Request for Proposals Arizona Department of Environmental Solicitation No. Quality ADEQ19-00008372 1110 W. Washington Street Description: Phoenix, AZ 85007 Ambient Stream Water Quality Monitoring

Section 2-A: Scope Document (Scope of Work) Date: 7-26-18

1.0 Purpose 1.1 The Arizona Department of Environmental Quality (ADEQ) is seeking a Contractor to collect, record and verify water quality data from approximately fifty-seven (57) ambient stream locations across Arizona, refer to Exhibit A – Sampling and Analysis Plan (as may be amended), Table A.2.2 – Stream Sample Plan - Contracted - Ambient Chemistry and Exhibit B – FY19 Ambient Chemistry Sites (as may be amended) for collection locations. Each location will typically be sampled two or three times a year for an estimated total of one hundred fifty (150) sampling events. The actual number of locations will be determined by cost per location, available ADEQ budget, and for impaired sites- until an impairment or attainment decision is made (eg. Could be less than three samples per site). This data will be analyzed to determine if those waterbodies are meeting water quality standards.

2.0 Background 2.1 The fifty-seven (57) sampling sites are pre-identified by ADEQ as perennial, wadeable, accessible locations where the following sample and data types can be collected: surface water samples, in-situ field parameter data, discharge and physical habitat measurements. Most sampling sites will be on public land, and accessible by four wheel drive (4WD) vehicle and via backpacking in short distances approximately 3-4 miles. This list of sites does not include streams in the Grand Canyon, or on tribal land. Sampling sites include impaired water sites, data gap sites for the Clean Water Act Assessment, reference sites and nutrient sites. Most nutrient, reference and data gap sites will be sampled two times. Pre-approval is needed before an impaired water can be sampled more than three (3) times.

2.2 All Contractor staff conducting fieldwork for this Ambient Stream Monitoring project must attend the ADEQ sixteen (16) hour mandatory Water Quality Monitoring Training Course. This hands-on training shall be provided by ADEQ soon after contract award, covering the following topics: • reference materials • Quality Assurance Program Plan (QAPP), • Sample plan, • standard operating procedures (SOP), • field forms, • attainment and impairment determinations • quality control measures, • data entry and data validation

PART 2 of the Solicitation Documents: SECTION 2-A: Scope Document (Scope of Scope and Pricing Documents Work) Template version 1.3.1 (13-Jan-2017) Date: 7/26/18 2 Page 1 of 5 Available online at:

Procure.AZ.gov

Request for Proposals Solicitation No. Arizona Department of Environmental Quality ADEQ19-00008372 1110 W. Washington Street Description: Phoenix, AZ 85007 Ambient Stream Water Quality Monitoring

2.3 Contractor shall be responsible for printing copies of field forms (approximately 5pp) and maps for each site. Contractor shall be responsible for obtaining site access permission, but ADEQ shall provide available site access directions and contact information. Contractor shall be responsible for thoroughly icing samples while in transit until samples are submitted at ADEQ contract labs in Phoenix. 2.4 ADEQ shall pay for contracted lab analysis.

3.0 Contractor Requirements 3.1 The Contractor shall provide and utilize their own 4WD vehicle(s) and transportation to sampling locations due to rugged terrain.

3.2 The Contractor shall utilize their own water quality and flow monitoring equipment • Probes for pH, temperature, conductivity, total dissolved solids, dissolved oxygen, turbidity. Resolution, accuracy and range for equipment ADEQ as approved in Exhibit A – Table A1. • Flow meter and rod and tapes • Churn splitter and DH-81 • Colilert or comparable E. coli processing equipment (unless a certified laboratory is used) • Geopump or equivalent for field filtration • Miscellaneous sampling supplies & equipment o 0.45 um filter capsules o Tubing o Gloves o Camera o GPS Some specialty equipment such as Colilert and churn splitters can be supplied by ADEQ if Contractor unable to procure by contract start date. Equipment shall only be loaned temporarily for a period not to exceed sixty (60) days. Preference is given to vendors who have all required equipment. The bid proposal shall include type, range, accuracy and resolution for all field equipment used to measure of pH, temperature, conductivity, total dissolved solids, dissolved oxygen and turbidity).

3.3 All water quality data shall be collected using ADEQ’s standardized methods, contained in the ADEQ Standard Operating Procedures (SOP) for Sampling Surface Water manual (Jones, 2018), located at the following link: http://static.azdeq.gov/wqd/sampling.pdf

3.4 For specific methods applicable to this scope of work, reference the following chapters and sections of the SOP: • Chapter 1 – Pre-Trip Activities o Sec. 1.4 Equipment Pre-Calibration

PART 2 of the Solicitation Documents: SECTION 2-A: Scope Document (Scope of Scope and Pricing Documents Work) Template version 1.3.1 (13-Jan-2017) Date: 7/26/18 2 Page 2 of 5 Available online at:

Procure.AZ.gov

Request for Proposals Solicitation No. Arizona Department of Environmental Quality ADEQ19-00008372 1110 W. Washington Street Description: Phoenix, AZ 85007 Ambient Stream Water Quality Monitoring

o Sec. 1.5 Cleaning Equipment o Sec. 1.6 Filtration and Tubing • Chapter 2 – General Field Procedures o Sec. 2.1 Field Data Sheets o Sec. 2.2 Equipment and Personnel Decontamination Procedures • Chapter 3 – Chemistry Procedures o Sec. 3.1 Field Measurements o Sec. 3.2 Collecting Water Chemistry Samples o Sec. 3.3 Stream Collection Techniques • Chapter 4 – Bacteria Collection & Processing o Sec. 4.1 Colilert System • Chapter 5 - Measuring Flow o Sec. 5.1 Instantaneous Discharge with Flow Meter o Sec. 5.2 Float method o Sec. 5.3 USGS staff gage o Sec. 5.4 Volumetric Measurement • Chapter 9 – Post-Trip Procedures o Sec. 9.1 Calculating Discharge o Sec. 9.3 Water Quality Meter Post-Trip Check o Sec. 9.4 Routine Maintenance • Chapter 10 – Data Management o Sec. 10.1 WQDB Basics o Sec. 10.2 General Workflow

3.5 All collected data shall adhere to ADEQ’s credible data rule in the Water Quality Standards Article 6- Impaired Water Identification Rule (AAC R18-11-602; http://apps.azsos.gov/public_services/Title_18/18- 11.pdf) and ADEQ’s Quality Assurance Program Plan (http://static.azdeq.gov/wqd/fish_advisory_SWS_QAPP.pdf).

3.6 Exhibit C - ADEQ Ambient Stream Monitoring FY19 Field Form (as may be amended) shall be used to collect water quality measurements. Entries shall be legible and associate the correct trip# and sample# with the samples listed on the chain of custody. At each stream location, water chemistry samples, stream flow and other measurements shall be collected following ADEQ Standard Operating Procedures for Surface Water Sampling at sites listed in Exhibit A - Sampling and Analysis Plan. Parameters and sampling frequency are listed in Table A.2.2 of Exhibit A.

3.7 Samples shall be submitted to ADEQ Contracted Labs, using ADEQ Trip#, Dataset# and Sample# obtained via Contractor access to the ADEQ Water Quality Database for each site ID and date.

PART 2 of the Solicitation Documents: SECTION 2-A: Scope Document (Scope of Scope and Pricing Documents Work) Template version 1.3.1 (13-Jan-2017) Date: 7/26/18 2 Page 3 of 5 Available online at:

Procure.AZ.gov

Request for Proposals Solicitation No. Arizona Department of Environmental Quality ADEQ19-00008372 1110 W. Washington Street Description: Phoenix, AZ 85007 Ambient Stream Water Quality Monitoring

3.8 Water samples shall be submitted to ADEQ Contracted Labs within five (5) days of collection date using ADEQ approved chain-of –custody (CoC) forms.

3.9 Sample tracking data shall be entered into a Sample Tracking spreadsheet daily on the shared google drive sheet. The sample tracking sheet is the primary way ADEQ tracks progress and includes basic information for what was sampled or not sampled at each site.

3.10 Exhibit D – FY19 Site Verification Form (as may be amended), shall be submitted by the COB on Friday of the sample week in the same pdf with the Field Form, scanned and uploaded to the shared Google Drive location.

3.11 Follow ADEQ 2019 Sampling and Analysis Plan for site lists & locations, water chemistry parameters, sampling frequency and special sample conditions, lab locations, and safety information. A list of “oversample” sites to replace any sites that may be dry or inaccessible is included in Exhibit A – Sampling and Analysis Plan.

3.12 Collect duplicate samples as per the ADEQ Quality Assurance Program Plan, at a rate of 10% of the total number of samples. The first duplicate sample shall be completed within the first four sample events.

3.13 The Contractor shall be responsible for providing electronic data records. This shall include entering field parameters, flow data, field notes and associated meta-data into the ADEQ water quality database, and approving datasets, within thirty (30) calendar days following lab report receipt date. The most current checklist, Exhibit E – Ambient Water Quality Data QC Checklist for Contractors (as may be amended) shall be used to ensure complete and accurate data entry (to be provided at training). Once the items in the checklist are completed, data shall be “approved” in the ADEQ WQDB. ADEQ shall conduct data audits to ensure accurate processing of data by Contractor and follow-up where needed.

3.14 Each crew chief or team lead must pass a field audit, which shall be scheduled shortly after training. The crew chief is the main sampler responsible for complete and accurate sample collection.

3.15 A sampling event is complete when each item detailed in Exhibit F – Completed Sampling Event Checklist (as may be amended) is accounted for.

3.16 Insurance certificate and endorsements shall be submitted within two (2) business days upon contract award.

PART 2 of the Solicitation Documents: SECTION 2-A: Scope Document (Scope of Scope and Pricing Documents Work) Template version 1.3.1 (13-Jan-2017) Date: 7/26/18 2 Page 4 of 5 Available online at:

Procure.AZ.gov

Request for Proposals Solicitation No. Arizona Department of Environmental Quality ADEQ19-00008372 1110 W. Washington Street Description: Phoenix, AZ 85007 Ambient Stream Water Quality Monitoring

4.0 Contractor Performance Review 4.1 The Contractor’s performance during the contract period shall be evaluated on an annual basis by the following items: • Number of incomplete sample events or untimely data shall be less than 5% of total sample events. • Each team lead passes each field audit with zero major corrections (affects data quality) and fewer than 5 minor (does not affect data quality) corrections. Refer to Appendix G on the following link: http://static.azdeq.gov/wqd/fish_advisory_SWS_QAPP.pdf. • Quality assurance review time (date approved minus date data received from lab) less than or equal to thirty (30) calendar days for each sample.

PART 2 of the Solicitation Documents: SECTION 2-A: Scope Document (Scope of Scope and Pricing Documents Work) Template version 1.3.1 (13-Jan-2017) Date: 7/26/18 2 Page 5 of 5 Available online at: Procure.AZ.gov Request for Proposals Solicitation No. ADEQ19-00008372 Arizona Department of Environmental Quality Description: Ambient Stream Water Quality 1110 W. Washington Street Monitoring Phoenix, AZ 85007 Exhibits to the Scope of Work

Exhibit A - Sampling and Analysis Plan

Exhibit B – FY19 Ambient Chemistry Sites

Exhibit C – ADEQ Ambient Stream Monitoring FY19 Field Form

Exhibit D – FY19 Site Verification Form

Exhibit E – Ambient Water Quality Data QC Checklist for Contractors

Exhibit F – Completed Sampling Event Checklist

Exhibit A

Sampling and Analysis Plan for

Water Quality (Streams, Lakes & Fish Tissue) Fiscal Year 2019 (July 1, 2018 to June 30, 2019)

Revised: 7/3/2018

Distribution List (Sent by email on 7/6/18) 1. Krista Osterberg, ADEQ Surface Water Section Manager, [email protected] 2. Rik Gay, ADEQ Monitoring & Assessment Unit Manager, [email protected] 3. Jason Jones, ADEQ Senior Scientist [email protected] 4. Jason Sutter, ADEQ, Hydrogeologist, [email protected] 5. Jade Dickens, Watershed Protection Unit, Supervisor, [email protected] 6. Sharma Torrens, AZDA PIO, Directors Office, [email protected] 7. Jack Peterson, AZDA [email protected] 8. John Rihs, USFS, Apache Sitegraves NF, [email protected] 9. Chad Yocum, USFS, Prescott NF, [email protected] 10. Grant Loomis, USFS, Tonto NF, [email protected] 11. Rory Steinke, USFS, Coconino NF, [email protected] 12. Salek Shafiqullah, USFS,Coronado NF, [email protected] 13. Janet Hashimoto, USEPA Region IX, [email protected] 14. Stephen Maurano, USEPA Region IX, [email protected] 15. Dave Weedman, AZG&F, [email protected] 16. Marc Dahlberg, AZG&F, [email protected] 17. Matt Bolt, USEPA, Region IX, [email protected]

Page 1 of 56

FY19 Sampling and Analysis Plan for Water Quality

1.0 INTRODUCTION

This Sampling and Analysis Plan is considered a living document and will be updated periodically throughout the current fiscal year to reflect changes in the field.

1.1 Overview This sample plan addresses water quality monitoring in streams and lakes throughout Arizona for the Surface Water Section Water Quality Planning and Improvement Valuestream hereafter refered to as the “Improvement VS”. Unlike previous years, much of the implementation of this plan will be done by contractors rather than internal staff.

The Improvement VS collaborates with the U.S. Geological Survey to monitor water quality in the Arizona’s larger rivers. Sampling locations, monitoring frequency, parametric coverage, field procedures, and reporting by USGS are documented in the Joint Funding Agreement for Water Resources Investigations.

1.2 Project Staff Improvement VS and Related Staff:

Rik Gay, Monitoring and Assessment Unit Supervisor ([email protected]) Jason D. Jones ([email protected]) Lee Johnson ([email protected]) Patti Spindler ([email protected]) John Woods ([email protected]) Sam Rector ([email protected]) Susan Fitch ([email protected]) Trey Dempsey ([email protected]) Catherine Gullo ([email protected]) Afag Abbasova ([email protected])

Jade Dickens, Watershed Protection Unit Supervisor ([email protected]) Jason Sutter ([email protected]) Kyle Palmer ([email protected]) Meghan Smart ([email protected]) Jessica Latzko ([email protected]) Ronald Tiller ([email protected]) Garrison Becher ([email protected])

2.0 OBJECTIVES

2.1 Improvement VS Program Objectives: The objectives of ADEQ Surface Water Quality Monitoring Unit are: • Restore and maintain the chemical, physical and biological integrity of Arizona’s lakes and streams • Conduct ongoing monitoring of the waters of the state as required by A.R.S. §49-225; • Provide credible data for surface water quality assessments required by §305(b) of the Clean Water Act; • Provide credible data to identify impaired surface waters pursuant to §303(d) of the Clean Water Act; • Determine compliance with applicable water quality standards; • Collect stream macroinvertebrate data on reference sites to adjust the indexes of biological integrity. • Provide credible data to characterize baseline water quality in Outstanding Arizona Waters and to determine whether water quality is being maintained, protected, or degraded. • Issue Fish Consumption Advisories based on fish tissue data.

3.0 MONITORING DESIGN

Sites typically meet more than one objective. For example, a site may be selected because additional data is needed for the 305(b) assessment, it is an Outstanding Arizona Water and it is a reference site.

Page 2 of 56 FY19 Sampling and Analysis Plan for Water Quality

3.1 Streams & Lakes Targeted sites are selected to address data gaps for reaches identified in the 305(b) assessment, to monitor Outstanding Waters, to monitor reference sites for the biocriteria program, to monitor effluent dominated waters and to monitor special studies such as impacts from wildfires.

3.1.1 Monitoring to Confirm Impairments or Delist Sampling of impaired waters is performed to either confirm impairments or delist a waterbody. This is typically done when the data causing the original listing is old, or right at the threshold for impairment. Sampling is completed in accordance with the ‘Sampling Impaired Water’s Worksheet’.

3.1.2 Monitoring to Fill Data Gaps for the Clean Water Act Assessment §305(b) of the Clean Water Act requires ADEQ to conduct a water quality assessment of Arizona’s surface waters every two years. Current EPA guidance states that each surface water assessed should be placed in one of five assessment categories. The five categories are as follows: 1) Surface waters where all designated uses are being attained; 2) Surface waters that are attaining some designated uses but there is insufficient data to assess the remaining uses; 3) Surface waters with insufficient data to assess any designated use; 4) Surface waters that are not attaining one or more designated uses, but a Total Maximum Daily Load (TMDL) analysis is not required; and 5) Surface waters that are impaired for one or more designated uses and a TMDL is required.

Surface waters with insufficient data to determine whether a surface water is attaining designated uses or is impaired are identified in categories 2 and 3 on the assessment list. Surface waters in categories 2 and 3 are included on a planning list and targeted for water quality monitoring to fill existing data gaps. In some cases, data sets for some sample sites are incomplete and do not include all core parameters required for §305(b) water quality assessment. In other cases, there were an insufficient number of sampling events to make an assessment.

