rabbit): 9530 mg/kg
2-Butoxyethanol Oral LD50 (Rat): 1300 mg/kg Inhalation ATE value: 550 mg/L (vapours) Dermal ATE value: 55000 mg/kg
Chronic Toxicity No known carcinogenic (R40, R45, R49), chronic (R33, R39, R48, R68), mutagenic (R46) or reproductive (R60, R61, R62, R63, R64) effects are associated with this product.
Aquatic Toxicity Whole Product Corophium volutator LC50 (10d): > 12037 mg/L Cyprinodon variegatus LC50 (48h): >3000 mg/L Acartia tonsa LC50 (48h): 644 mg/L Skeletonema costatum EC50 (72h): 36.6 mg/L
Ethanediol Pimephales promelas: LC50 (96h) = 72860 mg/L Pimephales promelas: LC50 (96h) = 8050000 µg/L Daphnia magna – neonate: LC50 (48h) = 41000000 µg/L Crangon crangon – LC50 (48h) 100000 µg/L Pseudokirchneriella subcapitata: EC50 (96h) >6500 mg/L Micro-organism: EC50 (30m) > 1995 mg/L
2-Butoxyethanol Menidia beryllina: LC50 (96h):1250000 µg/L Daphnia magna: LC50 (48h):1000 L Crangon crangon: LC50 (48h): 800000 µg/L
Biodegradation / Bioaccumulation
Ready Biodegradability Test Ethanediol OSPAR PLONOR Listed
2-Butoxyethanol Biodegradability 83% in 28 days
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%)
Octanol/Water Partition Coefficient Ethanediol OSPAR PLONOR Listed
2-Butoxyethanol Log Pow 2.89 Chronic Toxicity No known carcinogenic (R40, R45, R49), chronic (R33, R39, R48, R68), mutagenic (R46) or reproductive (R60, R61, R62, R63, R64) effects are associated with this product. Oceanic MacDermid Hydraulic Fluid 0.00698 Acute Mammalian Toxicity Yes HW540 Oral ATE value: 1184.9 mg/kg Ethanediol Oral LD50 (Rat): 7712 mg/kg Oral LD50 (Mouse): 5500 mg/kg Dermal LD50 (Mouse – male/female): 3500 mg/kg 2-Butoxyethanol Oral LD50 (Rat): 1300 mg/kg Inhalation ATE value: 550 mg/L (vapours) Dermal ATE value: 55000 mg/kg
Chronic Toxicity No known carcinogenic (R40, R45, R49), chronic (R33, R39, R48, R68), mutagenic (R46) or reproductive (R60, R61, R62, R63, R64) effects are associated with this product.
Aquatic Toxicity Whole Product Corophium volutator LC50 (10d): > 12037 mg/L Cyprinodon variegatus LC50 (48h): >3000 mg/L Acartia tonsa LC50 (48h): 644 mg/L Skeletonema costatum EC50 (72h): 36.6 mg/L
Ethanediol Pimephales promelas: LC50 (96h) = 72860 mg/L Pimephales promelas: LC50 (96h) = 8050000 µg/L Daphnia magna – neonate: LC50 (48h) = 41000000 µg/L Crangon crangon – LC50 (48h) 100000 µg/L Pseudokirchneriella subcapitata: EC50 (96h) >6500 mg/L Micro-organism: EC50 (30m) > 1995 mg/L
2-Butoxyethanol Menidia beryllina: LC50 (96h):1250000 µg/L Daphnia magna: LC50 (48h):1000 L Crangon crangon: LC50 (48h): 800000 µg/L
Biodegradation / Bioaccumulation
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%)
Ready Biodegradability Test Ethanediol OSPAR PLONOR Listed
2-Butoxyethanol Biodegradability 83% in 28 days
Octanol/Water Partition Coefficient Ethanediol OSPAR PLONOR Listed
2-Butoxyethanol Log Pow 2.89 Castrol Castrol Hydraulic Fluid 0.00698 Acute Mammalian Toxicity Yes Transaqua HT2 Whole Product Oral ATE value = 1086.9 mg/kg
Chronic Toxicity No known carcinogenic (R40, R45, R49), chronic (R33, R39, R48, R68), mutagenic (R46) or reproductive (R60, R61, R62, R63, R64) effects are associated with this product.
Aquatic Toxicity Component 1 (30-60%) OSPAR PLONOR Listed
Component 2 (30-60%) OSPAR PLONOR Listed
Component 3 (0-1%) Acartia tonsa LC50 (48h):1570 mg/L Skeletonema costatum EC50 (72h): 863 mg/L Scophthalmus maximus LC50 (96h): 1000 mg/L
Component 4 (0-1%) Acartia tonsa LC50 (48h): 20 mg/L Skeletonema costatum EC50 (72h): 6 mg/L Scophthalmus maximus LC50 (96h): > 13.3 mg/L Corophium volutator LC50 (10d): > 151.3 mg/L
Component 5 (1-5%) Acartia tonsa LC50 (48h): > 2000 mg/L Skeletonema costatum EC50 (72h): > 1000 mg/L Scophthalmus maximus LC50 (96h): > 1000 mg/L
Component 6 (0-1%)
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Acartia tonsa LC50 (48h): > 60 mg/L Skeletonema costatum EC50 (72h): > 146 mg/L Scophthalmus maximus LC50 (96h): > 23.7 mg/L Corophium volutator LC50 (10d): > 155 mg/L
Component 7 (1-5%) Acartia tonsa LC50 (48h): > 690 mg/L Skeletonema costatum EC50 (72h): > 1000 mg/L Scophthalmus maximus LC50 (96h): > 1000 mg/L Corophium volutator LC50 (10d): > 10 000 mg/L
Component 8 (0-1%) Acartia tonsa LC50 (48h):> 241 mg/L Skeletonema costatum EC50 (72h): 14 mg/L Scophthalmus maximus LC50 (96h): > 357 mg/L
Component 9 (0-1%) Acartia tonsa LC50 (48h): 57 mg/L Skeletonema costatum EC50 (72h): 4 mg/L Scophthalmus maximus LC50 (96h): > 218.4 mg/L
Component 10 (0-1%) Acartia tonsa LC50 (48h): 279 mg/L Skeletonema costatum EC50 (72h): 137 mg/L Scophthalmus maximus LC50 (96h): > 1000 mg/L
Component 11 (0-1%) Acartia tonsa LC50 (48h): 104.3 mg/L Skeletonema costatum EC50 (72h): 1000 mg/L Scophthalmus maximus LC50 (96h): > 1000 mg/L
Component 12 (0-1%) Acartia tonsa LC50 (48h): 399 mg/L Skeletonema costatum EC50 (72h): 654 mg/L Scophthalmus maximus LC50 (96h) > 1000 mg/L
Component 13 (0-1%) Acartia tonsa LC50 (48h): 429 mg/L Skeletonema costatum EC50 (72h): 423 mg/L Scophthalmus maximus LC50 (96h): 283 mg/L
Component 14 (0-1%) Acartia tonsa LC50 (48h): 442 mg/L Skeletonema costatum EC50 (72h): 40 mg/L Scophthalmus maximus LC50 (96h): > 1000 mg/L Corophium volutator LC50 (10d): 7195 mg/L
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%)
Biodegradation / Bioaccumulation
Readily Biodegradability Test Component 1 (30-60%) Not applicable OSPAR PLONOR Listed
Component 2 (30-60%) Not applicable OSPAR PLONOR Listed
Component 3 (0-1%) OECD 306 Biodegradability, 28 days 29.2%
Component 4 (0-1%) OECD 306 Biodegradability, 28 days 61%
Component 5 (1-5%) OECD 306 Biodegradability, 28 days 44%
Component 6 (0-1%) OECD 306 Biodegradability, 28 days 75.1%
Component 7 (1-5%) OECD 306 Biodegradability, 28 days 48%
Component 8 (0-1%) OECD 306 Biodegradability, 28 days 67.5%
Component 9 (0-1%) OECD 306 Biodegradability, 28 days 64.6% Component 10 (0-1%) OECD 306 Biodegradability, 28 days 32.9%
Component 11 (0-1%) OECD 306 Biodegradability, 28 days 23%
Component 12 (0-1%) Not applicable to inorganic substance
Component 13 (0-1%) Not applicable to inorganic substance
Component 14 (0-1%) OECD 306 Biodegradability, 28 days 30.7%
Octanol/Water Partition Coefficient (OECD 117)
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Component 1 (30-60%) Not applicable OSPAR PLONOR Listed
Component 2 (30-60%) Not applicable OSPAR PLONOR Listed
Component 3 (0-1%) Log Pow = 29.2
Component 4 (0-1%) MW > 700
Component 5 (1-5%) Log Pow <0
Component 6 (0-1%) Log Pow <3 Component 7 (1-5%) Log Pow <3
Component 8 (0-1%) Log Pow <3
Component 9 (0-1%) Log Pow <0
Component 10 (0-1%) Log Pow <0
Component 11 (0-1%) Log Pow <0
Component 12 (0-1%) Not applicable to inorganic substance
Component 13 (0-1%) Not applicable to inorganic substance
Component 14 (0-1%) Log Pow >3 CRW24830 Baker Hughes Corrosion 0.05023 Acute Mammalian Toxicity Yes Inhibitor Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines.
Component 2 (10-30%) No scientific data or research is available for this component.
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%)
Component 3 (10-30%) OSPAR PLONOR Listed
Component 4 (5-10%) Specie Rat (Oral) LD50: 4500 mg/kg
Component 5 (5-10%) Specie Rat (Oral): 426 mg/kg
Component 6 (5-10%) OSPAR PLONOR Listed
Component 7 (<1%) Specie: Rat (Oral) LD50: 6720 mg/kg
Chronic Toxicity No known carcinogenic (H350, H351), chronic (H341, H370, H371, H373), mutagenic (H340) or reproductive (H360, H361, H362) effects for this product.
Aquatic Toxicity Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Specie: Skeletonema costatum (marine algae) EC50 (72h).: 0.15 mg/L Specie: Acartia tonsa (marine invertebrate) LC50 (48h): 1.1 mg/L Specie: Cyprinodon variegatus (marine fish) LC50 (96h): >0.1 mg/L
Component 3 (10-30%) OSPAR PLONOR Listed
Component 4 (5-10%) Specie: Skeletonema costatum (marine algae) EC50 (48h): 500 – 5000 mg/L Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 2850 mg/L Specie: Lepomis macrochirus (freshwater fish) LC50 (96h): 1300 mg/L
Component 5 (5-10%) Specie: Algae: No scientific data or research is available for this component at this trophic level. Specie: Daphnia magna (freshwater invertebrate) LC50 (48h): 0.08 mg/L Specie: Pimephales promelas (freshwater fish) LC50 (96h): 0.66 mg/L Component 6 (5-10%) OSPAR PLONOR Listed
Component 7 (<1%) Specie: Chlorella sp. (freshwater algae) EC50 (48h): >10 mg/L
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Specie: Daphnia pulex (freshwater invertebrate) LC50 (48h): 337 mg/L Specie: Scophthalmus maximus (marine fish) LC50 (96h): 423 mg/L
Biodegradation / Bioaccumulation
Readily Biodegradability Test Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Method: OECD 306 Biodegradability 28 days: 39%
Component 3 (10-30%) OSPAR PLONOR Listed
Component 4 (5-10%) Method: OECD 306 Biodegradability 28 days: 75%
Component 5 (5-10%) No scientific data or research is available for this component.
Component 6 (5-10%) OSPAR PLONOR Listed
Component 7 (<1%) No scientific data or research is available for this component.
Octanol/Water Partition Coefficient Component 1 (30-60%) Natural product – exempted under the Chemical Disclosure Guidelines
Component 2 (10-30%) Not accumulative, molecular weight (MW) > 700
Component 3 (10-30%) OSPAR PLONOR Listed
Component 4 (5-10%) Method: OECD 177 (HPLC) Log (Pow): 0.2
Component 5 (5-10%) Not applicable to surfactants
Component 6 (5-10%) OSPAR PLONOR Listed
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Product in Product Name Supplier Purpose Toxicity & Ecotoxicity Info SDS Attached system (%) Component 7 (<1%) Method” OECD 117 (HPLC) Log (Pow): 3.35
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C. CHEMICAL LISTS Produced Formation Water Chemicals
Chemicals Within Produced Water Reinjection System CAS Number Mass Fraction (%) Water 7732-18-5 99.99167 Ethanediol 107-21-1 0.00429 Amine-Fatty Acid Condensate 68953-36-6 0.00076 Amines, N-Tallow Alkyltrimethylenedi-, Ethoxylated 61790-85-0 0.00082 2-(2-Butoxyethoxy)Ethanol 112-34-5 0.00068 Tofa/Deta Imidazoline Acetate 68140-11-4 0.00053 Tetrakis(Hydroxymethyl)Phosphonium Sulphate 55566-30-8 0.00050 Acetic Acid 64-19-7 0.00045 Dithiocarbamate 204079-86-7 0.00040 Fatty Amino Compound 61790-69-0 0.00038 2-Mercaptoethanol 60-24-2 0.00038 Ethoxylated Amine 61791-26-2 0.00038 Glutaraldehyde 111-30-8 0.00025 Distillates (Petroleum), Straight-Run Middle 64741-44-2 0.00022 2-Butoxyethanol 111-76-2 0.00019 Fatty Acids, Tall Oil, Reaction Products With 64754-93-4 0.00019 Polyethylenepolyamines, Acetates Amines, Coco Alkyl Propionates 91995-05-0 0.00019 Pyridine, Alkyl Derivatives; Crude Tar 68391-11-7 0.00019 Alkyl Amine 61788-46-3 0.00019 Alkyl (C3-5) Benzenes 64742-94-5 0.00016 Fatty Acids, Tall Oil, Reaction Products With 61790-69-0 0.00016 Diethylenetriamine Glycerol 56-81-5 0.00014 Monoethylene Glycol 53262-31-0 0.00011 2-Propenoic Acid, Polymer With Methyl 2-Propenoate 25302-81-2 0.00010 Methanol 67-56-1 0.00009 Fatty Acids 67762-38-3 0.00008 C12-16 Alkylbenzyldimethylammonium Chloride 68424-85-1 0.00008 Benzyl Alkyl Dimethyl Ammonium Chloride 8001-54-5 0.00007 Diphosphonic Acid 2809-21-4 0.00007 Cyclohexylamine 108-91-8 0.00006
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Chemicals Within Produced Water Reinjection System CAS Number Mass Fraction (%) Potassium Hydroxide 1310-58-3 0.00006 Chloroacetic Acid 79-11-8 0.00006 Polyalkylene Glycol 9003-13-8 0.00005 Ammonium Bisulphite 10192-30-0 0.00005 Sodium Thiosulphate 10102-17-7 0.00005 2-Aminoethanol 141-43-5 0.00005 2-Propenoic Acid, Homopolymer 9003-04-7 0.00003 Quaternary Ammonium Compound 68391-01-5 0.00003 Naphthalene 91-20-3 0.00002 Dipropylene Glycol 110-98-5 0.00002 Thioglycolic Acid 68-11-1 0.00002 1 2 4-Trimethylbenzene 95-63-6 0.00001 Nonyl Phenol Ethoxylate 9016-45-9 0.00001 Isopropanol 67-63-0 0.00001 Ethylbenzene 100-41-4 <0.00001 Mesitylene 108-67-8 <0.00001 Benzenesulphonic Acid, Dodecyl-, Amine Salt 25155-30-0 <0.00001 Diethylenetriamine 111-40-0 <0.00001 Fluorescein Sodium Salt 518-47-8 <0.00001 Polydimethylsiloxane 63428-62-9 <0.00001 Methyldiethanolamine 105-59-9 <0.00001 Piperazine 110-85-0 <0.00001 Triethylene Glycol 112-27-6 <0.00001 Xylene 1330-20-7 <0.00001 TOTAL ~100 %
Contingency Products
Chemicals Injected as Contingency Products CAS Number Mass Fraction (%) Water 7732-18-5 99.96394 Benzyl-(C12-C16 Alkyl)-Dimethyl-Ammonium Chloride 68424-85-1 0.02013 Ethanediol 107-21-1 0.01765 Ammonium Hydrogensulphite 10192-30-0 0.01633 Amine, N-Tallow Alkyltrimethylenedi-, Ethoxylated 61790-85-0 0.01507 Sodium Carbonate 497-19-8 0.00614 Fluorescein Dye 518-47-8 0.00511
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Chemicals Injected as Contingency Products CAS Number Mass Fraction (%) 2-(2-Butoxyethoxy)Ethanol 112-34-5 0.00502 Ethylene Glycol 107-21-1 0.00419 Dipropylene Glycol Monomethyl Ether 34590-94-8 0.00251 Acetic Acid 64-19-7 0.00251 C.I. Basic Violet (Rhodamine B Or D&C Red No 19) 81-88-9 0.00251 2-Butoxyethanol 111-76-2 0.00042 Triethanolamine 102-71-6 0.00035 Tetrakis(Hydroxymethyl)Phosphonium Sulphate(2:1) 55566-30-8 0.00012 Tall Oil, Deta Imidazoline Acetates 68140-11-4 0.00008 Thioglycolic Acid 68-11-1 0.00004 2-Bromo-2-Nitropropane-1,3-Diol 52-51-7 0.00001 Sodium Metabisulfite 761-57-4 <0.00001 Tributyltetradecylphosphonium Chloride 81741-28-8 <0.00001 Total ~100%
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Safety Data Sheet
CRO24009 1 . Identification of the material and supplier Product identifier : CRO24009 Product code : CRO24009 ADG : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains kerosene) Product type : Liquid. Identified uses : Corrosion inhibitor.
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : FLAMMABLE LIQUIDS - Category 4 substance or mixture ACUTE TOXICITY (inhalation) - Category 4 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (liver) - Category 2 ASPIRATION HAZARD - Category 1 LONG-TERM AQUATIC HAZARD - Category 2
GHS label elements Hazard pictograms :
Signal word : DANGER Hazard statements : H227 - Combustible liquid. H332 - Harmful if inhaled. H318 - Causes serious eye damage. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H304 - May be fatal if swallowed and enters airways. H373 - May cause damage to organs through prolonged or repeated exposure. (liver) H411 - Toxic to aquatic life with long lasting effects. Precautionary statements Prevention : Wear protective gloves: > 8 hours (breakthrough time): Nitrile gloves.. Wear eye or face protection. Keep away from flames and hot surfaces. - No smoking. Avoid release to the environment. Do not breathe vapour.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 1/11 CRO24009 2 . Hazards identification Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF IN EYES: Immediately call a POISON CENTER or physician. Storage : Keep cool. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Precautionary statements : P280, P210, P273, P260, P304 + P340, P301 + P310 + P331, P305 + P310, P235, (Code) P501 Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number Distillates (petroleum), straight-run middle 60 - 100 64741-44-2 2-(2-butoxyethoxy)ethanol 10 - 30 112-34-5 Fatty acids, tall-oil, reaction products with diethylenetriamine 1 - 5 61790-69-0 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Chemical burns must be treated promptly by a physician. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 15 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 2/11 CRO24009 4 . First aid measures Inhalation : Harmful if inhaled. Skin contact : Causes skin irritation. May cause an allergic skin reaction. Ingestion : May be fatal if swallowed and enters airways. Over-exposure signs/symptoms Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains,nausea or vomiting
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam. media Unsuitable extinguishing : Do not use water jet. media
Specific hazards arising : Combustible liquid. In a fire or if heated, a pressure increase will occur and the from the chemical container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide,nitrogen oxides decomposition products
Hazchem code : •3Z 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 3/11 CRO24009 6 . Accidental release measures For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not swallow. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved including any area. Store in original container protected from direct sunlight in a dry, cool and well- incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 4/11 CRO24009 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits Ingredient name Exposure limits 2-(2-butoxyethoxy)ethanol ACGIH TLV (United States, 3/2016). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapor
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust controls ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Nitrile gloves. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 5/11 CRO24009 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Amber. Odour : Characteristic. Odour threshold : Not available. pH : 9.6 Melting point : <0°C (<32°F) Boiling point : Not available. Flash point : Closed cup: 75°C (167°F) Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 0.816 to 0.836 (20°C) Solubility : Insoluble in the following materials: cold water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Kinematic (40°C): 1 to 10 cSt 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure Distillates (petroleum), LC50 Inhalation Dusts and mists Rat 1700 mg/m³ 4 hours straight-run middle 2-(2-butoxyethoxy)ethanol LD50 Dermal Rabbit 2700 mg/kg - LD50 Oral Rat 4500 mg/kg - Fatty acids, tall-oil, reaction LD50 Oral Rat >4000 mg/kg - products with diethylenetriamine Conclusion/Summary : Harmful if inhaled. Adverse health effects could include the following: central nervous system depression Irritation/Corrosion
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 6/11 CRO24009 11 . Toxicological information Product/ingredient name Result Species Score Exposure Observation Distillates (petroleum), Skin - Moderate irritant Rabbit - 500 - straight-run middle milligrams 2-(2-butoxyethoxy)ethanol Eyes - Moderate irritant Rabbit - 24 hours 20 - milligrams Eyes - Severe irritant Rabbit - 20 milligrams - Conclusion/Summary Skin : May cause skin irritation. Eyes : Risk of serious damage to eyes. May cause eye burns and permanent eye injury. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : May cause sensitisation by skin contact. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available.
Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Distillates (petroleum), straight-run middle Category 2 Not determined liver Aspiration hazard Name Result Distillates (petroleum), straight-run middle ASPIRATION HAZARD - Category 1
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : Harmful if inhaled. Skin contact : Causes skin irritation. May cause an allergic skin reaction. Ingestion : May be fatal if swallowed and enters airways.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 7/11 CRO24009 11 . Toxicological information Ingestion : stomach pains,nausea or vomiting
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Product/ingredient name Result Species Exposure 2-(2-butoxyethoxy)ethanol Acute LC50 1300000 μg/l Fresh water Fish - Lepomis macrochirus 96 hours Persistence and degradability Not available. Bioaccumulative potential
Product/ingredient name LogPow BCF Potential 2-(2-butoxyethoxy)ethanol 1 - low
Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 8/11 CRO24009 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID UN3082 ENVIRONMENTALLY 9 III HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains kerosene) ADG UN3082 ENVIRONMENTALLY 9 III HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains kerosene) IMDG UN3082 ENVIRONMENTALLY 9 III HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains kerosene) IATA UN3082 ENVIRONMENTALLY 9 III HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains kerosene) PG* : Packing group Regulatory Environmental Additional information** information hazards ADR/RID Class Yes. This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.
Tunnel code (E)
Hazchem code 3Z
ADG Class Yes. The product is not regulated as a dangerous good when transported by road or rail in either an IBC, or in other container types if ≤500 kg. The environmentally hazardous substance mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Hazchem code •3Z IMDG Class Yes. -
IATA Class Yes. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 9/11 CRO24009 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons 5 Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed.
Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. 16 . Other information History Date of printing : 12 November 2017. Date of issue/Date of : 12 November 2017 revision Date of previous issue : 28 December 2014 Version : 4 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Flam. Liq. 4, H227 On basis of test data Acute Tox. 4, H332 Calculation method Skin Irrit. 2, H315 Calculation method Eye Dam. 1, H318 Calculation method Skin Sens. 1, H317 Calculation method STOT RE 2, H373 (liver) Calculation method Asp. Tox. 1, H304 Calculation method Aquatic Chronic 2, H411 Calculation method
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 10/11 CRO24009 16 . Other information References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 28 December 2014 Version : 4 11/11 Safety Data Sheet
CRW24006 1 . Identification of the material and supplier Product identifier : CRW24006 Product code : CRW24006 ADG : AMINES, LIQUID, CORROSIVE, N.O.S. (diethylenetriamine, tall oil fatty acids reaction product) Product type : Liquid. Identified uses : Corrosion inhibitor.
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : ACUTE TOXICITY (inhalation) - Category 4 substance or mixture SKIN CORROSION/IRRITATION - Category 1B SKIN SENSITIZATION - Category 1 LONG-TERM AQUATIC HAZARD - Category 3
GHS label elements Hazard pictograms :
Signal word : DANGER Hazard statements : H332 - Harmful if inhaled. H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H412 - Harmful to aquatic life with long lasting effects. Precautionary statements Prevention : Wear protective gloves: > 8 hours (breakthrough time): Nitrile gloves. Neoprene gloves.. Wear eye or face protection. Wear protective clothing. Avoid release to the environment. Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or physician. IF IN EYES: Immediately call a POISON CENTER or physician. Storage : Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 4 October 2016 Version : 4 1/10 CRW24006 2 . Hazards identification Precautionary statements : P280, P273, P304 + P340 + P310, P301 + P310 + P331, P303 + P361 + P353 + (Code) P310, P305 + P310, P405, P501 Supplemental label : Not applicable. elements
Other hazards which do not : Causes digestive tract burns. result in classification 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number Fatty acids, tall-oil, reaction products with diethylenetriamine 10 - 30 61790-69-0 2-(2-butoxyethoxy)ethanol 10 - 30 112-34-5 acetic acid 5 - 10 64-19-7 thioglycolic acid 1 - 5 68-11-1 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Chemical burns must be treated promptly by a physician. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact : Get medical attention immediately. Call a poison center or physician. Wash affected area with soap and mild detergent for at least 20 - 60 minutes. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Call a poison center or physician. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : Harmful if inhaled. Skin contact : Causes severe burns. May cause an allergic skin reaction. Ingestion : Corrosive to the digestive tract. Causes burns. Over-exposure signs/symptoms
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 4 October 2016 Version : 4 2/10 CRW24006 4 . First aid measures Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide,nitrogen oxides,sulfur oxides decomposition products
Hazchem code : 2X 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 4 October 2016 Version : 4 3/10 CRW24006 6 . Accidental release measures
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits Ingredient name Exposure limits 2-(2-butoxyethoxy)ethanol ACGIH TLV (United States, 3/2016). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapor acetic acid Safe Work Australia (Australia, 1/2014). STEL: 37 mg/m³ 15 minutes. STEL: 15 ppm 15 minutes. TWA: 25 mg/m³ 8 hours. TWA: 10 ppm 8 hours. thioglycolic acid Safe Work Australia (Australia, 1/2014). Absorbed through skin. TWA: 3.8 mg/m³ 8 hours. Date of issue/Date of revision : 12 November 2017 Date of previous issue : 4 October 2016 Version : 4 4/10 CRW24006 8 . Exposure controls/personal protection TWA: 1 ppm 8 hours.
