A Value 7 ABO Blood Group System 1752, 1781 AB-Type 89 Abzyme
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Index A value 7 Aclacinomycin 2562, 2563, 2606 ABO blood group system 1752, 1781 Acosamine 902 AB-Type 89 Actinomycetales 2550 Abzyme 380, 393 Activation step 455 Acarbose 87 Active sites 2329, 2353 Acceptor 1391 Acyclic carbohydrates 13, 14 polymer-supported 1397 anti conformations 14 Aceric acid 898 gauche conformation 14 Acetalation 121 nomenclature 14 Acetal–ketal linkage 69 OO interactions 14 Acetals 122 zig-zag conformation 13 acyclic 127 Acyclic spacers 2079 benzylidene 248 Acyl migration, O→S 1802 mixed 1305 Acyl shift, S→N 1804 open-chain 2547 Acylation 129, 1430 Acetal-type protecting group 121 N-Acylation 1431 2-Acetamido-O-acetylated glycals 708 2-O-Acyl-hex-1-enitols 706 p-Acetamidobenzyl 115 Acyloxazolidinone 914 Acetates, anomeric 664 N-Acylpyrroles, α,β-unsaturated 1065 Acetobacter xylinum 78, 1476, 1482 Addition 249, 252, 265 Acetolysis 402 Michael 254 Acetonitrile participation 1327 radical 259 Acetonitrilium ions 580, 581 exo-Addition 316 p-Acetoxybenzyl ether 115 1,2-Addition, lithiated MeSO2Ph 1982 4-Acetoxy-2,2-dimethylbutanoyl 135 1,4-Addition 1061 2-Acetoxy-3,4,6-tri-O-acetyl-D-glucal 702 radical 1040 Acetylation 130 Addition–substitution, radical 329 regioselective 131 Adenosine 1119, 1121 Acetylene-cobalt complex 777 Adenosine triphosphate (ATP) 66 Acetylenosaccharides 2096 Adenosine-diphospho-glucose (ADPGlc) 69 N-Acetylgalactosamine 1798, 2162, 2648 ADEPT 2658 N-Acetylglucosamine 1798 Adhesion domains 2357 in bacterial peptidoglycan 1542 Adjuvants 2668 polymer, in biofilms 1585 ADP-[14C]Glc 1457 N-Acetylglucosaminyltransferases 2256, 2272 ADPGlc 67, 1457 β-N-Acetylhexosaminidases 1396 Adriamycin 2562, 2565 Acetyllactosamine 1750 Advanced glycation end products (AGEs) 415, N-Acetyllactosamine 1370 1740 N-Acetylmannosamine 1861 Affinity labeling 2346 N-Acetyl-D-muramic acid (NAM) 80 AFGP, C-linked 2547 N-Acetylneuraminic acid 20, 24, 534, 596, 724, Agar 1527 772, 787, 2045 Agelagalastatin 562, 643 2-O-Acetyl-3,4,6-tri-O-benzyl-D-glucopyranosyl Agelasphines 756 bromide 708 Aglycon delivery, intramolecular 465, 595, 1303 Achmatowicz reaction 348 Agrobacterium tumefaciens 194 Acid chlorides 1463 AGU 1497 Acid-alcohol modifications 1460 AIDS 1823 Acidic degradations 383 Ajugose 70 Acidulants 854 Alanine 874, 1032 2840 I Index Alaninol 886 Allyl boronates 883 Aldaric acids 190, 1098 Allyl carbonates 138 Aldehydes Allyl ethers 116 alkynylation 1071 Allyl glycoside 159, 620 allylation 883 latent 621, 625 Alditol acetates, methylated 2209, 2211 π-Allyl palladium complex 759 Alditols 194, 202, 2432 Allylation 117, 1036, 1046 Aldohexopyranuronic acid 20 asymmetric 903 Aldol 880 Allylic alkylations 1063 Aldol condensation 867, 891 Allylic stannane 907 SnCl4-promoted intramolecular 1982, 1983 Allylic trichloroacetimidate 389 Aldol cyclization 873 2-(Allyloxy) phenyl acetyl 134 Aldol dimerizations 878 Allyloxycarbonyl group 138 Aldol reactions 871, 882, 894, 2072 2 -(Allyloxycarbonyl)benzyl (ACB) glycosides 639 Aldolase antibodies 872 P-Allylpalladium complex 1990 Aldolases 864, 2161 Allylsamarium species 1990 Aldolization, Zn-proline-catalyzed 880 Allylsilane 