3.1.3 Outstanding Arizona Waters Monitoring MU staff collect surface water quality data to characterize existing water quality and to determine whether water quality is being maintained and protected in Arizona’s outstanding waters. Currently, there are 22 Outstanding Arizona Waters listed in Arizona’s Administrative Code R18-11-112. The primary purpose of monitoring outstanding waters is to collect surface water quality data to characterize baseline water quality. A long-term goal of this program is to acquire enough water quality data over time to determine water quality trends in Arizona’s outstanding waters and to determine whether state antidegradation requirements are being met (i.e., is water quality improving, being maintained, or is it degrading).

3.1.4 Biocriteria Reference Program Monitoring The MU’s goal is to conduct bioassessments at a minimum of 10 biocriteria reference sites in each fiscal year. MU staff collect benthic macroinvertebrate samples in wadeable, perennial streams with suitable riffle habitats during the spring index period (April, May, or June).

3.1.5 San Pedro Wildlife Area – National Resource Damage Assessment (NRDA) ADEQ is committed to collecting water quality samples at one site in the Lower San Pedro Wildlife Area, a restoration site being managed by the AGFD and Trustees, of which ADEQ is a member agency. The NRDA Restoration plan calls for various types of monitoring, in which ADEQ collected spring macroinvertebrate, water samples and habitat measurements from 2012-2016 at two sites, and will continue to collect these spring only SEM samples and measurements at one site every five years beginning in 2021 through 2041 (2021, 2026, 2031, 2036, 2041). ADEQ was responsible for a Data Compilation report on the 2012-16 dataset which was delivered to Trustee agency representatives in 2018. ADEQ is also responsible for an additional data report in 2041 or as requested by the Trustees, in the interim. ADEQ is also to attend Trustees committee meetings, Lower San Pedro Workgroup meetings, participation in public meetings held by the Trustees, outreach events and development of publicity materials for meetings, as needed. Funding has been provided for these activities through the Trustees and NRDA fund (see Linda Taunt or Tinsae Babo).

3.2 Fish Tissue Monitoring The Improvement VS monitors fish tissue to determine if the fish in Arizona’s lakes and streams contain pollutants. ADEQ issues fish consumption advisories for waterbodies, pollutants and fish species that are above water quality standards. Sites are currently selected using a random sampling design. Targeted sites are selected based on the following:

Page 3 of 56 FY19 Sampling and Analysis Plan for Water Quality

1) Waterbodies that are heavily fished. 2) Data gaps. Additional data needed to determine if a fish advisory is needed. Additional sampling may be required if not all possible catchable fish have been sampled in a particular waterbody. 3) Collecting data to resend a fish advisory or to determine progress toward removing an advisory is being achieved.

4.0 METHODS & DATA QUALITY

4.1 Surface Water 4.1.1 Methods ADEQ’s Standard Operating Procedures for Surface Water Sampling (Jones 2018) shall be followed for all sampling activities. Deviations from standard operating procedures will be noted on the field forms and in the Water Quality Database.

4.1.2 Data Quality Data collected by ADEQ shall be of the highest quality possible. The following rules and documents outline ADEQ’s approach to obtaining the highest quality data possible. Staff shall follow all of these documents to ensure the highest data quality. • The ‘Credible Data Rule’ (A.A.C) R18-11-602 • Standard Operating Procedures for Surface Water Sampling (Jones 2018). Sections 3.2.5 and 3.2.7.7. • Surface Water Section Quality Assurance Program Plan (Jones 2015)

5.0 LABORATORIES

5.1 Certification ADEQ certifies that the labs listed in Section 5.2 has/have the appropriate certification/accreditation, if necessary, to perform the analyses requested by ADEQ, as required by EPA’s Laboratory Competency Policy.”

The laboratories limits have been reviewed by ADEQ and shall meet the Measurement Quality Objectives in Section 2.3 of the Surface Water Section Quality Assurance Plan.

5.2 Contract Labs

# Name Lab Type Address / Phone Billing Code 1 SGS Accutest Chemistry (Streams, 1741 W University Dr, 18-198189 Lakes), Fish Tissue Tempe, AZ 85281 Tel: (480) 275-8931 2 Ecoanalysts, Inc Macroinvertebrate & 1420 S. Blaine Suite 14 Algae Moscow, ID 83843 (208) 882-2588 Tel 3 EPA Region IX Fish Tissue 1337 S 46th St, NA (Free) Richmond, CA (510) 412-2331 4 Rhithron Periphyton ID 33 Fort Missoula Rd. Missoula, Montana 59804 Phone: 406-721-1977 5 Test America Chemistry 4625 E Cotton Center 17-177217:4 Blvd #189 Phoenix, AZ (602) 437-3340 6 Walker Ecological Lake Havasu 5800 N. Kolb Rd #9150 18-176715 Services Biological Tucson, AZ 85750

7 Xenco SSC 2525 W Huntington Dr. 17-177219:1 Tempe AZ 85282

Page 4 of 56 FY19 Sampling and Analysis Plan for Water Quality

6.0 LABORATORY BUDGET

Table 7. FY19 Lab Budget (updated 7/16/18) Type Analyses Lab Unit Cost Total Cost Streams Chemistry Test America $429.00 $108,135.00 Streams Chem QC Test America $280.00 $10,813.00 Streams SSC Xenco $35.00 $2,450.00 Streams Bugs Ecoanalysts $590.00 $62,540.00 Streams Bug QC Ecoanalysts $590.00 $5900.00 Streams Chlorophyll a (benthic Xenco $110.00 $6490.00 and water column) Streams Chlorophyll a (benthic Xenco $110.00 $649.00 and water column) Streams PeriphytonID Rhithron $295.00 $31,270 Streams PeriphytonID- QC Rhithron $295.00 $2950.00 Lakes All Lakes Test America $1980.00 $61,290.00 Lakes Lakes QC Test America $1980.00 6,129.00 Lakes All Lakes Walker $640.00 $10,240.00 Lakes Lakes QC Walker $640.00 $1,024.00 Fish Hg, Se, Lipids, PCBs Test America $670.00 $14,070.00 Fish Fish QC Test America $670.00 $1407.00 Total $325,357.00

Table 8. Surface Water Budget by Lab based on new budget. Lab Total (regular + QC samples) Total * 1.051 RoundUP Ecoanalysts2 $68,440.00 $71,862.00 $72,000 Rhithron2 $34,220 $35,931.00 $36,000 Test America 201,844.00 $211936.20 $212,000.00 Walker $11,264.00 $11,827.00 $12,000 Xenco $9,589.00 $10,068.00 $11,000 Total $325,357.00 $341624.90 $342,000.00 1- Multiplier added to estimate increased lab cost, since current lab costs were used to calculate lab budget. 2- Cost for macroinvertebrates and periphyton identification samples are for samples collected in previous FY. FY18 sample analysis cost added to FY19 SAP because processing bugs/algae takes 3 to 6 months to complete and invoice cannot be completed until following fiscal year.

Page 5 of 56 FY19 Sampling and Analysis Plan for Water Quality

7.0 HEALTH AND SAFETY PLAN

7.1 General health and safety considerations: 1. “Safety First!” is the guiding principle for MU personnel involved in field activities. Personal safety always has priority over samples and sample collection. 2. Follow general site safety procedures from the Standard Operating Procedures Manual. 3. Prepare a detailed trip routing form and submit to Unit Manager for each sampling trip. Follow your itinerary. Notify the Unit Manager of any changes to your scheduled itinerary. 4. Follow telephone check-in procedures at end of the sampling day from Standard Operating Procedures Manual. 5. First aid, CPR, and personal protection training (in house) is required for all MU personnel. 6. Perform regular maintenance and walk-around checks on field vehicles. Inspect your truck before you go out. Make sure you have a spare tire! Check bolts holding down the camper shell. 7. Emergency tool kit for each field vehicle. 8. First aid kit for each field vehicle. 9. Carry extra clothes during winter months in case you get wet. 10. A minimum of two persons will comprise field crews. Never sample alone. 11. No sampling after dark. 12. Someone on the trip should have a cell or satellite phone. 13. If you have open wounds, wear protective clothing against water contact. 14. If the river is in flood, do not sample or attempt wading. 15. Wait for thunderstorms to pass before sampling. Be ready to evacuate in the event of flash flood. 16. Carry a first-aid kit on the trip, and if hiking to sites, carry a smaller one in the backpack. 17. Do not trespass on private property without permission. 18. Do not force confrontations with strangers. 19. Take necessary precautions against the sun. 20. If attacked by bees, run in a zigzag pattern until clear of the swarm. 21. During winter, take necessary precautions against the cold. 22. Wear proper clothing for protection when sampling or traveling to/from site. 23. Be careful of slippery stream banks. 24. Avoid jumping from low terraces or banks into the stream bed. Ankle and foot injuries can occur from impacts with hidden boulders or cobbles. 25. Hand-held two-way radios should be used if visual contact between field members is lost. 26. Wait until you are on the main road or in town before using the sealer. 27. Make sure the inReach locator beacon is charged before a trip (if one is used) 28. Be prepared to spend the night in case you get stuck in a remote site. Some good things to have: • Warm clothes (Gloves, hats, socks, etc.) • Rain Poncho • Bug Spray • Flashlight • Sun Screen • Waterproof matches • Multi-purpose tool (Leatherman) • Extra food/water • First Aid Kit

7.2 Specific safety precautions: 1. For those with allergic reactions to bee stings, they are expected to provide and have readily available a bee testing kit and/or epipen with them while doing field work. They are also expected to make their field partner aware of their allergy and provide instruction for their care if stung by a bee or other insects that may cause an allergic reaction. 2. Be careful when using acid preservatives in the field. Open all acid vials carefully and take care to avoid getting acid on your hands or clothes. Avoid inhaling fumes from acid vials. Empty entire acid vial into sample bottles when and properly store used acid vials for later disposal at ADEQ when you return from your trip. Store acid vials securely in their Styrofoam containers in the back of the truck (not in the truck cab). 3. Field crews should be aware of the potential for illegal drug activity along the U.S.- Mexico border and contact Boarder Patrol whenworking in those areas (e.g., Lower Santa Cruz River and Nogales Wash). 4. Rubber gloves and irrigation boots or waders should be used in contaminated or effluent-dominated waters. Carry and use antibacterial soap or hand sanitizer. 5. Field crews should stay in voice contact of each other at all times. Page 6 of 56

FY19 Sampling and Analysis Plan for Water Quality

6. Cell phones are recommended for field work for emergency use. Check out a satellite phone if you are going to a remote area where cell phone coverage is unlikely. 7. Stay hydrated! Don’t forget to drink water, especially when working in the summer heat. Body hydration is the most important factor in avoiding hyperthermia. Hyperthermia is a condition of increased body temperature caused by exposure to excessive heat and it is a real concern for a good part of the year in Arizona. Don’t discount the risk, it can happen to you! Contributing factors include physical exertion, lack of air movement, high temperatures, and lack of hydration. Early warning signs of hyperthermia are chilling, a throbbing pressure in the head, unsteadiness, dizziness, nausea, dry skin, rapid pulse, and muscle spasms. To avoid hypothermia, drink water in moderate amounts while you work…don’t wait until you are thirsty. Don’t substitute soda for water. Use good judgment when scheduling your daily fieldwork. Avoid working through the hottest part of the afternoon in the summer whenever possible. 8. Wear sun block. Take precautions against over-exposure to the sun. Wear a wide-brimmed hat & a long-sleeved shirt. 9. Wear your seat belt in the truck. 10. Do not wade in a stream when it is too deep or too fast. Observe the rule of 9. Do not attempt to wade in a stream when the velocity in ft/ second times depth is greater than 9. Always be aware of rapidly rising stages in the streams you are working in. With Arizona’s flashy hydrology, be aware of dangerous flash flood conditions that can occur in a short period of time. Don’t take chances! 11. Do not store food or drinks in sample coolers. Bring a dedicated cooler for food.

7.3 Emergency information: Emergency Telephone Numbers: (use 911 where appropriate) Fire: 911 Police: 911 Ambulance: 911

7.4 Safety Hazards

Table 8. Safety Hazards. Activity Identified Hazards Safety Measures a. Flow Gauging Immersion/Drowning Use the Rule of 9 (Velocity X depth) to determine whether stream is safe to enter. Falls/Slips Wear waders, boots, or sandals with good traction characteristics. Where possible, use the gauging rod to assist as a “third leg.” Infection from open If afflicted, wear waders or boots only to protect sores from water cuts/sores/blisters contact. b. Water Sample Immersion/Drowning See safety measures for flow gauging above Collection Falls/Slips Infection from open cuts/sores/blisters c. Sample Processing Acid Exposure/burns Familiarize with MSDS for chemical contact/inhalation dangers. Wear nitrile gloves when processing samples. Wear eye protection to protect against splash hazard. d. Bacteria Processing Exposure to Pathogens Wear gloves when processing bacteria samples. Do not pipette samples by mouth. Wash or disinfect hands thoroughly after processing/reading. Store incubated plates in a closed biohazard bag. Autoclave on return. e. Bacteria Reading Exposure to Pathogens See safety precautions for bacteria processing above f. Macroinvertebrate Immersion/Drowning See safety measure for flow gauging. Rule of Nine should be Collection Falls/Slips Infection from modified to Rule of Six for macroinvertebrate collections. open cuts/sores/blisters Insect bites For certain aquatic insects, care should be taken to avoid insect bites. Use a spoon or other implement to collect/transfer insects to collection jar. h. Macroinvertebrate Chemical Exposure Familiarize with MSDS for chemical contact/inhalation dangers. Processing Avoid inhalation of formalin vapors. Wear nitrile gloves when processing i. SEM protocols Immersion/Drowning See safety measure for flow gauging. Falls/Slips Infection from open cuts/sores/blisters

Page 7 of 56 FY19 Sampling and Analysis Plan for Water Quality

Activity Identified Hazards Safety Measures Animals/snakes/scorpions When working along banks, be watchful for encounters for wild animals. Do not place hands and feet where they cannot be seen. Do not provoke a cornered animal. Do not handle wild animals. j. Loading Strains/Muscle pulls For large coolers, packs, or other items, use two person teams. Lift with legs, not back. k. Transport Vehicular accidents If driving, check the vehicle beforehand for jack, spare tire, emergency kit, adequate gas and oil, etc. Follow all pertinent traffic rules and regulations. Ensure that all items transported are properly secured. Wear safety belts. l. Unloading Strains/Muscle pulls See safety precautions for loading (j). m. Environmental Sun exposure / heat Wear sunscreen. Wear hat and adequate protective clothing, Hazards exhaustion / heatstroke particularly if sun-sensitive. Use the river to cool off. Hypothermia For cold-weather runs, wear multiple layers of waterproof or water- resistant clothing. Avoid cotton. Follow trip lead recommendations. Bee stings Personnel allergic to bee stings should carry an epinephrine kit at all times on the river. Snakebite Do not place hands or feet where placement cannot be seen. Do not aggravate or handle snakes encountered. Keep distance. Ensure snakebite kit is present in event of bite. Rock fall Be cognizant of rock fall hazards when sampling. Flash floods Monitor weather during the trip, particularly thunderstorms building in the area. Be alert to conditions while sampling. Use extra caution in unforgiving areas where flooding could be catastrophic. Inclement Weather Ensure proper clothing and gear is present to protect against sunburn, heat exhaustion, hypothermia, and other environmental responses. Do not sample or gauge in thunderstorms. Injury due to Use care when hiking, stepping, or climbing to avoid falls or impact/concussion misplacement of limbs resulting in sprains, strains or muscle pulls. First aid kit should include materials for splinting/bandaging in the event of a broken limb.