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust controls ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Nitrile gloves. Neoprene gloves. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Amber. [Dark] Odour : Characteristic. Odour threshold : Not available. pH : 4.1 to 4.9 Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: Not applicable. Evaporation rate : Not available.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 4 October 2016 Version : 4 5/10 CRW24006 9 . Physical and chemical properties Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 0.99 to 1.01 (20°C) Solubility : Easily soluble in the following materials: cold water. Soluble in water Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available. 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure Fatty acids, tall-oil, reaction LD50 Oral Rat >4000 mg/kg - products with diethylenetriamine 2-(2-butoxyethoxy)ethanol LD50 Dermal Rabbit 2700 mg/kg - LD50 Oral Rat 4500 mg/kg - acetic acid LC50 Inhalation Gas. Mouse 5620 ppm 1 hours LD50 Oral Mouse 4960 mg/kg - LD50 Oral Rat 3310 mg/kg - thioglycolic acid LC50 Inhalation Vapour Rat 210 mg/m³ 4 hours LD50 Oral Rat 114 mg/kg - Conclusion/Summary : Harmful if inhaled. Adverse health effects could include the following: central nervous system depression Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation 2-(2-butoxyethoxy)ethanol Eyes - Moderate irritant Rabbit - 24 hours 20 - milligrams Eyes - Severe irritant Rabbit - 20 milligrams - acetic acid Eyes - Mild irritant Rabbit - 0.5 minutes - 5 milligrams Skin - Mild irritant Human - 24 hours 50 - milligrams Skin - Mild irritant Rabbit - 24 hours 50 - milligrams Skin - Severe irritant Rabbit - 525 - milligrams Conclusion/Summary
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 4 October 2016 Version : 4 6/10 CRW24006 11 . Toxicological information Skin : Causes pain and burns in contact with skin. May cause permanent skin damage. Eyes : Risk of serious damage to eyes. May cause eye burns and permanent eye injury. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : May cause sensitisation by skin contact. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available. Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure thioglycolic acid Category 2 Not determined Not determined Aspiration hazard Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : Harmful if inhaled. Skin contact : Causes severe burns. May cause an allergic skin reaction. Ingestion : Corrosive to the digestive tract. Causes burns.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 4 October 2016 Version : 4 7/10 CRW24006 11 . Toxicological information Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Product/ingredient name Result Species Exposure 2-(2-butoxyethoxy)ethanol Acute LC50 1300000 μg/l Fresh water Fish - Lepomis macrochirus 96 hours acetic acid Acute EC50 300.82 mg/l Marine water Algae 72 hours Acute EC50 73400 μg/l Fresh water Algae - Navicula seminulum 96 hours Acute EC50 300.82 mg/l Fresh water Daphnia 48 hours Acute LC50 117.6 ul/L Marine water Crustaceans - Artemia sp. 48 hours Acute LC50 300.82 mg/l Marine water Fish 96 hours Acute LC50 79000 μg/l Fresh water Fish - Pimephales promelas - 96 hours Juvenile (Fledgling, Hatchling, Weanling) thioglycolic acid Acute LC50 30000 μg/l Fresh water Fish - Pimephales promelas 96 hours Persistence and degradability Not available. Bioaccumulative potential
Product/ingredient name LogPow BCF Potential 2-(2-butoxyethoxy)ethanol 1 - low acetic acid -0.17 3.16 low thioglycolic acid -2.99 - low Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 4 October 2016 Version : 4 8/10 CRW24006 14 . Transport information Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (diethylenetriamine, tall oil fatty acids reaction product) ADG UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (diethylenetriamine, tall oil fatty acids reaction product) IMDG UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (diethylenetriamine, tall oil fatty acids reaction product) IATA UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (diethylenetriamine, tall oil fatty acids reaction product) PG* : Packing group Regulatory Environmental Additional information** information hazards ADR/RID Class No. Hazchem code 2X ADG Class No. Hazchem code 2X IMDG Class No. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons 5 Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 4 October 2016 Version : 4 9/10 CRW24006 15 . Regulatory information Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. 16 . Other information History Date of printing : 12 November 2017. Date of issue/Date of : 12 November 2017 revision Date of previous issue : 4 October 2016 Version : 4 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Acute Tox. 4, H332 Calculation method Skin Corr. 1B, H314 Calculation method Skin Sens. 1, H317 Calculation method Aquatic Chronic 3, H412 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 12 November 2017 Date of previous issue : 4 October 2016 Version : 4 10/10 Safety Data Sheet
CRW24200 1 . Identification of the material and supplier Product identifier : CRW24200 Product code : CRW24200 ADG : AMINES, LIQUID, CORROSIVE, N.O.S. (Oxyalkylated amine) Product type : Liquid. Identified uses : Corrosion inhibitor.
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : SKIN CORROSION/IRRITATION - Category 1B substance or mixture TOXIC TO REPRODUCTION (Fertility) - Category 2 ACUTE AQUATIC HAZARD - Category 2 LONG-TERM AQUATIC HAZARD - Category 2
GHS label elements Hazard pictograms :
Signal word : DANGER Hazard statements : H314 - Causes severe skin burns and eye damage. H361 - Suspected of damaging fertility. H411 - Toxic to aquatic life with long lasting effects. Precautionary statements Prevention : Obtain special instructions before use. Wear protective gloves: > 8 hours (breakthrough time): Neoprene gloves. Rubber gloves.. Wear eye or face protection. Wear protective clothing. Avoid release to the environment. Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or physician. IF IN EYES: Immediately call a POISON CENTER or physician. Storage : Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.
Date of issue/Date of revision : 14 November 2017 Date of previous issue : 1 January 2017 Version : 4 1/10 CRW24200 2 . Hazards identification Precautionary statements : P201, P280, P273, P304 + P340 + P310, P301 + P310 + P331, P303 + P361 + (Code) P353 + P310, P305 + P310, P405, P501 Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number 2-(2-butoxyethoxy)ethanol 10 - 30 112-34-5 Amines, N-tallow alkyltrimethylenedi-, ethoxylated 10 - 30 61790-85-0 cyclohexylamine 5 - 10 108-91-8 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Chemical burns must be treated promptly by a physician. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact : Get medical attention immediately. Call a poison center or physician. Wash affected area with soap and mild detergent for at least 20 - 60 minutes. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Call a poison center or physician. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : No known significant effects or critical hazards. Skin contact : Causes severe burns. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : pain,watering,redness Inhalation : reduced foetal weight,increase in foetal deaths,skeletal malformations
Date of issue/Date of revision : 14 November 2017 Date of previous issue : 1 January 2017 Version : 4 2/10 CRW24200 4 . First aid measures Skin contact : pain or irritation,redness,blistering may occur,reduced foetal weight,increase in foetal deaths,skeletal malformations Ingestion : stomach pains,reduced foetal weight,increase in foetal deaths,skeletal malformations
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide,nitrogen oxides,sulfur oxides decomposition products
Hazchem code : 2X 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
Date of issue/Date of revision : 14 November 2017 Date of previous issue : 1 January 2017 Version : 4 3/10 CRW24200 6 . Accidental release measures Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits Ingredient name Exposure limits 2-(2-butoxyethoxy)ethanol ACGIH TLV (United States, 3/2016). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapor cyclohexylamine Safe Work Australia (Australia, 1/2014). TWA: 41 mg/m³, 0 times per shift, 8 hours. TWA: 10 ppm, 0 times per shift, 8 hours.
Appropriate engineering : If user operations generate dust, fumes, gas, vapour or mist, use process controls enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Date of issue/Date of revision : 14 November 2017 Date of previous issue : 1 January 2017 Version : 4 4/10 CRW24200 8 . Exposure controls/personal protection Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Neoprene gloves. Rubber gloves. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. [Clear.] Colour : Amber to brown. Odour : Characteristic. Odour threshold : Not available. pH : 10 to 12 [Conc. (% w/w): 100%] Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 1.01 to 1.03 (20°C) Solubility : Easily soluble in the following materials: cold water.
Date of issue/Date of revision : 14 November 2017 Date of previous issue : 1 January 2017 Version : 4 5/10 CRW24200 9 . Physical and chemical properties Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available. 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure 2-(2-butoxyethoxy)ethanol LD50 Dermal Rabbit 2700 mg/kg - LD50 Oral Rat 4500 mg/kg - cyclohexylamine LC50 Inhalation Vapour Mouse 1070 mg/m³ 4 hours LC50 Inhalation Vapour Rat 2.3 mg/l 4 hours LC50 Inhalation Vapour Rat 7500 mg/m³ 4 hours Conclusion/Summary : No known significant effects or critical hazards. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation 2-(2-butoxyethoxy)ethanol Eyes - Moderate irritant Rabbit - 24 hours 20 - milligrams Eyes - Severe irritant Rabbit - 20 milligrams - cyclohexylamine Eyes - Severe irritant Rabbit - 24 hours 50 - Micrograms Eyes - Severe irritant Rabbit - 5 minutes - 100 microliters Skin - Severe irritant Human - 48 hours 125 - milligrams Skin - Severe irritant Rabbit - 24 hours 2 - milligrams Skin - Severe irritant Rabbit - 500 - microliters Conclusion/Summary Skin : Causes pain and burns in contact with skin. May cause permanent skin damage. Eyes : Risk of serious damage to eyes. May cause eye burns and permanent eye injury. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards.
Date of issue/Date of revision : 14 November 2017 Date of previous issue : 1 January 2017 Version : 4 6/10 CRW24200 11 . Toxicological information Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : Suspected of damaging fertility. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available. Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : No known significant effects or critical hazards. Skin contact : Causes severe burns. Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : pain,watering,redness Inhalation : reduced foetal weight,increase in foetal deaths,skeletal malformations Skin contact : pain or irritation,redness,blistering may occur,reduced foetal weight,increase in foetal deaths,skeletal malformations Ingestion : stomach pains,reduced foetal weight,increase in foetal deaths,skeletal malformations
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards.
Date of issue/Date of revision : 14 November 2017 Date of previous issue : 1 January 2017 Version : 4 7/10 CRW24200 11 . Toxicological information Developmental effects : No known significant effects or critical hazards. Fertility effects : Suspected of damaging fertility.
12 . Ecological information Toxicity : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Product/ingredient name Result Species Exposure 2-(2-butoxyethoxy)ethanol Acute LC50 1300000 μg/l Fresh water Fish - Lepomis macrochirus 96 hours Amines, N-tallow Acute LC50 2723 mg/l Marine water Crustaceans - Corophium 10 days alkyltrimethylenedi-, Volutator ethoxylated cyclohexylamine Acute EC50 20 mg/l Fresh water Algae - Pseudokirchneriella 96 hours subcapitata Acute LC50 44 mg/l Fresh water Fish - Oncorhynchus mykiss 96 hours Persistence and degradability Not available. Bioaccumulative potential
Product/ingredient name LogPow BCF Potential 2-(2-butoxyethoxy)ethanol 1 - low cyclohexylamine 3.7 3.162 low Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (Oxyalkylated amine)
ADG UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (Oxyalkylated amine)
IMDG UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (Oxyalkylated amine)
IATA UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (Oxyalkylated amine)
PG* : Packing group
Date of issue/Date of revision : 14 November 2017 Date of previous issue : 1 January 2017 Version : 4 8/10 CRW24200 14 . Transport information Regulatory Environmental Additional information** information hazards ADR/RID Class Yes. The environmentally hazardous substance mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Hazchem code 2X ADG Class No. Hazchem code 2X IMDG Class Yes. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons 5 Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed.
Date of issue/Date of revision : 14 November 2017 Date of previous issue : 1 January 2017 Version : 4 9/10 CRW24200 16 . Other information History Date of printing : 14 November 2017. Date of issue/Date of : 14 November 2017 revision Date of previous issue : 1 January 2017 Version : 4 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Skin Corr. 1B, H314 Calculation method Repr. 2, H361 (Fertility) Calculation method Aquatic Acute 2, H401 Calculation method Aquatic Chronic 2, H411 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 14 November 2017 Date of previous issue : 1 January 2017 Version : 4 10/10 Safety Data Sheet
CRW24830 1 . Identification of the material and supplier Product identifier : CRW24830 Product code : CRW24830 ADG : AMINES, LIQUID, CORROSIVE, N.O.S. (contains oxyalkylated amine) Product type : Liquid. Identified uses : Hydrotest Corrosion Inhibitor
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : ACUTE TOXICITY (oral) - Category 4 substance or mixture SKIN CORROSION/IRRITATION - Category 1B ACUTE AQUATIC HAZARD - Category 1 LONG-TERM AQUATIC HAZARD - Category 2
GHS label elements Hazard pictograms :
Signal word : DANGER Hazard statements : H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H400 - Very toxic to aquatic life. H411 - Toxic to aquatic life with long lasting effects. Precautionary statements Prevention : Wear protective gloves: > 8 hours (breakthrough time): Rubber gloves.. Wear eye or face protection. Wear protective clothing. Avoid release to the environment. Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or physician. IF IN EYES: Immediately call a POISON CENTER or physician. Storage : Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 1/11 CRW24830 2 . Hazards identification Precautionary statements : P280, P273, P304 + P340 + P310, P301 + P310 + P331, P303 + P361 + P353 + (Code) P310, P305 + P310, P405, P501 Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number Amines, N-tallow alkyltrimethylenedi-, ethoxylated 10 - 30 61790-85-0 ammonium hydrogensulphite 10 - 30 10192-30-0 2-(2-butoxyethoxy)ethanol 5 - 10 112-34-5 Quaternary ammonium compounds, benzyl-C12-14-alkyldimethyl, 5 - 10 .68424-85-1 chlorides (outside EU) ethanediol 5 - 10 107-21-1 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Chemical burns must be treated promptly by a physician. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact : Get medical attention immediately. Call a poison center or physician. Wash affected area with soap and mild detergent for at least 20 - 60 minutes. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Call a poison center or physician. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : No known significant effects or critical hazards. Skin contact : Causes severe burns. Ingestion : Harmful if swallowed.
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 2/11 CRW24830 4 . First aid measures Over-exposure signs/symptoms Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical This material is very toxic to aquatic life. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide,nitrogen oxides,sulfur oxides decomposition products
Hazchem code : 2X 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 3/11 CRW24830 6 . Accidental release measures Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits Ingredient name Exposure limits 2-(2-butoxyethoxy)ethanol ACGIH TLV (United States, 3/2016). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapor ethanediol Safe Work Australia (Australia, 1/2014). Absorbed through skin. TWA: 10 mg/m³ 8 hours. Form: Particulate STEL: 104 mg/m³ 15 minutes. Form: Vapour
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 4/11 CRW24830 8 . Exposure controls/personal protection TWA: 52 mg/m³ 8 hours. Form: Vapour TWA: 20 ppm 8 hours. Form: Vapour STEL: 40 ppm 15 minutes. Form: Vapour
Appropriate engineering : If user operations generate dust, fumes, gas, vapour or mist, use process controls enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Rubber gloves. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Brown. With yellow/green tinge. Odour : Mild. Odour threshold : Not available. pH : 5 to 7 [Conc. (% w/w): 100%] Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available.
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 5/11 CRW24830 9 . Physical and chemical properties Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 1.08 (20°C) Solubility : Easily soluble in the following materials: cold water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available. 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Not available. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure 2-(2-butoxyethoxy)ethanol LD50 Dermal Rabbit 2700 mg/kg - LD50 Oral Rat 4500 mg/kg - Quaternary ammonium LD50 Oral Rat 426 mg/kg - compounds, benzyl- C12-14-alkyldimethyl, chlorides ethanediol LC50 Inhalation Vapour Rat >2.5 mg/l 6 hours LD50 Dermal Mouse >3500 mg/kg - Conclusion/Summary : May be harmful if ingested. Can cause target organ damage. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation 2-(2-butoxyethoxy)ethanol Eyes - Moderate irritant Rabbit - 24 hours 20 - milligrams Eyes - Severe irritant Rabbit - 20 milligrams - Quaternary ammonium Skin - Severe irritant Rabbit - 25 milligrams - compounds, benzyl- C12-14-alkyldimethyl, chlorides ethanediol Eyes - Mild irritant Rabbit - 24 hours 500 - milligrams Eyes - Mild irritant Rabbit - 1 hours 100 - milligrams Eyes - Moderate irritant Rabbit - 6 hours 1440 - milligrams Skin - Mild irritant Rabbit - 555 - milligrams Conclusion/Summary Skin : Causes pain and burns in contact with skin. May cause permanent skin damage.
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 6/11 CRW24830 11 . Toxicological information Eyes : Risk of serious damage to eyes. May cause eye burns and permanent eye injury. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available.
Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : No known significant effects or critical hazards. Skin contact : Causes severe burns. Ingestion : Harmful if swallowed.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 7/11 CRW24830 11 . Toxicological information Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : Very toxic to aquatic organisms. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Product/ingredient name Result Species Exposure Amines, N-tallow Acute LC50 2723 mg/l Marine water Crustaceans - Corophium 10 days alkyltrimethylenedi-, Volutator ethoxylated 2-(2-butoxyethoxy)ethanol Acute LC50 1300000 μg/l Fresh water Fish - Lepomis macrochirus 96 hours ethanediol; ethylene glycol Acute EC50 6500 to 13000 mg/l Fresh Algae 72 hours water Acute EC50 >100 mg/l Fresh water Daphnia 48 hours Acute LC50 >100000 μg/l Marine water Crustaceans - Crangon crangon 48 hours - Adult Acute LC50 10000000 μg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 72860 mg/l Fresh water Fish 96 hours Acute LC50 10000000 μg/l Fresh water Fish - Pimephales promelas 96 hours Persistence and degradability Product/ingredient name Aquatic half-life Photolysis Biodegradability Quaternary ammonium - - Readily compounds, benzyl- C12-14-alkyldimethyl, chlorides ethanediol; ethylene glycol - - Readily Bioaccumulative potential
Product/ingredient name LogPow BCF Potential 2-(2-butoxyethoxy)ethanol 1 - low ethanediol -1.36 - low Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 8/11 CRW24830 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (contains oxyalkylated amine)
ADG UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (contains oxyalkylated amine)
IMDG UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (contains oxyalkylated amine)
IATA UN2735 AMINES, LIQUID, 8 III CORROSIVE, N.O.S. (contains oxyalkylated amine)
PG* : Packing group Regulatory Environmental Additional information** information hazards ADR/RID Class Yes. The environmentally hazardous substance mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Hazchem code 2X ADG Class No. Hazchem code 2X IMDG Class Yes. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons 5 Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted.
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 9/11 CRW24830 15 . Regulatory information References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. 16 . Other information History Date of printing : 6 August 2017. Date of issue/Date of : 6 August 2017 revision Date of previous issue : 13 April 2014 Version : 3 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Acute Tox. 4, H302 Calculation method Skin Corr. 1B, H314 Calculation method Aquatic Acute 1, H400 Calculation method Aquatic Chronic 2, H411 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 10/11 CRW24830 16 . Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 6 August 2017 Date of previous issue : 13 April 2014 Version : 3 11/11 Safety Data Sheet
DFO24986 1 . Identification of the material and supplier Product identifier : DFO24986 Product code : DFO24986 Product type : Liquid. Identified uses : Defoamer.
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : ACUTE TOXICITY (oral) - Category 4 substance or mixture SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A
GHS label elements Hazard pictograms :
Signal word : WARNING Hazard statements : H302 - Harmful if swallowed. H319 - Causes serious eye irritation. H315 - Causes skin irritation. Precautionary statements Prevention : Wear protective gloves. Wear eye or face protection. Do not eat, drink or smoke when using this product. Response : IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Storage : Not applicable. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Precautionary statements : P280, P270, P301 + P312, P305 + P351, P501 (Code) Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification
Date of issue/Date of revision : 21 November 2016 Date of previous issue : 24 January 2016 Version : 4 1/9 DFO24986 3 . Composition/information on ingredients Substance/mixture : Substance
Ingredient name % (w/w) CAS number Polyalkylene glycol 60 - 100 Trade secret. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First-aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention. Continue to rinse for at least 15 minutes. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Get medical attention if adverse health effects persist or are severe. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 15 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : Causes skin irritation. Ingestion : Harmful if swallowed. Over-exposure signs/symptoms Eye contact : pain or irritation,watering,redness Inhalation : No specific data. Skin contact : irritation,redness Ingestion : No specific data.
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Date of issue/Date of revision : 21 November 2016 Date of previous issue : 24 January 2016 Version : 4 2/9 DFO24986 5 . Fire-fighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide decomposition products
6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use.
Date of issue/Date of revision : 21 November 2016 Date of previous issue : 24 January 2016 Version : 4 3/9 DFO24986 7 . Handling and storage Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits
Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Date of issue/Date of revision : 21 November 2016 Date of previous issue : 24 January 2016 Version : 4 4/9 DFO24986 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Colourless. to Yellow. Odour : Characteristic. Odour threshold : Not available. pH : 5 to 8.5 [Conc. (% w/w): 16.7% - (62.5% IPA:37.5% Water)] Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: 188°C (370.4°F) [ASTM D93] Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : <0.0013 kPa (<0.01 mm Hg) Vapour density : >1 [Air = 1] Relative density : 1 (20°C) Solubility : Not available. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Kinematic (40°C): 370 cSt Pour point : -23.3°C (-9.9°F) 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Conclusion/Summary : May be harmful if ingested. Can cause target organ damage. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Polyalkylene glycol Eyes - Mild irritant Rabbit - 24 hours 500 - milligrams Skin - Mild irritant Rabbit - 24 hours 500 - milligrams Skin - Mild irritant Rabbit - 4 hours 80 - milligrams Skin - Mild irritant Rabbit - 500 - milligrams Conclusion/Summary Skin : May cause skin irritation.
Date of issue/Date of revision : 21 November 2016 Date of previous issue : 24 January 2016 Version : 4 5/9 DFO24986 11 . Toxicological information Eyes : May cause eye irritation. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available. Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard Name Result Not available.
Information on the likely : Not available. routes of exposure Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : Causes skin irritation. Ingestion : Harmful if swallowed.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : pain or irritation,watering,redness Inhalation : No specific data. Skin contact : irritation,redness Ingestion : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure
Date of issue/Date of revision : 21 November 2016 Date of previous issue : 24 January 2016 Version : 4 6/9 DFO24986 11 . Toxicological information Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : No known significant effects or critical hazards. Product/ingredient name Result Species Exposure Polyalkylene glycol Acute EC50 95 ppm Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 50 ppm Fresh water Fish - Pimephales promelas 96 hours Persistence and degradability Not available. Bioaccumulative potential
Product/ingredient name LogPow BCF Potential Polyalkylene glycol 1.18 to 4.37 - low Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID Not regulated. - - -
ADG Not regulated. - - -
IMDG Not regulated. - - -
IATA Not regulated. - - -
PG* : Packing group
Date of issue/Date of revision : 21 November 2016 Date of previous issue : 24 January 2016 Version : 4 7/9 DFO24986 14 . Transport information Regulatory Environmental Additional information information hazards ADR/RID Class No. Hazchem code - ADN Class No. Hazchem code - IMDG Class No. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of MARPOL 73/78 and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons Not regulated. Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed.
Date of issue/Date of revision : 21 November 2016 Date of previous issue : 24 January 2016 Version : 4 8/9 DFO24986 16 . Other information History Date of printing : 21 November 2016. Date of issue/Date of : 21 November 2016 revision Date of previous issue : 24 January 2016 Version : 4 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Acute Tox. 4, H302 Calculation method Skin Irrit. 2, H315 Calculation method Eye Irrit. 2A, H319 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 21 November 2016 Date of previous issue : 24 January 2016 Version : 4 9/9 SAFETY DATA SHEET NALCO® EC1477A
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : NALCO® EC1477A
Other means of identification : Not applicable.
Recommended use : CORROSION INHIBITOR
Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits.