771, 777 Aldol-type condensations 308 Allylstannane 781 Aldonic acids 181, 194, 1095 Allyltrimethylsilane 339, 769 Aldonolactones 181, 202, 203, 210, 217, 892 Aloe polysaccharides 1529 Aldopentopyranoses 17 Alternan 75, 1199 Aldoses 843, 876 Alternansucrase 75 Aldosyl phosphates 168 Altohyrtin (spongistatin) 782 Aldosyl phosphites 168 D-Altritol 1093 Aldulosonic acids 2433 Altrosuronic acid 20 Alexine 1895 Alzheimer’s disease 414, 419, 2422 ALG (asparagine-linked glycosylation) 2268 Amadori–Heyns compounds 415 Alginates (algins) 82, 1522 Amicoratopsis trehalostatica 1964 Alkali cellulose 1520 Amide coupling 2083 Alkaline degradations 383 Amide-linked sugars 2080 Alkaloids 2619, 2624 Amido groups 1416 Alkene 682 Amination 1432 isolated 250 reductive 1748, 2123 Alkoxylation 1508 Amino acid, unnatural 1864 Alkoxymethyl ether 128 L-Amino acids, β-deuterated 1034 Alkoxyphosphonium, salt 239 α-Amino aldehyde 888 Alkyl ether 1506 α-Amino nitriles 1038 O-Alkyl glycosyl donor 569 Aminoalditols 880 Alkyl substituents 2142 2-Aminoaldonolactone 893 Alkylation 107, 1013, 1034, 1046, 1051, 1430 p-Aminobenzylether 115 1-O-Alkylation 154 Aminocyclitol antibiotic 2569 Alkyllithium 306, 1050 (1R,2S)-2-Aminocyclopentanecarboxylic acid 874 Alkylmalic acids 1033 6-Amino-6-deoxy starch 1463 Alkyne-cobalt complex 1247 D-/L-2-Amino-2-deoxy-arabinose 893 1-Alkyn-5-ols 725 Aminodeoxycarbohydrates 892 D-Allal 705, 709 4-Amino-4-deoxyfructose 881 Alligator hepatic lectin (AHL) 2457 2-Amino-2-deoxyglyceraldehyde 885 Allomorph 1481, 1482 4-Amino-4-deoxyheptono-1,4-lactam 909 (+)-D-Allonojirimycin 921 2-Amino-2-deoxypyranosyl chlorides 708 Allosamidin 1913, 1915, 1951, 1952 4-Amino-4-deoxy-threo-pentulose 881 Allosamizoline 1952, 1953, 1957, 1963, 1964, 4-Amino-4,5-dideoxy-L-lyxose 916 1972 Aminoglycoside antibiotics 1144, 2569, 2570 D-/L-Allose 876, 878, 879 Aminoglycosides 510, 2126, 2615 Index I 2841 Aminooxy 2164 Anhydrosugars 273, 284, 675, 830, 2384 α-Aminophosphonic acid ester 1039 classification 273 Aminopolyols 924 donors 684 Aminosaccharides 2427 endo-cyclic rings 284 Aminosugars 287, 816, 818, 831, 882, 888, 2574, exo-cyclic rings 284 2605, 2612 reactivity 273 preparation from sugar epoxides 286 1,2-Anhydrosugars 281, 439, 780 3-Amino-2,3,6-trideoxy pyranoses 723 1,3-Anhydrosugars 747 Amphiphatic helix 1774 1,4-Anhydrosugars 748, 784 Amphotericin 1299, 2612 1,6-Anhydrosugars 816, 830 Amygdalin 2548 1,6-Anhydrosugars, C-branched 333 α-Amylases 1195, 1451, 2093, 2331 Anhydrosugars, modified 276 β-Amylases 1452, 2621 2,5-Anhydro-5-thio-D-mannitol 2004 Amylogenin 1742 6,3-Anhydro-6-thio-octanoates 2004 Amylolyases 2340 Animal tests 2146 Amylomaize-5 73, 1441 Ankaraholide A 2558 Amylomaize-7 73, 1441 Annotation 2233 Amylopectin 73, 1426, 1440, 1450 Anomer 377 Amyloplasts 1442 Anomeric O-acylation 160 Amylose 72, 1426, 1440 Anomeric O-alkylation 455 retrograded and dehydrated 1451 Anomeric anion 791, 1356 water-soluble 1441 Anomeric center 153, 154, 180, 202, 213 Anchimeric assistance 463, 2001 Anomeric configurations 2209 Angiogenesis 2579 Anomeric conformation 2202 Angucyclines 2563, 2564 Anomeric O-deacylation 164 Anhydrides, intramolecular 272 Anomeric effect 3, 7, 8, 10, 19 Anhydro amino sugar 751 dipole