7.5 Arizona Hospitals

Table 9. List of Arizona Hospitals (Updated AG4 6/2015) City Hospital Name Phone # Address Benson Benson Hospital (520) 586-2261 450 S. Ocotillo Street Bisbee Copper Queen Community Hospital (520) 432-5383 101 Cole Avenue Casa Grande Casa Grande Regional Medical Center (520) 381-3600 1800 E. Florence Boulevard Cottonwood Verde Valley Medical Center (928) 634-2251 269 S. Candy Lane Douglas Southeast Arizona Medical Center (520) 364-7931 2174 W. Oak Avenue Flagstaff Flagstaff Medical Center (928) 779-3366 1200 N. Beaver Street Globe Cobre Valley Community Hospital (928) 425-3261 5880 S. Hospital Drive Goodyear West Valley Emergency Center (623) 882-1500 13677 W McDowell Rd Kingman Kingman Regional Medical Center (928) 757-2101 3269 Stockton Hill Road Lake Havasu City Havasu Regional Medical Center (928) 855-8185 101 Civic Center Lane Mesa Banner Baywood Medical Center (480) 321-2000 6644 E. Baywood Avenue (in east Mesa) Nogales Carondelet Holy Cross Hospital (520) 285-3000 1171 W. Target Range Road Parker La Paz Regional Hospital (928) 669-9201 1200 Mohave Road Payson Payson Regional Medical Center (928) 474-3222 807 S. Ponderosa Street Phoenix John C. Lincoln Deer Valley Hospital (623) 879-6100 19829 N. 27th Avenue (I-17 & 101) Phoenix Mayo Clinic Hospital (480) 515-6296 5777 E. Mayo Boulevard (near the 101) Prescott Yavapai Regional Medical Center (928) 445-2700 1003 Willow Creek Road Safford Mt. Graham Community Hospital (928) 348-4000 1600 S. 20th Avenue Page 8 of 56 FY19 Sampling and Analysis Plan for Water Quality

City Hospital Name Phone # Address Sedona Verde Valley Medical Center (928) 204-3000 3700 Hwy 89A Show Low Summit Healthcare Regional Medical Center (928) 537-4375 2200 E. Show Low Lake Road Sierra Vista Canyon Vista Medical Center (520) 263-2000 5700 E. Hwy 90 Sierra Vista Raymond W. Bliss Army Health Center (520) 533-9200 2240 Winrow Rd. Springerville White Mountain Regional Medical Center (928) 333-4368 118 S. Mountain Avenue Tucson Northwest Medical Center (520) 742-9000 6200 N. La Cholla Blvd Tucson Oro Valley Hospital (520) 901-3500 1551 East Tangerine Road Tucson Tucson Medical Center (520) 327-5461 5301 E. Grant Road (Craycroft & Grant) Tucson Carondelet St. Mary’s Hospital (520) 872-3000 1601 W. St. Mary’s Ro Tucson Banner University Community Medical Center (520) 694-8888 1501 N. Campbell Avenue Wickenburg Wickenburg Regional Hospital (928) 684-5421 520 Rose Lane Willcox Northern Cochise Community Hospital (520) 384-3541 901 W. Rex Allen Drive Winslow Winslow Memorial Hospital (928) 289-4691 1501 Williamson Avenue Yuma Yuma Regional Medical Center (928) 366-2000 2400 S. Avenue A

7.6 Trip Routing Form The trip routing form is to be completed by project lead for every trip prior to departure.

7.7 Check-In Procedures Check in with the Primary Contact listed on the routing form at the end of the day (time specified on routing form). The goal is to physically communicate with the check-in person that you are at the hotel or home and everything is fine. Leaving a message is acceptable but not preferred. Text messages are also acceptable but ideally the contact person will verify that they received the message. After working hours check-in calls should be placed to the contact person’s home or cell phone. Let the contact person know of any deviations from the routing form.

7.8 Vehicle Problems

(Source http://www.azdot.gov/Inside_adot/Equipment_Services/brochure.asp#Breakdown) VEHICLE BREAKDOWNS - WHAT TO DO

We hope you will never experience a breakdown while on the road, but if one should occur, your first responsibility is for your own safety. Please get well off the road and be aware of any local hazards or traffic conditions that might pose a danger.

If your vehicle is still operable, drive it to the nearest safe haven or to a repair facility. If a "RED" warning light comes on, safely pull off the road, turn the engine off and call for help. If the "Check Engine" or "Service Engine Soon" light comes on; take the vehicle to the nearest ADOT Equipment Services Shop as soon as possible.

During Normal Working Hours To request vehicle breakdown service Monday - Friday During Normal Work Hours (6:00 AM - 1:30 PM), please use the following procedures: • Call the ADOT-ES vehicle repair shop closest to your location. • Write down the vehicle data information on the back cover of your handbook. Please be sure to take this handbook with you if you have to leave the vehicle to call the ADOT-ES vehicle repair shop. • You will need the following information when making the call to the appropriate shop: o Your Name, Agency and Agency telephone number o Your location; (nearest intersection or highway milepost marker and direction of travel) o Vehicle Number, VIN#, Make, Model, Year, and Color of vehicle o Telephone number where you can be contacted o Nature of the problem • Call your Fleet Manager and/or Supervisor to advise them of your status. NOTE: In most cases, the vehicle operator is responsible for changing a flat tire. Please review your fleet policy or contact your fleet manager regarding their policy on changing flat tires. If you are instructed not to change the tire, you are physically unable to change the tire, or the location of the vehicle makes changing the tire unsafe, call the ADOT Equipment Services 24-hour vehicle breakdown hotline at 1.877.800.8520.

Page 9 of 56 FY19 Sampling and Analysis Plan for Water Quality

After Normal Working Hours, Weekends and Holidays To request vehicle breakdown service Monday - Friday After Normal Work Hours (1:30 PM - 6:00 AM), Weekends and Holidays, please use the following procedures: • Call the ADOT Equipment Services 24-Hour vehicle breakdown Hotline at 1.877.800.8520. The call will be answered by ADOT's contract vendor for providing statewide vehicle breakdown service. • Please provide the representative with the following information: o Your Name, Agency and Agency telephone number o Your location; (nearest intersection or highway milepost marker and direction of travel) o Vehicle Number, VIN#, Make, Model, Year, and Color of vehicle o Telephone number where you can be contacted o Nature of the problem • The representative will arrange for a tow truck to be dispatched to your location. In most breakdown cases, the vehicle will be towed to the nearest ADOT-ES vehicle repair shop, maintenance yard or dealership for repairs. • Contact your Fleet manager and/or supervisor to advise them of your status. • The tow truck is authorized to bring fuel out to your location. If your vehicle's fuel gauge is low, notify the tow truck driver in advance to bring fuel. • You may ride with the tow truck to the ADOT-ES vehicle repair shop, maintenance yard or dealership. However, you are responsible for arranging for your transportation from the repair shop, maintenance yard or dealership. You (the vehicle operator) are not expected to pay for the towing service. Advise the tow truck driver that ADOT-ES will be paying for the towing service. The tow truck driver should give you a towing service "invoice/record". Please sign the invoice and leave it on the front seat of the vehicle.

NOTE: As previously noted, in most cases the vehicle operator is responsible for changing a flat tire. Please review your fleet policy or contact your fleet manager regarding their policy on changing flat tires. If you are instructed not to change the tire, you are physically unable to change the tire, or the location of the vehicle makes changing the tire unsafe, call the vehicle breakdown Hotline at 1.877.800.8520. During Weekends and Holidays . . . follow the procedures listed under After Normal Working Hours.

Table 10. ADOT Equipment Service Shops (Source: http://www.azdot.gov/Inside_adot/Equipment_Services/Shops2.asp, Updated 7/31/13) CITY/TOWN STREET HOURS PHONE NO. LOCATION HWY ROUTE A.M. - P.M. CONTACT AVONDALE 1702 E. Elesio Fleix Jr. Way ALL YEAR 623.932.3204 6:00 - 2:30 Jeremy Cleavenger CASA GRANDE 15614 W. Boxelder Dr. ALL YEAR 520.423.2378 6:00 - 4:30. Richard Dearie DOUGLAS 21st & "B" Ave. ALL YEAR 520.364.4742 7:30 - 4:00 Abe Varela FLAGSTAFF 5701 RAILHEAD AVE. ALL YEAR 928.526.0957 7:00 - 3:30 Kenny Macias FREDONIA US 89A, MP 610.9 ALL YEAR 928.643.7249 (Page Satellite Shop) 6:00 - 2:30 Wes McAllister GAME AND FISH 5000 W. CAREFREE HWY ALL YEAR 623.780.4160 6:00 - 5:00 Norman Rose GLOBE US 60, MP 253 ALL YEAR 928.402.5640 (NORTHBOUND ) 6:30 - 3:00 Robert Gillespie HOLBROOK 2407 E. NAVAJO BLVD ALL YEAR 928.524.5466 7:00 - 3:30 Carl Sandefur KAYENTA Hwy 163, MP 394.5 Call Page Shop 928.645.2147 Hank Surzyn KINGMAN 3540 E. HWY. 66 ALL YEAR 928.681.6211 7:00 - 3:30 Steve Carspecken LITTLEFIELD Old Hwy 91, MP 8 ALL YEAR 928.347.5936 MESA 2409 N. COUNTRY CLUB ALL YEAR 480.644.7923 (Phoenix Satellite Shop) 5:00 - 3:30 Lydia Zavala

Page 10 of 56 FY19 Sampling and Analysis Plan for Water Quality

CITY/TOWN STREET HOURS PHONE NO. LOCATION HWY ROUTE A.M. - P.M. CONTACT PAGE US 89, MP 551.2 ALL YEAR 928.645.2147 6:00 - 2:30 Hank Surzyn PAYSON 200 N. COLCORD ALL YEAR 928.468.5081 (Prescott Valley Satellite Shop) 7:00 -3:30 Bill Williams PHOENIX 2225 S. 22ND. AVE ALL YEAR 602.712.6634 (MAIN COMPLEX) 6:00 - 3:30 602.712.6917 602.712.7044 After Hours Kevin Thomas 877.800.8520 602.712.6634 - PM Appointments PHOENIX 1522 W. JACKSON ST. ALL YEAR 602.542.3206 CAPITOL MALL (Phoenix Satellite Shop) 6:00 - 4:30 Matt Sharpe PRESCOTT VALLEY 6901 E. 2nd St. ALL YEAR 928.775.5079 x 3102 7:00 - 3:30 Chris Fuller SAFFORD 1st Ave. and 32nd St. ALL YEAR 928.428.2909 7:30 - 4:00 Dan Hays SHOW LOW 200 W. MCNEIL ALL YEAR 928.532.2381 7:00 - 3:30 Alex Romero SPRINGERVILLE US 60, MP 388.7 ALL YEAR 928.333.5460 (Show Low Satellite Shop) 7:00 - 3:30 Ken Witt ST. JOHNS US 180, MP 369 ALL YEAR 928.337.2332 (Show Low Satellite Shop) 7:00 - 3:30 Ken Witt TUCSON 1444 W. GRANT RD. ALL YEAR 520.838.2860/2861 BLDG #9 6:00 am-10:30 pm Scott Moody YUMA 2243 GILA RIDGE RD. ALL YEAR 928.317.2170 7:00 - 3:30 Charles McKinley

7.9 Staff Contacts

Table 11. Staff Contacts (Updated June 2018 by RG11) First Last Home Phone Mobile Work Ext. DOUG MCCARTY (623) 907-3157 (602) 421-2595 4521 JADE DICKENS (520) 808-3968 4115 JASON JONES (480) 298-3205 2235 JASON SUTTER (602) 361-3720 4468 JOHN WOODS (602) 402-2250 4471 KRISTA OSTERBERG (602) 337 7833 4635 KYLE PALMER (602) 920-2012 4540 LEE JOHNSON (480) 855-5762 (480) 259-9159 4520 MEGHAN SMART (480) 250-2616 4506 PATTI SPINDLER (602) 329-4610 4543 SAM RECTOR (480) 772-0264 4536 SUSAN FITCH (480) 580-7480 4541 CATHERINE GULLO (774) 766-2190 5228 TREY DEMPSEY (858) 437-3569 8157 RIK GAY (720) 327-5813 8787 AFA ABBASOVA (602) 820-3487 2264

Page 11 of 56 FY19 Sampling and Analysis Plan for Water Quality

8.0 REFERENCE MATERIAL

ADEQ, 2018, Jones, J., ed. Standard Operating Procedures for Surface Water Quality Sampling. Arizona Department of Environmental Quality TM06-02. Phoenix, AZ.

ADEQ. 2015. Jones, J. Surface Water Section Quality Assurance Program Plan. Phoenix, AZ

.

Page 12 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

APPENDIX A. STREAM PARAMETERS & SITES

A.1 Stream Target Analytes All monitoring sites are sampled for a basic group of target analytes to assess whether surface water quality standards are being met. The basic group represents information that is typically gathered by most ambient water quality monitoring programs. The basic group includes general water chemistry, nutrients, total and dissolved metals, and bacteria (See TABLES A1, A2 & A3). Analytes in the basic group provides investigators with a basic understanding of the general chemistry of the surface water. Standardization of a basic suite of target analytes also provides consistency of information across surface waters. Additional parameters (e.g., total and free chlorine for effluent dependent water) may be added to the basic group if warranted by site-specific conditions.

A suite of field measurements are taken in addition to the basic chemical group at all sites. Field measurements such as dissolved oxygen, percent saturation dissolved oxygen, water temperature, and stream flow can only be measured in the field and are important for understanding the physical properties of the water body. Other measurements, such as pH, specific conductance, and turbidity are taken in the field because of their nature to be altered during sample transport to the laboratory. Macroinvertebrates are collected to assess the biological integrity of surface waters and to determine if aquatic life designated uses are supported.

Table A1. Field Parameters with required minimum ranges, accuracy and resolution Parameter Range Accuracy Resolution Specific Conductivity 0-100 mS/cm / 5-100 mS/cm ± 0.5% 0.001 mS/cm pH 0-14 Units ± 0.2 units / +0.1 units 0.01 units Water Temperature -5 to 50 º C ± 0.10 º C 0.01 º C Dissolved Oxygen (optical) 0-50 mg/L + 0.1mg/L; + 0.2 mg/L; + 10% of reading 0.01 mg/L Turbidity 0 – 1000 NTU ± 2% of reading from 0-500 NTU 0.01 NTU ± 3% of reading between 500-1000 NTU Flow -0.5 to +19.99 ft/sec ± 2% of reading + zero stability NA

Table A2. Sample Containers and Preservation Analysis Type Bottle Preservation Inorganics 1 L Plastic None, Wet Ice Nutrients 1 L Plastic H2SO4, Wet Ice Dissolved Metals 500 mL Plastic HN03, Wet Ice Total Metals 500 mL Plastic HN03, Wet Ice Suspended Sediment Concentration (SSC) 1 L ‘wide mouth’ Nalgene None Chlorophyll a (water column) 2 L Amber Bottle, 30mL Amber bottle Chilled and Dark Chlorophyll a (benthic) 500 mL Composite Bottle, 30mL Amber bottle Chilled and Dark Periphyton ID 250 mL Composite Bottle Chilled and Dark, 2+ mL Lugol’s Solution Macroinvertebrates 1 L Nalgene Isopropyl Alcohol E. Coli 100 mL Plastic None

Table A3 (new). Test America - Holding Times, Reporting Limits and Analytical Methods for Streams

Page 13 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

Chemical Analysis Type Method Lab MRL MRL Unit Parameter group Holding Time SUSPENDED SEDIMENT CONCENTRATION SUSPENDED ASTM D3977C Xenco 1.0 MG/L SSC NONE E. Coli NA Colilert DEQ 1 CFU/100 mL E. Coli 6 Hours ALUMINUM DISSOLVED EPA 200.7 TAX 0.1 mg/L Dissolved Metals 6 MONTHS ALUMINUM TOTAL EPA 200.7 TAX 0.1 mg/L Total Metals 6 MONTHS BORON (BORON AND BORATES ONLY) DISSOLVED EPA 200.7 TAX 0.05 mg/L Dissolved Metals 6 MONTHS BORON (BORON AND BORATES ONLY) TOTAL EPA 200.7 TAX 0.05 mg/L Total Metals 6 MONTHS CALCIUM DISSOLVED EPA 200.7 TAX 2 mg/L Dissolved Metals 6 MONTHS CALCIUM TOTAL EPA 200.7 TAX 2 mg/L Total Metals 6 MONTHS IRON DISSOLVED EPA 200.7 TAX 0.1 mg/L Dissolved Metals 6 MONTHS IRON TOTAL EPA 200.7 TAX 0.1 mg/L Total Metals 6 MONTHS MAGNESIUM DISSOLVED EPA 200.7 TAX 2 mg/L Dissolved Metals 6 MONTHS MAGNESIUM TOTAL EPA 200.7 TAX 2 mg/L Total Metals 6 MONTHS POTASSIUM DISSOLVED EPA 200.7 TAX 0.5 mg/L Dissolved Metals 6 MONTHS POTASSIUM TOTAL EPA 200.7 TAX 0.5 mg/L Total Metals 6 MONTHS SODIUM DISSOLVED EPA 200.7 TAX 0.5 mg/L Dissolved Metals 6 MONTHS SODIUM TOTAL EPA 200.7 TAX 0.5 mg/L Total Metals 6 MONTHS STRONTIUM DISSOLVED EPA 200.7 TAX 0.1 mg/L Dissolved Metals 6 MONTHS ANTIMONY DISSOLVED EPA 200.8 TAX 0.001 mg/L Dissolved Metals 6 MONTHS ANTIMONY TOTAL EPA 200.8 TAX 0.001 mg/L Total Metals 6 MONTHS ARSENIC, INORGANIC DISSOLVED EPA 200.8 TAX 0.001 mg/L Dissolved Metals 6 MONTHS ARSENIC, INORGANIC TOTAL EPA 200.8 TAX 0.001 mg/L Total Metals 6 MONTHS BARIUM DISSOLVED EPA 200.8 TAX 0.0005 mg/L Dissolved Metals 6 MONTHS BARIUM TOTAL EPA 200.8 TAX 0.0005 mg/L Total Metals 6 MONTHS BERYLLIUM AND COMPOUNDS DISSOLVED EPA 200.8 TAX 0.001 mg/L Dissolved Metals 6 MONTHS BERYLLIUM AND COMPOUNDS TOTAL EPA 200.8 TAX 0.001 mg/L Total Metals 6 MONTHS CADMIUM DISSOLVED EPA 200.8 TAX 0.0001 mg/L Dissolved Metals 6 MONTHS CADMIUM TOTAL EPA 200.8 TAX 0.0001 mg/L Total Metals 6 MONTHS CHROMIUM DISSOLVED EPA 200.8 TAX 0.001 mg/L Dissolved Metals 6 MONTHS CHROMIUM TOTAL EPA 200.8 TAX 0.001 mg/L Total Metals 6 MONTHS COBALT DISSOLVED EPA 200.8 TAX 0.0005 mg/L Dissolved Metals 6 MONTHS COBALT TOTAL EPA 200.8 TAX 0.0005 mg/L Total Metals 6 MONTHS COPPER DISSOLVED EPA 200.8 TAX 0.0005 mg/L Dissolved Metals 6 MONTHS COPPER TOTAL EPA 200.8 TAX 0.0005 mg/L Total Metals 6 MONTHS LEAD AND COMPOUNDS (INORGANIC) DISSOLVED EPA 200.8 TAX 0.0005 mg/L Dissolved Metals 6 MONTHS