Company : ECOLAB PTY LTD 2 Drake Avenue Macquarie Park NSW 2113 Australia A.B.N. 59 000 449 990 TEL: 1300 654 224 FAX: +61 2 8870 8680
Emergency telephone : 1800 205 506 number International: +64 7 958 2372
Issuing date : 17.06.2016
Section: 2. HAZARDS IDENTIFICATION
GHS Classification Acute toxicity (Inhalation) : Category 4 Skin corrosion/irritation : Category 1B Serious eye damage/eye : Category 1 irritation Skin sensitization : Category 1
GHS Label element Hazard pictograms :
Signal Word : Danger
Hazard Statements : Causes severe skin burns and eye damage. May cause an allergic skin reaction. Harmful if inhaled.
Precautionary Statements : Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. If skin irritation or rash occurs: Get medical advice/ attention.Wash contaminated clothing before reuse.IF INHALED: Remove person to fresh air
1 / 9 SAFETY DATA SHEET
NALCO® EC1477A
and keep comfortable for breathing. Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant.
Other hazards : None known.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Pure substance/mixture : Mixture
Chemical Name CAS-No. Concentration: (%) Tall Oil, DETA Imidazoline Acetates 68140-11-4 5 - 10 Benzyl-(C12-C16 Linear Alkyl)-Dimethyl-Ammonium Chloride 68424-85-1 1 - 5 Thioglycolic Acid 68-11-1 1 - 5
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Contact the Poison's Information Centre (eg Australia 13 1126; New Zealand 0800 764 766).
If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms : See Section 11 for more detailed information on health effects and symptoms. and effects, both acute and delayed
Section: 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing : None known. media
Specific hazards during : Not flammable or combustible. firefighting
Hazardous combustion : Decomposition products may include the following materials: Carbon oxides products
2 / 9 SAFETY DATA SHEET
NALCO® EC1477A
Special protective equipment : Use personal protective equipment. for firefighters
Specific extinguishing : Fire residues and contaminated fire extinguishing water must be disposed of in methods accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Hazchem Code : 2X
Section: 6. ACCIDENTAL RELEASE MEASURES
Initial Emergency Response : 37 Guide No
Personal precautions, : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. protective equipment and Avoid inhalation, ingestion and contact with skin and eyes. When workers are emergency procedures facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non- containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only with adequate ventilation.
Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Avoid direct sunlight. At temperatures greater than 30°C a component of this product may degrade leading to the production of hydrogen sulfide (H2S).
Suitable material : Keep in properly labelled containers.
Unsuitable material : not determined
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Form of exposure Permissible Basis concentration Thioglycolic Acid 68-11-1 TWA 1 ppm AU OEL 3.8 mg/m3 Thioglycolic Acid 68-11-1 WES-TWA 1 ppm NZ OEL 3.8 mg/m3 Thioglycolic Acid 68-11-1 TWA 1 ppm ACGIH TWA 1 ppm NIOSH REL 4 mg/m3
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NALCO® EC1477A
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.
Personal protective equipment
Eye protection : Safety goggles Face-shield
Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing
Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid Colour : amber Odour : Pungent Flash point : does not flash pH : 3.7 Odour Threshold : no data available Melting point/freezing point : no data available Initial boiling point and boiling : no data available range Evaporation rate : no data available Flammability (solid, gas) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : no data available Relative density : 0.98 - 1.02, (25.0 °C), Density : no data available Water solubility : completely soluble Solubility in other solvents : no data available Partition coefficient: n- : no data available octanol/water Auto-ignition temperature : no data available Thermal decomposition : no data available
4 / 9 SAFETY DATA SHEET
NALCO® EC1477A temperature Viscosity, dynamic : no data available Viscosity, kinematic : no data available Molecular weight : no data available VOC : 4.6 %
Section: 10. STABILITY AND REACTIVITY
Chemical stability : At temperatures greater than 30°C a component of this product may degrade leading to the production of hydrogen sulfide (H2S).
Possibility of hazardous : No dangerous reaction known under conditions of normal use. reactions
Conditions to avoid : None known.
Incompatible materials : None known
Hazardous decomposition : Decomposition products may include the following materials: products Carbon oxides
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of : Inhalation, Eye contact, Skin contact exposure
Potential Health Effects
Eyes : Causes serious eye damage.
Skin : Causes severe skin burns. May cause allergic skin reaction.
Ingestion : Causes digestive tract burns.
Inhalation : Harmful if inhaled. May cause nose, throat, and lung irritation.
Chronic Exposure : Health injuries are not known or expected under normal use.
Experience with human exposure
Eye contact : Redness, Pain, Corrosion
Skin contact : Redness, Pain, Irritation, Corrosion, Allergic reactions
Ingestion : Corrosion, Abdominal pain
Inhalation : Respiratory irritation, Cough
Toxicity
Product Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg Acute inhalation toxicity : Acute toxicity estimate: 1.18 mg/l Exposure time: 4 h Acute dermal toxicity : Acute toxicity estimate: > 2,000 mg/kg
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NALCO® EC1477A
Skin corrosion/irritation : no data available Serious eye damage/eye : no data available irritation Respiratory or skin : no data available sensitization Carcinogenicity : No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive effects : No toxicity to reproduction Germ cell mutagenicity : Contains no ingredient listed as a mutagen Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : No aspiration toxicity classification Human Hazard Characterization Based on our hazard characterization, the potential human hazard is: High
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity
Environmental Effects : This product has no known ecotoxicological effects.
Product Toxicity to fish : no data available
Toxicity to daphnia and other : no data available aquatic invertebrates
Toxicity to algae : no data available
Components Toxicity to fish : Tall Oil, DETA Imidazoline Acetates LC50 : > 0.23 mg/l Exposure time: 96 h
Components Toxicity to daphnia and other : Tall Oil, DETA Imidazoline Acetates aquatic invertebrates EC50 : 0.72 mg/l Exposure time: 48 h
Benzyl-(C12-C16 Linear Alkyl)-Dimethyl-Ammonium Chloride EC50 Daphnia magna (Water flea): 0.016 mg/l Exposure time: 48 h
Components Toxicity to algae : Tall Oil, DETA Imidazoline Acetates EC50 : 0.17 mg/l Exposure time: 72 h
Components
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NALCO® EC1477A
Toxicity to bacteria : Tall Oil, DETA Imidazoline Acetates 175 mg/l
Persistence and degradability
The organic portion of this preparation is expected to be inherently biodegradable.
Mobility
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages;
Air : <5% Water : 30 - 50% Soil : 50 - 70%
The portion in water is expected to be soluble or dispersible.
Bioaccumulative potential
Component substances have a low potential to bioconcentrate.
Other information no data available
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low
Section: 13. DISPOSAL CONSIDERATIONS
Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
Land transport
Proper shipping name : CORROSIVE LIQUID, N.O.S. Technical name(s): : Tall Oil, DETA Imidazoline Acetates, Benzyl-(C12-C16 Alkyl)- Dimethyl-Ammonium Chloride UN/ID No. : UN 1760 Transport hazard class(es) : 8 Packing group : III IERG No : 37
7 / 9 SAFETY DATA SHEET
NALCO® EC1477A
Hazchem Code : 2X
Special precautions for user : Dangerous goods of Class 8 (Acids) are incompatible in a placard load with any of the following: Class 1 Explosives Class 4.3 Dangerous when wet substances Class 5.1 Oxidising agents Class 5.2 Organic peroxides Class 6 Cyanides only Class 7 Radioactive substances and are incompatible with food or food packaging in any quantity.
Air transport (IATA)
UN/ID No. : UN 1760 Proper shipping name : CORROSIVE LIQUID, N.O.S. Technical name(s) : Tall Oil, DETA Imidazoline Acetates, Benzyl-(C12-C16 Alkyl)- Dimethyl-Ammonium Chloride Transport hazard class(es) : 8 Packing group : III
Sea transport (IMDG/IMO)
UN/ID No. : UN 1760 Proper shipping name : CORROSIVE LIQUID, N.O.S. Technical name(s) : Tall Oil, DETA Imidazoline Acetates, Benzyl-(C12-C16 Alkyl)- Dimethyl-Ammonium Chloride Transport hazard class(es) : 8 Packing group : III
Section: 15. REGULATORY INFORMATION
Standard for the Uniform : No poison schedule number allocated Scheduling of Medicines and Poisons INTERNATIONAL CHEMICAL CONTROL LAWS :
AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).
CHINA All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC).
JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).
KOREA All substances in this product comply with the Chemical Control Act (CCA) and are listed on the Existing Chemicals List (ECL)
PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS).
8 / 9 SAFETY DATA SHEET
NALCO® EC1477A
Section: 16. OTHER INFORMATION
REFERENCES
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Revision Date : 17.06.2016 Date of first issue : 17.06.2016 Version Number : 1.0 Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. For additional copies of an SDS visit www.nalco.com and request access.
9 / 9 Safety Data Sheet
HDW24106 FLUORESCEIN DYE 1 . Identification of the material and supplier Product identifier : HDW24106 FLUORESCEIN DYE Product code : HDW24106 ADG : - Product type : Liquid. Identified uses : Liquid Dye
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 substance or mixture
GHS label elements Hazard pictograms :
Signal word : DANGER Hazard statements : H318 - Causes serious eye damage. Precautionary statements Prevention : Wear eye or face protection. Response : IF IN EYES: Rinse cautiously with water for several minutes. Immediately call a POISON CENTER or physician. Storage : Not applicable. Disposal : Not applicable. Precautionary statements : P280, P305 + P351 + P310 (Code) Supplemental label : Not applicable. elements
Other hazards which do not : Causes digestive tract burns. result in classification
Date of issue/Date of revision : 5 July 2017 Date of previous issue : 12 March 2015 Version : 2 1/9 HDW24106 FLUORESCEIN DYE 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number sodium carbonate 10 - 30 497-19-8 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Chemical burns must be treated promptly by a physician. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 15 minutes. Get medical attention if adverse health effects persist or are severe. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : Corrosive to the digestive tract. Causes burns. Over-exposure signs/symptoms Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Date of issue/Date of revision : 5 July 2017 Date of previous issue : 12 March 2015 Version : 2 2/9 HDW24106 FLUORESCEIN DYE 4 . First aid measures See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide,metal oxide/oxides decomposition products
Hazchem code : - 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Date of issue/Date of revision : 5 July 2017 Date of previous issue : 12 March 2015 Version : 2 3/9 HDW24106 FLUORESCEIN DYE 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits
Appropriate engineering : If user operations generate dust, fumes, gas, vapour or mist, use process controls enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Rubber gloves. Nitrile gloves. Neoprene gloves.
Date of issue/Date of revision : 5 July 2017 Date of previous issue : 12 March 2015 Version : 2 4/9 HDW24106 FLUORESCEIN DYE 8 . Exposure controls/personal protection Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Brown with a fluorescent tinge [Dark] Odour : None. Odour threshold : Not available. pH : 9.5 [Conc. (% w/w): 100%] Melting point : 0°C (32°F) Boiling point : 100°C (212°F) Flash point : Closed cup: Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 1.12 to 1.16 (20°C) Solubility : Easily soluble in the following materials: cold water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available. 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Not available. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure sodium carbonate LD50 Oral Rat 4090 mg/kg - Conclusion/Summary : No known significant effects or critical hazards.
Date of issue/Date of revision : 5 July 2017 Date of previous issue : 12 March 2015 Version : 2 5/9 HDW24106 FLUORESCEIN DYE 11 . Toxicological information Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation sodium carbonate Eyes - Mild irritant Rabbit - 0.5 minutes - 100 milligrams Eyes - Moderate irritant Rabbit - 24 hours 100 - milligrams Eyes - Severe irritant Rabbit - 50 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 - milligrams Conclusion/Summary Skin : No known significant effects or critical hazards. Eyes : Risk of serious damage to eyes. May cause eye burns and permanent eye injury. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure sodium carbonate Category 3 Not applicable. Respiratory tract irritation Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : Corrosive to the digestive tract. Causes burns.
Symptoms related to the physical, chemical and toxicological characteristics
Date of issue/Date of revision : 5 July 2017 Date of previous issue : 12 March 2015 Version : 2 6/9 HDW24106 FLUORESCEIN DYE 11 . Toxicological information Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : No known significant effects or critical hazards. Product/ingredient name Result Species Exposure sodium carbonate Acute EC50 242000 μg/l Fresh water Algae - Navicula seminulum 96 hours Acute EC50 199.82 to 298.9 mg/l Crustaceans - Ceriodaphnia 48 hours Fresh water dubia - Neonate Acute LC50 176000 μg/l Fresh water Crustaceans - Amphipoda 48 hours Persistence and degradability Not available. Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations
Date of issue/Date of revision : 5 July 2017 Date of previous issue : 12 March 2015 Version : 2 7/9 HDW24106 FLUORESCEIN DYE 14 . Transport information Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID Not regulated. - - -
ADG Not regulated. - - -
IMDG Not regulated. - - -
IATA Not regulated. - - -
PG* : Packing group Regulatory Environmental Additional information information hazards ADR/RID Class No. Hazchem code - ADG Class No. Hazchem code - IMDG Class No. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons Not regulated. Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed.
Date of issue/Date of revision : 5 July 2017 Date of previous issue : 12 March 2015 Version : 2 8/9 HDW24106 FLUORESCEIN DYE 15 . Regulatory information Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. 16 . Other information History Date of printing : 5 July 2017. Date of issue/Date of : 5 July 2017 revision Date of previous issue : 12 March 2015 Version : 2 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Eye Dam. 1, H318 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 5 July 2017 Date of previous issue : 12 March 2015 Version : 2 9/9 REVISION DATE 06/03/2015
MATERIAL SAFETY DATA SHEET Hydrosure Biocide Stick (AU) (CHP917409)
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
APPLICATION Biocides for water treatment. SUPPLIER Ecolab Pty Ltd 2 Drake Avenue Macquarie Park NSW 2113 Australia A.B.N. 59 000 449 990 +61 2 8870 8100 +61 2 8870 8680 EMERGENCY TELEPHONE 1800 205 506 International: +65 6542 9595 Free call: +800 2537 8747 PROPER SHIPPING NAME 2-BROMO-2-NITROPROPANE-1, 3-DIOL
2 HAZARDS IDENTIFICATION
RISK PHRASES R41 Risk of serious damage to eyes. R21/22 Harmful in contact with skin and if swallowed. R37/38 Irritating to respiratory system and skin. R50 Very toxic to aquatic organisms. STATEMENT OF HAZARDOUS NATURE HAZARDOUS SUBSTANCE (According to criteria of NOHSC). DANGEROUS GOODS (According to ADG Code). DG CLASS Class 4.1: Flammable solids, self-reactive substances and solid desensitised explosives. PACKING GROUP III UN NO. 3241 HAZCHEM CODE 1Y
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name EC No. CAS-No. Content % Classification (67/548)
BRONOPOL (INN) 200-143-0 52-51-7 90-100% Xn;R21/22 Xi;R37/38,R41 N;R50
The Full Text for all R-Phrases is Displayed in Section 16
4 FIRST-AID MEASURES
INHALATION Move the exposed person to fresh air at once. Get medical attention. Provide rest, warmth and fresh air. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. INGESTION DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Immediately rinse mouth and drink plenty of water (200-300 ml). Get medical attention immediately! SKIN CONTACT Remove contaminated clothing immediately and wash skin with soap and water. Contact physician if irritation continues. EYE CONTACT Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.
1 / 5 REVISION DATE 06/03/2015 Hydrosure Biocide Stick (AU) (CHP917409)
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA Water spray. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Foam. Use fire-extinguishing media appropriate for surrounding materials. SPECIAL FIRE FIGHTING PROCEDURES Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control. If risk of water pollution occurs, notify appropriate authorities. UNUSUAL FIRE & EXPLOSION HAZARDS When heated and in case of fire, irritating vapours/gases may be formed. SPECIFIC HAZARDS Fire or high temperatures create: Bromine. Oxides of: Carbon. Nitrogen. PROTECTIVE MEASURES IN FIRE Wear full protective clothing. Use air-supplied respirator during fire fighting. HAZCHEM CODE 1Y
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. ENVIRONMENTAL PRECAUTIONS Do not discharge into drains, water courses or onto the ground. SPILL CLEAN UP METHODS Shovel into dry containers. Cover and move the containers. Flush the area with water. Wear necessary protective equipment. Do not contaminate water sources or sewer. Avoid generation and spreading of dust.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS Avoid spilling, skin and eye contact. Provide good ventilation. Avoid inhalation of dust and contact with skin and eyes. STORAGE PRECAUTIONS Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Store below 25°C.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
INGREDIENT COMMENTS No exposure limits noted for ingredient(s). PROTECTIVE EQUIPMENT
ENGINEERING MEASURES Provide adequate ventilation. RESPIRATORY EQUIPMENT In case of inadequate ventilation or risk of inhalation of vapours, use suitable respiratory equipment with combination filter (type A2/P3). HAND PROTECTION Use gauntlet type rubber gloves. Nitrile gloves are recommended. EYE PROTECTION Wear tight-fitting goggles or face shield. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of skin contact. HYGIENE MEASURES Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. Wash contaminated clothing before reuse.
2 / 5 REVISION DATE 06/03/2015 Hydrosure Biocide Stick (AU) (CHP917409)
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Solid Waxy COLOUR White. ODOUR Characteristic. SOLUBILITY Completely soluble in water BOILING POINT (°C) >200°C MELTING POINT (°C) 130-133°C pH-VALUE, DILUTED SOLUTION 5.0-7.0 @1% DECOMPOSITION TEMPERATURE 140°C (°C) FLASH POINT (°C) Will not flash. PARTITION COEFFICIENT >6 (N-Octanol/Water) SOLUBILITY VALUE (g/100g >250 H2O@20°C)
10 STABILITY AND REACTIVITY
STABILITY Stable under normal temperature conditions. CONDITIONS TO AVOID Avoid heat, flames and other sources of ignition. Water, moisture. MATERIALS TO AVOID Strong alkalis. Strong oxidising substances. HAZARDOUS DECOMPOSITION PRODUCTS Fire creates: Bromine. Oxides of: Carbon. Nitrogen.
11 TOXICOLOGICAL INFORMATION
TOXIC DOSE 1 - LD 50 180 mg/kg (oral rat) TOXIC DOSE 2 - LD 50 1600 mg/l (rat dermal) TOXIC CONC. - LC 50 >5000 mg/m3/6hr rat (inh)
INHALATION Irritating to respiratory system. INGESTION Harmful if swallowed. Irritating. May be absorbed in the body and cause dizziness, nausea and vomiting. SKIN CONTACT Harmful in contact with skin. May cause sensitisation by skin contact. May be absorbed through the skin. Irritating to skin. EYE CONTACT Risk of serious damage to eyes. TARGET ORGANS Skin Eyes Respiratory system, lungs
12 ECOLOGICAL INFORMATION
ECOTOXICITY The product contains a substance which may have adverse effects on waste water treatment processes. The product contains a substance which is very toxic to aquatic organisms. LC 50, 96 Hrs, FISH mg/l ~40 EC 50, 48 Hrs, DAPHNIA, mg/l <10 (acartia tonsa) IC 50, 72 Hrs, ALGAE, mg/l <1 (skeletonema costatum)
MOBILITY The product is soluble in water.
3 / 5 REVISION DATE 06/03/2015 Hydrosure Biocide Stick (AU) (CHP917409) BIOACCUMULATION The product does not contain any substances expected to be bioaccumulating. DEGRADABILITY The product is not expected to be biodegradable.
13 DISPOSAL CONSIDERATIONS
GENERAL INFORMATION Empty containers should be taken for local recycling, recovery or waste disposal DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
FLAMMABLE SOLID 4
PROPER SHIPPING NAME 2-BROMO-2-NITROPROPANE-1, 3-DIOL UN NO. 3241 ADG CLASS NO. 4.1 DG CLASS Class 4.1: Flammable solids, self-reactive substances and solid desensitised explosives. PACKING GROUP III HAZCHEM CODE 1Y UN NO. SEA 3241 IMDG CLASS 4.1 IMDG PACK GR. III EMS F-J S-G UN NO. AIR 3241 AIR SUB CLASS 4.1 AIR PACK GR. III
15 REGULATORY INFORMATION
LABELLING
Harmful Dangerous for the environment CONTAINS BRONOPOL (INN)
RISK PHRASES R41 Risk of serious damage to eyes. R21/22 Harmful in contact with skin and if swallowed. R37/38 Irritating to respiratory system and skin. R50 Very toxic to aquatic organisms. SAFETY PHRASES S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
4 / 5 REVISION DATE 06/03/2015 Hydrosure Biocide Stick (AU) (CHP917409) S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. S24/25 Avoid contact with skin and eyes. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S57 Use appropriate containment to avoid environmental contamination.
NATIONAL REGULATIONS AND REFERENCES Approved Criteria for Classifying Hazardous Substances. National Code of Practice for the Preparation of Material Safety Data Sheets.
16 OTHER INFORMATION
REVISION COMMENTS Revised to Nalco Champion template. Revised due to change in contact information. ISSUED BY YQ REVISION DATE 06/03/2015 REV. NO./REPL. SDS 8 GENERATED RISK PHRASES IN FULL R21/22 Harmful in contact with skin and if swallowed. R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. R50 Very toxic to aquatic organisms.
5 / 5 SAFETY DATA SHEET Hydrosure™ Fluorescein Dye Stick, 26x100
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Hydrosure™ Fluorescein Dye Stick, 26x100
Other means of identification : Not applicable.
Recommended use : HYDROTEST CHEMICAL
Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits.
Company : ECOLAB PTY LTD 2 Drake Avenue Macquarie Park NSW 2113 Australia A.B.N. 59 000 449 990 TEL: 1300 654 224 FAX: +61 2 8870 8680
Emergency telephone : 1800 205 506 number International: +64 7 958 2372
Issuing date : 24.06.2016
Section: 2. HAZARDS IDENTIFICATION
GHS Classification Serious eye damage/eye : Category 2A irritation
GHS Label element Hazard pictograms :
Signal Word : Warning
Hazard Statements : Causes serious eye irritation.
Precautionary Statements : Prevention: Wash skin thoroughly after handling. Wear eye protection/face protection. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention.
Other hazards : None known.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Concentration: (%) Sodium Carbonate 497-19-8 10 - 30
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
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minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention.
In case of skin contact : Wash off with soap and plenty of water. Get medical attention if symptoms occur.
If swallowed : Rinse mouth. Get medical attention if symptoms occur.
Contact the Poison's Information Centre (eg Australia 13 1126; New Zealand 0800 764 766).
If inhaled : Get medical attention if symptoms occur.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms : See Section 11 for more detailed information on health effects and symptoms. and effects, both acute and delayed
Section: 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing : None known. media
Specific hazards during : Not flammable or combustible. firefighting
Hazardous combustion : Decomposition products may include the following materials: Carbon oxides products nitrogen oxides (NOx) Sulphur oxides
Special protective equipment : Use personal protective equipment. for firefighters
Specific extinguishing : Fire residues and contaminated fire extinguishing water must be disposed of in methods accordance with local regulations.
Section: 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Ensure clean-up is conducted by trained personnel only. Refer to protective protective equipment and measures listed in sections 7 and 8. emergency procedures
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for : Sweep up and shovel into suitable containers for disposal. containment and cleaning up
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Avoid contact with skin and eyes. Wash hands thoroughly after handling.
Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable
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labeled containers.
Suitable material : Keep in properly labelled containers.
Unsuitable material : not determined
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters Contains no substances with occupational exposure limit values.
Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
Personal protective equipment
Eye protection : Safety glasses with side-shields
Hand protection : Wear protective gloves. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin protection : Wear suitable protective clothing.
Respiratory protection : No personal respiratory protective equipment normally required.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : solid Colour : red brown Odour : no data available Flash point : does not flash pH : 8 - 9.5 Odour Threshold : no data available Melting point/freezing point : no data available Initial boiling point and boiling : no data available range Evaporation rate : Not applicable. Flammability (solid, gas) : no data available Upper explosion limit : Not applicable. Lower explosion limit : Not applicable. Vapour pressure : Not applicable. Relative vapour density : Not applicable. Relative density : no data available Density : no data available Water solubility : Miscible
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Solubility in other solvents : no data available Partition coefficient: n- : no data available octanol/water Auto-ignition temperature : > 400 °C Thermal decomposition : no data available temperature Viscosity, dynamic : Not applicable. Viscosity, kinematic : Not applicable. Molecular weight : no data available VOC : no data available
Section: 10. STABILITY AND REACTIVITY
Chemical stability : Stable under normal conditions.
Possibility of hazardous : No dangerous reaction known under conditions of normal use. reactions
Conditions to avoid : None known.
Incompatible materials : Strong acids Strong oxidizing agents
Hazardous decomposition : Decomposition products may include the following materials: products Carbon oxides nitrogen oxides (NOx) Sulphur oxides
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of : Eye contact, Skin contact exposure
Potential Health Effects
Eyes : Causes serious eye irritation.
Skin : Health injuries are not known or expected under normal use.
Ingestion : Health injuries are not known or expected under normal use.
Inhalation : Health injuries are not known or expected under normal use.
Chronic Exposure : Health injuries are not known or expected under normal use.
Experience with human exposure
Eye contact : Redness, Pain, Irritation
Skin contact : No symptoms known or expected.