dipole repulsion 8, 10 1,6-Anhydro bridge 828 exo 9 1,7-Anhydro derivatives 279 kinetic 455, 1301 Anhydro linkage 272 thermodynamic 455 Anhydro sugars, anomeric 738 Anomeric ester 525 Anhydroalditols 213, 214 Anomeric leaving group 664 1,5-Anhydro-2-deoxy-D-arabino- Anomeric oxygen 455 hex-1-enitol 700 Anomeric radicals 785, 2049, 2055 Anhydroerythritol 1101, 1121 Anomeric sulfones 2034 1,6-Anhydrofuranoses 279, 738 Anomerization 408, 430 synthesis 279 in situ 767 3,6-Anhydrofuranoses 293 Antagonist 1226 D-Anhydroglucopyranose 1476 Antarctic fish 1773 1,6-Anhydro-β-D-glucopyranose 274 Antennae 1749, 1750, 2461 1,3-Anhydroglucopyranoses 284 Anthocyanidin glycosides 2548 1,6-Anhydro-β-D-glucose 1111 Anthocyanins 2548, 2593 2,6-Anhydroheptitols 925–927 Anthracyclines 2562, 2604 1,6-Anhydrohexofuranoses 748 Anti-adhesive 2367 1,6-Anhydro-ε-D-hexopyranoses 21 Antibacterial 2430 1,6-Anhydro-D-ido-pyranose 275 Antibiotics 510, 1831, 2008, 2600 1,6-Anhydromuropeptide 742 activity 1763 2,3-Anhydro-nucleoside 289 resistances 2550 1,6-Anhydropyranoses 21, 738, 783 Antibodies 1815, 2145, 2386, 2666 boat conformation 21 Anticancer vaccines 1810 chair conformations 21 Anti-epileptic 2426 Anhydrosucrose 297 Antifreeze glycoproteins (AFGPs) 1773, 2547 derivatives 297 Antigen, F1α 551, 1821 2842 I Index Antigen presentation 2661 Ascorbic acid 186, 199, 211, 852, 985, 2631 Antigenic determinants 1752, 1755 Asialoglycoprotein receptor 1787, 2455 Antigens 2661, 2719 Aspartame 846 tumor-associated 1782, 2655 Aspergillus niger 1452 tumor-specific 2154 Asterosaponins 2559 O-Antigens 85 Asx-Turn 1778 biosynthesis 1566 Asymmetric synthesis 1029, 1031 structural diversity 1562 Atropisomerism 1763, 2575 Anti-β-hydroxy-α-aminoacids 880 Aureolic acids 2559, 2608 Anti-inflammatory drugs 1789, 1843 Australine 1895 Antimycobacterial 2407 Automated synthesis 1233 Antioxidative activity 2596 Auxiliary 1321, 1324 Antiperiplanar lone pair hypothesis (ALPH) 586 Avermectins 534, 2550, 2552, 2610 Antisense 1861 Avian virus H5N1 1947 Antithrombotic 2407 Avidity 2449 Antitumor activity 2604 Avilamycin 2554 Antiviral 996, 2407 Axes of symmetry, two-fold 2464 APC 2660 Axial attack 771 L-Apiose 837, 889 Axial bonds 64 Apoptosis 2663 Aza-Achmatowicz reaction 945 Aprosulate 2094 Aza-Cope/Mannich tandem reactions 391 APTS 1880 Aza-C-disaccharides 1154 L-Arabinal 701 1-Azafagomine 915, 916 Arabinans 1489 Azafuranose 1892 D-Arabinaric acid 1100 Azasugars 299, 366, 401, 751, 906, 1888 D-Arabinitol 87, 898 naked 930 Arabinofuranose 1575 septanose-type 299 β-Arabinofuranosylation 559 Azidation 251 stereoselective 636 p-Azido benzyl 115 Arabinogalactans 78, 498, 1425, 1530, 1536, 1572, Azido group 1339 1621, 2288 Azidoaldehydes 869 biosynthesis 1576 4-Azido-3-chlorobenzyl (ClAzb) 1256 drug target 1581 6-Azidoketones 868 larch 1530 Azidonitration 199, 253 Arabinoglucuronoxylan 1490 Azidophenyl selenylation 200, 260 D-Arabinonic acid 1098 Azidosphingosine glycosylation procedure 482 D-Arabinose 985 3 -Azidothymidine (AZT) 295, 2015 L-Arabinose 1489 Aziridine ring opening 1938 Arabinose-binding protein, bacterial 2459 meso-Aziridines Arabinosyltransferase catalytic desymmetrization (CDMA) 1950 inhibitors 1581 catalytic enantioselective