Page 14 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

Chemical Analysis Type Method Lab MRL MRL Unit Parameter group Holding Time LEAD AND COMPOUNDS (INORGANIC) TOTAL EPA 200.8 TAX 0.0005 mg/L Total Metals 6 MONTHS MANGANESE DISSOLVED EPA 200.8 TAX 0.0005 mg/L Dissolved Metals 6 MONTHS MANGANESE TOTAL EPA 200.8 TAX 0.0005 mg/L Total Metals 6 MONTHS MOLYBDENUM DISSOLVED EPA 200.8 TAX 0.0005 mg/L Dissolved Metals 6 MONTHS MOLYBDENUM TOTAL EPA 200.8 TAX 0.0005 mg/L Total Metals 6 MONTHS NICKEL DISSOLVED EPA 200.8 TAX 0.0005 mg/L Dissolved Metals 6 MONTHS NICKEL TOTAL EPA 200.8 TAX 0.0005 mg/L Total Metals 6 MONTHS SELENIUM AND COMPOUNDS DISSOLVED EPA 200.8 TAX 0.0005 mg/L Dissolved Metals 6 MONTHS SELENIUM AND COMPOUNDS TOTAL EPA 200.8 TAX 0.0005 mg/L Total Metals 6 MONTHS SILVER DISSOLVED EPA 200.8 TAX 0.0001 mg/L Dissolved Metals 6 MONTHS SILVER TOTAL EPA 200.8 TAX 0.0001 mg/L Total Metals 6 MONTHS THALLIUM DISSOLVED EPA 200.8 TAX 0.0001 mg/L Dissolved Metals 6 MONTHS THALLIUM TOTAL EPA 200.8 TAX 0.0001 mg/L Total Metals 6 MONTHS URANIUM (CONTENT) TOTAL EPA 200.8 TAX 0.0001 mg/L Total Metals 6 MONTHS VANADIUM DISSOLVED EPA 200.8 TAX 0.0001 mg/L Dissolved Metals 6 MONTHS VANADIUM TOTAL EPA 200.8 TAX 0.0001 mg/L Total Metals 6 MONTHS ZINC DISSOLVED EPA 200.8 TAX 0.0125 mg/L Dissolved Metals 6 MONTHS ZINC TOTAL EPA 200.8 TAX 0.0125 mg/L Total Metals 6 MONTHS MERCURY, ELEMENTAL DISSOLVED EPA 245.1 TAX 0.2 UG/L Dissolved Metals 28 DAYS MERCURY, ELEMENTAL TOTAL EPA 245.1 TAX 0.2 UG/L Total Metals 28 DAYS CHLORIDE TOTAL EPA 300.0 TAX 2 MG/L Inorganics NONE FLUORIDE TOTAL EPA 300.0 TAX 0.4 MG/L Inorganics 28 DAYS SULFATE TOTAL EPA 300.0 TAX 2 MG/L Inorganics 28 DAYS Periphyton Identification NA NRSA 2013 FOM Rhithron NA NA Periphyton ID NONE Chlorophyll a (benthic) TOTAL SM 10200H Walker 0.10 UG/L Chlorophyll a NONE Chlorophyll a (water column) TOTAL SM 10200H Walker 0.10 UG/L Chlorophyll a NONE ALKALINITY, PHENOLPHTHALEIN TOTAL SM 2320B TAX 6 MG/L Inorganics 14 DAYS CALCIUM CARBONATE TOTAL SM 2320B TAX 6 MG/L Inorganics 14 DAYS CARBONATE TOTAL SM 2320B TAX 6 MG/L Inorganics 14 DAYS HYDROGEN CARBONATE TOTAL SM 2320B TAX 6 MG/L Inorganics 14 DAYS HARDNESS (CACO3 + MGCO3) - DISSOLVED CALCULATED SM 2340B TAX 13 MG/L Inorganics 6 MONTHS HARDNESS (CACO3 + MGCO3) – TOTAL CALCULATED SM 2340B TAX 13 MG/L Inorganics 6 MONTHS SPECIFIC CONDUCTIVITY STANDARD SM 2510B TAX 2 UMHOS/CM Inorganics FIELD TOTAL DISSOLVED SOLIDS DISSOLVED SM 2540C TAX 20 MG/L Inorganics 7 DAYS

Page 15 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

Chemical Analysis Type Method Lab MRL MRL Unit Parameter group Holding Time PH TOTAL SM 4500-H+ TAX 1.68 SU Inorganics 15 MINUTES AMMONIA AS NITROGEN TOTAL SM 4500NH3 D, BG TAX 0.05 MG/L Nutrients 28 DAYS KJELDAHL NITROGEN TOTAL SM 4500-NH3 D, E-97 TAX 0.5 MG/L Nutrients 28 DAYS PHOSPHORUS TOTAL SM 4500-PE TAX 0.1 MG/L Nutrients 28 DAYS NITRATE + NITRITE TOTAL SM4500 NO3 E-00 TAX 0.1 MG/L Nutrients 28 DAYS

A.2.1 Stream Sample Plan - INTERNAL

Table A4. Site List and Schedule (Updated on 6/29/18). Parameter SiteID Site Name Lat Long Site Type Set Frequency Lead Site access MGAFR, Agua Fria River, AZPDES Full set Quarterly JOW 15070102-031B downstream of Softwinds mobile home park MGGLR167.44 Gila River- Abv diversion 33.229167 -112.767500 Data Gap Full set Quarterly JOW FROM HWY 85 SOUTH, TURN at gillespie dam; USGS RIGHT ON OLD HWY 80 gage (MARKED FOR PALO VERDE AND ARLINGTON). PROCEED WEST APPROX. 1 MILE TO A T- JUNCTION. TURN LEFT (SOUTH) AND FOLLOW ROAD 1/2 MI TO OLD HWY 80. TURN RIGHT AND PROCEED WEST 3.6 MI THROUGH PALO VERDE TO HASSAYAMPA BR MGHSR058.80 Hassayampa River- at 34.045167 -112.710111 Data Gap Full set Quarterly JOW FROM WICKENBURG, N ON HWY BLM gage, box cyn dam 93 TO APPROX MP 195. TURN RIGHT ON SCENIC LOOP RD. AND PROCEED APPROX 7.1 MILES TO TURNOFF TO BOX CYN (UNMARKED, BUT THERE IS A BLM NO DUMPING SIGN) ON THE RIGHT. FOLLOW ROAD DOWN INTO RIVER BED, TURN EAST AND TRAVEL UPSTREAM TO

Page 16 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

Parameter SiteID Site Name Lat Long Site Type Set Frequency Lead Site access MGLSY000.42 Little Sycamore Creek at 34.363444 -111.974361 Data Gap Full set Quarterly JOW FROM PHOENIX: DRIVE NORTH FS boundary ON I-17 TO DUGAS RD EXIT. DRIVE EAST ON DUGAS ROAD TO CROSSING OF LITTLE SYCAMORE CREEK. CONTINUE ON DUGAS ROAD THROUGH ABANDONED RANCH SITE (A FEW OLD BUILDINGS). LOOK FOR DUGAS RANCH GATE ON THE LEFT. MUST CALL THE LANDOW MGMIN001.38 Mineral Cr, At Hwy 177 34.399920 -110.976222 AZPDES Full set Quarterly JOW bridge, downstream of ASARCO Ray Mine tunnel discharge SCSON015.35 Sonoita Creek 31.515833 -110.792778 Existing DO only As needed JOW Impaired SPGRA007.71 Grant Creek 32.651883 -109.925179 Data Gap Full set Quarterly JD16 FROM SAFFORD: TAKE HWY191 SOUTH THRU TOWN AND CONTINUE SEVERAL MILES SOUTH TO HWY266 (NOT 366). TURN RIGHT AND GO APPROX 22MI TO FORT GRANT PRISON. TAKE DRIVEWAY UP TOWARDS PRISON BUT TURN RIGHT ONTO FR157 THRU RESIDENCES TO UNLOCKED GATE, THEN UP THE MO SPMLC012.68 Miller Canyon 31.405640 -110.291120 Data Gap Full set Quarterly JD16

Page 17 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

Parameter SiteID Site Name Lat Long Site Type Set Frequency Lead Site access SPRMC011.11 Ramsey Canyon 31.441639 -110.316889 Data Gap Full set Quarterly JD16 FROM SIERRA VISTA, TAKE HWY 92 SOUTH TO RAMSEY CANYON RD (WEST). TRAVEL DOWN ROAD TO NATURE CONSERVANCY AND INFORM STAFF OF NEED TO USE ACCESS RD. TAKE ROAD TO HEAD OF TRAIL. FOLLOW CRK UPSTREAM TO JUST ABOVE FOREST BOUNDARY AT BOX CANYON. SPSPR022.15 San Pedro River at Hwy77 32.742556 -110.647833 Data Gap Full set Quarterly JOW FROM WINKELMAN, SOUTH ON near Mammoth HWY 77 APPROX 20 MI TO BRIDGE OVER SAN PEDRO RIVER (2ND BRIDGE). PARK BEYOND GUARDRAIL ON EAST SIDE, SOUTH SIDE OF RIVER, ACROSS FROM MAMMOTH WWTP. SPTUR028.53 Turkey Creek, abv upper 31.853537 -109.328285 Data Gap Full set Quarterly JD16 NA Campground SRHOU, Houston Cr, downstream AZPDES Full set Quarterly CG8 15060105-024 of Houston Landing WWTP (Star valley) UGBLR030.24 Blue River 33.540611 -109.203417 Data Gap Full set Quarterly CG8 UGGLR401.85 Gila River - Bylas/Safford 33.093889 -110.030833 Data Gap Full set Quarterly JD16 UGGLR446.02 Gila River - Safford 32.863228 -109.546928 Data Gap Full set Quarterly JD16 FROM SOLOMON: TAKE THE BUENA VISTA ROAD ( PRISON RD) APPROXIMATELY 2 MILES THE SAN JOSE ROAD APPROXIMATELY 1 MILES TO END OF ROAD. PASS OVER CANAL BRIDGE. SAMPLE BELOW CHECK DAM 300 METERS.

Page 18 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

Parameter SiteID Site Name Lat Long Site Type Set Frequency Lead Site access UGKPK011.18 K P Creek, blw KP 33.583611 -109.343056 Data Gap Full set Quarterly CG8 FROM HWY 191 NEAR Cienega HANNAGAN MEADOW, TAKE THE KP CIENEGA CAMPGRAND ROAD TO TRAIL HEAD # 70. HIKE DOWN APPROXIMATELY 1.5 MILES. THE SAMPLE SITE IS WHERE THE TRAIL CROSSES THE CREEK 1.5 MILES DOWN FROM THE TRAILHEAD. VRBIT004.06/Alt Bitter Creek, blw Jerome 34.755722 -112.106667 AZPDES Full set Quarterly CG8 NA ernate WWTP (KOUI) VROAK016.70 Oak Creek blw Page 34.759048 -111.893905 AZPDES Full set Quarterly CG8 FROM COTTONWOOD: TAKE Springs FH ALT 89/260 SOUTH OUT OF TOWN, THEN ALT 89 E-NE AND CROSS OVER VERDE RIVER. CONTINUE 5-6 MI, TURN RIGHT ONTO HWY 134, THEN PROCEED ANOTHER 2-3 MI TO PAGE SPRINGS FISH HATCHERY. TAKE A LEFT ON DIRT ROAD JUST NORTH OF HATCHERY (ACRO 1 All coordinates are in datum NAD83. 2 Full suite = Inorganics, Nutrients, Dissolved Metals, Total Metals, Suspended Sediment Concentration (SSC) for ALL QUARTERS Chlorophyll a, Periphyton ID & Macroinvertebrates in the 4th QUARTER DURING SPRING INDEX PERIOD

Page 19 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

A.2.2 STREAM SAMPLE PLAN – CONTRACTED – AMBIENT CHEMISTRY

Table A5. Site List and Schedule (Updated on 7/5/18). SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access LCLCR323.69 Little Colorado 34.314444 -109.362222 Existing Limited Stormflow & Contractor NA River, abv Impaired parameters: Field Spring runoff Lyman lake parameters, SSC, turb, flow. BWBOU006.01 Boulder Creek, 34.614143 -113.220615 Existing Limited Low flow, Contractor blw Butte Creek Impaired parameters: begin Q2 (Int camera site) Metals, inorganics, field parameters, flow BWBOU007.13 Boulder Creek, 34.625844 -113.216667 Existing Limited Low flow, Contractor TAKE COORS LAKE RD FROM blw Hillside Impaired parameters: begin Q2 FMI GATE TO HILLSIDE MINE; Mine LTP Metals, ACCESS ROAD TO MTP HAS inorganics, field BEEN OBLITERATED BY UTP parameters, flow REMEDIATION. TAKE LEFT AT UPPER PILE TOWARD HEADFRAMS. PARK WHEN ROAD NARROWS AND HIKE DOWN TO MTP. FROM MTP FOLLOW PATH DOWNSTREAM TO LOWER TAILINGS PILE; BWBOU007.76 Boulder Creek, 34.632770 -113.212465 Existing Limited Low flow, Contractor TAKE COORS LAKE ROAD FROM blw Hillside Impaired parameters: begin Q2 FMI GATE TO HILLSIDE MINE; Mine MTP Metals, ACCESS ROAD TO MTP HAS inorganics, field BEEN OBLITERATED BY UTP parameters, flow REMEDIATION. AT UTP TAKE LEFT TURN TOWARD MTP; PARK WHERE ROAD NARROWS AND HIKE DOWN TO MTP. TAKE PATH FROM SOUTH SIDE OF MTP UNTIL ROCK WALLS (OLD BUILD

Page 20 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access BWBOU008.28 Boulder Creek, 34.638278 -113.212028 Existing Limited Low flow, Contractor TAKE COORS LAKE ROAD FROM abv Hillside Impaired parameters: begin Q2 PHELPS DODGE GATE TO Mine UTP Metals, HILLSIDE MINE; ACCESS ROAD inorganics, field TO MTP HAS BEEN parameters, flow OBLITERATED. PARK NEAR REMEDIATED UTP AND HIKE DOWNSTREAM TO SITE. SITE IS LOCATED IN BEDROCK OUTCROP IN STREAM CHANNNEL. SITE PHOTOS AND LAT/LONG ARE NEEDED TO LO BWBOU008.42 Boulder Creek, 34.638712 -113.207204 Existing Limited Low flow, Contractor TAKE COORS LAKE ROAD NEAR blw Hillside Impaired parameters: begin Q2 FMI BAGDAD MINE ENTRANCE Mine UTP Metals, TO HILLSIDE MINE, FOLLOW inorganics, field ROAD TO THE RIGHT AT parameters, flow REMEDIATED UPPER TAILINGS PILE. PARK NEAR NORTHERN END OF PILE AND HIKE DOWON TO BOULDER CREEK. FOLLOW CREEK UPSTREAM 1/4 MILE AND SAMPLE NEAR REW OF CHANNEL CGBDW000.70 Beaver Dam 36.899139 -113.930278 Nutrient Full suite Q2 & Q3 Contractor or Wash blw Chem CGBDW000.01 Virgin R WWTP outfall, abv confluence with Virgin R CGVGR038.80 Virgin River 36.891667 -113.924444 New Full suite Q2 & Q3 Contractor Impaired Chem CGVGR044.58 Virgin River 36.921389 -113.860556 New Full suite Q2 & Q3 Contractor FROM I-15 BRIDGE AT Impaired Chem LITTLEFIELD AZ: DRIVE NORTH ON HWY 91 2.1 MILES MAKE RIGHT TURN. AT 4.1 MILES VERE LEFT @ 5.1 MILES VERE LEFT @ 5.8 MILES MAKE RIGHT TURN PAST FENCE @ 6.4 MAKE LEFT TOWARDS RIVER.