Ingestion : No symptoms known or expected.
Inhalation : No symptoms known or expected.
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Toxicity
Product Acute oral toxicity : no data available Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye : no data available irritation Respiratory or skin : no data available sensitization Carcinogenicity : no data available Reproductive effects : no data available Germ cell mutagenicity : no data available Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : no data available Components Acute oral toxicity : Sodium Carbonate LD50 rat: 2,800 mg/kg
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity
Environmental Effects : This product has no known ecotoxicological effects.
Product Toxicity to fish : no data available
Toxicity to daphnia and other : no data available aquatic invertebrates
Toxicity to algae : no data available
Components Toxicity to fish : Sodium Carbonate LC50 Lepomis macrochirus (Bluegill sunfish): 300 mg/l Exposure time: 96 h
Components Toxicity to daphnia and other : Sodium Carbonate aquatic invertebrates EC50 Ceriodaphnia (water flea): 213.5 mg/l Exposure time: 48 h
Persistence and degradability no data available
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Mobility no data available
Bioaccumulative potential no data available
Other information no data available
Section: 13. DISPOSAL CONSIDERATIONS
Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
Land transport
Proper shipping name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION Air transport (IATA)
Proper shipping name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION
Sea transport (IMDG/IMO)
Proper shipping name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION
Section: 15. REGULATORY INFORMATION
Standard for the Uniform : Schedule 6 Scheduling of Medicines and Poisons INTERNATIONAL CHEMICAL CONTROL LAWS :
AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).
CHINA All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC).
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Section: 16. OTHER INFORMATION
REFERENCES
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Revision Date : 24.06.2016 Date of first issue : 24.06.2016 Version Number : 1.0 Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. For additional copies of an SDS visit www.nalco.com and request access.
7 / 7 Safety Data Sheet
FLUORESCEIN LIQUID DYE 1 . Identification of the material and supplier Product identifier : FLUORESCEIN LIQUID DYE Product code : HDW24838 ADG : - Product type : Liquid. Identified uses : Liquid Dye
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A substance or mixture
GHS label elements Hazard pictograms :
Signal word : WARNING Hazard statements : H319 - Causes serious eye irritation. Precautionary statements Prevention : Wear eye or face protection. Wash hands thoroughly after handling. Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Storage : Not applicable. Disposal : Not applicable. Precautionary statements : P280, P264, P305 + P351 + P338 (Code) Supplemental label : Not applicable. elements
Other hazards which do not : Causes digestive tract burns. result in classification
Date of issue/Date of revision : 15 March 2017 Date of previous issue : 11 May 2014 Version : 2 1/9 FLUORESCEIN LIQUID DYE 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number sodium carbonate 1 - 5 497-19-8 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Continue to rinse for at least 15 minutes. Check for and remove any contact lenses. Get medical attention. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : Corrosive to the digestive tract. Causes burns. Over-exposure signs/symptoms Eye contact : pain or irritation,watering,redness Inhalation : No specific data. Skin contact : No specific data. Ingestion : stomach pains
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Date of issue/Date of revision : 15 March 2017 Date of previous issue : 11 May 2014 Version : 2 2/9 FLUORESCEIN LIQUID DYE 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide,metal oxide/oxides decomposition products
Hazchem code : - 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Date of issue/Date of revision : 15 March 2017 Date of previous issue : 11 May 2014 Version : 2 3/9 FLUORESCEIN LIQUID DYE 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits
Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Rubber gloves. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Date of issue/Date of revision : 15 March 2017 Date of previous issue : 11 May 2014 Version : 2 4/9 FLUORESCEIN LIQUID DYE 8 . Exposure controls/personal protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Brownish Odour : None. Odour threshold : Not available. pH : 6 to 8 Melting point : 0°C (32°F) Boiling point : 100°C (212°F) Flash point : Closed cup: Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 0.98 to 1.02 (20°C) Solubility : Easily soluble in the following materials: cold water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available. 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Not available. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure sodium carbonate LD50 Oral Rat 4090 mg/kg -
Conclusion/Summary : No known significant effects or critical hazards. Irritation/Corrosion
Date of issue/Date of revision : 15 March 2017 Date of previous issue : 11 May 2014 Version : 2 5/9 FLUORESCEIN LIQUID DYE 11 . Toxicological information Product/ingredient name Result Species Score Exposure Observation sodium carbonate Eyes - Mild irritant Rabbit - 0.5 minutes - 100 milligrams Eyes - Moderate irritant Rabbit - 24 hours 100 - milligrams Eyes - Severe irritant Rabbit - 50 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 - milligrams Conclusion/Summary Skin : No known significant effects or critical hazards. Eyes : May cause eye irritation. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure sodium carbonate Category 3 Not applicable. Respiratory tract irritation Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : Corrosive to the digestive tract. Causes burns.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : pain or irritation,watering,redness
Date of issue/Date of revision : 15 March 2017 Date of previous issue : 11 May 2014 Version : 2 6/9 FLUORESCEIN LIQUID DYE 11 . Toxicological information Inhalation : No specific data. Skin contact : No specific data. Ingestion : stomach pains
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : No known significant effects or critical hazards. Product/ingredient name Result Species Exposure sodium carbonate Acute EC50 242000 μg/l Fresh water Algae - Navicula seminulum 96 hours Acute EC50 199.82 to 298.9 mg/l Crustaceans - Ceriodaphnia 48 hours Fresh water dubia - Neonate Acute LC50 176000 μg/l Fresh water Crustaceans - Amphipoda 48 hours Persistence and degradability Not available. Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations
Date of issue/Date of revision : 15 March 2017 Date of previous issue : 11 May 2014 Version : 2 7/9 FLUORESCEIN LIQUID DYE 14 . Transport information Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID Not regulated. - - -
ADG Not regulated. - - -
IMDG Not regulated. - - -
IATA Not regulated. - - -
PG* : Packing group Regulatory Environmental Additional information information hazards ADR/RID Class No. Hazchem code - ADG Class No. Hazchem code - IMDG Class No. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons Not regulated. Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed.
Date of issue/Date of revision : 15 March 2017 Date of previous issue : 11 May 2014 Version : 2 8/9 FLUORESCEIN LIQUID DYE 15 . Regulatory information Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. 16 . Other information History Date of printing : 15 March 2017. Date of issue/Date of : 15 March 2017 revision Date of previous issue : 11 May 2014 Version : 2 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Eye Irrit. 2A, H319 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 15 March 2017 Date of previous issue : 11 May 2014 Version : 2 9/9 SAFETY DATA SHEET Hydrosure™ O-3670R
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Hydrosure™ O-3670R
Other means of identification : Not applicable.
Recommended use : OXYGEN SCAVENGER, CORROSION INHIBITOR, HYDROTEST CHEMICAL
Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits.
Company : ECOLAB PTY LTD 2 Drake Avenue Macquarie Park NSW 2113 Australia A.B.N. 59 000 449 990 TEL: 1300 654 224 FAX: +61 2 8870 8680
Emergency telephone : 1800 205 506 number International: +64 7 958 2372
Issuing date : 09.06.2016
Section: 2. HAZARDS IDENTIFICATION
GHS Classification Acute toxicity (Oral) : Category 4 Skin corrosion/irritation : Category 1B Serious eye damage/eye : Category 1 irritation
GHS Label element Hazard pictograms :
Signal Word : Danger
Hazard Statements : Harmful if swallowed. Causes severe skin burns and eye damage.
Precautionary Statements : Prevention: Do not breathe dusts or mists. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Wash contaminated clothing before reuse. Storage: Store locked up. Disposal:
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Dispose of contents/ container to an approved waste disposal plant.
Other hazards : Do not mix with bleach or other chlorinated products – will cause chlorine gas. Contact with acids liberates toxic gas.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Pure substance/mixture : Mixture
Chemical Name CAS-No. Concentration: (%) Benzyl-(C12-C16 Alkyl)-Dimethyl-Ammonium Chloride 68424-85-1 10 - 30 Dipropylene Glycol Monomethyl Ether 34590-94-8 1 - 5 Ethylene Glycol 107-21-1 1 - 5 Acetic Acid 64-19-7 1 - 5 C.I. Basic Violet 10 (Rhodamine B or D&C Red No 19) 81-88-9 1 - 5
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Contact the Poison's Information Centre (eg Australia 13 1126; New Zealand 0800 764 766).
If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms : See Section 11 for more detailed information on health effects and symptoms. and effects, both acute and delayed
Section: 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing : None known. media
Specific hazards during : Not flammable or combustible. firefighting
Hazardous combustion : Decomposition products may include the following materials: Carbon oxides products nitrogen oxides (NOx) Sulphur oxides
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Hydrosure™ O-3670R
Special protective equipment : Use personal protective equipment. for firefighters
Specific extinguishing : Collect contaminated fire extinguishing water separately. This must not be methods discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Hazchem Code : 2X
Section: 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. protective equipment and Avoid inhalation, ingestion and contact with skin and eyes. When workers are emergency procedures facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non- containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only with adequate ventilation. Do not mix with bleach or other chlorinated products – will cause chlorine gas.
Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers.
Suitable material : Keep in properly labelled containers.
Unsuitable material : not determined
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Components CAS-No. Form of exposure Permissible Basis concentration Dipropylene Glycol 34590-94-8 TWA 50 ppm AU OEL Monomethyl Ether 308 mg/m3 Dipropylene Glycol 34590-94-8 WES-STEL 150 ppm NZ OEL Monomethyl Ether 909 mg/m3 WES-TWA 100 ppm NZ OEL 606 mg/m3 Dipropylene Glycol 34590-94-8 TWA 100 ppm ACGIH Monomethyl Ether STEL 150 ppm ACGIH STEL 150 ppm NIOSH REL
3 / 10 SAFETY DATA SHEET
Hydrosure™ O-3670R
900 mg/m3 TWA 100 ppm NIOSH REL 600 mg/m3 TWA 100 ppm OSHA Z1 600 mg/m3 Ethylene Glycol 107-21-1 TWA (Vapour.) 20 ppm AU OEL 52 mg/m3 VLE (Vapour.) 40 ppm AU OEL 104 mg/m3 TWA 10 mg/m3 AU OEL (Particulate.) Ethylene Glycol 107-21-1 WES-Ceiling 50 ppm NZ OEL (Vapour and mist) 127 mg/m3 Ethylene Glycol 107-21-1 Ceiling (Aerosol 100 mg/m3 ACGIH only) Acetic Acid 64-19-7 VLE 15 ppm AU OEL 37 mg/m3 TWA 10 ppm AU OEL 25 mg/m3 Acetic Acid 64-19-7 WES-TWA 10 ppm NZ OEL 25 mg/m3 WES-STEL 15 ppm NZ OEL 37 mg/m3 Acetic Acid 64-19-7 TWA 10 ppm ACGIH STEL 15 ppm ACGIH STEL 15 ppm NIOSH REL 37 mg/m3 TWA 10 ppm NIOSH REL 25 mg/m3 TWA 10 ppm OSHA Z1 25 mg/m3
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.
Personal protective equipment
Eye protection : Safety goggles Face-shield
Hand protection : Wear the following personal protective equipment: Standard glove type. Laminate film Nitrile Unsupported neoprene PVC Natural rubber Neoprene/natural rubber blend Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing
Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove
4 / 10 SAFETY DATA SHEET
Hydrosure™ O-3670R
and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid Colour : colourless Odour : Pungent Flash point : 95 °C, Not applicable. pH : 4 - 6 Odour Threshold : no data available Melting point/freezing point : no data available Initial boiling point and boiling : Not applicable. range Evaporation rate : no data available Flammability (solid, gas) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : not determined Relative vapour density : no data available Relative density : 1.045 - 1.075, (20 °C), Density : no data available Water solubility : completely miscible Solubility in other solvents : no data available Partition coefficient: n- : no data available octanol/water Auto-ignition temperature : no data available Thermal decomposition : no data available temperature Viscosity, dynamic : < 20 mPa.s (20 °C) Viscosity, kinematic : 10 mm2/s (40 °C) Molecular weight : no data available VOC : no data available
Section: 10. STABILITY AND REACTIVITY
Chemical stability : Stable under normal conditions.
Possibility of hazardous : Do not mix with bleach or other chlorinated products – will cause chlorine gas. reactions
Conditions to avoid : None known.
Incompatible materials : None known.
Hazardous decomposition : Decomposition products may include the following materials:
5 / 10 SAFETY DATA SHEET
Hydrosure™ O-3670R products Carbon oxides nitrogen oxides (NOx) Sulphur oxides
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of : Inhalation, Eye contact, Skin contact exposure
Potential Health Effects
Eyes : Causes serious eye damage.
Skin : Causes severe skin burns.
Ingestion : Harmful if swallowed. Causes digestive tract burns.
Inhalation : May cause nose, throat, and lung irritation.
Chronic Exposure : Health injuries are not known or expected under normal use.
Experience with human exposure
Eye contact : Redness, Pain, Corrosion
Skin contact : Redness, Pain, Corrosion
Ingestion : Corrosion, Abdominal pain
Inhalation : Respiratory irritation, Cough
Toxicity
Product Acute oral toxicity : Acute toxicity estimate: 1,500 mg/kg Acute inhalation toxicity : Acute toxicity estimate: 0.25 mg/l Exposure time: 4 h Acute dermal toxicity : Acute toxicity estimate: > 2,000 mg/kg Skin corrosion/irritation : no data available Serious eye damage/eye : no data available irritation Respiratory or skin : no data available sensitization Carcinogenicity : No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive effects : No toxicity to reproduction Germ cell mutagenicity : Contains no ingredient listed as a mutagen Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : No aspiration toxicity classification
6 / 10 SAFETY DATA SHEET
Hydrosure™ O-3670R
Human Hazard Characterization Based on our hazard characterization, the potential human hazard is: High
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity
Environmental Effects : This product has no known ecotoxicological effects.
Product Toxicity to fish : no data available
Toxicity to daphnia and other : no data available aquatic invertebrates
Toxicity to algae : no data available
Components Toxicity to fish : Dipropylene Glycol Monomethyl Ether LC50 Fish: > 1,000 mg/l Exposure time: 96 h
Ethylene Glycol LC50 : 72,860 mg/l Exposure time: 96 h
Acetic Acid LC50 : 75 mg/l Exposure time: 96 h
Components Toxicity to daphnia and other : Benzyl-(C12-C16 Alkyl)-Dimethyl-Ammonium Chloride aquatic invertebrates EC50 Daphnia magna (Water flea): 0.016 mg/l Exposure time: 48 h
Ethylene Glycol EC50 : > 100 mg/l Exposure time: 48 h
Components Toxicity to algae : Ethylene Glycol EC50 : 6,500 mg/l Exposure time: 96 h
Components Toxicity to bacteria : Ethylene Glycol > 1,995 mg/l
Components Toxicity to fish (Chronic : Ethylene Glycol toxicity) NOEC: 15,380 mg/l Exposure time: 7 d
Components Toxicity to daphnia and other : Ethylene Glycol
7 / 10 SAFETY DATA SHEET
Hydrosure™ O-3670R aquatic invertebrates NOEC: 8,590 mg/l (Chronic toxicity) Exposure time: 7 d
Persistence and degradability no data available
Mobility no data available
Bioaccumulative potential no data available
Other information no data available
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low
Section: 13. DISPOSAL CONSIDERATIONS
Disposal methods : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
Land transport
Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Technical name(s): : Quaternary ammonium compound UN/ID No. : UN 3265 Transport hazard class(es) : 8 Packing group : II Hazchem Code : 2X
Air transport (IATA)
UN/ID No. : UN 3265 Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Technical name(s) : Quaternary ammonium compound Transport hazard class(es) : 8 Packing group : II
Sea transport (IMDG/IMO)
UN/ID No. : UN 3265
8 / 10 SAFETY DATA SHEET
Hydrosure™ O-3670R
Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Technical name(s) : Quaternary ammonium compound Transport hazard class(es) : 8 Packing group : II Marine pollutant : Quaternary ammonium compound
Section: 15. REGULATORY INFORMATION
Standard for the Uniform : Schedule 6 Scheduling of Medicines and Poisons INTERNATIONAL CHEMICAL CONTROL LAWS :
TOXIC SUBSTANCES CONTROL ACT (TSCA) The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).
AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).
CHINA All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC).
JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).
KOREA All substances in this product comply with the Chemical Control Act (CCA) and are listed on the Existing Chemicals List (ECL)
NEW ZEALAND All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals.
PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS).
Section: 16. OTHER INFORMATION
REFERENCES
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
9 / 10 SAFETY DATA SHEET
Hydrosure™ O-3670R
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Revision Date : 09.06.2016 Date of first issue : 09.06.2016 Version Number : 1.0 Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. For additional copies of an SDS visit www.nalco.com and request access.
10 / 10 SAFETY DATA SHEET Hydrosure™ Oxygen Scav E2 Stick, 26x100
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Hydrosure™ Oxygen Scav E2 Stick, 26x100
Other means of identification : Not applicable.
Recommended use : OXYGEN SCAVENGER
Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits.
Company : ECOLAB PTY LTD 2 Drake Avenue Macquarie Park NSW 2113 Australia A.B.N. 59 000 449 990 TEL: 1300 654 224 FAX: +61 2 8870 8680
Emergency telephone : 1800 205 506 number International: +64 7 958 2372
Issuing date : 24.06.2016
Section: 2. HAZARDS IDENTIFICATION
GHS Classification Serious eye damage/eye : Category 1 irritation
GHS Label element Hazard pictograms :
Signal Word : Danger
Hazard Statements : Causes serious eye damage.
Precautionary Statements : Prevention: Wear eye protection/face protection. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.
Other hazards : None known.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Concentration: (%) Sodium Metabisulfite 7681-57-4 30 - 60
Section: 4. FIRST AID MEASURES
1 / 8 SAFETY DATA SHEET
Hydrosure™ Oxygen Scav E2 Stick, 26x100
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
In case of skin contact : Wash off with soap and plenty of water. Get medical attention if symptoms occur.
If swallowed : Rinse mouth. Get medical attention if symptoms occur.
Contact the Poison's Information Centre (eg Australia 13 1126; New Zealand 0800 764 766).
If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms : See Section 11 for more detailed information on health effects and symptoms. and effects, both acute and delayed
Section: 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing : None known. media
Specific hazards during : Not flammable or combustible. firefighting
Hazardous combustion : Decomposition products may include the following materials: Carbon oxides products nitrogen oxides (NOx) Sulphur oxides
Special protective equipment : Use personal protective equipment. for firefighters
Specific extinguishing : Fire residues and contaminated fire extinguishing water must be disposed of in methods accordance with local regulations.
Section: 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. protective equipment and Avoid inhalation, ingestion and contact with skin and eyes. When workers are emergency procedures facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for : Sweep up and shovel into suitable containers for disposal. containment and cleaning up
Section: 7. HANDLING AND STORAGE
2 / 8 SAFETY DATA SHEET
Hydrosure™ Oxygen Scav E2 Stick, 26x100
Advice on safe handling : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling.
Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers.
Suitable material : Keep in properly labelled containers.
Unsuitable material : not determined
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Form of exposure Permissible Basis concentration Sodium Metabisulfite 7681-57-4 TWA 5 mg/m3 AU OEL Sodium Metabisulfite 7681-57-4 WES-TWA 5 mg/m3 NZ OEL Sodium Metabisulfite 7681-57-4 TWA 5 mg/m3 NIOSH REL TWA 5 mg/m3 ACGIH
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.
Personal protective equipment
Eye protection : Safety goggles Face-shield
Hand protection : Wear protective gloves. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin protection : Wear suitable protective clothing.
Respiratory protection : No personal respiratory protective equipment normally required.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Solid Colour : White, to, light yellow Odour : Ammonia Flash point : Not applicable. pH : Not applicable Odour Threshold : no data available Melting point/freezing point : 133 °C Initial boiling point and boiling : Not applicable. range
3 / 8 SAFETY DATA SHEET
Hydrosure™ Oxygen Scav E2 Stick, 26x100
Evaporation rate : Not applicable. Flammability (solid, gas) : no data available Upper explosion limit : Not applicable. Lower explosion limit : Not applicable. Vapour pressure : no data available Relative vapour density : no data available Relative density : no data available Density : no data available Water solubility : soluble Solubility in other solvents : no data available Partition coefficient: n- : no data available octanol/water Auto-ignition temperature : no data available Thermal decomposition : no data available temperature Viscosity, dynamic : Not applicable. Viscosity, kinematic : no data available Molecular weight : no data available VOC : no data available
Section: 10. STABILITY AND REACTIVITY
Chemical stability : Stable under normal conditions.
Possibility of hazardous : No dangerous reaction known under conditions of normal use. reactions
Conditions to avoid : None known.
Incompatible materials : Strong acids Strong bases Strong oxidizing agents
Hazardous decomposition : Decomposition products may include the following materials: products Carbon oxides nitrogen oxides (NOx) Sulphur oxides
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of : Eye contact, Skin contact exposure
Potential Health Effects
Eyes : Causes serious eye damage.
Skin : Health injuries are not known or expected under normal use.
Ingestion : Health injuries are not known or expected under normal use.
4 / 8 SAFETY DATA SHEET
Hydrosure™ Oxygen Scav E2 Stick, 26x100
Inhalation : Health injuries are not known or expected under normal use.
Chronic Exposure : Health injuries are not known or expected under normal use.
Experience with human exposure
Eye contact : Redness, Pain, Corrosion
Skin contact : No symptoms known or expected.
Ingestion : No symptoms known or expected.
Inhalation : No symptoms known or expected.
Toxicity
Product Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye : no data available irritation Respiratory or skin : no data available sensitization Carcinogenicity : no data available Reproductive effects : no data available Germ cell mutagenicity : no data available Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : no data available Components Acute inhalation toxicity : Sodium Metabisulfite LC50 rat: > 5.5 mg/l Exposure time: 4 h
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity
Environmental Effects : This product has no known ecotoxicological effects.
Product Toxicity to fish : no data available
Toxicity to daphnia and other : no data available aquatic invertebrates
Toxicity to algae : no data available
5 / 8 SAFETY DATA SHEET
Hydrosure™ Oxygen Scav E2 Stick, 26x100
Components Toxicity to fish : Sodium Metabisulfite LC50 Fish: 150 mg/l Exposure time: 96 h
Persistence and degradability no data available
Mobility no data available
Bioaccumulative potential no data available
Other information no data available
Section: 13. DISPOSAL CONSIDERATIONS
Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
Land transport
Proper shipping name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION Air transport (IATA)
Proper shipping name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION
Sea transport (IMDG/IMO)
Proper shipping name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION
Section: 15. REGULATORY INFORMATION
Standard for the Uniform : Schedule 5 Scheduling of Medicines and Poisons
6 / 8 SAFETY DATA SHEET
Hydrosure™ Oxygen Scav E2 Stick, 26x100
INTERNATIONAL CHEMICAL CONTROL LAWS :
AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).
CHINA All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC).
JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).
KOREA All substances in this product comply with the Chemical Control Act (CCA) and are listed on the Existing Chemicals List (ECL)
PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS).
Section: 16. OTHER INFORMATION
REFERENCES
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Revision Date : 24.06.2016 Date of first issue : 24.06.2016 Version Number : 1.0 Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
7 / 8 SAFETY DATA SHEET
Hydrosure™ Oxygen Scav E2 Stick, 26x100 quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. For additional copies of an SDS visit www.nalco.com and request access.
8 / 8 SAFETY DATA SHEET
JEFFTREAT® MP Version Revision Date: SDS Number: Date of last issue: - 1.0 24.07.2017 400001001353 Date of first issue: 24.07.2017
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : JEFFTREAT® MP
Manufacturer or supplier's details Company : Huntsman Corporation Australia Pty Limited
Address : 61 Market Road Brooklyn, Victoria 3012 Australia Telephone : 1300 301 529
E-mail address : [email protected]
Emergency telephone number : Australia: 1800 786 152 (ALL HOURS) International: +65 6336 6011 (ALL HOURS)
Recommended use of the chemical and restrictions on use Recommended use : Gas treating
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification Skin corrosion/irritation : Category 1B
Serious eye damage/eye : Category 1 irritation
Respiratory sensitisation : Category 1
Skin sensitisation : Category 1
Reproductive toxicity : Category 2
Acute aquatic toxicity : Category 3
GHS label elements Hazard pictograms :
Signal word : Danger
Hazard statements : H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
SDS_AU-PP – EN – 400001001353 1 / 17 SAFETY DATA SHEET
JEFFTREAT® MP Version Revision Date: SDS Number: Date of last issue: - 1.0 24.07.2017 400001001353 Date of first issue: 24.07.2017
H361 Suspected of damaging fertility or the unborn child. H402 Harmful to aquatic life.
Precautionary statements : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P273 Avoid release to the environment. Response: P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards which do not result in classification None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous components Chemical name CAS-No. Concentration (% w/w) Amine compounds – >= 60 - <= 100
piperazine 110-85-0 >= 10 - <= 30
SDS_AU-PP – EN – 400001001353 2 / 17 SAFETY DATA SHEET
JEFFTREAT® MP Version Revision Date: SDS Number: Date of last issue: - 1.0 24.07.2017 400001001353 Date of first issue: 24.07.2017
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.
