Page 1/7 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 31.08.2018 Version 2 Revision: 31.08.2018

* SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name: Vacuum grease B03 968 006 S03 968 006 Registration number There is no registration number for this substance as the substance or its use in accordance with Article 2 REACH Regulation (EC) 1907/2006 are exempted from registration, the annual tonnage does not require registration or the registration is provided at a later date. 1.2 Relevant identified uses of the substance or mixture and uses advised against Not applicable. Application of the substance / the preparation: Laboratory chemicals 1.3 Details of the supplier of the safety data sheet Manufacturer/ Supplier: Elementar Analysensysteme GmbH Tel.: +49 (6184) 9393-0 Elementarstraße 1 Fax: +49 (6184) 9393-400 63505 Langenselbold E-mail: [email protected] www.elementar.de Further information obtainable from: Elementar Sales Tel.: +49 (6184) 9393-0 E-mail: [email protected] 1.4 Emergency telephone number: Poison Control Center Mainz +49 (0) 6131-19240 (24h)

SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 The product is not classified, according to the CLP regulation. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 Void Hazard pictograms Void Signal word Void Hazard statements Void 2.3 Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.

* SECTION 3: Composition/information on ingredients 3.2 Chemical characterisation: Mixtures Description: Mixture consisting of the following components. Polydimethylsiloxane Dodecamethylcyclohexasiloxane EC No. 208-762-8, CAS No. 540-97-6,

REACH-Reg. No. 01-2119517435-42 ¡ 0,1 - < 0,5 wt% Dangerous components: Void

* SECTION 4: First aid measures 4.1 Description of first aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air; consult doctor in case of complaints. Material cannot be inhaled under normal conditions. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. (Contd. on page 2) GB

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Trade name: Vacuum grease B03 968 006 S03 968 006

(Contd. of page 1) If symptoms persist consult doctor. After swallowing: After swallowing, rinse mouth with plenty of water if person is conscious. Do not induce vomiting. If symptoms persist consult doctor. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.

* SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. For safety reasons unsuitable extinguishing agents: Water with full jet 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. 5.3 Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Additional information Avoid contaminated fire fighting water getting into surface waters or ground water.

SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Particular danger of slipping on leaked/spilled product. 6.2 Environmental precautions: Do not allow product to reach sewage system or any water course. 6.3 Methods and material for containment and cleaning up: Pick up mechanically. Use cleansing agents instead of solvents Warm water and cleansing agent Dispose of the material collected according to regulations. 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

* SECTION 7: Handling and storage 7.1 Precautions for safe handling Handle in accordance with good industrial hygiene and safety practice. - don't eat, drink or smoke in working area, - wash hands before breaks, after use and at the end of workday, - take off contaminated cloth and protective equipment before entering social rooms. Information about fire - and explosion protection: No special measures required. 7.2 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Keep container tightly closed. Information about storage in one common storage facility: Storage in the near of other chemicals or products has to be verified. Further information about storage conditions: Protect from heat and direct sunlight. Storage temperature below 50 °C. (Contd. on page 3) GB

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Trade name: Vacuum grease B03 968 006 S03 968 006

(Contd. of page 2) Store in dry conditions. 7.3 Specific end use(s) No further relevant information available.

* SECTION 8: Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. DNELs Not determined. PNECs Not determined. Additional information: The lists valid during the making were used as basis. 8.2 Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Wash hands before breaks and at the end of work. Keep away from foodstuffs, beverages and feed. Respiratory protection: Use suitable respiratory protective device only when aerosol or mist is formed. Filter FFP1 Protection of hands: Wear gloves for the protection against chemical hazards according to EN 374. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Butyl rubber, BR Nitrile rubber, NBR Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. > 480 min, material thickness: 0,5 mm Eye protection: Tightly sealed goggles Body protection: Protective work clothing Limitation and supervision of exposure into the environment See section 6 and 12 for further information.

* SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties General Information Appearance: Form: Pasty Colour: Different according to colouring Odour: Light Odour threshold: Not applicable. pH-value: Not applicable. Change in condition Melting point/freezing point: Not determined. (Contd. on page 4) GB

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Trade name: Vacuum grease B03 968 006 S03 968 006

(Contd. of page 3) Initial boiling point and boiling range: Not applicable. Flash point: > 300 °C (ISO 2592) Flammability (solid, gas): Product is not flammable. Decomposition temperature: Not determined. Auto-ignition temperature: Product is not self-igniting. Explosive properties: Product does not present an explosion hazard. Explosion limits: Lower: Not applicable. Oxidising properties The substance is not oxidizing. Vapour pressure: Not applicable. Density at 20 °C: 0.97 g/cm³ Relative density Not determined. Vapour density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with water: Insoluble. Partition coefficient: n-octanol/water: Not determined. Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity 10.1 Reactivity See Section 10.3 10.2 Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions No hazardous reactions when stored and handled properly. 10.4 Conditions to avoid Keep ignition sources away - Do not smoke. Elektrostatic discharge 10.5 Incompatible materials: No further relevant information available. 10.6 Hazardous decomposition products: No dangerous decomposition products known. above 150 °C Small amounts of: Formaldehyde In case of fire: see chapter 5.