Page 21 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access LCLCR336.72 Little Colorado 34.186533 -109.302721 Existing Limited Stormflow & Contractor NORTH FROM SPRINGERVILLE River Impaired paramters: Field Spring runoff ON 180, Turn right onto HOOPER parameters, SSC, for Q2- Q3 RANCH ROAD and follow to bridge turb, flow. crossing the LCR before WENIMA RAnch. Park at turnout and sample downstream of bridge crossing. LCNUT003.29 Nutrioso Cr, ds 34.138694 -109.252611 Existing Full suite. Stormflow & Contractor SOUTH OF SPRINGERVILLE of Picnic Cr Impaired Stormflow spring runoff NEAR MURRAY SAFFEL & condition: Field Q2 & Q3 PROJECT AT CONFLUENCE WITH Nutrient parameters, SSC, PICNIC CREEK OFF HWY 180 turb, flow. LCNUT012.99 Nutrioso Creek, 34.063328 -109.198639 Existing Full suite. Stormflow & Contractor FROM SPRINGERVILLE TAKE ds of old USGS Impaired Stormflow spring runoff HWY 191 SOUTH. PARK AT gage station & condition: Field Q2 & Q3 GUARD RAIL JUST AFTER THE Nutrient parameters, SSC, BRIDGE (BEFORE MILE MARKER turb, flow. 409). LOCATED JUST NORTH OF NELSON-+S RESERVOIR. MGAFR091.65 Agua Fria River 34.351389 -112.103056 Nutrient Full suite Q2 & Q3 Contractor NA at Arcosanti Chem MGAFR110.01 Agua Fria River 34.489900 -112.230944 Nutrient Full suite Q2 & Q3 Contractor FROM HWY 69 TURN RIGHT near Dewey- Chem ONTO AN UNMARKED DIRT Humbolt ROAD JUST PAST A RED BARN LIKE BUILDING CALLED REATA PASS AUCTIONS. DRIVE EAST ON ROAD FOR 1 MILE TO SITE (STAY RIGHT AT FORK). CROSS STREAM AND PARK IN TURNOUT. SAMPLE UPSTREAM OF ROAD CROSSING.

Page 22 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access MGGLR183.10 Gila River at 33.333633 -112.623061 New Full suite Q2 & Q3 Contractor FROM HWY 85 SOUTH, or SR85, or at Impaired Chem CONTINUE OVER THE GILA MGGLR179.53 Robbins Butte RIVER BRIDGE TOWARDS GILA BEND. APPROX. 1 MILE BEYOND THE BRIDGE, TURN LEFT (EAST) AT A CROSSOVER AND FOLLOW THE ROAD EASTWARD APPROX 0.1 MI. TURN LEFT AND CONTINUE TO FOLLOW THE ROAD BACK TOWARDS THE RIVER TO A MGGLR313.73 Gila River at 33.102778 -110.974722 New Full suite Q2 & Q3 Contractor NA Kelvin bridge Impaired Chem crossing, USGS gage, just us of Mineral Cr confluence MGHSR000.77, Hassayampa 33.322694 -112.711111 New Full suite Q2 & Q3 Contractor FROM HWY 85 SOUTH, TURN MGHSR002.67 River - at Impaired Chem RIGHT ON OLD HWY 80 Arlington Canal (MARKED FOR PALO VERDE AND ARLINGTON). PROCEED WEST APPROX. 1 MILE TO A T- JUNCTION. TURN LEFT (SOUTH) AND FOLLOW ROAD 1/2 MI TO OLD HWY 80. TURN RIGHT AND PROCEED WEST 3.0 MI THROUGH PALO VERDE TO 307TH AVE. (DIRT). TURN LEFT AND PROCEED 1.5 MI TO SIPHON CROSSING OF ARLINGTON CANAL WITH HASSAYAMPA RIVER. NOTE: LAST 1/2 MI IS GATED PRIVATE PROPERTY. OBTAIN PERMISSION.

Page 23 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access MGHSR048.20 Hassayampa 33.937944 -112.699694 Nutrient Full suite Q2 & Q3 Contractor FROM PHOENIX TAKE I-17 TO River at TNC Chem HWY 74. TURN RIGHT ON I-60 property AND DRIVE NORTH WEST UNTIL YOU REACH THE PRESERVE ON THE LEFT HAND SIDE OF THE INTERSATE. LOCATED AT 49614 U.S. 60, WICKENBERG, AZ 85390. MGLAS004.52 Little Ash Cr 34.383779 -112.025850 Nutrient Full suite Q2 & Q3 Contractor FROM PHOENIX: DRIVE NORTH Chem ON I-17 TO DUGAS RD EXIT#268. DRIVE EAST ON DUGAS RD PAST ESTLER PEAK and cattle guard, approx. 3.4mi and LOOK FOR PRIMITIVE, Unmarked DIRT ROAD ON RIGHT THAT GOES TO DISTINCT RIPARIAN AREA with a turnaround area. DRIVE IN and SPARA019.41 Aravaipa Creek 32.897778 -110.441111 Nutrient/R Full suite Q2 & Q3 Contractor FROM WILLCOX: FOLLOW FORT (east) eference Chem GRANT ROAD SEVERAL MILES TO T INTERSECTION AT BONITA. GO LEFT ONTO BONITA- KLONDYKE ROAD ALL THE WAY THRU KLONDYKE TO ARAVAIPA CANYON. DRIVE TO THE END OF THE ROAD AT THE ARAVAIPA TRAILHEAD/WILDERNESS BOUNDARY. SITE IS LOCATED UP

Page 24 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access SPCRC013.37 Carr Canyon 31.426922 -110.307231 Nutrient Full suite Q2 & Q3 Contractor FROM SIERRA VISTA: TRAVEL Chem SOUTH ON HWY 92 TO FR #368. FOLLOW FR #368 WEST UP THE CANYON UNTIL THE ROAD ENDS. PARK AND LOOK FOR THE GREY TRAIL SIGN FOR RAMSEY CANYON AND COMFORT SPRING. FOLLOW THE TRAIL NORTH TO THE SECOND DRAINAGE CROSSED WHICH IS CAR SPSPR126.35 San Pedro River 31.637422 -110.175567 Nutrient Full suite Q2 & Q3 Contractor FROM SIERRA VISTA: TAKE at Charleston Chem HWY 90 NORTH FOR CA. 1/4 MILE AND THEN TURN EAST ON TO CHARLESTON RD. TAKE CHARLESTON RD EAST AND NORTHEAST TOWARDS TOMBSTONE. ALMOST IMMEDIATELY AFTER CROSSING SAN PEDRO RIVER WATCH FOR PULLOUTS ON NORTH SIDE OF ROAD. FIND TR SRBLR102.24 Black River at 33.704028 -109.452583 Nutrient Full suite Q2 & Q3 Contractor FROM ALPINE: HWY 191 SOUTH FR25 Crossing Chem APPROX 35 MILES TO F.S. ROAD 25. DRIVE APPROX 15 MILES TO WHERE THE RIVER CROSSES THE ROAD. HIKE UP STREAM OF ROAD. SRBON001.69 Boneyard Cr 33.869815 -109.298885 Nutrient Full suite Q2 & Q3 Contractor NA abv Clabber Chem city

Page 25 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access SRCGN009.78 Campaign 33.524175 -111.087261 Nutrient/R Full suite Q2 & Q3 Contractor FROM GLOBE: DRIVE NORTH Creek eference Chem ON HWY 88, PAST HWY 288 JUNCTION, TO FR449 (1-2 MILES PAST ROOSEVELT LAKES RESORT TURNOFF; IT IS THE FIRST LEFT AFTER SCHOOLHOUSE PT. TURNOFF). TURN LEFT ONTO FR449 AND DRIVE THRU SEVERAL WASH CROSSINGS TO END OF ROAD AT REEVIS SRCKN001.61 Conklin Cr, abv 33.681858 -109.444113 Nutrient Full suite Q2 & Q3 Contractor FROM ALPINE: DRIVE SOUTH FR25 road Chem ON HWY 666 TO FS RD 25. DRIVE crossing WEST THEN NORTH TO CONKLIN CREEK CROSSING (CA. 0.5 MILES BEFORE BLACK RIVER BRIDGE CROSSING). HIKE UPSTREAM CA. 1/4 MILES TO SAMPLE REACH. WATER LEVEL TOO LOW TO SAMPLE IN 1994. SRCOO003.57 Coon Creek 33.712628 -110.847239 Nutrient/R Full suite Q2 & Q3 Contractor NA eference Chem SRCRS006.19 Christopher Cr 34.344194 -111.015694 Nutrient/R Full suite Q2 & Q3 Contractor NA (upper) eference Chem SRDEV000.38 Devils Chasm 33.822965 -110.860810 Nutrient/R Full suite Q2 & Q3 Contractor FROM GLOBE: DRIVE NORTH ON Cr eference Chem HWY88 TO HWY 288 (YOUNG HWY). DRIVE NORTH ON HWY 288 CROSS SALT RIVER TO FR203, THE CHERRY CR. RD. DRIVE EAST AND THEN NORTH ON FR203 UP CHERRY CR TO DEVILS CHASM CROSSING. SAMPLE JUST UPSTREAM OF CONFLUENCE WITH CHERRY CR.

Page 26 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access SRHAG007.47 Haigler Cr, 34.203790 -111.008600 Nutrient Full suite Q2 & Q3 Contractor FROM PAYSON: DRIVE EAST ON FY18 leftover Chem HWY 260. PAST CHRISTOPHER CREEK, TURN RIGHT ON FS RD 291 (COLCORD RD). TURN SOUTHWEST ON FS RD 200. DRIVE ON RD 200, PAST HAIGLER CANYON CAMPGROUND, ACROSS HAIGLER CR. FORD, TO FS RD 249. DRIVE WEST ON RD 249 TO UNNAMED WA SRNFB012.35 North Fork East Nutrient Full suite Q2 & Q3 Contractor FROM ALPINE: GO NORTH ON Fork Black Chem HWY191 FOR 1.5MI THEN TURN River LEFT ONTO FR249 AND DRIVE APPROX. 10MI TO THREE FORKS AREA. PARK IN TURNOUT BEFORE/EAST OF NORTH FORK BRIDGE AND ACROSS FROM THREE FORKS PARKING LOT. GO ACROSS BRIDGE AND HIKE 33.855561 -109.315081 UPSTREAM ON RB SIDE OF NFB SRRES000.33 Reservation Nutrient Full suite Q2 & Q3 Contractor FROM ALPINE: DRIVE SOUTH ON Creek, abv Chem RT. 191 TO FS RD 25. DRIVE WEST Black river THEN NORTH TO BLACK RIVER confl BRIDGE CROSSING. CONTINUE PAST RIVER TO RIDGE POINT (WILDCAT POINT, FOLLOW TOP MAP). HIKE DOWN RIDGE (FAIRLY STEEP) TO DRY WASH INTO RESERVATION CREEK. LOOK FOR 33.699183 -109.477397 FL SRTON055.09 Tonto Creek Nutrient Full suite Q2 & Q3 Contractor blw crossing at Chem Bear Flats 34.300278 -111.067861 NA

Page 27 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access SRTON062.28 Tonto Creek Nutrient Full suite Q2 & Q3 Contractor FROM PAYSON: GO 21MI EAST ON blw AGFD Fish Chem HWY 260. TURN LEFT ONTO Hatchery TONTO CR FISH HATCHERY RD BEFORE KOHLS RANCH. DRIVE 4MI ON PAVED ROAD TO END AT FH. PARK IN LOT OUTSIDE AGFD ENTRANCE SIGN. FOLLOW TRAIL TO CREEK@ CASCADE. SAMPLE 34.37808 -111.0991 LOCATION IS BELOW CASCADE. SRWPN004.47 West Pinto Cr, Nutrient Full suite Q2 & Q3 Contractor FROM SUPERIOR OR GLOBE, TAKE FY18 leftover Chem US 60 TO FS ROAD 287 (BHP MINE ROAD), FOLLOW ALL SIGNS THROUGH MINE WORKS (STAY ON PUBLIC ROAD) TO HAUNTED CANYON AND CROSS IRON BRIDGE (DO NOT TURN LEFT AT INTERSECTION BEFORE IRON BRIDGE), DRIVE 0.1 MILES TO 33.439608 -111.064008 FIRST INTERSECT UGBLR008.09 Blue River, at New Full suite Q2 & Q3 Contractor old USGS gage Impaired Chem ds of Juan Miller Rd crossing 33.290833 -109.196111 NA UGBLR046.35 Blue River blw Nutrient Full suite Q2 & Q3 Contractor FROM ALPINE: DRIVE EAST END jackson box Chem OF ALPINE NEAR LUNA LAKE, TURN SOUTH ON FS RD 281 (BLUE RIVER ROAD). DRIVE SOUTH ON 281 DOWN TO CAMPBELL BLUE CREEK, ALONG CREEK TO CONFLUENCE WITH BLUE RIVER, DOWNSTREAM ALONG BLUE RIVER TO BELOW JACKSON BOX. 33.684489 -109.083056 WHEN PAST THE

Page 28 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access UGCMB004.23 Campbell blue Nutrient Full suite Q2 & Q3 Contractor FROM ALPINE: DRIVE EAST ON Chem HWY180 TOWARDS LUNA LAKE. TURN SOUTH ON FR 281/APACHE CNTY 2104. DRIVE SOUTH ON FR281 7.8MI TO FR30/LUCE RANCH RD ALONG CAMPBELL BLUE CREEK. TAKE FR30 UPSTREAM ALONG CAMPBELL BLUE CREEK. DRIVE CA. 1.8MI TO 33.738803 -109.097157 SAMPLE SITE. VRELL009.02 Ellison Cr near Nutrient Full suite Q2 & Q3 Contractor FROM PAYSON: TAKE STATE HWY headwaters Chem 260 NORTH EAST TO THE JUNCTION OF FS RD # 64. THIS IS LOCATED APPROXIMATELY 0.9 MILES PAST MILE MARKER 155 (TONTO VILLAGE TURN OFF). TURN LEFT ONTO 64, WHICH IS ALSO REFERRED TO AS THE FIRE CONTROL ROAD. FOLLOW 64 34.3789 -111.175537 NORTH WE VREVR045.50 East Verde R Nutrient Full suite Q2 & Q3 Contractor FROM THE TOWN OF PAYSON, abv Second Chem TAKE STATE ROUTE 87 NORTH TO crossing FOREST SERVICE ROAD 199 (HOUSTON MESA ROAD). FOLLOW 199 NORTH FOR ABOUT 8.3 MILES UNTIL YOU REACH THE SECOND CROSSING ON THE EAST VERDE RIVER. PULL OFF ONTO THE SHOULDER AREA AND PARK 34.355803 -111.283083 THE VEHICLE.

Page 29 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access VREVR051.15 East Verde R at Nutrient Full suite Q2 & Q3 Contractor FROM PAYSON: GO NORTH ON Washington Chem STATE HWY 87, TURN RIGHT ON Park HOUSTON MESA ROAD (AKA HWY 199 NORTH) AND DRIVE FOR 10.6 MILES. AT A T INTERSECTION TURN LEFT ON FS RD 64 FOR .6 MILES. THEN TURN RIGHT ON FS RD 32 FOR 3.3 MILES (THROUGH A 34.421111 -111.263293 RESIDENTIAL AREA). N VRFOS011.88 Fossil Cr Nutrient Full suite Q2 & Q3 Contractor MUST USE THE CAMP VERDE Chem ROUTE. I-17 TO HWY 260 TURN RT ON FOSSIL CR ROAD TO PARKING 34.416944 -111.603722 LOT. VROAK031.26 Oak Creek blw Nutrient Full suite Q2 & Q3 Contractor Red Rock Chem crossing 34.825333 -111.808183 NA VROAK048.92 Oak Cr (upper, Nutrient/R Full suite Q2 & Q3 Contractor PULLOFFS ON EAST AND WEST blw Pine flats eference Chem SIDE OF 89A 1.5 N OF WEST FORK subdiv) OAK CREEK TURNOFF; SAMPLE 35.00475 -111.735417 ABOVE SMALL BUILDING ON LEW VRPIE008.19 Pine Creek at Nutrient Full suite Q2 & Q3 Contractor FROM PAYSON TAKE HWY 87 Tonto Natural Chem NORTH TO TONTO NATURAL Bridge BRIDGE. CHECK IN AT KIOSK AND LET THEM KNOW YOU WILL BE SAMPLING. DRIVE TO THE END OF THE PARKING LOT (AS FAR SOUTH AS YOU CAN DRIVE) AND PARK. FOLLOW TRAIL TO SAMPLE SITE JUST BELOW PEDESTRIAN BRIDGE. 34.319222 -111.457506 THE

Page 30 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access VRPIE016.49 Pine Creek Nutrient/R Full suite Q2 & Q3 Contractor FROM THE CITY OF PAYSON, TAKE (upper) eference Chem STATE ROUTE 87 NORTH TO THE TOWN OF PINE. AS YOU PASS THROUGH THE TOWN YOU WILL CROSS OVER PINE CREEK. APPROXIMATELY 0.6 MILES NORTH OF THE CREEK CROSSING IS A TURN-OFF TO THE RIGHT, WITH A CHURCH BUILDING ON 34.421033 -111.4409 THE CORNER. VRROU002.93 Roundtree Cr Nutrient/R Full suite Q2 & Q3 Contractor FROM PHOENIX: TAKE I-17 eference Chem NORTH TO BLOODY BASIN RD EXIT (FEW MILES SOUTH OF CORDES JUNCTION). DRIVE EAST ON BLOODY BASIN ROAD (FS ROAD 269)CA. 26 MILES TO CAVE CREEK RD JUNCTION. DRIVE SOUTH ON CAVE CREEK ROAD 1.2 MILES TO 34.139591 -111.84675 ROUNDTREE SPRINGS. USE TOPO VRSYW000.77 Sycamore Cr- Nutrient Full suite Q2 & Q3 Contractor near wilderness Chem boundary 34.869056 -112.069083 NA VRVER108.49 Verde R blw Nutrient Full suite Q2 & Q3 Contractor Squaw peak Chem cyn, us of West Clear Cr confluence 34.515556 -111.838611 NA