If inhaled : Call a physician or poison control centre immediately. If unconscious, place in recovery position and seek medical advice.
In case of skin contact : Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If on skin, rinse well with water. If on clothes, remove clothes.
In case of eye contact : Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital.
Most important symptoms : None known. and effects, both acute and delayed
Notes to physician : No information available.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Dry chemical Water spray Foam Carbon dioxide (CO2)
Unsuitable extinguishing : High volume water jet media
Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
SDS_AU-PP – EN – 400001001353 3 / 17 SAFETY DATA SHEET
JEFFTREAT® MP Version Revision Date: SDS Number: Date of last issue: - 1.0 24.07.2017 400001001353 Date of first issue: 24.07.2017
firefighting courses.
Hazardous combustion : No hazardous combustion products are known products
Specific extinguishing : Collect contaminated fire extinguishing water separately. This methods must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Special protective equipment : Wear self-contained breathing apparatus for firefighting if for firefighters necessary.
Hazchem Code : 2X
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : No action shall be taken involving any personal risk or without protective equipment and suitable training. emergency procedures Use personal protective equipment. Evacuate personnel to safe areas. Ensure adequate ventilation. In case of inadequate ventilation wear respiratory protection.
Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for : Neutralise with acid. containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.
SECTION 7. HANDLING AND STORAGE
Advice on protection against : Normal measures for preventive fire protection. fire and explosion
Advice on safe handling : Avoid formation of aerosol. Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.
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Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.
Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards.
Further information on : No decomposition if stored and applied as directed. storage stability
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Engineering measures : Maintain air concentrations below occupational exposure standards.
Personal protective equipment Respiratory protection : In the case of vapour formation use a respirator with an approved filter. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Refer to Australian/New Zealand Standard AS/NZS 1715 and AS/NZS 1716 for guidance on selection and use of respiratory devices.
Hand protection Remarks : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Refer to Australian/New Zealand Standard AS/NZS 2161.1: 2000 for guidance on selection and use of protective gloves. Eye protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection:
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Tightly fitting safety goggles Eye wash bottle with pure water Wear face-shield and protective suit for abnormal processing problems. Ensure that eyewash stations and safety showers are close to the workstation location. Refer to Australian/New Zealand Standard AS/NZS 1337:1992 for guidance on selection and use of protective eyeware. Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Colour : amber
Odour : amine-like
Odour Threshold : No data available
pH : 10 - 11
Melting point/freezing point : No data available
Boiling point : 187 °C
Flash point : > 200 °C Method: open cup
Evaporation rate : No data available
Flammability (solid, gas) : No data is available on the product itself.
Flammability (liquids) : No data is available on the product itself.
Upper explosion limit / Upper : No data available flammability limit
Lower explosion limit / Lower : No data available flammability limit
Vapour pressure : 5.9985 hPa (20 °C)
Relative vapour density : 1
Relative density : 1.03
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Density : 1.043 g/cm3 (20 °C)
Solubility(ies) Water solubility : soluble
Solubility in other solvents : not determined
Partition coefficient: n- : No data available octanol/water Auto-ignition temperature : not determined
Decomposition temperature : No data available
Self-Accelerating : No data is available on the product itself. decomposition temperature (SADT)
Viscosity Viscosity, kinematic : 69 mm2/s (40 °C)
Explosive properties : No data is available on the product itself.
Oxidizing properties : No data is available on the product itself.
Molecular weight : No data available
Particle size : No data is available on the product itself.
SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous : Reacts with the following substances: reactions Nitrous acid and other nitrosating agents No decomposition if stored and applied as directed.
Conditions to avoid : No data available
Incompatible materials : Incompatible with acids. Incompatible with oxidizing agents.
Hazardous decomposition : Carbon dioxide (CO2) products Carbon monoxide Nitrogen oxides (NOx)
SECTION 11. TOXICOLOGICAL INFORMATION
Exposure routes : No data is available on the product itself.
Acute toxicity Components: Amine compounds: Acute oral : LD50 (Rat, male and female): 4,680 mg/kg
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toxicityComponents Method: OECD Test Guideline 401
piperazine: Acute oral : LD50 (Rat, male and female): 2,600 mg/kg toxicityComponents Method: OECD Test Guideline 401
Components: Amine compounds: Acute inhalation toxicity : LC50 (Rat, male and female): 6.5 mg/m3 Exposure time: 6 h Test atmosphere: dust/mist
Components: Amine compounds: Acute dermal toxicity : LD50 (Rabbit, male): 10,244 mg/kg Method: OECD Test Guideline 402
LD50 (Rabbit, female): 11,336 mg/kg Method: OECD Test Guideline 402
piperazine: Acute dermal toxicity : LD50 (Rabbit, male and female): 8,300 mg/kg Method: OECD Test Guideline 402
Acute toxicity (other routes of : No data available administration)
Skin corrosion/irritation Product: Remarks: Extremely corrosive and destructive to tissue.
Serious eye damage/eye irritation Product: Remarks: May cause irreversible eye damage.
Respiratory or skin sensitisation Product: Remarks: Causes sensitisation.
Assessment: No data available
Chronic toxicity Germ cell mutagenicity Components:
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Amine compounds: Genotoxicity in vitro : Concentration: 100 - 10000 ug/plate Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative
Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative
piperazine: Genotoxicity in vitro : Concentration: 0 - 10000 ug/plate Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative
Concentration: 0 - 110 µg/L Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: negative
Concentration: 0 - 500 µg/L Metabolic activation: Metabolic activation Method: OECD Test Guideline 476 Result: positive
Concentration: 0 - 500 µg/L Metabolic activation: negative Method: OECD Test Guideline 476 Result: negative
Components: Amine compounds: Genotoxicity in vivo : Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 Result: negative
piperazine: Genotoxicity in vivo : Dose: 5000 mg/kg Result: negative
Carcinogenicity No data available
Carcinogenicity - : No data available Assessment
Reproductive toxicity Components: piperazine: Effects on fertility : Species: Rat, male and female Application Route: Oral General Toxicity F1: No observed adverse effect level: 125 mg/kg body weight
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Method: OECD Test Guideline 416 Result: positive
Components: Amine compounds: Effects on foetal : Species: Rat, male and female development Application Route: Dermal General Toxicity Maternal: No observed adverse effect level: 250 mg/kg body weight Result: No teratogenic effects
piperazine: Species: Rat, female Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 420 mg/kg body weight Result: No teratogenic effects
Components: piperazine: Reproductive toxicity - : Some evidence of adverse effects on sexual function and Assessment fertility, and/or on development, based on animal experiments.
STOT - single exposure No data available
STOT - repeated exposure No data available
Repeated dose toxicity Components: Amine compounds: Species: Rat, male and female NOAEL: 750 mg/kg Application Route: Skin contact Exposure time: 2,160 h Number of exposures: 5 d Method: Subchronic toxicity
piperazine: Species: Rat, male and female NOAEL: 627 mg/kg/d Application Route: Ingestion Exposure time: 2,160 h Number of exposures: 7 d Method: Subchronic toxicity
Species: Humans LOAEL: 30 mg/kg/d Application Route: Ingestion Exposure time: 168 h
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Method: Subacute toxicity
Repeated dose toxicity - : No data available Assessment
Aspiration toxicity No data available
Experience with human exposure General Information: No data available
Inhalation: No data available
Skin contact: No data available
Eye contact: No data available
Ingestion: No data available
Toxicology, Metabolism, Distribution No data available
Neurological effects No data available
Further information Product: Remarks: No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity Components: Amine compounds: Toxicity to fish : LC50 (Leuciscus idus (Golden orfe)): 1,000 - 2,200 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water Method: DIN 38412
piperazine: Toxicity to fish : LC50 (Poecilia reticulata (guppy)): > 1,800 mg/l Exposure time: 96 h
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Test Type: semi-static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.1.
Components: Amine compounds: Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 233 mg/l aquatic invertebrates Exposure time: 48 h Test Type: static test Test substance: Fresh water
piperazine: Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 21 mg/l aquatic invertebrates Exposure time: 48 h Test Type: static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.2.
Components: Amine compounds: Toxicity to algae : ErC50 (Desmodesmus subspicatus (green algae)): 176 mg/l Exposure time: 72 h Test substance: Fresh water Method: DIN 38412
piperazine: Toxicity to algae : NOECr (Selenastrum capricornutum (green algae)): > 1,000 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201
M-Factor (Acute aquatic : No data available toxicity)
Toxicity to fish (Chronic : No data available toxicity)
Components: piperazine: Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 12.5 mg/l aquatic invertebrates Exposure time: 21 d (Chronic toxicity) Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 211
M-Factor (Chronic aquatic : No data available toxicity)
Components: Amine compounds: Toxicity to microorganisms : EC50 (Pseudomonas putida): 413.8 mg/l
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Exposure time: 17 h Method: DIN 38 412 Part 8
Toxicity to soil dwelling : No data available organisms
Plant toxicity : No data available
Sediment toxicity : No data available
Toxicity to terrestrial : No data available organisms
Ecotoxicology Assessment Acute aquatic toxicity : No data available
Chronic aquatic toxicity : No data available
Toxicity Data on Soil : No data available
Other organisms relevant to : No data available the environment
Persistence and degradability Components: Amine compounds: Biodegradability : Inoculum: activated sludge Concentration: 41 mg/l Result: Readily biodegradable. Biodegradation: 96 % Exposure time: 18 d Method: OECD Test Guideline 301A
piperazine: Biodegradability : Inoculum: activated sludge Result: Readily biodegradable. Biodegradation: 70.2 % Exposure time: 28 d Method: OECD Test Guideline 301F
Biochemical Oxygen : No data available Demand (BOD)
Chemical Oxygen Demand : No data available (COD)
BOD/COD : No data available
ThOD : No data available
BOD/ThOD : No data available
Dissolved organic carbon : No data available (DOC)
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Physico-chemical : No data available removability
Stability in water : No data available
Components: piperazine: Photodegradation : Test Type: Air Rate constant: < .00001 Degradation (direct photolysis): 50 %
Impact on Sewage : No data available Treatment
Bioaccumulative potential Components: Amine compounds: Bioaccumulation : Bioconcentration factor (BCF): 3.16 Remarks: Does not bioaccumulate.
Partition coefficient: n- : Remarks: No data available octanol/water - Product
Mobility in soil Mobility : No data available
Components: Amine compounds: Distribution among : Koc: 1 environmental compartments piperazine: Distribution among : Koc: 507 environmental compartments Method: OECD Test Guideline 106
Stability in soil : No data available
Other adverse effects Environmental fate and : No data available pathways
Results of PBT and vPvB : No data available assessment
Endocrine disrupting : No data available potential
Adsorbed organic bound : No data available halogens (AOX)
Hazardous to the ozone layer
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Ozone-Depletion Potential Not applicable
Additional ecological : An environmental hazard cannot be excluded in the event of information - Product unprofessional handling or disposal. Harmful to aquatic life.
Global warming potential : No data available (GWP)
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company.
Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers.
SECTION 14. TRANSPORT INFORMATION
International Regulations
IATA UN/ID No. : UN 2735 Proper shipping name : Amines, liquid, corrosive, n.o.s. (PIPERAZINE) Class : 8 Packing group : II Labels : Corrosive Packing instruction (cargo : 855 aircraft) Packing instruction : 851 (passenger aircraft)
IMDG UN number : UN 2735 Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S. (PIPERAZINE) Class : 8 Packing group : II Labels : 8 EmS Code : F-A, S-B Marine pollutant : no
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Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
National Regulations
ADG UN number : UN 2735 Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S. (PIPERAZINE) Class : 8 Packing group : II Labels : 8 Hazchem Code : 2X
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture Standard for the Uniform : No poison schedule number allocated Scheduling of Medicines and Poisons
Australia Work Health and Safety Regulations - : Not listed Schedule 10 Prohibited carcinogens, restricted carcinogens and restricted hazardous chemicals.
Other international regulations The components of this product are reported in the following inventories: CH INV : The formulation contains substances listed on the Swiss Inventory DSL : All components of this product are on the Canadian DSL
AICS : On the inventory, or in compliance with the inventory
NZIoC : not determined
ENCS : On the inventory, or in compliance with the inventory
KECI : On the inventory, or in compliance with the inventory
PICCS : On the inventory, or in compliance with the inventory
IECSC : On the inventory, or in compliance with the inventory
TCSI : On the inventory, or in compliance with the inventory
TSCA : On the inventory, or in compliance with the inventory
Inventories
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AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
SECTION 16. OTHER INFORMATION
Revision Date : 24.07.2017 Date format : dd.mm.yyyy
The information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.
THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined by the user and made known to handlers, processors and end users.
The trademarks above are the property of Huntsman Corporation or an affiliate thereof.
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.
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MEG WATER 90:10 1 . Identification of the material and supplier Product identifier : MEG WATER 90:10 Product code : MEGWATER9010 ADG : - Product type : Liquid. Identified uses : Solvent.
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : ACUTE TOXICITY (oral) - Category 4 substance or mixture
GHS label elements Hazard pictograms :
Signal word : WARNING Hazard statements : H302 - Harmful if swallowed. Precautionary statements Prevention : Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Response : IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. Storage : Not applicable. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Precautionary statements : P270, P264, P301 + P312 + P330, P501 (Code) Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification
Date of issue/Date of revision : 5 September 2017 Date of previous issue : 10 January 2013 Version : 3 1/9 MEG WATER 90:10 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number ethanediol 60 - 100 107-21-1 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Continue to rinse for at least 15 minutes. Check for and remove any contact lenses. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : Harmful if swallowed. Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data.
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Date of issue/Date of revision : 5 September 2017 Date of previous issue : 10 January 2013 Version : 3 2/9 MEG WATER 90:10 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide decomposition products
6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
Date of issue/Date of revision : 5 September 2017 Date of previous issue : 10 January 2013 Version : 3 3/9 MEG WATER 90:10 7 . Handling and storage Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits Ingredient name Exposure limits ethanediol Safe Work Australia (Australia, 1/2014). Absorbed through skin. TWA: 10 mg/m³ 8 hours. Form: Particulate STEL: 104 mg/m³ 15 minutes. Form: Vapour TWA: 52 mg/m³ 8 hours. Form: Vapour TWA: 20 ppm 8 hours. Form: Vapour STEL: 40 ppm 15 minutes. Form: Vapour
Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Rubber gloves. Nitrile gloves. Neoprene gloves.
Date of issue/Date of revision : 5 September 2017 Date of previous issue : 10 January 2013 Version : 3 4/9 MEG WATER 90:10 8 . Exposure controls/personal protection Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Colourless. Odour : Faint odour. Odour threshold : Not available. pH : 8.5 Melting point : <-13°C (<8.6°F) Boiling point : Not available. Flash point : Closed cup: Not applicable. [Pensky-Martens.] Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 1.065 to 1.135 (25°C) Solubility : Easily soluble in the following materials: cold water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Kinematic (40°C): <10 cSt 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure ethanediol LC50 Inhalation Vapour Rat >2.5 mg/l 6 hours LD50 Dermal Mouse >3500 mg/kg -
Date of issue/Date of revision : 5 September 2017 Date of previous issue : 10 January 2013 Version : 3 5/9 MEG WATER 90:10 11 . Toxicological information Conclusion/Summary : May be harmful if ingested. Can cause target organ damage. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation ethanediol Eyes - Mild irritant Rabbit - 24 hours 500 - milligrams Eyes - Mild irritant Rabbit - 1 hours 100 - milligrams Eyes - Moderate irritant Rabbit - 6 hours 1440 - milligrams Skin - Mild irritant Rabbit - 555 - milligrams Conclusion/Summary Skin : No known significant effects or critical hazards. Eyes : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available. Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : Harmful if swallowed.
Symptoms related to the physical, chemical and toxicological characteristics
Date of issue/Date of revision : 5 September 2017 Date of previous issue : 10 January 2013 Version : 3 6/9 MEG WATER 90:10 11 . Toxicological information Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : No known significant effects or critical hazards. Product/ingredient name Result Species Exposure ethanediol; ethylene glycol Acute EC50 6500 to 13000 mg/l Fresh Algae 72 hours water Acute EC50 >100 mg/l Fresh water Daphnia 48 hours Acute LC50 >100000 μg/l Marine water Crustaceans - Crangon crangon 48 hours - Adult Acute LC50 10000000 μg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 72860 mg/l Fresh water Fish 96 hours Acute LC50 10000000 μg/l Fresh water Fish - Pimephales promelas 96 hours Persistence and degradability Product/ingredient name Aquatic half-life Photolysis Biodegradability ethanediol; ethylene glycol - - Readily Bioaccumulative potential
Product/ingredient name LogPow BCF Potential ethanediol -1.36 - low Other adverse effects : No known significant effects or critical hazards.
Date of issue/Date of revision : 5 September 2017 Date of previous issue : 10 January 2013 Version : 3 7/9 MEG WATER 90:10 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID Not regulated. - - -
ADG Not regulated. - - -
IMDG Not regulated. - - -
IATA Not regulated. - - -
PG* : Packing group Regulatory Environmental Additional information** information hazards ADR/RID Class No. -
ADG Class No. -
IMDG Class No. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons 6 Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
Date of issue/Date of revision : 5 September 2017 Date of previous issue : 10 January 2013 Version : 3 8/9 MEG WATER 90:10 15 . Regulatory information International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. 16 . Other information History Date of printing : 5 September 2017. Date of issue/Date of : 5 September 2017 revision Date of previous issue : 10 January 2013 Version : 3 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Acute Tox. 4, H302 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 5 September 2017 Date of previous issue : 10 January 2013 Version : 3 9/9
Safety Data Sheet
OSW24514 1 . Identification of the material and supplier Product identifier : OSW24514 Product code : OSW24514 ADG : - Product type : Liquid. Identified uses : Oxygen scavenger
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : ACUTE TOXICITY (oral) - Category 4 substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
GHS label elements Hazard pictograms :
Signal word : DANGER Hazard statements : H302 - Harmful if swallowed. H318 - Causes serious eye damage. Precautionary statements Prevention : Wear eye or face protection. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Response : IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Immediately call a POISON CENTER or physician. Storage : Not applicable. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Precautionary statements : P280, P270, P264, P301 + P312, P305 + P310, P501 (Code) Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification
Date of issue/Date of revision : 29 November 2017 Date of previous issue : 7 February 2017 Version : 4 1/9 OSW24514 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number ammonium hydrogensulphite 30 - 60 10192-30-0 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Chemical burns must be treated promptly by a physician. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 15 minutes. Get medical attention if adverse health effects persist or are severe. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : Harmful if swallowed. Over-exposure signs/symptoms Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Date of issue/Date of revision : 29 November 2017 Date of previous issue : 7 February 2017 Version : 4 2/9 OSW24514 4 . First aid measures
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : nitrogen oxides,sulfur oxides decomposition products
Hazchem code : - 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Date of issue/Date of revision : 29 November 2017 Date of previous issue : 7 February 2017 Version : 4 3/9 OSW24514 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits
Appropriate engineering : If user operations generate dust, fumes, gas, vapour or mist, use process controls enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Nitrile gloves. Neoprene gloves.
Date of issue/Date of revision : 29 November 2017 Date of previous issue : 7 February 2017 Version : 4 4/9 OSW24514 8 . Exposure controls/personal protection Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Clear. / Yellow. Odour : sulfur oxides Odour threshold : Not available. pH : 4.7 to 5.4 [Conc. (% w/w): 100%] Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 1.35 (20°C) Solubility : Easily soluble in the following materials: cold water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available. 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced.
Date of issue/Date of revision : 29 November 2017 Date of previous issue : 7 February 2017 Version : 4 5/9 OSW24514 11 . Toxicological information Information on toxicological effects Acute toxicity Conclusion/Summary : May be harmful if ingested. Can cause target organ damage. Irritation/Corrosion Conclusion/Summary Skin : No known significant effects or critical hazards. Eyes : Risk of serious damage to eyes. May cause eye burns and permanent eye injury. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available.
Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : Harmful if swallowed.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains
Date of issue/Date of revision : 29 November 2017 Date of previous issue : 7 February 2017 Version : 4 6/9 OSW24514 11 . Toxicological information Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : No known significant effects or critical hazards. Persistence and degradability Not available. Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID Not regulated. - - -
ADG Not regulated. - - -
IMDG Not regulated. - - -
IATA Not regulated. - - -
PG* : Packing group
Date of issue/Date of revision : 29 November 2017 Date of previous issue : 7 February 2017 Version : 4 7/9 OSW24514 14 . Transport information Regulatory Environmental Additional information** information hazards ADR/RID Class No. Hazchem code - ADG Class No. Hazchem code - IMDG Class No. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons Not regulated. Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed.
Date of issue/Date of revision : 29 November 2017 Date of previous issue : 7 February 2017 Version : 4 8/9 OSW24514 16 . Other information History Date of printing : 29 November 2017. Date of issue/Date of : 29 November 2017 revision Date of previous issue : 7 February 2017 Version : 4 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Acute Tox. 4, H302 Calculation method Eye Dam. 1, H318 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 29 November 2017 Date of previous issue : 7 February 2017 Version : 4 9/9 Safety Data Sheet
TRETOLITE™ RBW24136 1 . Identification of the material and supplier Product identifier : TRETOLITE™ RBW24136 Product code : RBW24136 ADG : CORROSIVE LIQUID, N.O.S. (potassium hydroxide) Product type : Liquid. Identified uses : Water clarifier.
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : SKIN CORROSION/IRRITATION - Category 1A substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
GHS label elements Hazard pictograms :
Signal word : DANGER Hazard statements : H314 - Causes severe skin burns and eye damage. Precautionary statements Prevention : Wear protective gloves: > 8 hours (breakthrough time): Nitrile gloves. Neoprene gloves. Rubber gloves.. Wear eye or face protection. Wear protective clothing. Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or physician. IF IN EYES: Immediately call a POISON CENTER or physician. Storage : Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Precautionary statements : P280, P304 + P340 + P310, P301 + P310 + P331, P303 + P361 + P353 + P310, (Code) P305 + P310, P405, P501 Supplemental label : Not applicable. elements
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 5 October 2016 Version : 4 1/9 TRETOLITE™ RBW24136 2 . Hazards identification Other hazards which do not : None known. result in classification 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number dithiocarbamate 10 - 30 Trade secret. potassium hydroxide 1 - 5 1310-58-3 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Chemical burns must be treated promptly by a physician. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Skin contact : Get medical attention immediately. Call a poison center or physician. Wash affected area with soap and mild detergent for at least 20 - 60 minutes. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Call a poison center or physician. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : Causes severe burns. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 5 October 2016 Version : 4 2/9 TRETOLITE™ RBW24136 4 . First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : metal oxide/oxides decomposition products
Hazchem code : 2X 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 5 October 2016 Version : 4 3/9 TRETOLITE™ RBW24136 6 . Accidental release measures Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits Ingredient name Exposure limits potassium hydroxide Safe Work Australia (Australia, 1/2014). TWA: 2 mg/m³ 8 hours.
Appropriate engineering : If user operations generate dust, fumes, gas, vapour or mist, use process controls enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 5 October 2016 Version : 4 4/9 TRETOLITE™ RBW24136 8 . Exposure controls/personal protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Nitrile gloves. Neoprene gloves. Rubber gloves. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Amber. to Red. Odour : Rotten eggs. Odour threshold : Not available. pH : 10.5 to 12 [Conc. (% w/w): 100%] Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 1.08 (20°C) Solubility : Easily soluble in the following materials: cold water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Kinematic (20°C): <20 cSt 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Highly reactive or incompatible with the following materials: acids. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 5 October 2016 Version : 4 5/9 TRETOLITE™ RBW24136 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure potassium hydroxide LD50 Oral Rat 273 mg/kg - Conclusion/Summary : No known significant effects or critical hazards. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation potassium hydroxide Eyes - Moderate irritant Rabbit - 24 hours 1 - milligrams Skin - Severe irritant Guinea pig - 24 hours 50 - milligrams Skin - Severe irritant Human - 24 hours 50 - milligrams Skin - Severe irritant Rabbit - 24 hours 50 - milligrams Conclusion/Summary Skin : Causes pain and burns in contact with skin. May cause permanent skin damage. Eyes : May cause eye irritation. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available. Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye irritation.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 5 October 2016 Version : 4 6/9 TRETOLITE™ RBW24136 11 . Toxicological information Inhalation : No known significant effects or critical hazards. Skin contact : Causes severe burns. Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : pain,watering,redness Inhalation : No specific data. Skin contact : pain or irritation,redness,blistering may occur Ingestion : stomach pains
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : No known significant effects or critical hazards. Product/ingredient name Result Species Exposure Potassium hydroxide and Acute LC50 80 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours mixtures which contain 5% or more. Persistence and degradability Not available. Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 5 October 2016 Version : 4 7/9 TRETOLITE™ RBW24136 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID UN1760 CORROSIVE LIQUID, N.O.S. 8 III (potassium hydroxide)
ADG UN1760 CORROSIVE LIQUID, N.O.S. 8 III (potassium hydroxide)
IMDG UN1760 CORROSIVE LIQUID, N.O.S. 8 III (potassium hydroxide)
IATA UN1760 CORROSIVE LIQUID, N.O.S. 8 III (potassium hydroxide)
PG* : Packing group Regulatory Environmental Additional information** information hazards ADR/RID Class No. Tunnel code (E)
Hazchem code 2X
ADG Class No. Hazchem code 2X IMDG Class No. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons 5 Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 5 October 2016 Version : 4 8/9 TRETOLITE™ RBW24136 15 . Regulatory information References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. 16 . Other information History Date of printing : 13 November 2017. Date of issue/Date of : 13 November 2017 revision Date of previous issue : 5 October 2016 Version : 4 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Skin Corr. 1A, H314 Expert judgment Eye Irrit. 2A, H319 Expert judgment References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 5 October 2016 Version : 4 9/9 Safety Data Sheet
TRETOLITE™ RBW24362 1 . Identification of the material and supplier Product identifier : TRETOLITE™ RBW24362 Product code : RBW24362 ADG : - Product type : Liquid. Identified uses : Water Clarifier
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : Not classified. substance or mixture
GHS label elements Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. Precautionary statements : (Code) Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification 3 . Composition/information on ingredients Substance/mixture : Mixture
There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 9 November 2016 Version : 4 1/8 TRETOLITE™ RBW24362 4 . First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data.