* SECTION 11: Toxicological information 11.1 Information on toxicological effects No further relevant information available. Acute oral toxicity 540-97-6 Dodecamethylcyclohexasiloxane Oral LD50 > 2000 mg/kg (rat) NOAEL (C) 1000 mg/kg (rat) 63148-62-9 Polydimethylsiloxane Oral LD50 > 5000 mg/kg (rat)

NOAEL (C) ¡ 1000 mg/kg (rat) (Contd. on page 5) GB

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Trade name: Vacuum grease B03 968 006 S03 968 006

(Contd. of page 4) Acute dermal toxicity 540-97-6 Dodecamethylcyclohexasiloxane Dermal LD50 > 2000 mg/kg (rat) 63148-62-9 Polydimethylsiloxane Dermal LD50 > 2000 mg/kg (rat) Primary irritant effect: On the skin: Based on available data, the classification criteria are not met. On the eye: Based on available data, the classification criteria are not met. Respiratory or skin sensitisation No data available. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity No data available. Carcinogenicity No data available. Reproductive toxicity No data available. STOT-single exposure No data available. STOT-repeated exposure No data available. Aspiration hazard Based on available data, the classification criteria are not met.

* SECTION 12: Ecological information 12.1 Toxicity No further relevant information available. Fish toxicity 63148-62-9 Polydimethylsiloxane LC0 200 mg/L (fish) (96h, Leuciscus idus) NOEC > 10000 mg/L (fish) (28d, Oncorhynchus mykiss) Daphnia toxicity 63148-62-9 Polydimethylsiloxane EC0 > 0.0001 mg/L (Daphnia magna) (48 h) Algae toxicity 63148-62-9 Polydimethylsiloxane IC50 > 100000 mg/L (Algae) (72h, Skeletonema costatum) 12.2 Persistence and degradability Not easily biodegradable 12.3 Bioaccumulative potential No data available. 12.4 Mobility in soil No further relevant information available. Ecotoxical effects: Remark: According to current knowledge adverse effects on water purification plants are not expected. Other information: Technically correct releases of minimal concentrations to adapted biological sewage plants, will not disturb the biodegradability of activated sludge. General notes: Do not allow product to reach ground water, water course or sewage system. 12.5 Results of PBT and vPvB assessment PBT: Remarks: Dodecamethylcyclohexasiloxan (D6) meets the criteria for vPvB. However, D6 does not behave similary to known PBT/vPvB substances. The weight of scientific evidence from field studies shows that D6 is not biomagnifying in aquatic and terrestrial food webs. vPvB: s. PBT 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations 13.1 Waste treatment methods Recommendation Disposal must be made according to official regulations. (Contd. on page 6) GB

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(Contd. of page 5) Uncleaned packaging: Recommendation: Packagings that cannot be cleaned are to be disposed of in the same manner as the product. Packaging may be reused or recycled after cleaning.

SECTION 14: Transport information 14.1 UN-Number ADR, ADN, IMDG, IATA Void 14.2 UN proper shipping name ADR, ADN, IMDG, IATA Void 14.3 Transport hazard class(es) ADR, ADN, IMDG, IATA Class Void 14.4 Packing group ADR, IMDG, IATA Void 14.5 Environmental hazards: Marine pollutant: No 14.6 Special precautions for user Not applicable. 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. Transport/Additional information: ADR Limited quantities (LQ) -

* SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Directive 2012/18/EU Named dangerous substances - ANNEX I None of the components is listed. National regulations: Other regulations, limitations and prohibitive regulations Details of international registration status: Listed on or in accordance with the following inventories EINECS - Europe ECL - Korea ENCS - AICS - IECSC - DSL - Canada PICCS - Philippines TSCA - USA Substances of very high concern (SVHC) according to REACH, Article 57 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals (Contd. on page 7) GB

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(Contd. of page 6) EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) PBT: Persistent, Bioaccumulative and Toxic SVHC: Substances of Very High Concern vPvB: very Persistent and very Bioaccumulative Sources Manufacturer's information. * Data compared to the previous version altered. GB

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