Page 31 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access VRVER127.02 Verde R at Nutrient Full suite Q2 & Q3 Contractor FROM CAMP VERDE: AT EXIT 1000 trails Chem FROM I-17, TAKE 279 NORTH TO Mobile home FS 147. TURN EAST OFF STATE park ROUTE 279 ONTO THE ROAD TO THOUSAND TRAILS TRAILER PARK. THERE IS A ROAD JUST NORTH OF THE RV PARKING AREA THAT ALLOWS YOU TO DRIVE DOWN TO A FENCED AREA THAT HAS AN 34.675232 -111.939479 ACCE VRVER136.93 Verde R at Nutrient Full suite Q2 & Q3 Contractor Riverfront park 34.751132 -112.016268 Chem NA VRVER185.21 Verde R at Nutrient Full suite Q2 & Q3 Contractor FROM PRESCOTT: GO NORTH ON Inscription Chem HWY89 THRU PAULDEN, WHICH IS point 13MI PAST WATSON LAKE. TURN RIGHT ON FR354 FOR 4-5MI,THEN TURN LEFT ONTO FR638 FOR 2MI, THEN BEAR RIGHT AND IMMED LEFT ONTO FR635 TOWARDS VERDE RANCH. TURN LEFT BEFORE RANCH AND DRIVE TO 34.867489 -112.401836 RIVER ABV P VRWBV006.50 Wet Beaver Cr Nutrient Full suite Q2 & Q3 Contractor at Montezuma Chem Well 34.648333 -111.751111 NA

Page 32 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access VRWBV009.31 Wet Beaver Cr Nutrient Full suite Q2 & Q3 Contractor FROM CAMP VERDE: DRIVE at Chem NORTH ON FS RD 646 TO Campgrounds MONTEZUMA CASTLE NATIONAL MONUMENT (PORTION NEAREST CAMP VERDE). PARK IN PARKING AREA ACROSS FROM ENTRANCE TO BEAVER CREEK CAMPGROUND, ON SOUTHWEST SIDE OF FS RD 618. PARK IN PARKING AREA 34.667383 -111.716122 ACROSS FROM ENTRANC VRWBV012.56 Wet Beaver Cr Nutrient/R Full suite Q2 & Q3 Contractor FROM PHOENIX, DRIVE NORTH ON eference Chem I-17 TO EXIT 298 (PAST CAMP VERDE). DRIVE EAST AND TAKE SECOND RIGHT NEAR THE WET BEAVER WILDERNESS RANGER STATION. DRIVE INTO DIRT PARKING LOT. FOLLOW TRAIL TO USGS GAGE. RULE OF THUMB: IF 34.673921 -111.670166 TRAIL FORKS STAY ON RIGHT (FYI VRWCL005.10 West Clear Cr Nutrient Full suite Q2 & Q3 Contractor FROM CAMP VERDE: DRIVE EAST at Campground Chem ON FH9 (ROAD TO STRAWBERRY/PAYSON). DRIVE TO JUST BEFORE ROAD CROSSES WEST CLEAR CREEK. TURN LEFT INTO CLEAR CREEK CAMPGROUND. SAMPLE JUST UPSTREAM OF THE 34.514176 -111.756645 CAMPGROUND.

Page 33 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Crew cheif Site Access VRWCL036.37 West Clear Cr Nutrient/R Full suite Q2 & Q3 Contractor FROM PAYSON: TAKE HWY 87 (upper) eference Chem NORTH OF PAYSON, PAST STRAWBERRY/PINE TO CLINT?S WELL. TURN LEFT ONTO FH3 AND DRIVE NORTH 7MI. TURN LEFT ON FR81 (NOTE WCC TRAILHEAD SIGN). DRIVE SW ON FR81, IT TURNS INTO FR81E. BEAR RIGHT AT ?MAXWELL TRAIL? FAINT 34.553139 -111.407528 SIGNPOST AT 7. 1 All coordinates are in datum NAD83. 2 Full suite = Inorganics, Nutrients, Dissolved Metals, Total Metals, Suspended Sediment Concentration (SSC) for ALL QUARTERS SEM = Chlorophyll a, Periphyton ID & Macroinvertebrates in the 4th QUARTER DURING SPRING INDEX PERIOD

A.2.3 Stream Sample Plan – CONTRACTED – SEM 4th Quarter Table A6. Site List and Schedule (Updated on 7/5/18). SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access LCLCR323.69 Little Colorado 34.314444 -109.362222 Existing Full Suite SEM Q4 SEM Contractor NA River, abv Impaired Lyman lake CGBDW000.70 Beaver Dam 36.899139 -113.930278 Nutrient Full Suite SEM Q4 SEM Contractor or Wash blw CGBDW000.01 Virgin R WWTP outfall, abv confluence with Virgin R CGVGR038.80 Virgin River 36.891667 -113.924444 New Full Suite SEM Q4 SEM Contractor Impaired CGVGR044.58 Virgin River 36.921389 -113.860556 New Full Suite SEM Q4 SEM Contractor FROM I-15 BRIDGE AT Impaired LITTLEFIELD AZ: DRIVE NORTH ON HWY 91 2.1 MILES MAKE RIGHT TURN. AT 4.1 MILES VERE LEFT @ 5.1 MILES VERE LEFT @ 5.8 MILES MAKE RIGHT TURN PAST FENCE @ 6.4 MAKE LEFT TOWARDS RIVER.

Page 34 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access LCLCR336.72 Little Colorado 34.186533 -109.302721 Existing Full Suite SEM Q4 SEM Contractor NORTH FROM SPRINGERVILLE River Impaired ON 180, Turn right onto HOOPER RANCH ROAD and follow to bridge crossing the LCR before WENIMA RAnch. Park at turnout and sample downstream of bridge crossing. LCNUT003.29 Nutrioso Cr, ds 34.138694 -109.252611 Existing Full Suite SEM Q4 SEM Contractor SOUTH OF SPRINGERVILLE of Picnic Cr Impaired NEAR MURRAY SAFFEL & PROJECT AT CONFLUENCE WITH Nutrient PICNIC CREEK OFF HWY 180 LCNUT012.99 Nutrioso Creek, 34.063328 -109.198639 Existing Full Suite SEM Q4 SEM Contractor FROM SPRINGERVILLE TAKE ds of old USGS Impaired HWY 191 SOUTH. PARK AT gage station & GUARD RAIL JUST AFTER THE Nutrient BRIDGE (BEFORE MILE MARKER 409). LOCATED JUST NORTH OF NELSON-+S RESERVOIR. MGAFR091.65 Agua Fria River 34.351389 -112.103056 Nutrient Full Suite SEM Q4 SEM Contractor NA at Arcosanti MGAFR110.01 Agua Fria River 34.489900 -112.230944 Nutrient Full Suite SEM Q4 SEM Contractor FROM HWY 69 TURN RIGHT near Dewey- ONTO AN UNMARKED DIRT Humbolt ROAD JUST PAST A RED BARN LIKE BUILDING CALLED REATA PASS AUCTIONS. DRIVE EAST ON ROAD FOR 1 MILE TO SITE (STAY RIGHT AT FORK). CROSS STREAM AND PARK IN TURNOUT. SAMPLE UPSTREAM OF ROAD CROSSING. MGGLR183.10 Gila River at 33.333633 -112.623061 New Full Suite SEM Q4 SEM Contractor FROM HWY 85 SOUTH, or SR85, or at Impaired CONTINUE OVER THE GILA MGGLR179.53 Robbins Butte RIVER BRIDGE TOWARDS GILA BEND. APPROX. 1 MILE BEYOND THE BRIDGE, TURN LEFT (EAST) AT A CROSSOVER AND FOLLOW THE ROAD EASTWARD APPROX 0.1 MI. TURN LEFT AND CONTINUE TO FOLLOW THE ROAD BACK TOWARDS THE RIVER TO A

Page 35 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access MGGLR313.73 Gila River at 33.102778 -110.974722 New Full Suite SEM Q4 SEM Contractor NA Kelvin bridge Impaired crossing, USGS gage, just us of Mineral Cr confluence MGHSR000.77, Hassayampa 33.322694 -112.711111 New Full Suite SEM Q4 SEM Contractor FROM HWY 85 SOUTH, TURN MGHSR002.67 River - at Impaired RIGHT ON OLD HWY 80 Arlington Canal (MARKED FOR PALO VERDE AND ARLINGTON). PROCEED WEST APPROX. 1 MILE TO A T- JUNCTION. TURN LEFT (SOUTH) AND FOLLOW ROAD 1/2 MI TO OLD HWY 80. TURN RIGHT AND PROCEED WEST 3.0 MI THROUGH PALO VERDE TO 307TH AVE. (DIRT). TURN LEFT AND PROCEED 1.5 MI TO SIPHON CROSSING OF ARLINGTON CANAL WITH HASSAYAMPA RIVER. NOTE: LAST 1/2 MI IS GATED PRIVATE PROPERTY. OBTAIN PERMISSION. MGHSR048.20 Hassayampa 33.937944 -112.699694 Nutrient Full Suite SEM Q4 SEM Contractor FROM PHOENIX TAKE I-17 TO River at TNC HWY 74. TURN RIGHT ON I-60 property AND DRIVE NORTH WEST UNTIL YOU REACH THE PRESERVE ON THE LEFT HAND SIDE OF THE INTERSATE. LOCATED AT 49614 U.S. 60, WICKENBERG, AZ 85390.

Page 36 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access MGLAS004.52 Little Ash Cr 34.383779 -112.025850 Nutrient Full Suite SEM Q4 SEM Contractor FROM PHOENIX: DRIVE NORTH ON I-17 TO DUGAS RD EXIT#268. DRIVE EAST ON DUGAS RD PAST ESTLER PEAK and cattle guard, approx. 3.4mi and LOOK FOR PRIMITIVE, Unmarked DIRT ROAD ON RIGHT THAT GOES TO DISTINCT RIPARIAN AREA with a turnaround area. DRIVE IN and SPARA019.41 Aravaipa Creek 32.897778 -110.441111 Nutrient/R Full Suite SEM Q4 SEM Contractor FROM WILLCOX: FOLLOW FORT (east) eference GRANT ROAD SEVERAL MILES TO T INTERSECTION AT BONITA. GO LEFT ONTO BONITA- KLONDYKE ROAD ALL THE WAY THRU KLONDYKE TO ARAVAIPA CANYON. DRIVE TO THE END OF THE ROAD AT THE ARAVAIPA TRAILHEAD/WILDERNESS BOUNDARY. SITE IS LOCATED UP SPCRC013.37 Carr Canyon 31.426922 -110.307231 Nutrient Full Suite SEM Q4 SEM Contractor FROM SIERRA VISTA: TRAVEL SOUTH ON HWY 92 TO FR #368. FOLLOW FR #368 WEST UP THE CANYON UNTIL THE ROAD ENDS. PARK AND LOOK FOR THE GREY TRAIL SIGN FOR RAMSEY CANYON AND COMFORT SPRING. FOLLOW THE TRAIL NORTH TO THE SECOND DRAINAGE CROSSED WHICH IS CAR

Page 37 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access SPSPR126.35 San Pedro River 31.637422 -110.175567 Nutrient Full Suite SEM Q4 SEM Contractor FROM SIERRA VISTA: TAKE at Charleston HWY 90 NORTH FOR CA. 1/4 MILE AND THEN TURN EAST ON TO CHARLESTON RD. TAKE CHARLESTON RD EAST AND NORTHEAST TOWARDS TOMBSTONE. ALMOST IMMEDIATELY AFTER CROSSING SAN PEDRO RIVER WATCH FOR PULLOUTS ON NORTH SIDE OF ROAD. FIND TR SRBLR102.24 Black River at 33.704028 -109.452583 Nutrient Full Suite SEM Q4 SEM Contractor FROM ALPINE: HWY 191 SOUTH FR25 Crossing APPROX 35 MILES TO F.S. ROAD 25. DRIVE APPROX 15 MILES TO WHERE THE RIVER CROSSES THE ROAD. HIKE UP STREAM OF ROAD. SRBON001.69 Boneyard Cr 33.869815 -109.298885 Nutrient Full Suite SEM Q4 SEM Contractor NA abv Clabber city SRCGN009.78 Campaign 33.524175 -111.087261 Nutrient/R Full Suite SEM Q4 SEM Contractor FROM GLOBE: DRIVE NORTH Creek eference ON HWY 88, PAST HWY 288 JUNCTION, TO FR449 (1-2 MILES PAST ROOSEVELT LAKES RESORT TURNOFF; IT IS THE FIRST LEFT AFTER SCHOOLHOUSE PT. TURNOFF). TURN LEFT ONTO FR449 AND DRIVE THRU SEVERAL WASH CROSSINGS TO END OF ROAD AT REEVIS

Page 38 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access SRCKN001.61 Conklin Cr, abv 33.681858 -109.444113 Nutrient Full Suite SEM Q4 SEM Contractor FROM ALPINE: DRIVE SOUTH FR25 road ON HWY 666 TO FS RD 25. DRIVE crossing WEST THEN NORTH TO CONKLIN CREEK CROSSING (CA. 0.5 MILES BEFORE BLACK RIVER BRIDGE CROSSING). HIKE UPSTREAM CA. 1/4 MILES TO SAMPLE REACH. WATER LEVEL TOO LOW TO SAMPLE IN 1994. SRCOO003.57 Coon Creek 33.712628 -110.847239 Nutrient/R Full Suite SEM Q4 SEM Contractor NA eference SRCRS006.19 Christopher Cr 34.344194 -111.015694 Nutrient/R Full Suite SEM Q4 SEM Contractor NA (upper) eference SRDEV000.38 Devils Chasm 33.822965 -110.860810 Nutrient/R Full Suite SEM Q4 SEM Contractor FROM GLOBE: DRIVE NORTH ON Cr eference HWY88 TO HWY 288 (YOUNG HWY). DRIVE NORTH ON HWY 288 CROSS SALT RIVER TO FR203, THE CHERRY CR. RD. DRIVE EAST AND THEN NORTH ON FR203 UP CHERRY CR TO DEVILS CHASM CROSSING. SAMPLE JUST UPSTREAM OF CONFLUENCE WITH CHERRY CR. SRHAG007.47 Haigler Cr, 34.203790 -111.008600 Nutrient Full Suite SEM Q4 SEM Contractor FROM PAYSON: DRIVE EAST ON FY18 leftover HWY 260. PAST CHRISTOPHER CREEK, TURN RIGHT ON FS RD 291 (COLCORD RD). TURN SOUTHWEST ON FS RD 200. DRIVE ON RD 200, PAST HAIGLER CANYON CAMPGROUND, ACROSS HAIGLER CR. FORD, TO FS RD 249. DRIVE WEST ON RD 249 TO UNNAMED WA

Page 39 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access SRNFB012.35 North Fork East Nutrient Full Suite SEM Q4 SEM Contractor FROM ALPINE: GO NORTH ON Fork Black HWY191 FOR 1.5MI THEN TURN River LEFT ONTO FR249 AND DRIVE APPROX. 10MI TO THREE FORKS AREA. PARK IN TURNOUT BEFORE/EAST OF NORTH FORK BRIDGE AND ACROSS FROM THREE FORKS PARKING LOT. GO ACROSS BRIDGE AND HIKE 33.855561 -109.315081 UPSTREAM ON RB SIDE OF NFB SRRES000.33 Reservation Nutrient Full Suite SEM Q4 SEM Contractor FROM ALPINE: DRIVE SOUTH ON Creek, abv RT. 191 TO FS RD 25. DRIVE WEST Black river THEN NORTH TO BLACK RIVER confl BRIDGE CROSSING. CONTINUE PAST RIVER TO RIDGE POINT (WILDCAT POINT, FOLLOW TOP MAP). HIKE DOWN RIDGE (FAIRLY STEEP) TO DRY WASH INTO RESERVATION CREEK. LOOK FOR 33.699183 -109.477397 FL SRTON055.09 Tonto Creek Nutrient Full Suite SEM Q4 SEM Contractor blw crossing at Bear Flats 34.300278 -111.067861 NA SRTON062.28 Tonto Creek Nutrient Full Suite SEM Q4 SEM Contractor FROM PAYSON: GO 21MI EAST ON blw AGFD Fish HWY 260. TURN LEFT ONTO Hatchery TONTO CR FISH HATCHERY RD BEFORE KOHLS RANCH. DRIVE 4MI ON PAVED ROAD TO END AT FH. PARK IN LOT OUTSIDE AGFD ENTRANCE SIGN. FOLLOW TRAIL TO CREEK@ CASCADE. SAMPLE 34.37808 -111.0991 LOCATION IS BELOW CASCADE.