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : No specific data. decomposition products
Hazchem code : -
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 9 November 2016 Version : 4 2/8 TRETOLITE™ RBW24362 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits
Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 9 November 2016 Version : 4 3/8 TRETOLITE™ RBW24362 8 . Exposure controls/personal protection Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Recommended: > 8 hours (breakthrough time): Rubber gloves. Nitrile gloves. Neoprene gloves. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : White. Odour : Not available. Odour threshold : Not available. pH : 2 to 3 [Conc. (% w/w): 100%] Melting point : -3°C (26.6°F) Boiling point : Not available. Flash point : Closed cup: Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 1 to 1.04 (20°C) Solubility : Not available. Forms an emulsion with water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 9 November 2016 Version : 4 4/8 TRETOLITE™ RBW24362 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Not available. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Conclusion/Summary : No known significant effects or critical hazards. Irritation/Corrosion Conclusion/Summary Skin : No known significant effects or critical hazards. Eyes : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available. Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available.
Aspiration hazard Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 9 November 2016 Version : 4 5/8 TRETOLITE™ RBW24362 11 . Toxicological information Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : No known significant effects or critical hazards. Persistence and degradability Not available. Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 9 November 2016 Version : 4 6/8 TRETOLITE™ RBW24362 14 . Transport information Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID Not regulated. - - -
ADG Not regulated. - - -
IMDG Not regulated. - - -
IATA Not regulated. - - -
PG* : Packing group Regulatory Environmental Additional information** information hazards ADR/RID Class No. Hazchem code - ADG Class No. Hazchem code - IMDG Class No. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons Not regulated. Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed.
Stockholm Convention on Persistent Organic Pollutants Not listed.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 9 November 2016 Version : 4 7/8 TRETOLITE™ RBW24362 15 . Regulatory information Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. 16 . Other information History Date of printing : 13 November 2017. Date of issue/Date of : 13 November 2017 revision Date of previous issue : 9 November 2016 Version : 4 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Not classified. References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 9 November 2016 Version : 4 8/8 SAFETY DATA SHEET Cortron SRN-6023 (CHP802965)
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Cortron SRN-6023 (CHP802965)
Other means of identification : Not applicable.
Recommended use : CORROSION INHIBITOR
Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits.
Company : ECOLAB PTY LTD 2 Drake Avenue Macquarie Park NSW 2113 Australia A.B.N. 59 000 449 990 TEL: 1300 654 224 FAX: +61 2 8870 8680
Emergency telephone : 1800 205 506 number International: +64 7 958 2372
Issuing date : 24.06.2016
Section: 2. HAZARDS IDENTIFICATION
GHS Classification Acute toxicity (Oral) : Category 4 Skin corrosion/irritation : Category 1B Serious eye damage/eye : Category 1 irritation Skin sensitization : Category 1 Germ cell mutagenicity : Category 2 Specific target organ toxicity : Category 2 (Kidney) - repeated exposure
GHS Label element Hazard pictograms :
Signal Word : Danger
Hazard Statements : Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Suspected of causing genetic defects. May cause damage to organs (Kidney) through prolonged or repeated exposure.
Precautionary Statements : Prevention: Do not breathe dust/fume/gas/mist/vapours/spray. Wash skin thoroughly after handling. Wear protective gloves/ protective clothing/ eye protection/ face protection. Use personal protective equipment as required. Response: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth.IF SWALLOWED: Rinse mouth. Do NOT induce
1 / 9 SAFETY DATA SHEET
Cortron SRN-6023 (CHP802965)
vomiting.IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. IF exposed or concerned: Get medical advice/attention.
Other hazards : None known.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Concentration: (%) Ethylene Glycol 107-21-1 60 - 100 2-Butoxyethanol 111-76-2 5 - 10
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Contact the Poison's Information Centre (eg Australia 13 1126; New Zealand 0800 764 766).
If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms : See Section 11 for more detailed information on health effects and symptoms. and effects, both acute and delayed
Section: 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing : None known. media
Specific hazards during : Not flammable or combustible. firefighting
Hazardous combustion : Decomposition products may include the following materials: Carbon oxides products nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus
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Cortron SRN-6023 (CHP802965)
Special protective equipment : Use personal protective equipment. for firefighters
Specific extinguishing : Fire residues and contaminated fire extinguishing water must be disposed of in methods accordance with local regulations.
Hazchem Code : 2X
Section: 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. protective equipment and Avoid inhalation, ingestion and contact with skin and eyes. When workers are emergency procedures facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non- containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only with adequate ventilation.
Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Avoid direct sunlight. At temperatures greater than 30°C a component of this product may degrade leading to the production of hydrogen sulfide (H2S).
Suitable material : Keep in properly labelled containers.
Unsuitable material : not determined
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Form of exposure Permissible Basis concentration Ethylene Glycol 107-21-1 TWA (Vapour.) 20 ppm AU OEL 52 mg/m3 VLE (Vapour.) 40 ppm AU OEL 104 mg/m3 TWA 10 mg/m3 AU OEL (Particulate.) Ethylene Glycol 107-21-1 WES-Ceiling 50 ppm NZ OEL (Vapour and mist) 127 mg/m3 Ethylene Glycol 107-21-1 Ceiling (Aerosol 100 mg/m3 ACGIH only) 2-Butoxyethanol 111-76-2 TWA 20 ppm AU OEL 96.9 mg/m3 VLE 50 ppm AU OEL
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Cortron SRN-6023 (CHP802965)
242 mg/m3 2-Butoxyethanol 111-76-2 WES-TWA 25 ppm NZ OEL 121 mg/m3 2-Butoxyethanol 111-76-2 TWA 20 ppm ACGIH TWA 5 ppm NIOSH REL 24 mg/m3 TWA 50 ppm OSHA Z1 240 mg/m3
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.
Personal protective equipment
Eye protection : Safety goggles Face-shield
Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing
Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid Colour : dark brown Odour : no data available Flash point : does not flash pH : 5 - 7 Odour Threshold : no data available Melting point/freezing point : no data available Initial boiling point and boiling : no data available range Evaporation rate : no data available Flammability (solid, gas) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : no data available Relative density : 1.055 - 1.065, (25 °C),
4 / 9 SAFETY DATA SHEET
Cortron SRN-6023 (CHP802965)
Density : no data available Water solubility : no data available Solubility in other solvents : no data available Partition coefficient: n- : no data available octanol/water Auto-ignition temperature : no data available Thermal decomposition : no data available temperature Viscosity, dynamic : no data available Viscosity, kinematic : no data available Molecular weight : no data available VOC : no data available
Section: 10. STABILITY AND REACTIVITY
Chemical stability : At temperatures greater than 30°C a component of this product may degrade leading to the production of hydrogen sulfide (H2S).
Possibility of hazardous : No dangerous reaction known under conditions of normal use. reactions
Conditions to avoid : None known.
Incompatible materials : None known.
Hazardous decomposition : Decomposition products may include the following materials: products Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of : Inhalation, Eye contact, Skin contact exposure
Potential Health Effects
Eyes : Causes serious eye damage.
Skin : Causes severe skin burns. May cause allergic skin reaction.
Ingestion : Harmful if swallowed. Causes digestive tract burns.
Inhalation : May cause nose, throat, and lung irritation.
Chronic Exposure : Suspected of causing genetic defects.
Experience with human exposure
Eye contact : Redness, Pain, Corrosion
Skin contact : Redness, Pain, Irritation, Corrosion, Allergic reactions
5 / 9 SAFETY DATA SHEET
Cortron SRN-6023 (CHP802965)
Ingestion : Corrosion, Abdominal pain
Inhalation : Respiratory irritation, Cough
Toxicity
Product Acute oral toxicity : Acute toxicity estimate: 526.69 mg/kg Acute inhalation toxicity : Acute toxicity estimate: > 20 mg/l Exposure time: 4 h Acute dermal toxicity : Acute toxicity estimate: > 2,000 mg/kg Skin corrosion/irritation : no data available Serious eye damage/eye : no data available irritation Respiratory or skin : no data available sensitization Carcinogenicity : no data available Reproductive effects : no data available Germ cell mutagenicity : no data available Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : no data available
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity
Environmental Effects : This product has no known ecotoxicological effects.
Product Toxicity to fish : no data available
Toxicity to daphnia and other : no data available aquatic invertebrates
Toxicity to algae : no data available
Components Toxicity to fish : Ethylene Glycol LC50 : 72,860 mg/l Exposure time: 96 h
2-Butoxyethanol LC50 : 1,474 mg/l Exposure time: 96 h
Components Toxicity to daphnia and other : Ethylene Glycol aquatic invertebrates EC50 : > 100 mg/l
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Cortron SRN-6023 (CHP802965)
Exposure time: 48 h
2-Butoxyethanol EC50 : 690 mg/l Exposure time: 48 h
Components Toxicity to algae : Ethylene Glycol EC50 : 6,500 mg/l Exposure time: 96 h
2-Butoxyethanol EC50 : 911 mg/l Exposure time: 72 h
Components Toxicity to bacteria : Ethylene Glycol > 1,995 mg/l
2-Butoxyethanol 463 mg/l
Components Toxicity to fish (Chronic : Ethylene Glycol toxicity) NOEC: 15,380 mg/l Exposure time: 7 d
2-Butoxyethanol NOEC: > 100 mg/l Exposure time: 21 d
Components Toxicity to daphnia and other : Ethylene Glycol aquatic invertebrates NOEC: 8,590 mg/l (Chronic toxicity) Exposure time: 7 d
2-Butoxyethanol NOEC: > 100 mg/l Exposure time: 21 d
Persistence and degradability no data available
Mobility no data available
Bioaccumulative potential no data available
Other information no data available
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Cortron SRN-6023 (CHP802965)
Section: 13. DISPOSAL CONSIDERATIONS
Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
Land transport
Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Technical name(s): : Amines, coco alkyl, propionates, Mono-Coco Alkyl-Amine UN/ID No. : UN 3265 Transport hazard class(es) : 8 Packing group : III Hazchem Code : 2X
Air transport (IATA)
UN/ID No. : UN 3265 Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Technical name(s) : Amines, coco alkyl, propionates, Mono-Coco Alkyl-Amine Transport hazard class(es) : 8 Packing group : III
Sea transport (IMDG/IMO)
UN/ID No. : UN 3265 Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Technical name(s) : Amines, coco alkyl, propionates, Mono-Coco Alkyl-Amine Transport hazard class(es) : 8 Packing group : III
Section: 15. REGULATORY INFORMATION
Standard for the Uniform : Schedule 6 Scheduling of Medicines and Poisons INTERNATIONAL CHEMICAL CONTROL LAWS :
AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).
Section: 16. OTHER INFORMATION
REFERENCES
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
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Cortron SRN-6023 (CHP802965)
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Revision Date : 24.06.2016 Date of first issue : 24.06.2016 Version Number : 1.0 Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. For additional copies of an SDS visit www.nalco.com and request access.
9 / 9 SAFETY DATA SHEET Transaqua HT2
Section 1. Identification GHS product identifier Transaqua HT2 Product code 462602-AU24 SDS no. 462602 Relevant identified uses of the substance or mixture and uses advised against Use of the substance/ Hydraulic fluid mixture For specific application advice see appropriate Technical Data Sheet or consult our company representative. Manufacturer Supplier Castrol Australia Pty Ltd Level 17, 717 Bourke Street Docklands, Victoria 3008 ABN 87 008 459 407 www.castrol.com.au
Tel: +61 (03) 9268 4111 Fax: +61 (03) 9268 3321 EMERGENCY TELEPHONE +61 2801 44558 (or 1800 14 14 74 within Australia) NUMBER OTHER PRODUCT Technical Advice Helpline Number: 1300 557 998 INFORMATION Section 2. Hazard(s) identification Classification of the ACUTE TOXICITY (oral) - Category 4 substance or mixture SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE (kidneys) - Category 2
GHS label elements Hazard pictograms
Signal word WARNING Hazard statements H302 - Harmful if swallowed. H373 - May cause damage to organs through prolonged or repeated exposure. (kidneys) Precautionary statements Prevention P260 - Do not breathe vapour. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. Response P314 - Get medical attention if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. Storage Not applicable. Disposal P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Supplemental label Not applicable. elements
Product name Transaqua HT2 Product code 462602-AU24 Page: 1/10 Version 2.02 Date of issue 27/10/2017 Format Australia Language ENGLISH (Australia) (ENGLISH) Section 2. Hazard(s) identification Other hazards which do not Defatting to the skin. result in classification Note: High Pressure Applications Injections through the skin resulting from contact with the product at high pressure constitute a major medical emergency. See 'Notes to physician' under First-Aid Measures, Section 4 of this Safety Data Sheet. Section 3. Composition and ingredient information Substance/mixture Mixture Ethylene glycol; ethanediol. Proprietary performance additives. Ingredient name % (w/w) CAS number Ethylene glycol ≥30 - ≤60 107-21-1 Triethanolamine ≤5 102-71-6 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses. Get medical attention. Inhalation If inhaled, remove to fresh air. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Get medical attention if symptoms occur. Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if symptoms occur. Ingestion If ingested, call a physician or Poison Control Center immediately. Get medical attention urgently informing the doctor that a product containing ethylene glycol has been ingested and specific treatment may be required. Transport casualty together with the product container, its label, or the safety data sheet urgently to hospital. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.
Most important symptoms/effects, acute and delayed See Section 11 for more detailed information on health effects and symptoms. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Note: High Pressure Applications Injections through the skin resulting from contact with the product at high pressure constitute a major medical emergency. Injuries may not appear serious at first but within a few hours tissue becomes swollen, discoloured and extremely painful with extensive subcutaneous necrosis. Surgical exploration should be undertaken without delay. Thorough and extensive debridement of the wound and underlying tissue is necessary to minimise tissue loss and prevent or limit permanent damage. Note that high pressure may force the product considerable distances along tissue planes.
Specific treatments Ethylene Glycol: Gastric irrigation, ethanol or fomepizole may have value in treatment. Consult physician. Product name Transaqua HT2 Product code 462602-AU24 Page: 2/10 Version 2.02 Date of issue 27/10/2017 Format Australia Language ENGLISH (Australia) (ENGLISH) Section 4. First aid measures Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Section 5. Firefighting measures Extinguishing media Suitable extinguishing In case of fire, use water fog, alcohol resistant foam, dry chemical or carbon dioxide media extinguisher or spray. Unsuitable extinguishing Do not use water jet. media
Specific hazards arising In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Hazardous thermal Combustion products may include the following: decomposition products carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide) nitrogen oxides (NO, NO₂ etc.)
Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective Fire-fighters should wear positive pressure self-contained breathing apparatus equipment for fire-fighters (SCBA) and full turnout gear. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Contact emergency personnel. For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".
Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up Small spill Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Contaminated absorbent material may pose the same hazard as the spilt product. Dispose of via a licensed waste disposal contractor.
Product name Transaqua HT2 Product code 462602-AU24 Page: 3/10 Version 2.02 Date of issue 27/10/2017 Format Australia Language ENGLISH (Australia) (ENGLISH) Section 7. Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid contact with eyes, skin and clothing. Do not ingest. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container. Do not breathe vapour or mist. Advice on general Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. DO NOT ADD NITRITES TO THIS FLUID. Not suitable Prolonged exposure to elevated temperature
Section 8. Exposure controls and personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits Ethylene glycol Safe Work Australia (Australia). Absorbed through skin. TWA: 10 mg/m³ 8 hours. Issued/Revised: 8/2005 Form: Particulate STEL: 104 mg/m³ 15 minutes. Issued/ Revised: 8/2005 Form: Vapour TWA: 52 mg/m³ 8 hours. Issued/Revised: 8/2005 Form: Vapour TWA: 20 ppm 8 hours. Issued/Revised: 8/2005 Form: Vapour STEL: 40 ppm 15 minutes. Issued/Revised: 8/2005 Form: Vapour Triethanolamine Safe Work Australia (Australia). Skin sensitiser. TWA: 5 mg/m³ 8 hours. Issued/Revised: 4/1997
Appropriate engineering All activities involving chemicals should be assessed for their risks to health, to controls ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained. Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards. Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits. The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.
Product name Transaqua HT2 Product code 462602-AU24 Page: 4/10 Version 2.02 Date of issue 27/10/2017 Format Australia Language ENGLISH (Australia) (ENGLISH) Section 8. Exposure controls and personal protection Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Safety glasses with side shields. Skin protection Hand protection Wear protective gloves if prolonged or repeated contact is likely. Wear chemical resistant gloves. Recommended: Butyl gloves. Neoprene gloves. The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Skin protection Use of protective clothing is good industrial practice. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716 Gloves:AS/NZS 2161.1 Eye protection:AS/NZS 1336 and AS/NZS 1337 Section 9. Physical and chemical properties Appearance Physical state Liquid. Colour Brown. [Light] Odour Not available. Odour threshold Not available. pH 8.7 to 9 Melting point Not available. Boiling point Not available. Flash point Closed cup: Not applicable. [Water content interferes with flash point determination.] Evaporation rate Not available. Product name Transaqua HT2 Product code 462602-AU24 Page: 5/10 Version 2.02 Date of issue 27/10/2017 Format Australia Language ENGLISH (Australia) (ENGLISH) Section 9. Physical and chemical properties Flammability (solid, gas) Not applicable. Based on - Physical state Lower and upper explosive Not available. (flammable) limits Vapour pressure Not available. Vapour density Not available. Relative density Not available. Density >1000 kg/m³ (>1 g/cm³) at 15°C Solubility Miscible in water. Partition coefficient: n- Not available. octanol/water Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Kinematic: 2.1 to 2.5 mm2/s (2.1 to 2.5 cSt) at 40°C Section 10. Stability and reactivity Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information. Chemical stability The product is stable. Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur. reactions Under normal conditions of storage and use, hazardous polymerisation will not occur. Conditions to avoid Avoid excessive heat. Incompatible materials Reactive or incompatible with the following materials: oxidising materials. Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products products should not be produced. Section 11. Toxicological information Information on toxicological effects Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Ethylene glycol Category 2 Oral kidneys
Information on likely routes Routes of entry anticipated: Dermal, Inhalation. of exposure Potential acute health effects Eye contact No known significant effects or critical hazards. Inhalation Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Skin contact Defatting to the skin. May cause skin dryness and irritation. Ingestion Harmful if swallowed. Ethylene glycol: Ingestion of ethylene glycol can cause metabolic acidosis, kidney damage, central nervous system depression, and convulsions. The estimated human lethal dose is approximately 100 ml (3.4 ounces for an adult).
Symptoms related to the physical, chemical and toxicological characteristics Eye contact No specific data. Inhalation May be harmful by inhalation if exposure to vapour, mists or fumes resulting from thermal decomposition products occurs.
Product name Transaqua HT2 Product code 462602-AU24 Page: 6/10 Version 2.02 Date of issue 27/10/2017 Format Australia Language ENGLISH (Australia) (ENGLISH) Section 11. Toxicological information Skin contact Adverse symptoms may include the following: irritation dryness cracking Ingestion Adverse symptoms may include the following: nausea or vomiting
Delayed and immediate effects as well as chronic effects from short and long-term exposure Eye contact Potential risk of transient stinging or redness if accidental eye contact occurs. Skin contact Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/ or dermatitis. General May cause damage to organs through prolonged or repeated exposure. (kidney) Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects Birth defects and decreased fetal weight have been observed in laboratory animals fed ethylene glycol in large amounts repeatedly during pregnancy. Fertility effects No known significant effects or critical hazards.
Numerical measures of toxicity Acute toxicity estimates Route ATE value Oral 1086.9 mg/kg
Section 12. Ecological information
Persistence and degradability Expected to be biodegradable. Product/ingredient name Aquatic half-life Photolysis Biodegradability Triethanolamine - - Readily
Bioaccumulative potential This product is not expected to bioaccumulate through food chains in the environment.
Mobility in soil Soil/water partition Not available. coefficient (KOC) Mobility Spillages may penetrate the soil causing ground water contamination.
Other ecological information Miscible in water.
Product name Transaqua HT2 Product code 462602-AU24 Page: 7/10 Version 2.02 Date of issue 27/10/2017 Format Australia Language ENGLISH (Australia) (ENGLISH) Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimised wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Diluted fluid should not be discharged into sewage systems unless provided for by local regulations. Dispose under conditions approved by the local authority or via a licensed waste disposal contractor. Special Precautions for No additional special precautions identified. Landfill or Incineration Section 14. Transport information
ADG IMDG IATA UN number Not regulated. Not regulated. Not regulated.
UN proper - - - shipping name Transport hazard - - - class(es)
Packing group - - - Environmental No. No. No. hazards Additional - - - information
Special precautions for user Not available.
Section 15. Regulatory information Standard Uniform Schedule of Medicine and Poisons 6 Consumer products - This material is a scheduled poison and must be stored, maintained and used in accordance with the relevant regulations. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances. Model Work Health and Safety Regulations - Scheduled Substances No listed substance Montreal Protocol (Annexes A, B, C, E) Ingredient name List name Status Not listed.
Stockholm Convention on Persistent Organic Pollutants
Product name Transaqua HT2 Product code 462602-AU24 Page: 8/10 Version 2.02 Date of issue 27/10/2017 Format Australia Language ENGLISH (Australia) (ENGLISH) Section 15. Regulatory information Ingredient name List name Status Not listed.
Rotterdam Convention on Prior Informed Consent (PIC) Ingredient name List name Status Not listed.
International lists National inventory REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1. Australia inventory (AICS) All components are listed or exempted. Canada inventory At least one component is not listed in DSL but all such components are listed in NDSL. China inventory (IECSC) At least one component is not listed. Japan inventory (ENCS) At least one component is not listed. Korea inventory (KECI) At least one component is not listed. Philippines inventory At least one component is not listed. (PICCS) Taiwan Chemical At least one component is not listed. Substances Inventory (TCSI) United States inventory All components are listed or exempted. (TSCA 8b)
Section 16. Any other relevant information History Date of printing 27/10/2017 Date of issue/Date of 27/10/2017 revision Date of previous issue 27/10/2017 Version 2.02 Prepared by Product Stewardship Key to abbreviations ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation [Regulation (EC) No. 1907/2006] STEL = Short term exposure limit SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations TWA = Time weighted average VOC = Volatile Organic Compound SADT = Self-Accelerating Decomposition Temperature Varies = may contain one or more of the following 101316-69-2, 101316-70-5, 101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4, Product name Transaqua HT2 Product code 462602-AU24 Page: 9/10 Version 2.02 Date of issue 27/10/2017 Format Australia Language ENGLISH (Australia) (ENGLISH) Section 16. Any other relevant information 64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7, 64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0, 72623-87-1, 74869-22-0, 90669-74-2 Procedure used to derive the classification Classification Justification Acute Tox. 4, H302 Calculation method STOT RE 2, H373 (kidneys) Calculation method Indicates information that has changed from previously issued version. Notice to reader All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited.
Product name Transaqua HT2 Product code 462602-AU24 Page: 10/10 Version 2.02 Date of issue 27/10/2017 Format Australia Language ENGLISH (Australia) (ENGLISH) SAFETY DATA SHEET
TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : TRIETHYLENE GLYCOL
Manufacturer or supplier's details Company : Huntsman Corporation Australia Pty Limited Address : 61 Market Road Brooklyn, Victoria 3012 Australia Telephone : 1300 301 529
E-mail address : [email protected]
Emergency telephone : Australia: 1800 786 152 (ALL HOURS) International: +65 6336 6011 (ALL HOURS)
Recommended use of the chemical and restrictions on use Recommended use : Solvent
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification Not a hazardous substance or mixture. GHS Label element Not a hazardous substance or mixture. Other hazards which do not result in classification No information available.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Substance
Hazardous ingredients Chemical Name CAS-No. Concentration (%) Triethylene glycol 112-27-6 >= 60 - <= 100
SECTION 4. FIRST AID MEASURES
General advice : No hazards which require special first aid measures.
If inhaled : Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion. If symptoms persist, call a physician.
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TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
In case of skin contact : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water.
In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing.
If swallowed : Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person.