Page 40 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access SRWPN004.47 West Pinto Cr, Nutrient Full Suite SEM Q4 SEM Contractor FROM SUPERIOR OR GLOBE, TAKE FY18 leftover US 60 TO FS ROAD 287 (BHP MINE ROAD), FOLLOW ALL SIGNS THROUGH MINE WORKS (STAY ON PUBLIC ROAD) TO HAUNTED CANYON AND CROSS IRON BRIDGE (DO NOT TURN LEFT AT INTERSECTION BEFORE IRON BRIDGE), DRIVE 0.1 MILES TO 33.439608 -111.064008 FIRST INTERSECT UGBLR008.09 Blue River, at New Full Suite SEM Q4 SEM Contractor old USGS gage Impaired ds of Juan Miller Rd crossing 33.290833 -109.196111 NA UGBLR046.35 Blue River blw Nutrient Full Suite SEM Q4 SEM Contractor FROM ALPINE: DRIVE EAST END jackson box OF ALPINE NEAR LUNA LAKE, TURN SOUTH ON FS RD 281 (BLUE RIVER ROAD). DRIVE SOUTH ON 281 DOWN TO CAMPBELL BLUE CREEK, ALONG CREEK TO CONFLUENCE WITH BLUE RIVER, DOWNSTREAM ALONG BLUE RIVER TO BELOW JACKSON BOX. 33.684489 -109.083056 WHEN PAST THE

Page 41 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access UGCMB004.23 Campbell blue Nutrient Full Suite SEM Q4 SEM Contractor FROM ALPINE: DRIVE EAST ON HWY180 TOWARDS LUNA LAKE. TURN SOUTH ON FR 281/APACHE CNTY 2104. DRIVE SOUTH ON FR281 7.8MI TO FR30/LUCE RANCH RD ALONG CAMPBELL BLUE CREEK. TAKE FR30 UPSTREAM ALONG CAMPBELL BLUE CREEK. DRIVE CA. 1.8MI TO 33.738803 -109.097157 SAMPLE SITE. VRELL009.02 Ellison Cr near Nutrient Full Suite SEM Q4 SEM Contractor headwaters

FROM PAYSON: TAKE STATE HWY 260 NORTH EAST TO THE JUNCTION OF FS RD # 64. THIS IS LOCATED APPROXIMATELY 0.9 MILES PAST MILE MARKER 155 (TONTO VILLAGE TURN OFF). TURN LEFT ONTO 64, WHICH IS ALSO REFERRED TO AS THE FIRE CONTROL ROAD. FOLLOW 64 34.3789 -111.175537 NORTH WE VREVR045.50 East Verde R Nutrient Full Suite SEM Q4 SEM Contractor FROM THE TOWN OF PAYSON, abv Second TAKE STATE ROUTE 87 NORTH TO crossing FOREST SERVICE ROAD 199 (HOUSTON MESA ROAD). FOLLOW 199 NORTH FOR ABOUT 8.3 MILES UNTIL YOU REACH THE SECOND CROSSING ON THE EAST VERDE RIVER. PULL OFF ONTO THE SHOULDER AREA AND PARK 34.355803 -111.283083 THE VEHICLE.

Page 42 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access VREVR051.15 East Verde R at Nutrient Full Suite SEM Q4 SEM Contractor FROM PAYSON: GO NORTH ON Washington STATE HWY 87, TURN RIGHT ON Park HOUSTON MESA ROAD (AKA HWY 199 NORTH) AND DRIVE FOR 10.6 MILES. AT A T INTERSECTION TURN LEFT ON FS RD 64 FOR .6 MILES. THEN TURN RIGHT ON FS RD 32 FOR 3.3 MILES (THROUGH A 34.421111 -111.263293 RESIDENTIAL AREA). N VRFOS011.88 Fossil Cr Nutrient Full Suite SEM Q4 SEM Contractor MUST USE THE CAMP VERDE ROUTE. I-17 TO HWY 260 TURN RT ON FOSSIL CR ROAD TO PARKING 34.416944 -111.603722 LOT. VROAK031.26 Oak Creek blw Nutrient Full Suite SEM Q4 SEM Contractor Red Rock crossing 34.825333 -111.808183 NA VROAK048.92 Oak Cr (upper, Nutrient/R Full Suite SEM Q4 SEM Contractor PULLOFFS ON EAST AND WEST blw Pine flats eference SIDE OF 89A 1.5 N OF WEST FORK subdiv) OAK CREEK TURNOFF; SAMPLE 35.00475 -111.735417 ABOVE SMALL BUILDING ON LEW VRPIE008.19 Pine Creek at Nutrient Full Suite SEM Q4 SEM Contractor FROM PAYSON TAKE HWY 87 Tonto Natural NORTH TO TONTO NATURAL Bridge BRIDGE. CHECK IN AT KIOSK AND LET THEM KNOW YOU WILL BE SAMPLING. DRIVE TO THE END OF THE PARKING LOT (AS FAR SOUTH AS YOU CAN DRIVE) AND PARK. FOLLOW TRAIL TO SAMPLE SITE JUST BELOW PEDESTRIAN BRIDGE. 34.319222 -111.457506 THE

Page 43 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access VRPIE016.49 Pine Creek Nutrient/R Full Suite SEM Q4 SEM Contractor FROM THE CITY OF PAYSON, TAKE (upper) eference STATE ROUTE 87 NORTH TO THE TOWN OF PINE. AS YOU PASS THROUGH THE TOWN YOU WILL CROSS OVER PINE CREEK. APPROXIMATELY 0.6 MILES NORTH OF THE CREEK CROSSING IS A TURN-OFF TO THE RIGHT, WITH A CHURCH BUILDING ON 34.421033 -111.4409 THE CORNER. VRROU002.93 Roundtree Cr Nutrient/R Full Suite SEM Q4 SEM Contractor FROM PHOENIX: TAKE I-17 eference NORTH TO BLOODY BASIN RD EXIT (FEW MILES SOUTH OF CORDES JUNCTION). DRIVE EAST ON BLOODY BASIN ROAD (FS ROAD 269)CA. 26 MILES TO CAVE CREEK RD JUNCTION. DRIVE SOUTH ON CAVE CREEK ROAD 1.2 MILES TO 34.139591 -111.84675 ROUNDTREE SPRINGS. USE TOPO VRSYW000.77 Sycamore Cr- Nutrient Full Suite SEM Q4 SEM Contractor near wilderness boundary 34.869056 -112.069083 NA VRVER108.49 Verde R blw Nutrient Full Suite SEM Q4 SEM Contractor Squaw peak cyn, us of West Clear Cr confluence 34.515556 -111.838611 NA

Page 44 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access VRVER127.02 Verde R at Nutrient Full Suite SEM Q4 SEM Contractor FROM CAMP VERDE: AT EXIT 1000 trails FROM I-17, TAKE 279 NORTH TO Mobile home FS 147. TURN EAST OFF STATE park ROUTE 279 ONTO THE ROAD TO THOUSAND TRAILS TRAILER PARK. THERE IS A ROAD JUST NORTH OF THE RV PARKING AREA THAT ALLOWS YOU TO DRIVE DOWN TO A FENCED AREA THAT HAS AN 34.675232 -111.939479 ACCE VRVER136.93 Verde R at Nutrient Full Suite SEM Q4 SEM Contractor Riverfront park 34.751132 -112.016268 NA VRVER185.21 Verde R at Nutrient Full Suite SEM Q4 SEM Contractor FROM PRESCOTT: GO NORTH ON Inscription HWY89 THRU PAULDEN, WHICH IS point 13MI PAST WATSON LAKE. TURN RIGHT ON FR354 FOR 4-5MI,THEN TURN LEFT ONTO FR638 FOR 2MI, THEN BEAR RIGHT AND IMMED LEFT ONTO FR635 TOWARDS VERDE RANCH. TURN LEFT BEFORE RANCH AND DRIVE TO 34.867489 -112.401836 RIVER ABV P VRWBV006.50 Wet Beaver Cr Nutrient Full Suite SEM Q4 SEM Contractor at Montezuma Well 34.648333 -111.751111 NA

Page 45 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access VRWBV009.31 Wet Beaver Cr Nutrient Full Suite SEM Q4 SEM Contractor FROM CAMP VERDE: DRIVE at NORTH ON FS RD 646 TO Campgrounds MONTEZUMA CASTLE NATIONAL MONUMENT (PORTION NEAREST CAMP VERDE). PARK IN PARKING AREA ACROSS FROM ENTRANCE TO BEAVER CREEK CAMPGROUND, ON SOUTHWEST SIDE OF FS RD 618. PARK IN PARKING AREA 34.667383 -111.716122 ACROSS FROM ENTRANC VRWBV012.56 Wet Beaver Cr Nutrient/R Full Suite SEM Q4 SEM Contractor FROM PHOENIX, DRIVE NORTH ON eference I-17 TO EXIT 298 (PAST CAMP VERDE). DRIVE EAST AND TAKE SECOND RIGHT NEAR THE WET BEAVER WILDERNESS RANGER STATION. DRIVE INTO DIRT PARKING LOT. FOLLOW TRAIL TO USGS GAGE. RULE OF THUMB: IF 34.673921 -111.670166 TRAIL FORKS STAY ON RIGHT (FYI VRWCL005.10 West Clear Cr Nutrient Full Suite SEM Q4 SEM Contractor FROM CAMP VERDE: DRIVE EAST at Campground ON FH9 (ROAD TO STRAWBERRY/PAYSON). DRIVE TO JUST BEFORE ROAD CROSSES WEST CLEAR CREEK. TURN LEFT INTO CLEAR CREEK CAMPGROUND. SAMPLE JUST UPSTREAM OF THE 34.514176 -111.756645 CAMPGROUND.

Page 46 of 56 FY19 Sampling and Analysis Plan for Water Quality Streams

SITEID Site Name Lat Long Site Type Parameter set Frequency Lead Site Access VRWCL036.37 West Clear Cr Nutrient/R Full Suite SEM Q4 SEM Contractor FROM PAYSON: TAKE HWY 87 (upper) eference NORTH OF PAYSON, PAST STRAWBERRY/PINE TO CLINT?S WELL. TURN LEFT ONTO FH3 AND DRIVE NORTH 7MI. TURN LEFT ON FR81 (NOTE WCC TRAILHEAD SIGN). DRIVE SW ON FR81, IT TURNS INTO FR81E. BEAR RIGHT AT ?MAXWELL TRAIL? FAINT 34.553139 -111.407528 SIGNPOST AT 7.

Page 47 of 56 FY19 Sampling and Analysis Plan for Water Quality Lakes

APPENDIX B LAKE PARAMETERS & SITES

B.1 Lake Target Analytes All monitoring sites are sampled for a basic group of target analytes to assess whether surface water quality standards are being met. The basic group represents information that is typically gathered by most ambient water quality monitoring programs. The basic group includes general water chemistry, nutrients, total and dissolved metals, and bacteria (See TABLES 1, 2 & 3). Analytes in the basic group provides investigators with a basic understanding of the general chemistry of the surface water. Standardization of a basic suite of target analytes also provides consistency of information across surface waters. Additional parameters (e.g., total and free chlorine for effluent dependent water) may be added to the basic group if warranted by site-specific conditions.

A suite of field measurements are taken in addition to the basic chemical group at all sites. Field measurements such as dissolved oxygen, percent saturation dissolved oxygen, water temperature, and can only be measured in the field and are important for understanding the physical properties of the water body. Other measurements, such as pH, specific conductance, and turbidity are taken in the field because of their nature to be altered during sample transport to the laboratory.

Table B1. Field Parameters Parameter Equipment Range Accuracy Response Resolution Depth Xylem EXO2 Deep: 0-820 ft, 250 m +/-0.04% FS (+/-0.10m or +/-0.33 ft) T63<30 sec 0.001 ft, 0.001 m Medium: 0-328 ft, 100 m +/-0.04 % FS(+/10.04 m or +/-0.13 ft) T63<30 sec Shallow: 0-33 ft, 10 m +/-0.04 % FS(+/10.04 m or +/-0.13 ft) T63<30 sec Specific Conductivity Xylem EXO2 0-200 mS/cm 0-100: ± 0.5% of reading or 0.001; T63<30 sec 0.0001 to 0.01 mS/cm 100-200: ±1% of reading pH Xylem EXO2 0-14 Units ± 0.1 units within +/-10oC of T63<3 sec8 0.01 units calibration temp; +/-0.2 pH units for entire temp range Air Temperature SupCo ST09 -40 to 392 º F ± 0.10 º F 0.01 º F Water Temperature Xylem EXO2 -5 to 35 º C; 35 to 50 º C ± 0.01 º C2; ±0.05C2 T63<1 sec 0.001 º C Dissolved Oxygen Xylem EXO2 0-50 mg/L ± 0.1 mg/L for 20 mg/L or less; T63<5 sec5 0.01 mg/L (optical) ± 5% of reading for 20 to 50 mg/L T63<5 sec5

Dissolved Oxygen % sat Xylem EXO2 0-500% air saturation 0 to 200%: +/-1% of reading or 1% T63<5 sec5 0.10% air saturation whichever is greater;200-500%:+/-5% of reading TDS Xylem EXO2 Calculated from SpC Not specified Variable

ORP Xylem EXO2 -999 to +999 mV +/-20 mV in Redox standard solution 0.1 mV

Secchi Secchi Disk 0.1-100 m +/-0.05 m 0.05 m Turbidity Hach 2100P 0 – 1000 NTU ± 2% of reading from 0-500 NTU 0.01 NTU Turbidity Meter ± 3% of reading between 500-1000 NTU

Page 48 of 56 FY19 Sampling and Analysis Plan for Water Quality Lakes

Parameter Equipment Range Accuracy Response Resolution fDOM Xylem EXO2 0 to 300 ppb quinine sulfate equiv Linearity: R2>0.999 for serial dilution T63<2 sec 0.01 ppb QSU (QSU) o 300 ppb QS solution Chlorophyll Xylem EXO2 0 to 400 ug/L Chl; 0 to 100 Linearity: R2>0.999 for serial dilution T63<2 sec 0.01 ug/L Chl;0.01 RFU rhodamine fluouresent units (RFU) of Rhodamine WT solution Blue-green algae, Xylem EXO2 0 to 100 ug/L; 0-100 RFU Linearity: R2>0.999 for serial dilution T63<2 sec 0.01 ug/L; 0.01 RFU phycocyanin of Rhodamine WT solution from 0 to 100 ug/ml BGA-PC equiv

Table B2. Sample Containers and Preservation Analysis Type Bottle Preservation Inorganics 1 L Plastic None, Wet Ice Total Nutrients 500 mL Plastic H2SO4, Wet Ice Ortho-P 250 mL Plastic Wet Ice Dissolved Metals 500 mL Plastic Filter, HN03, Wet Ice Total Metals 500 mL Plastic HN03, Wet Ice Chlorophyll A Dark Plastic 1L Wet Ice TOC/DOC Amber Glass 250 or 500 mL H2SO4, Wet Ice Algae ID 250 mL Plastic Lugols, Wet Ice Zooplankton 250 mL Plastic ETOH, Wet Ice Microcystin 250 mL Plastic Wet Ice or Cool Pack E. Coli 100 mL Plastic None

Table B3 New. Use after 9/1.- Holding Times, Reporting Limits and Analytical Methods for Lakes (Updated on 9/25/17 LWJ) MRL Holding Lab Chemical Analysis Type Method MRL Unit Bottle Time E. Coli NA Colilert 1 CFU/100 E. Coli 6 Hours ADEQ mL ALUMINUM DISSOLVED EPA 200.7 0.1 mg/L Dissolved Metals 6 MONTHS TAX ALUMINUM TOTAL EPA 200.7 0.1 mg/L Total Metals 6 MONTHS TAX BORON (BORON AND BORATES ONLY) DISSOLVED EPA 200.7 0.05 mg/L Dissolved Metals 6 MONTHS TAX BORON (BORON AND BORATES ONLY) TOTAL EPA 200.7 0.05 mg/L Total Metals 6 MONTHS TAX CALCIUM DISSOLVED EPA 200.7 2 mg/L Dissolved Metals 6 MONTHS TAX CALCIUM TOTAL EPA 200.7 2 mg/L Total Metals 6 MONTHS TAX IRON DISSOLVED EPA 200.7 0.1 mg/L Dissolved Metals 6 MONTHS TAX IRON TOTAL EPA 200.7 0.1 mg/L Total Metals 6 MONTHS TAX MAGNESIUM DISSOLVED EPA 200.7 2 mg/L Dissolved Metals 6 MONTHS TAX MAGNESIUM TOTAL EPA 200.7 2 mg/L Total Metals 6 MONTHS TAX POTASSIUM DISSOLVED EPA 200.7 0.5 mg/L Dissolved Metals 6 MONTHS TAX