Most important symptoms : None known. and effects, both acute and delayed
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Carbon dioxide (CO2) Foam Dry chemical
Unsuitable extinguishing : No data is available on the product itself. media
Specific extinguishing : Standard procedure for chemical fires. methods
Special protective equipment : In the event of fire, wear self-contained breathing apparatus. for fire-fighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Not applicable for product as supplied. protective equipment and emergency procedures
Environmental precautions : No special environmental precautions required.
Methods and materials for : Wipe up with absorbent material (e.g. cloth, fleece). containment and cleaning up Keep in suitable, closed containers for disposal.
SECTION 7. HANDLING AND STORAGE
Advice on protection against : Normal measures for preventive fire protection. fire and explosion
Advice on safe handling : For personal protection see section 8. No special handling advice required.
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TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
Hygiene measures : General industrial hygiene practice.
Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place.
Materials to avoid : Keep away from oxidizing agents.
No special restrictions on storage with other products.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Refer to Australian/New Zealand Standard AS/NZS 1715 and AS/NZS 1716 for guidance on selection and use of respiratory devices.
Hand protection Remarks : For prolonged or repeated contact use protective gloves. Refer to Australian/New Zealand Standard AS/NZS 2161.1: 2000 for guidance on selection and use of protective gloves. Eye protection : Safety glasses Refer to Australian/New Zealand Standard AS/NZS 1337:1992 for guidance on selection and use of protective eyeware. Skin and body protection : Protective suit
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Color : colorless
Odor : sweet
Odor Threshold : No data available
pH : 6.5 - 8, Concentration: 500 g/l
Melting point : -7 °C
Boiling point : 285 °C
Flash point : 154 °C Method: closed cup
Evaporation rate : No data available
Flammability (solid, gas) : No data is available on the product itself.
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TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
Upper explosion limit : 9.2 %(V)
Lower explosion limit : 0.9 %(V)
Vapor pressure : 0.013 hPa (20 °C)
Relative vapor density : 5.2
Relative density : 1.13
Density : 1.13 g/cm3
Solubility(ies) Water solubility : > 100 g/l (25 °C) Method: No information available.
Solubility in other solvents : partly soluble Solvent: Diethyl ether
Partition coefficient: n- : No data available octanol/water Autoignition temperature : 370 °C
Thermal decomposition : No data is available on the product itself.
Viscosity Viscosity, dynamic : 49 mPa.s (20 °C)
Viscosity, kinematic : 43 mm2/s (20 °C)
Self-Accelerating : No data is available on the product itself. decomposition temperature (SADT)
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Stable under recommended storage conditions. Chemical stability : The product is chemically stable. Possibility of hazardous : No dangerous reaction known under conditions of normal use. reactions No hazards to be specially mentioned.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Incompatible with oxidizing agents.
Hazardous decomposition : Carbon dioxide (CO2) products Carbon monoxide
SECTION 11. TOXICOLOGICAL INFORMATION
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TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
Routes of exposure : No data is available on the product itself.
Acute toxicity Acute oral toxicity - Product : LD50 (Rat): 18,000 mg/kg
Acute inhalation toxicity : No data available
Acute dermal toxicity : No data available
Acute toxicity (other routes of : No data available administration)
Skin corrosion/irritation Product: Remarks: According to the classification criteria of the European Union, the product is not considered as being a skin irritant.
Serious eye damage/eye irritation Product: Remarks: According to the classification criteria of the European Union, the product is not considered as being an eye irritant.
Respiratory or skin sensitization Product: Routes of exposure: Skin Species: Humans Method: No information available. Result: Does not cause skin sensitization.
Remarks: No data available
Assessment: No data available
Chronic toxicity Germ cell mutagenicity Genotoxicity in vitro : No data available
Genotoxicity in vivo : No data available
Carcinogenicity No data available
Carcinogenicity - : No data available Assessment
Reproductive toxicity Effects on fertility : No data available
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TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
Effects on fetal development : No data available
Reproductive toxicity - : No data available Assessment
STOT-single exposure No data available
STOT-repeated exposure No data available
Repeated dose toxicity No data available
Repeated dose toxicity - : No data available Assessment
Aspiration toxicity No data available
Experience with human exposure General Information: No data available
Inhalation: No data available
Skin contact: No data available
Eye contact: No data available
Ingestion: No data available
Toxicology, Metabolism, Distribution No data available
Neurological effects No data available
Further information Product: Remarks: No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
SDS_AU-PP – EN – 400001003343 6 / 11 SAFETY DATA SHEET
TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
Toxicity to fish - Product : LC50: > 10,000 mg/l Exposure time: 96 h
Ingredients: Triethylene glycol: Toxicity to daphnia and other : EC50: 39,305 mg/l aquatic invertebrates Exposure time: 48 h
Toxicity to algae : No data available
M-Factor (Acute aquatic : No data available toxicity)
Toxicity to fish (Chronic : No data available toxicity)
Toxicity to daphnia and other : No data available aquatic invertebrates (Chronic toxicity)
M-Factor (Chronic aquatic : No data available toxicity)
Toxicity to bacteria : No data available
Toxicity to soil dwelling : No data available organisms
Plant toxicity : No data available
Sediment toxicity : No data available
Toxicity to terrestrial : No data available organisms
Ecotoxicology Assessment Acute aquatic toxicity : No data available
Chronic aquatic toxicity : No data available
Toxicity Data on Soil : No data available
Other organisms relevant to : No data available the environment
Further information: No data available
Persistence and degradability Ingredients: Triethylene glycol: Biodegradability : Result: Readily biodegradable. Biodegradation: > 70 % Exposure time: 28 d
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TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
Method: AS Method, other
Biochemical Oxygen : 0.5 mg/l Demand (BOD) - Product Incubation time: 10 d
Chemical Oxygen Demand : No data available (COD)
BOD/COD : No data available
ThOD : No data available
BOD/ThOD : No data available
Dissolved organic carbon : No data available (DOC)
Physico-chemical : No data available removability
Stability in water : No data available
Photodegradation : No data available
Impact on Sewage : No data available Treatment
Bioaccumulative potential Bioaccumulation : No data available
Partition coefficient: n- : Remarks: No data available octanol/water - Product
Mobility in soil Mobility : No data available
Distribution among : No data available environmental compartments
Stability in soil : No data available
Other adverse effects Environmental fate and : No data available pathways
Results of PBT and vPvB : No data available assessment
Endocrine disrupting : No data available potential
Adsorbed organic bound : No data available halogens (AOX)
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TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
Hazardous to the ozone layer Ozone-Depletion Potential Not applicable
Additional ecological : There is no data available for this product. information - Product Global warming potential : No data available (GWP)
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods Waste from residues : Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging : Empty remaining contents. Empty containers should be taken to an approved waste handling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulation
IATA Not regulated as a dangerous good
IMDG Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
Domestic regulation
ADG Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture Standard for the Uniform : No poison schedule number allocated Scheduling of Medicines and Poisons
Australia Work Health and Safety Regulations - : Not listed Schedule 10 Prohibited carcinogens, restricted carcinogens and restricted hazardous chemicals.
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TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
Other international regulations The ingredients of this product are reported in the following inventories: CH INV : The mixture contains substances listed on the Swiss Inventory
TSCA : On TSCA Inventory
DSL : All components of this product are on the Canadian DSL.
AICS : On the inventory, or in compliance with the inventory
NZIoC : On the inventory, or in compliance with the inventory
ENCS : On the inventory, or in compliance with the inventory
KECI : On the inventory, or in compliance with the inventory
PICCS : On the inventory, or in compliance with the inventory
IECSC : On the inventory, or in compliance with the inventory
Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
Date format : dd.mm.yyyy
While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE. THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined by the user and made known to handlers, processors and end users.
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY
SDS_AU-PP – EN – 400001003343 10 / 11 SAFETY DATA SHEET
TRIETHYLENE GLYCOL Version Revision Date: SDS Number: Date of last issue: - 1.0 16.12.2015 400001003343 Date of first issue: 16.12.2015
CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS, WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY AT THE ABOVE ADDRESS.
SDS_AU-PP – EN – 400001003343 11 / 11 Safety Data Sheet
WAO24026 1 . Identification of the material and supplier Product identifier : WAO24026 Product code : WAO24026 ADG : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Aromatic hydrocarbons) Product type : Liquid. Identified uses : Antifoulant
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : FLAMMABLE LIQUIDS - Category 4 substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 ASPIRATION HAZARD - Category 1 ACUTE AQUATIC HAZARD - Category 2 LONG-TERM AQUATIC HAZARD - Category 2
GHS label elements Hazard pictograms :
Signal word : DANGER Hazard statements : H227 - Combustible liquid. H319 - Causes serious eye irritation. H351 - Suspected of causing cancer. H304 - May be fatal if swallowed and enters airways. H411 - Toxic to aquatic life with long lasting effects. Precautionary statements Prevention : Obtain special instructions before use. Wear protective gloves: > 8 hours (breakthrough time): Nitrile gloves.. Wear eye or face protection. Keep away from flames and hot surfaces. - No smoking. Avoid release to the environment. Response : IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. Storage : Keep cool. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 1/11 WAO24026 2 . Hazards identification Precautionary statements : P201, P280, P210, P273, P301 + P310 + P331, P235, P501 (Code) Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number Solvent naphtha (petroleum), heavy arom. 60 - 100 64742-94-5 2-(2-butoxyethoxy)ethanol 10 - 30 112-34-5 naphthalene 5 - 10 91-20-3 1,2,4-trimethylbenzene 1 - 5 95-63-6 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Continue to rinse for at least 15 minutes. Check for and remove any contact lenses. Get medical attention. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 15 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : May be fatal if swallowed and enters airways. Over-exposure signs/symptoms Eye contact : pain or irritation,watering,redness Inhalation : No specific data. Skin contact : No specific data. Ingestion : nausea or vomiting
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 2/11 WAO24026 4 . First aid measures Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam. media Unsuitable extinguishing : Do not use water jet. media
Specific hazards arising : Combustible liquid. In a fire or if heated, a pressure increase will occur and the from the chemical container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide decomposition products
Hazchem code : •3Z 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 3/11 WAO24026 6 . Accidental release measures Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not swallow. Avoid breathing vapour or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved including any area. Store in original container protected from direct sunlight in a dry, cool and well- incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits Ingredient name Exposure limits Solvent naphtha (petroleum), heavy arom. EH40/2005 WELs (United Kingdom (UK)). TWA: 500 mg/m³, (Total hydrocarbon vapour) 8 hours. Form: Vapour 2-(2-butoxyethoxy)ethanol ACGIH TLV (United States, 3/2016). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapor naphthalene Safe Work Australia (Australia, 1/2014). STEL: 79 mg/m³, 0 times per shift, 15 minutes. STEL: 15 ppm, 0 times per shift, 15 minutes. TWA: 52 mg/m³, 0 times per shift, 8 hours. TWA: 10 ppm, 0 times per shift, 8 hours. 1,2,4-trimethylbenzene Safe Work Australia (Australia, 1/2014).
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 4/11 WAO24026 8 . Exposure controls/personal protection TWA: 123 mg/m³, 0 times per shift, 8 hours. TWA: 25 ppm, 0 times per shift, 8 hours.
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust controls ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Nitrile gloves. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. [Clear to slightly hazy liquid.] Colour : Yellow. Odour : Aromatic. Odour threshold : Not available. pH : 5.7 [Conc. (% w/w): 10% - (75%IPA:25%H2O)] Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: >65°C (>149°F) Evaporation rate : Not available. Flammability (solid, gas) : Not available.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 5/11 WAO24026 9 . Physical and chemical properties Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 0.896 to 0.916 (20°C) Solubility : Not available. Dispersible in water. Soluble in aromatic solvents. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Kinematic (40°C): 1 to 10 cSt 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure Solvent naphtha (petroleum), LD50 Oral Rat 3200 mg/kg - heavy arom. LD50 Oral Rat >2000 mg/kg - 2-(2-butoxyethoxy)ethanol LD50 Dermal Rabbit 2700 mg/kg - LD50 Oral Rat 4500 mg/kg - naphthalene LD50 Oral Rat 490 mg/kg - 1,2,4-trimethylbenzene LC50 Inhalation Vapour Rat 18000 mg/m³ 4 hours LD50 Oral Rat 5 g/kg - Conclusion/Summary : No known significant effects or critical hazards. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Solvent naphtha (petroleum), Skin - Mild irritant Rabbit - 24 hours 500 - heavy arom. microliters 2-(2-butoxyethoxy)ethanol Eyes - Moderate irritant Rabbit - 24 hours 20 - milligrams Eyes - Severe irritant Rabbit - 20 milligrams - naphthalene Skin - Mild irritant Rabbit - 495 - milligrams Skin - Severe irritant Rabbit - 24 hours 0. - 05 Mililiters Conclusion/Summary Skin : No known significant effects or critical hazards. Eyes : May cause eye irritation. Respiratory : No known significant effects or critical hazards. Sensitisation
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 6/11 WAO24026 11 . Toxicological information Conclusion/Summary Skin : No known significant effects or critical hazards. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : Suspected of causing cancer. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure 1,2,4-trimethylbenzene Category 3 Not applicable. Respiratory tract irritation Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard Name Result Solvent naphtha (petroleum), heavy arom. ASPIRATION HAZARD - Category 1
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : May be fatal if swallowed and enters airways.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : pain or irritation,watering,redness Inhalation : No specific data. Skin contact : No specific data. Ingestion : nausea or vomiting
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 7/11 WAO24026 11 . Toxicological information Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Product/ingredient name Result Species Exposure Solvent naphtha (petroleum), Acute LC50 2 to 5 mg/l Fish 96 hours heavy arom. 2-(2-butoxyethoxy)ethanol Acute LC50 1300000 μg/l Fresh water Fish - Lepomis macrochirus 96 hours naphthalene Acute EC50 1.96 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute EC50 1.6 ppm Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 2800 μg/l Marine water Crustaceans - Elasmopus 48 hours pectenicrus - Adult Acute LC50 315 μg/l Fresh water Fish - Melanotaenia fluviatilis - 96 hours Larvae Chronic NOEC 0.67 ppm Fresh water Fish - Oncorhynchus kisutch 40 days 1,2,4-trimethylbenzene Acute LC50 4910 μg/l Marine water Crustaceans - Elasmopus 48 hours pectenicrus Acute LC50 22.4 mg/l Fresh water Fish - Tilapia zillii 96 hours Persistence and degradability Product/ingredient name Aquatic half-life Photolysis Biodegradability Solvent naphtha (petroleum), - - Not readily heavy arom. naphthalene - - Not readily Bioaccumulative potential
Product/ingredient name LogPow BCF Potential Solvent naphtha (petroleum), 2.8 to 6.5 99 to 5780 high heavy arom. 2-(2-butoxyethoxy)ethanol 1 - low naphthalene 3.4 36.5 to 168 low 1,2,4-trimethylbenzene 3.63 243 low Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 8/11 WAO24026 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID UN3082 ENVIRONMENTALLY 9 III HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Aromatic hydrocarbons) ADG UN3082 ENVIRONMENTALLY 9 III HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Aromatic hydrocarbons) IMDG UN3082 ENVIRONMENTALLY 9 III HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Aromatic hydrocarbons) IATA UN3082 ENVIRONMENTALLY 9 III HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Aromatic hydrocarbons) PG* : Packing group Regulatory Environmental Additional information** information hazards ADR/RID Class Yes. This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.
Tunnel code (E)
Hazchem code 3Z
ADG Class Yes. The product is not regulated as a dangerous good when transported by road or rail in either an IBC, or in other container types if ≤500 kg. The environmentally hazardous substance mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Hazchem code •3Z IMDG Class Yes. -
IATA Class Yes. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 9/11 WAO24026 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons 5 Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed.
Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Ingredient name List name Status PAHs POPs - Annex 3 Listed 16 . Other information History Date of printing : 13 November 2017. Date of issue/Date of : 13 November 2017 revision Date of previous issue : 7 February 2017 Version : 3 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Flam. Liq. 4, H227 On basis of test data Eye Irrit. 2A, H319 Calculation method Carc. 2, H351 Calculation method Asp. Tox. 1, H304 Calculation method Aquatic Acute 2, H401 Calculation method Aquatic Chronic 2, H411 Calculation method
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 10/11 WAO24026 16 . Other information References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 7 February 2017 Version : 3 11/11 Safety Data Sheet
WCW24160 1 . Identification of the material and supplier Names Product name : WCW24160 Product code : WCW24160 ADG : AMINES, LIQUID, CORROSIVE, N.O.S. (contains ethoxylated amines) Supplier : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) Uses Material uses : Corrosion/Scale Inhibitor
2 . Hazards identification Classification : C; R34 N; R51/53 Risk phrases : R34- Causes burns. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases : S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61- Avoid release to the environment. Refer to special instructions/safety data sheet. Statement of hazardous/ : HAZARDOUS SUBSTANCE. DANGEROUS GOODS. dangerous nature GHS Classification Classification of the : SKIN CORROSION/IRRITATION - Category 1B substance or mixture SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 LONG-TERM AQUATIC HAZARD - Category 2 Hazard pictograms :
Signal word : Danger Hazard statements : Causes severe skin burns and eye damage. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. Precautionary statements
Version : 2 Page: 1/9 WCW24160 2 . Hazards identification General : Not applicable. Prevention : Wear protective gloves. Wear eye or face protection. Wear protective clothing. Avoid release to the environment. Do not breathe vapour. Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or physician. IF IN EYES: Immediately call a POISON CENTER or physician. Storage : Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Other hazards which do not : None known. result in classification 3 . Composition/information on ingredients
Ingredient name CAS number Concentration 2-(2-butoxyethoxy)ethanol 112-34-5 10 - 30 ethanediol 107-21-1 10 - 30 Amines, N-tallow alkyltrimethylenedi-, ethoxylated 61790-85-0 5 - 10 glycerol 56-81-5 5 - 10 Ammonium, alkyldimethylbenzyl-, chloride 8001-54-5 1 - 5 Other ingredients, determined not to be hazardous according to Safe Work Australia criteria, and not dangerous according to the ADG Code, make up the product concentration to 100%. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4 . First-aid measures Inhalation : Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Ingestion : Get medical attention immediately. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Skin contact : Get medical attention immediately. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Eye contact : Obtain immediate medical attention after the following First Aid measures have been administered. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Version : 2 Page: 2/9 WCW24160 4 . First-aid measures Advice to doctor : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. 5 . Fire-fighting measures Suitable : Use dry chemical, CO2, water spray (fog) or alcohol resistant foam Not suitable : Do not use water jet. Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide nitrogen oxides sulfur oxides metal oxide/oxides Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazchem code : 2X 6 . Accidental release measures Personal precautions : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Absorb with an inert dry material and place in an appropriate waste disposal container. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Storage : Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well- ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Version : 2 Page: 3/9 WCW24160 8 . Exposure controls/personal protection Occupational exposure limits Ingredient name Exposure limits 2-(2-butoxyethoxy)ethanol ACGIH TLV (United States, 4/2014). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapor ethanediol Safe Work Australia (Australia, 1/2014). Absorbed through skin. TWA: 10 mg/m³ 8 hours. Form: Particulate STEL: 104 mg/m³ 15 minutes. Form: Vapor TWA: 52 mg/m³ 8 hours. Form: Vapor TWA: 20 ppm 8 hours. Form: Vapor STEL: 40 ppm 15 minutes. Form: Vapor glycerol Safe Work Australia (Australia, 1/2014). TWA: 10 mg/m³ 8 hours. Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace procedures atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Skin : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9 . Physical and chemical properties Physical state : Liquid. Colour : Amber. Melting point : -22°C (-7.6°F) Relative density : 1.066 (20°C) Flash point : Closed cup: >72°C (>161.6°F) [Pensky-Martens.] pH : 7.1 Viscosity : Kinematic (room temperature): 0.07 cm2/s (7 cSt) Solubility : Easily soluble in the following materials: cold water.
Version : 2 Page: 4/9 WCW24160 10 . Stability and reactivity Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid release to the environment. Refer to special instructions/safety data sheet. Materials to avoid : Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced.
11 . Toxicological information Potential acute health effects Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Ingestion : May cause burns to mouth, throat and stomach. Skin contact : Corrosive to the skin. Causes burns. Eye contact : Corrosive to eyes. Causes burns. Acute toxicity Product/ingredient name Result Species Dose Exposure 2-(2-Butoxyethoxy)ethanol LD50 Dermal Rabbit 2700 mg/kg - LD50 Oral Rat 4500 mg/kg - Ethanediol LC50 Inhalation Vapour Rat >2.5 mg/l 6 hours LD50 Dermal Mouse >3500 mg/kg - glycerol LD50 Intraperitoneal Rat 4420 mg/kg - TDLo Intramuscular Rat >5000 mg/kg - Ammonium, LD50 Oral Rat 240 mg/kg - alkyldimethylbenzyl-, chloride Conclusion/Summary : Not available. Potential chronic health effects Chronic toxicity Conclusion/Summary : Not available. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation 2-(2-Butoxyethoxy)ethanol Eyes - Moderate Rabbit - 24 hours 20 - irritant milligrams Eyes - Severe Rabbit - 20 milligrams - irritant Ethanediol Eyes - Mild irritant Rabbit - 24 hours 500 - milligrams Eyes - Mild irritant Rabbit - 1 hours 100 - milligrams Eyes - Moderate Rabbit - 6 hours 1440 - irritant milligrams Skin - Mild irritant Rabbit - 555 - milligrams glycerol Eyes - Mild irritant Rabbit - 24 hours 500 - milligrams Skin - Mild irritant Rabbit - 24 hours 500 - milligrams Ammonium, alkyldimethylbenzyl-, chloride Eyes - Severe Human - 50 - irritant Micrograms Eyes - Severe Monkey - 24 hours 2 - irritant milligrams Eyes - Mild irritant Rabbit - 10 milligrams -
Version : 2 Page: 5/9 WCW24160 11 . Toxicological information Eyes - Severe Rabbit - 24 hours 1 - irritant milligrams Skin - Mild irritant Human - 72 hours 150 - Micrograms Intermittent Skin - Mild irritant Human - 24 hours 3 - Percent Skin - Moderate Human - 48 hours 1 - irritant Percent Skin - Moderate Rabbit - 24 hours 50 - irritant milligrams Conclusion/Summary : Not available. Sensitiser Conclusion/Summary : Not available. Carcinogenicity Conclusion/Summary : Not available. Mutagenicity Conclusion/Summary : Not available. Teratogenicity Conclusion/Summary : Not available. Reproductive toxicity Conclusion/Summary : Not available. Chronic effects : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Inhalation : No specific data. Ingestion : Adverse symptoms may include the following: stomach pains Irritation to digestive system Skin : Adverse symptoms may include the following: pain or irritation redness blistering may occur Eyes : Adverse symptoms may include the following: pain watering redness Target organs : Contains material which may cause damage to the following organs: blood, kidneys, mucous membranes, heart, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.
12 . Ecological information Ecotoxicity : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Aquatic ecotoxicity Product/ingredient name Result Species Exposure
Version : 2 Page: 6/9 WCW24160 12 . Ecological information 2-(2-Butoxyethoxy)ethanol Acute LC50 1300000 μg/l Fresh water Fish - Lepomis macrochirus 96 hours Ethanediol Acute EC50 6500 to 13000 mg/l Fresh Algae 96 hours water Acute EC50 >100 mg/l Fresh water Daphnia 48 hours Acute LC50 100000 μg/l Marine water Crustaceans - Crangon crangon 48 hours - Adult Acute LC50 10000000 μg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 72860 mg/l Fresh water Fish 96 hours Acute LC50 10000000 μg/l Fresh water Fish - Pimephales promelas 96 hours Amines, N-tallow Acute LC50 2723 mg/l Marine water Crustaceans - Corophium 10 days alkyltrimethylenedi-, Volutator ethoxylated Ammonium, Acute EC50 56 μg/l Fresh water Algae - Chlorella pyrenoidosa - 72 hours alkyldimethylbenzyl-, chloride Exponential growth phase Acute EC50 56 μg/l Fresh water Algae - Chlorella pyrenoidosa - 96 hours Exponential growth phase Acute EC50 <1 ppm Marine water Aquatic plants - Macrocystis 4 days pyrifera - Young Acute EC50 18 μg/l Fresh water Daphnia - Daphnia magna 48 hours Acute EC50 750 μg/l Fresh water Fish - Oryzias latipes 96 hours Chronic NOEC 0.3 mg/l Fresh water Crustaceans - Macrobrachium 48 hours rosenbergii - Intermolt Conclusion/Summary : Not available. Other ecological information Persistence/degradability Conclusion/Summary : Not available. Product/ingredient name Aquatic half-life Photolysis Biodegradability Ethanediol - - Readily Bioaccumulative potential
Product/ingredient name LogPow BCF Potential 2-(2-Butoxyethoxy)ethanol 1 - low Ethanediol -1.36 - low glycerol -1.76 - low Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Methods of disposal : This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
14 . Transport information
Regulation UN number Proper shipping name Classes PG* Label Additional information ADG UN2735 AMINES, LIQUID, 8 II Hazchem code CORROSIVE, N.O.S. 2X (contains ethoxylated amines)
Version : 2 Page: 7/9 WCW24160 14 . Transport information ADR UN2735 AMINES, LIQUID, 8 II UK Hazchem: 2X CORROSIVE, N.O.S. (contains ethoxylated amines)
IMDG UN2735 AMINES, LIQUID, 8 II - CORROSIVE, N.O.S. (contains ethoxylated amines)
IATA UN2735 AMINES, LIQUID, 8 II - CORROSIVE, N.O.S. (contains ethoxylated amines) PG* : Packing group 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons 6 Sector of Use : Industrial Professional Control of Scheduled Carcinogenic Substances Ingredient name Schedule No listed substance Australia inventory (AICS) : All components are listed or exempted. EU Classification : Xn; R48/22 Xi; R41 N; R51/53 Risk phrases : R34- Causes burns. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases : S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61- Avoid release to the environment. Refer to special instructions/safety data sheet. National regulations : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
Version : 2 Page: 8/9 WCW24160 16 . Other information Date of printing : 16 September 2015. Date of issue/ Date of : 16 September 2015 revision Date of previous issue : 2 August 2010 Version : 2 Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Version : 2 Page: 9/9 Safety Data Sheet
XC24117 1 . Identification of the material and supplier Product identifier : XC24117 Product code : XC24117 ADG : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Glutaraldehyde) Product type : Liquid. Identified uses : Biocide.
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : ACUTE TOXICITY (oral) - Category 4 substance or mixture ACUTE TOXICITY (inhalation) - Category 4 SKIN CORROSION/IRRITATION - Category 1B RESPIRATORY SENSITISATION - Category 1 SKIN SENSITISATION - Category 1 SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 2
GHS label elements Hazard pictograms :
GHS05 GHS08 GHS07 Signal word : DANGER Hazard statements : H302 + H332 - Harmful if swallowed or if inhaled. H314 - Causes severe skin burns and eye damage. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 - May cause an allergic skin reaction. H401 - Toxic to aquatic life. Precautionary statements Prevention : Wear protective gloves: > 8 hours (breakthrough time): Butyl rubber gloves. Nitrile rubber gloves.. Wear eye or face protection. Wear protective clothing. In case of inadequate ventilation wear respiratory protection. Use only outdoors or in a well- ventilated area. Avoid release to the environment. Avoid breathing vapour. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. If experiencing respiratory symptoms: Call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical attention. IF IN Date of issue/Date of revision : 30 January 2018 Date of previous issue : 13 November 2017 Version : 5.01 1/10 XC24117 2 . Hazards identification EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. Storage : Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Precautionary statements : P280, P273, P304 + P340 + P310, P301 + P310 + P331, P303 + P361 + P353 + (Code) P310, P305 + P310, P405, P501 Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number glutaral; 1,5-pentanedial 10 - 30 111-30-8
Quaternary ammonium compounds, benzyl-C12-14-alkyldimethyl, 1 - 5 .68424-85-1 chlorides (outside EU) There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. Inhalation : Get medical attention immediately. Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. In the event of any complaints or symptoms, avoid further exposure. Skin contact : Get medical attention immediately. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Get medical attention immediately. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin contact : Causes severe burns. May cause an allergic skin reaction.
Date of issue/Date of revision : 30 January 2018 Date of previous issue : 13 November 2017 Version : 5.01 2/10 XC24117 4 . First aid measures Ingestion : Harmful if swallowed. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain,watering,redness Inhalation : Adverse symptoms may include the following: wheezing and breathing difficulties,asthma Skin contact : Adverse symptoms may include the following: pain or irritation,redness,blistering may occur Ingestion : Adverse symptoms may include the following: stomach pains
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical This material is toxic to aquatic life. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide decomposition products
Hazchem code : 2X 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Date of issue/Date of revision : 30 January 2018 Date of previous issue : 13 November 2017 Version : 5.01 3/10 XC24117 6 . Accidental release measures Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitisation problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits Ingredient name Exposure limits glutaral; 1,5-pentanedial Safe Work Australia (Australia, 1/2014). Skin sensitiser. TWA: 0.1 ppm 8 hours. TWA: 0.41 mg/m³ 8 hours.
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust controls ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Date of issue/Date of revision : 30 January 2018 Date of previous issue : 13 November 2017 Version : 5.01 4/10 XC24117 8 . Exposure controls/personal protection Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. Recommended: > 8 hours (breakthrough time): Butyl rubber gloves. Nitrile rubber gloves. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Clear. / Colourless. Odour : Fruity. Medicinal product [Strong] Odour threshold : Not available. pH : 4 to 6 [Conc. (% w/w): 10% - (H2O)] Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 1.033 to 1.053 (20°C) Solubility : Soluble in the following materials: cold water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available.
Date of issue/Date of revision : 30 January 2018 Date of previous issue : 13 November 2017 Version : 5.01 5/10 XC24117 9 . Physical and chemical properties Decomposition temperature : Not available. Viscosity : Not available. 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure glutaral; 1,5-pentanedial LD50 Dermal Rabbit 1749 mg/kg - LD50 Oral Rat 200 mg/kg - Quaternary ammonium LD50 Oral Rat 426 mg/kg - compounds, benzyl- C12-14-alkyldimethyl, chlorides Conclusion/Summary : Harmful if inhaled. May be harmful if ingested. Can cause target organ damage. Adverse health effects could include the following: central nervous system depression Irritation/Corrosion Skin : Causes pain and burns in contact with skin. May cause permanent skin damage. Eyes : Risk of serious damage to eyes. May cause eye burns and permanent eye injury. Respiratory : No known significant effects or critical hazards. Sensitisation Skin : May cause sensitisation by skin contact. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Respiratory : May cause sensitisation by inhalation. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available. Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard
Date of issue/Date of revision : 30 January 2018 Date of previous issue : 13 November 2017 Version : 5.01 6/10 XC24117 11 . Toxicological information Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin contact : Causes severe burns. May cause an allergic skin reaction. Ingestion : Harmful if swallowed.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain,watering,redness Inhalation : Adverse symptoms may include the following: wheezing and breathing difficulties,asthma Skin contact : Adverse symptoms may include the following: pain or irritation,redness,blistering may occur Ingestion : Adverse symptoms may include the following: stomach pains
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : Toxic to aquatic organisms. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Product/ingredient name Result Species Exposure glutaral; 1,5-pentanedial Acute EC50 0.61 mg/l Algae 72 hours
Acute EC50 0.69 mg/l Daphnia 48 hours
Acute LC50 13 mg/l Fish 96 hours Persistence and degradability
Date of issue/Date of revision : 30 January 2018 Date of previous issue : 13 November 2017 Version : 5.01 7/10 XC24117 12 . Ecological information Product/ingredient name Test Result Dose Inoculum glutaral; 1,5-pentanedial - 90 to 100 % - Readily - 28 - - days
Product/ingredient name Aquatic half-life Photolysis Biodegradability glutaral; 1,5-pentanedial - - Readily
Quaternary ammonium - - Readily compounds, benzyl- C12-14-alkyldimethyl, chlorides Bioaccumulative potential
Product/ingredient name LogPow BCF Potential glutaral; 1,5-pentanedial -0.36 - low 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID UN3265 CORROSIVE LIQUID, ACIDIC, 8 III ORGANIC, N.O.S. (Glutaraldehyde)
ADG UN3265 CORROSIVE LIQUID, ACIDIC, 8 III ORGANIC, N.O.S. (Glutaraldehyde)
IMDG UN3265 CORROSIVE LIQUID, ACIDIC, 8 III ORGANIC, N.O.S. (Glutaraldehyde)
IATA UN3265 CORROSIVE LIQUID, ACIDIC, 8 III ORGANIC, N.O.S. (Glutaraldehyde)
PG* : Packing group Regulatory Environmental Additional information information hazards ADR/RID Class No. Hazchem code 2X ADG Class No. Hazchem code 2X
IMDG Class No. -
IATA Class No. The environmentally hazardous substance mark may appear if required by other transportation regulations. Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Date of issue/Date of revision : 30 January 2018 Date of previous issue : 13 November 2017 Version : 5.01 8/10 XC24117 14 . Transport information
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons 6 Model Work Health and Safety Regulations - Scheduled Substances Ingredient name Schedule methanol Restricted hazardous chemical [For spray painting if the substance contains more than 1% by volume] Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances.
National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. 16 . Other information History Date of printing : 30 January 2018. Date of issue/Date of : 30 January 2018 revision Date of previous issue : 13 November 2017 Version : 5.01 Key to abbreviations : ADG = Australian Dangerous Goods ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
Date of issue/Date of revision : 30 January 2018 Date of previous issue : 13 November 2017 Version : 5.01 9/10 XC24117 16 . Other information NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Acute Tox. 4, H302 Calculation method Acute Tox. 4, H332 Calculation method Skin Corr. 1B, H314 Calculation method Resp. Sens. 1, H334 Calculation method Skin Sens. 1, H317 Calculation method Aquatic Acute 2, H401 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
Date of issue/Date of revision : 30 January 2018 Date of previous issue : 13 November 2017 Version : 5.01 10/10 Safety Data Sheet
XC24359 BIOCIDE 1 . Identification of the material and supplier Product identifier : XC24359 BIOCIDE Product code : XC24359 ADG : - Product type : Liquid. Identified uses : Biocide.
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : ACUTE TOXICITY (inhalation) - Category 4 substance or mixture SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1 SKIN SENSITISATION - Category 1 REPRODUCTIVE TOXICITY (Unborn child) - Category 2 SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 2 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3
GHS label elements Hazard pictograms :
GHS05 GHS08 GHS07 Signal word : DANGER Hazard statements : H332 - Harmful if inhaled. H318 - Causes serious eye damage. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H361 - Suspected of damaging the unborn child. H401 - Toxic to aquatic life. H412 - Harmful to aquatic life with long lasting effects. Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves: > 8 hours (breakthrough time): Nitrile gloves. Neoprene gloves.. Wear eye or face protection. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Avoid breathing vapour. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.
Date of issue/Date of revision : 5 September 2018 Date of previous issue : No previous validation Version : 1 1/10 XC24359 BIOCIDE 2 . Hazards identification Response : IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. Storage : Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Precautionary statements : P201, P280, P273, P304 + P340, P305 + P310, P405, P501 (Code) Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number tetrakis(hydroxymethyl)phosphonium sulphate(2:1) 10 - 30 55566-30-8 tributyltetradecylphosphonium chloride 0 - 1 81741-28-8 There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. Inhalation : Get medical attention immediately. Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Skin contact : Get medical attention immediately. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Get medical attention immediately. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : Harmful if inhaled.
Date of issue/Date of revision : 5 September 2018 Date of previous issue : No previous validation Version : 1 2/10 XC24359 BIOCIDE 4 . First aid measures Skin contact : Causes skin irritation. May cause an allergic skin reaction. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain,watering,redness Inhalation : Adverse symptoms may include the following: reduced foetal weight,increase in foetal deaths,skeletal malformations Skin contact : Adverse symptoms may include the following: pain or irritation,redness,blistering may occur,reduced foetal weight,increase in foetal deaths,skeletal malformations Ingestion : Adverse symptoms may include the following: stomach pains,reduced foetal weight,increase in foetal deaths,skeletal malformations
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical This material is toxic to aquatic life. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide,sulfur oxides,phosphorus oxides,halogenated decomposition products compounds
Hazchem code : - 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Date of issue/Date of revision : 5 September 2018 Date of previous issue : No previous validation Version : 1 3/10 XC24359 BIOCIDE 6 . Accidental release measures
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.
Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits Ingredient name Exposure limits tetrakis(hydroxymethyl)phosphonium sulphate(2:1) ACGIH TLV (United States, 3/2017). Skin sensitiser. TWA: 2 mg/m³ 8 hours.
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust controls ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Date of issue/Date of revision : 5 September 2018 Date of previous issue : No previous validation Version : 1 4/10 XC24359 BIOCIDE 8 . Exposure controls/personal protection Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. Recommended: > 8 hours (breakthrough time): Nitrile gloves. Neoprene gloves. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. [Clear.] Colour : Colourless. Odour : Moderate. Odour threshold : Not available. pH : 3.4 [Conc. (% w/w): 100%] Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available. Vapour density : Not available. Relative density : 1.065 (20°C) Solubility : Easily soluble in the following materials: cold water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available.
Date of issue/Date of revision : 5 September 2018 Date of previous issue : No previous validation Version : 1 5/10 XC24359 BIOCIDE 9 . Physical and chemical properties Decomposition temperature : Not available. Viscosity : Not available. 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Reactive or incompatible with the following materials: alkalis. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure tetrakis(hydroxymethyl) LC50 Inhalation Dusts and mists Rat 0.591 mg/l @ 4 hours phosphonium sulphate(2:1) 75% THPS (Aqueous solution) LD50 Dermal Rat >2000 mg/kg - (75% solution) LD50 Oral Rat 575 mg/kg (75% - solution) Conclusion/Summary : Harmful if inhaled. Adverse health effects could include the following: breathing difficulty or shortness of breath Irritation/Corrosion Skin : May cause skin irritation. Eyes : Risk of serious damage to eyes. May cause eye burns and permanent eye injury. Respiratory : No known significant effects or critical hazards. Sensitisation Skin : May cause sensitisation by skin contact. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : Suspected of damaging the unborn child. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available. Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard
Date of issue/Date of revision : 5 September 2018 Date of previous issue : No previous validation Version : 1 6/10 XC24359 BIOCIDE 11 . Toxicological information Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : Harmful if inhaled. Skin contact : Causes skin irritation. May cause an allergic skin reaction. Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain,watering,redness Inhalation : Adverse symptoms may include the following: reduced foetal weight,increase in foetal deaths,skeletal malformations Skin contact : Adverse symptoms may include the following: pain or irritation,redness,blistering may occur,reduced foetal weight,increase in foetal deaths,skeletal malformations Ingestion : Adverse symptoms may include the following: stomach pains,reduced foetal weight,increase in foetal deaths,skeletal malformations
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Suspected of damaging the unborn child. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
12 . Ecological information Toxicity : Toxic to aquatic organisms. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Product/ingredient name Result Species Exposure tetrakis(hydroxymethyl) Acute EC50 0.66 mg/l Algae 96 hours phosphonium sulphate(2:1)
Acute EC50 15.1 mg/l Daphnia 48 hours
Acute LC50 95 mg/l Fish 96 hours
Chronic NOEC 0.064 mg/l Algae 96 hours
Date of issue/Date of revision : 5 September 2018 Date of previous issue : No previous validation Version : 1 7/10 XC24359 BIOCIDE 12 . Ecological information Chronic NOEC 0.032 mg/l Daphnia 21 days
Chronic NOEC 1.1 mg/l Fish 32 days tributyltetradecylphosphonium Acute EC50 25.2 ppb Fresh water Daphnia - Daphnia magna 48 hours chloride
Acute LC50 58.6 ppb Fresh water Fish - Lepomis macrochirus 96 hours Persistence and degradability Not available. Product/ingredient name Test Result Dose Inoculum tetrakis(hydroxymethyl) - 70 % - Readily - 21 days - - phosphonium sulphate(2:1)
Product/ingredient name Aquatic half-life Photolysis Biodegradability tetrakis(hydroxymethyl) - - Readily phosphonium sulphate(2:1) 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID Not regulated. - - -
ADG Not regulated. - - -
IMDG Not regulated. - - -
IATA Not regulated. - - -
PG* : Packing group Regulatory Environmental Additional information information hazards ADR/RID Class No. Hazchem code - ADG Class No. Hazchem code -
IMDG Class No. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Date of issue/Date of revision : 5 September 2018 Date of previous issue : No previous validation Version : 1 8/10 XC24359 BIOCIDE 14 . Transport information Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons Not regulated. Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances.
National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. 16 . Other information History Date of printing : 5 September 2018. Date of issue/Date of : 5 September 2018 revision Date of previous issue : No previous validation Version : 1 Key to abbreviations : ADG = Australian Dangerous Goods ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification
Date of issue/Date of revision : 5 September 2018 Date of previous issue : No previous validation Version : 1 9/10 XC24359 BIOCIDE 16 . Other information Classification Justification Acute Tox. 4, H332 Calculation method Skin Irrit. 2, H315 Calculation method Eye Dam. 1, H318 Calculation method Skin Sens. 1, H317 Calculation method Repr. 2, H361 (Unborn child) Calculation method Aquatic Acute 2, H401 Calculation method Aquatic Chronic 3, H412 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
Date of issue/Date of revision : 5 September 2018 Date of previous issue : No previous validation Version : 1 10/10 Safety Data Sheet
XC24380 1 . Identification of the material and supplier Product identifier : XC24380 Product code : XC24380 ADG : TOXIC LIQUID, ORGANIC, N.O.S. (tetrakishydroxymethylphosphonium sulphate) Product type : Liquid. Identified uses : Biocide.
Supplier's details : Baker Hughes, Australia 5 Walker Street, Braeside, Victoria 3195, Australia
Tel: +613 9580 9004 Fax: +613 9580 6004 Emergency telephone : CHEMTREC Emergency Telephone Numbers (Australasia Geomarket): number - Australia: (02) 9037 2994 - New Zealand: 9801 0034 - PNG: +(61) 2 9037 2994 ------UK: +(44) 870-820-0418 - USA: +(1) 703-527-3887 (CHEMTREC International 24 hour) 2 . Hazards identification Classification of the : ACUTE TOXICITY (oral) - Category 4 substance or mixture ACUTE TOXICITY (inhalation) - Category 3 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1 TOXIC TO REPRODUCTION (Unborn child) - Category 2 ACUTE AQUATIC HAZARD - Category 1 LONG-TERM AQUATIC HAZARD - Category 2
GHS label elements Hazard pictograms :
Signal word : DANGER Hazard statements : H331 - Toxic if inhaled. H302 - Harmful if swallowed. H318 - Causes serious eye damage. H317 - May cause an allergic skin reaction. H361 - Suspected of damaging the unborn child. H400 - Very toxic to aquatic life. H411 - Toxic to aquatic life with long lasting effects. Precautionary statements Prevention : Obtain special instructions before use. Wear protective gloves: > 8 hours (breakthrough time): Butyl rubber gloves. Neoprene gloves. Nitrile gloves. Avoid gloves made of PVA.. Wear eye or face protection. Avoid release to the environment. Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Immediately call a POISON CENTER or physician. Storage : Store locked up.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 20 January 2017 Version : 5 1/10 XC24380 2 . Hazards identification Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Precautionary statements : P201, P280, P273, P304 + P340, P305 + P310, P405, P501 (Code) Supplemental label : Not applicable. elements
Other hazards which do not : None known. result in classification 3 . Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % (w/w) CAS number tetrakis(hydroxymethyl)phosphonium sulphate(2:1) 60 - 100 55566-30-8 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4 . First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Chemical burns must be treated promptly by a physician. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 15 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : Toxic if inhaled. Skin contact : May cause an allergic skin reaction. Ingestion : Harmful if swallowed. Over-exposure signs/symptoms Eye contact : pain,watering,redness Inhalation : reduced foetal weight,increase in foetal deaths,skeletal malformations Skin contact : pain or irritation,redness,blistering may occur,reduced foetal weight,increase in foetal deaths,skeletal malformations
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 20 January 2017 Version : 5 2/10 XC24380 4 . First aid measures Ingestion : stomach pains,reduced foetal weight,increase in foetal deaths,skeletal malformations
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11) 5 . Firefighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical This material is very toxic to aquatic life. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal : carbon dioxide,carbon monoxide,sulfur oxides,phosphorus oxides decomposition products
Hazchem code : 2X 6 . Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
Methods and material for containment and cleaning up
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 20 January 2017 Version : 5 3/10 XC24380 6 . Accidental release measures Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7 . Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8 . Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Control parameters Occupational exposure limits Ingredient name Exposure limits tetrakis(hydroxymethyl)phosphonium sulphate(2:1) ACGIH TLV (United States, 3/2016). Skin sensitiser. TWA: 2 mg/m³ 8 hours.
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust controls ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 20 January 2017 Version : 5 4/10 XC24380 8 . Exposure controls/personal protection Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: > 8 hours (breakthrough time): Butyl rubber gloves. Neoprene gloves. Nitrile gloves. Avoid gloves made of PVA. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. 9 . Physical and chemical properties Appearance Physical state : Liquid. Colour : Colourless. Odour : Pungent. Odour threshold : Not available. pH : 3 to 6 Melting point : -43°C (-45.4°F) Boiling point : Not available. Flash point : Closed cup: Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapour pressure : Not available.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 20 January 2017 Version : 5 5/10 XC24380 9 . Physical and chemical properties Vapour density : Not available. Relative density : 1.39 (20°C) Solubility : Soluble in the following materials: cold water. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Kinematic (25°C): 30 cSt 10 . Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. 11 . Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure tetrakis(hydroxymethyl) LC50 Inhalation Dusts and mists Rat 0.591 mg/l @ 4 hours phosphonium sulphate(2:1) 75% THPS (Aqueous solution) LD50 Dermal Rat >2000 mg/kg - (75% solution) LD50 Oral Rat 575 mg/kg (75% - solution) Conclusion/Summary : May be toxic if inhaled. May be harmful if ingested. Can cause target organ damage. Adverse health effects could include the following: breathing difficulty or shortness of breath Irritation/Corrosion Conclusion/Summary Skin : No known significant effects or critical hazards. Eyes : Risk of serious damage to eyes. May cause eye burns and permanent eye injury. Respiratory : No known significant effects or critical hazards. Sensitisation Conclusion/Summary Skin : May cause sensitisation by skin contact. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Respiratory : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : Suspected of damaging the unborn child. Teratogenicity
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 20 January 2017 Version : 5 6/10 XC24380 11 . Toxicological information Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Not available. Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Not available. Aspiration hazard Name Result Not available.
Information on likely routes : Not available. of exposure Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : Toxic if inhaled. Skin contact : May cause an allergic skin reaction. Ingestion : Harmful if swallowed.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : pain,watering,redness Inhalation : reduced foetal weight,increase in foetal deaths,skeletal malformations Skin contact : pain or irritation,redness,blistering may occur,reduced foetal weight,increase in foetal deaths,skeletal malformations Ingestion : stomach pains,reduced foetal weight,increase in foetal deaths,skeletal malformations
Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Suspected of damaging the unborn child. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 20 January 2017 Version : 5 7/10 XC24380 12 . Ecological information Toxicity : Very toxic to aquatic organisms. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Product/ingredient name Result Species Exposure tetrakis(hydroxymethyl) Acute EC50 0.66 mg/l Algae 96 hours phosphonium sulphate(2:1) Acute EC50 15.1 mg/l Daphnia 48 hours Acute LC50 95 mg/l Fish 96 hours Chronic NOEC 0.064 mg/l Algae 96 hours Chronic NOEC 0.032 mg/l Daphnia 21 days Chronic NOEC 1.1 mg/l Fish 32 days Persistence and degradability Product/ingredient name Test Result Dose Inoculum tetrakis(hydroxymethyl) - 70 % - Readily - 21 days - - phosphonium sulphate(2:1)
Product/ingredient name Aquatic half-life Photolysis Biodegradability tetrakis(hydroxymethyl) - - Readily phosphonium sulphate(2:1) Other adverse effects : No known significant effects or critical hazards. 13 . Disposal considerations Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14 . Transport information International transport regulations Regulatory UN number Proper shipping name Transport PG* Label information hazard class(es) ADR/RID UN2810 TOXIC LIQUID, ORGANIC, N. 6.1 III O.S. (tetrakishydroxymethylphosphonium sulphate)
ADG UN2810 TOXIC LIQUID, ORGANIC, N. 6.1 III O.S. (tetrakishydroxymethylphosphonium sulphate)
IMDG UN2810 TOXIC LIQUID, ORGANIC, N. 6.1 III O.S. (tetrakishydroxymethylphosphonium sulphate)
IATA UN2810 TOXIC LIQUID, ORGANIC, N. 6.1 III O.S. (tetrakishydroxymethylphosphonium sulphate) PG* : Packing group
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 20 January 2017 Version : 5 8/10 XC24380 14 . Transport information Regulatory Environmental Additional information** information hazards ADR/RID Class Yes. The environmentally hazardous substance mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Tunnel code (E)
Hazchem code 2X ADG Class No. Hazchem code 2X IMDG Class Yes. -
IATA Class No. -
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of Marpol and the IBC Code 15 . Regulatory information Standard Uniform Schedule of Medicine and Poisons Not regulated. Model Work Health and Safety Regulations - Scheduled Substances Australia inventory (AICS) : All components are listed or exempted. References : National Code of Practice for the Control of Workplace Hazardous Substances. National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 20 January 2017 Version : 5 9/10 XC24380 16 . Other information History Date of printing : 13 November 2017. Date of issue/Date of : 13 November 2017 revision Date of previous issue : 20 January 2017 Version : 5 Key to abbreviations : ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification Justification Acute Tox. 4, H302 Calculation method Acute Tox. 3, H331 Calculation method Eye Dam. 1, H318 Calculation method Skin Sens. 1, H317 Calculation method Repr. 2, H361 (Unborn child) Calculation method Aquatic Acute 1, H400 Calculation method Aquatic Chronic 2, H411 Calculation method References : Not available. Indicates information that has changed from previously issued version. Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 13 November 2017 Date of previous issue : 20 January 2017 Version : 5 10/10