Page 49 of 56 FY19 Sampling and Analysis Plan for Water Quality Lakes

MRL Holding Lab Chemical Analysis Type Method MRL Unit Bottle Time POTASSIUM TOTAL EPA 200.7 0.5 mg/L Total Metals 6 MONTHS TAX SODIUM DISSOLVED EPA 200.7 0.5 mg/L Dissolved Metals 6 MONTHS TAX SODIUM TOTAL EPA 200.7 0.5 mg/L Total Metals 6 MONTHS TAX STRONTIUM DISSOLVED EPA 200.7 0.1 mg/L Dissolved Metals 6 MONTHS TAX ANTIMONY DISSOLVED EPA 200.8 0.001 mg/L Dissolved Metals 6 MONTHS TAX ANTIMONY TOTAL EPA 200.8 0.001 mg/L Total Metals 6 MONTHS TAX ARSENIC, INORGANIC DISSOLVED EPA 200.8 0.001 mg/L Dissolved Metals 6 MONTHS TAX ARSENIC, INORGANIC TOTAL EPA 200.8 0.001 mg/L Total Metals 6 MONTHS TAX BARIUM DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 5 BARIUM TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 5 BERYLLIUM AND COMPOUNDS DISSOLVED EPA 200.8 0.001 mg/L Dissolved Metals 6 MONTHS TAX BERYLLIUM AND COMPOUNDS TOTAL EPA 200.8 0.001 mg/L Total Metals 6 MONTHS TAX CADMIUM DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 1 CADMIUM TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 1 CHROMIUM DISSOLVED EPA 200.8 0.001 mg/L Dissolved Metals 6 MONTHS TAX CHROMIUM TOTAL EPA 200.8 0.001 mg/L Total Metals 6 MONTHS TAX COBALT DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 5 COBALT TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 5 COPPER DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 5 COPPER TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 5 LEAD AND COMPOUNDS (INORGANIC) DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 5 LEAD AND COMPOUNDS (INORGANIC) TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 5 MANGANESE DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 5 MANGANESE TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 5 MOLYBDENUM DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 5 Page 50 of 56 FY19 Sampling and Analysis Plan for Water Quality Lakes

MRL Holding Lab Chemical Analysis Type Method MRL Unit Bottle Time MOLYBDENUM TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 5 NICKEL DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 5 NICKEL TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 5 SELENIUM AND COMPOUNDS DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 5 SELENIUM AND COMPOUNDS TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 5 SILVER DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 1 SILVER TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 1 THALLIUM DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 1 THALLIUM TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 1 URANIUM (CONTENT) TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 1 VANADIUM DISSOLVED EPA 200.8 0.000 mg/L Dissolved Metals 6 MONTHS TAX 1 VANADIUM TOTAL EPA 200.8 0.000 mg/L Total Metals 6 MONTHS TAX 1 ZINC DISSOLVED EPA 200.8 0.012 mg/L Dissolved Metals 6 MONTHS TAX 5 ZINC TOTAL EPA 200.8 0.012 mg/L Total Metals 6 MONTHS TAX 5 MERCURY DISSOLVED EPA 245.1 0.2 UG/L Dissolved Metals 6 MONTHS TAX MERCURY, ELEMENTAL TOTAL EPA 245.1 0.2 UG/L Total Metals 28 DAYS TAX CHLORIDE TOTAL EPA 300.0 2 MG/L Inorganics 28 DAYS TAX FLUORIDE TOTAL EPA 300.0 0.4 MG/L Inorganics 28 DAYS TAX SULFATE TOTAL EPA 300.0 2 MG/L Inorganics 28 DAYS TAX Chlorophyll/pheophytin/phycocyanin TOTAL EPA 445 0.1 UG/L Chlorophyll 48 HOURS Walker Zooplankton ID TOTAL Microscopy 1 Unit/ML Zooplankton 14 DAYS (P) Walker Microcystin TOTAL Polyclonal ELISA Ng/mL Microcystin NA Walker (ADDA-specific) 0.1 Algae ID TOTAL Sedgewick-Rafter Slide 1 Unit/ML Algae ID 14 DAYS (P) Walker

Page 51 of 56 FY19 Sampling and Analysis Plan for Water Quality Lakes

MRL Holding Lab Chemical Analysis Type Method MRL Unit Bottle Time Chlorophyll a TOTAL SM 10020H 0.1 UG/L Chlorophyll 48 HOURS Walker Pheophytin a TOTAL SM 10020H 0.1 UG/L Chlorophyll 48 HOURS Walker ALKALINITY, PHENOLPHTHALEIN TOTAL SM 2320B 6 MG/L Inorganics 14 DAYS TAX CALCIUM CARBONATE (Total Alk) TOTAL SM 2320B 6 MG/L Inorganics 14 DAYS TAX CARBONATE TOTAL SM 2320B 6 MG/L Inorganics 14 DAYS TAX HYDROGEN CARBONATE TOTAL SM 2320B 5 MG/L Inorganics 14 DAYS TAX HARDNESS (CACO3 + MGCO3) - TAX DISSOLVED CALCULATED SM 2340B 13 MG/L Inorganics 6 MONTHS HARDNESS (CACO3 + MGCO3) – TOTAL CALCULATED SM 2340B 13 MG/L Inorganics 6 MONTHS TAX UMHOS/C TAX SPECIFIC CONDUCTIVITY STANDARD SM 2510B 2 M Inorganics FIELD TOTAL DISSOLVED SOLIDS DISSOLVED SM 2540C 20 MG/L Inorganics 7 DAYS TAX TOTAL SUSPENDED SOLIDS DISSOLVED SM 2540D 10 MG/L Inorganics 7 DAYS TAX SM 3500Fe-D/ EPA TAX IRON DISSOLVED 200.7 100 UG/L Dissolved Metals 6 MONTHS 15 TAX PH TOTAL SM 4500-H+ 1.68 SU Inorganics MINUTES KJELDAHL NITROGEN TOTAL SM 4500-NH3 D or E 0.5 MG/L Nutrients 28 DAYS TAX SM 4500-NH3 D, E, TAX AMMONIA AS NITROGEN TOTAL BG 0.05 MG/L Nutrients 28 DAYS NITRATE + NITRITE TOTAL SM 4500-NO3 E 0.1 MG/L Nutrients 28 DAYS TAX Dissolved Organic Carbon DISSOLVED SM 5310 C 0.5 MG/L TOC/DOC 28 DAYS (P) TAX Total Organic Carbon TOTAL SM 5310 C 0.5 MG/L TOC/DOC 28 DAYS (P) TAX PHOSPHORUS TOTAL SM18 4500-P-E 0.1 MG/L Nutrients 28 DAYS TAX

Table B4. Site List and Schedule

B.2.1 Lake Sample Plan - INTERNAL Frequency1,2 WBID SITEID Site Name Lat Long Site Type Parameter set ,3,4 Crew_chief Site Access AZL1502001 LCASH-A Ashurst 35.013611 -111.40444 Data Gap Full suite1,2,3 4 Quarters STF/LWJ . 5-1924 Lake AZL1506020 VRWHH-A White Horse 35.1175 -112.013333 Data Gap Full suite1,2,3 4 Quarters STF/LWJ 2-1630 Lake AZL1502001 LCBLC-A Black 34.331083 Existing Full suite1,2,3 1 quarter STF/LWJ From Phoenix, I-10 East To Loop 202 East, 0-0180 Canyon 33 -110.6984722 Impaired Hwy 87 North To Hwy 260 East Of Forest Lake Lakes, South On F.S Rd. 300.

Page 52 of 56 FY19 Sampling and Analysis Plan for Water Quality Lakes

Frequency1,2 WBID SITEID Site Name Lat Long Site Type Parameter set ,3,4 Crew_chief Site Access AZL1503010 CLHAV-A Lake 34.297778 -114.138889 High Full 4 Quarters STF/LWJ Fron Phoenix, North on I -17 to Carefree Hwy 1-0590 CLHAV-215.1 Havasu 34.512365 -114.3780966 Recreation Suite1,2,3,4 (AZ 74), West to Hwy 60, North to CLHAV-207.7 34.436397 -114.321143 Wickenburg, East to AZ 72, East To 95 North Thru Parker to Lake Havasu City. AZL1505030 SCPAT-A Patagonia 31.492222 110.869444 High Full suite1,2,3 4 Quarters STF/LWJ FROM TUCSON, TRAVEL EAST ON 1-1050 SCPAT-B Lake 31.498611 110.848056 Recreation INTERSTATE 10 TO STATE ROUTE 83 (EXIT 281) AND TURN SOUTH 50 MILES THROUGH SONOITA TO PARKER CANYON LAKE AZL1502001 LCMAU-A Upper Lake 35.080556 -111.534444 New Full suite1,2,3 4 Quarters STF/LWJ South of Flagstaff on lake Mary Rd. about 20 5-0900 Mary Impaired miles. AZL1505030 SCPEN-A Pena Blanca 31.408611 -111.085278 New Full suite1,2,3 4 Quarters STF/LWJ From Nogales: I-19 Norht to Hwy 289 to lake. 1-1070 SCPEN-B Lake 31.405278 -111.086667 Impaired SCPEN-C 31.400556 -111.0875

1 All coordinates are in datum NAD83. 2 Full suite = All parameters listed in Table 3 except Microsistyn and Zoo Plankton ID counts. If algal bloom present use microcystin test strips. If test strips indicate toxin present above 4 ug/L for microcystin then collect sample and notify Jason Jones and Catherine Gullo. 3 Zoo Plankton at Dam Site or Single Site Lake. 4 Lake Havasu : Microcystin and Zoo-P ID/counts at 3 sites each sampling event.

B.2.2 Lake Sample Plan - CONTRACTED

Long

WBID SITEID Site Name Lat Site Type Parameter set Frequency Crew_chief Site Access AZL1501000 SCARI-A Arivaca Lake 31.532778 -111.40444 Data Gap Full Q2, Q3, Q4 sample events Contractor From Tucson: South I-19 to 4-0480 suite1,2,3 West Arivaca Rd. to lake.

AZL1501000 CGKAI-A Kaibab Lake 35.284444 -112.127222 Data Gap Full Q2, Q3, Q4 sample events Contractor I-40 to Hwy 47 to F.S. Rd. 47 to 4-0710 suite1,2,3 lake.

AZL1502000 LCBRR-A Blue Ridge 34.553665 -111.185483 Data Gap Full Q2, Q3, Q4 sample events Contractor From Payson: Hwy 87 to F.S. 8-0200 Reservoir suite1,2,3 Rd. 715 to lake.

Page 53 of 56 FY19 Sampling and Analysis Plan for Water Quality Lakes

Long

WBID SITEID Site Name Lat Site Type Parameter set Frequency Crew_chief Site Access AZL1506010 MGTTL-B Tempe Town 33.433083 -111.919167 Data Gap Full Q2, Q3, Q4 sample events Contractor In Tempe, Scottsdale Rd. and 6B-1588 Lake suite1,2,3 Loop 202.

AZL1506010 MGALV- Alvord Park 33.99996 -112.137222 New Full Q2, Q3, Q4 sample events Contractor 35th Ave South of Base Line 6B-0050 EAST Lake Impaired suite1,2,3 as needed to determine Rd. Phoenix impairment status AZL1506010 MGCHA-A Chaparral Park 33.511389 -111.907778 New Full Q2, Q3, Q4 sample events Contractor North Hayden Rd. and East 6B-0300 Lake Impaired suite1,2,3 as needed to determine Chaparral Rd. impairment status

AZL1506020 VRPEC-A Pecks Lake 34.780833 -112.03306 New Full Q2, Q3, Q4 sample events Contractor Sample if permission from 2-1060 Impaired suite1,2,3 as needed to determine Freeport impairment status 1 All coordinates are in datum NAD83. 2 Full suite = All parameters listed in Table 3 except Microsistyn and Zoo Plankton ID counts. If algal bloom present use microcystin test strips. If test strips indicate toxin present above 4 ug/L for microcystin then collect sample and notify Jason Jones and Catherine Gullo. 3 Zoo Plankton at Dam Site or Single Site Lake. 4 Lake Havasu : Microcystin, and Zoo-P ID/counts at 3 sites each sampling event.

Page 54 of 56 FY19 Sampling and Analysis Plan for Water Quality Fish APPENDIX C - FISH PARAMETERS & SITES

C.1 Fish Target Analytes

Table C2. Sample Containers and Preservation Analysis Type Bottle Preservation Fish Tissue Fish Bottle Dry Ice/Frozen

Table C3. Test America - Holding Times, Reporting Limits and Analytical Methods for Fish Chemical Analysis Type Method MRL MRL Unit Bottle Holding Time MERCURY, ELEMENTAL TOTAL EPA 7473 0.05 UG/L Fish Bottle 6 MONTHS 40 Days Polychlorinated Biphenols (Aroclors) Total 8082 25 Ug/kg Fish Bottle (recommended) Selenium Total 6020A 0.25 mg/Kg Fish Bottle 6 Months

C4 FISH SAMPLE PLAN - INTERNAL WBID SITEID Site Name Lat/long Site Type Parameter set Frequency Crew_chief Site Access AZL15010004- Dogtown Res. Fish Probability study Hg, Se, PCBs 1 fish tissue composite SMR 0480 AZL15020001- Roper Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite SMR 1550 AZL15030101- Topock Marsh Fish Probability study Hg, Se, PCBs 1 fish tissue composite SMR 1530 AZL15030107- Mittry Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite SMR 0950 AZL15040004- Luna Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite SMR 0840 AZL15040006- Dankworth Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite SMR 0440 AZL15050301- Kennedy Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite SMR 0720 AZL15050301- Parker Canyon Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite SMR 1040 AZL15060203- Horseshoe Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite SMR 0620 AZL15070102- Lake Pleasant Fish Probability study Hg, Se, PCBs 1 fish tissue composite SMR 1100

Page 55 of 56 FY19 Sampling and Analysis Plan for Water Quality Fish C5. FISH SAMPLE PLAN - CONTRACTED WBID SITEID Site Name Lat/long Site Type Parameter set Frequency Crew_chief Site Access AZL15010004- Santa Fe Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15010004- 1340 1340 AZL15020001- Tunnel Reservoir Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15020001- 1550 1550 AZL15020005- Rainbow Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15020005- 1170 1170 AZL15020005- Woodland Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15020005- 1690 1690 AZL15020008- Blue Ridge Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15020008- 0200 Res/Cragin 0200 Reservoir AZL15040005- Cluff Ranch Ponds Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15040005- 0350 0350 AZL15050301- Silverbell Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15050301- 0396 0396 AZL15050302- Alvord Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15050302- 0760 0760 AZL15050302- Lakeside Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15050302- 0760 0760 AZL15060103- Papago Ponds Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15060103- 1030 1030 AZL15060106B- Riverview Lake Fish Probability study Hg, Se, PCBs 1 fish tissue composite Contractor AZL15060106B- 1225 1225

Table C4. Site List and Schedule (Updated on 4/25/16). 1 All coordinates are in datum NAD83. 2 Q1 between July 1 – Sept 30 (Summer) Q2 between Oct 1 – Dec 31 (Fall) Q3 between Jan 1 – Mar 30 (Winter) Q4 between Apr 1 – June 30 (Spring) 3 Collect at least this number of target species. 4 LMB = Large Mouth Bass; BG = Blue Gill; WE = Wall Eye; CC = Common Carp, SF = Sun Fish; Flathead = Flathead Catfish

Page 56 of 56

EXHIBIT C- ADEQ AMBIENT STREAM MONITORING FY19 FIELD FORM

1.1 CHEMISTRY SITE INFORMATION Trip # ______- _ _ -_ _ _ _ Sample # ______Site Code ______. _ _ Date _ _ / _ _ / _ _ _ _ Sample Time Site Name Field Crew

1.2 FIELD DATA

E. coli CFU TDS (meters give g/L) mg/L Air Temp. °C Sp Cond. S/cm Water Temp. °C pH SU D.O. mg/L Turbidity NTU D.O. % % Site Photos Collected

1.3 FIELD CALIBRATIONS Barometric Pressure in mm Hg = ______Nominal stability % D.O. Post-cal. Reading = %______Stable Multiprobe name______Turbidity Standard = Standard solution reading = % Diff = % Diff = ((Standard Value – Measured Value)/Standard Value) * 100 Typically < 0.5 NTU for lowest standard Acceptable difference is 0-10%. Rerun if between 5-10%. Do not enter turbidity into WQDB if % difference is greater than 10%.

1.4 SAMPLE COLLECTION INFORMATION Grab Equal Width Increment (EWI) Modified EWI Equal Discharge Increment Circle where grab sample LEW----- ¾ ----- ½ ----- ¼ -----REW Run , Riffle, , Pool taken

1.5 QUALITY CONTROL SAMPLE INFORMATION Type of QC Sample (ie blank, dup, Your Identifying Code Lab Tracking Number etc)

1.6 QC POST-CHECK (PH AND CONDUCTIVITY) Post check completed; data accurate Post check completed; QC failed for ______parameter(s). Flag data with event codes:

Equipment problems assoc with visit & QA-R Rejected data due to QAQC problems in AZWQDB

Form Checked by Page 1 of 5 ADEQ – AMBIENT STREAM MONITORING FIELD FORM REVISED JULY 2018 1.7 SITE OBSERVATIONS (CHECK ALL THAT APPLY UNLESS INDICATED OTHERWISE) General appearance in the No refuse visible ; Small refuse visible ; Small volume refuse channel common ; Large volume refuse (tires, carts) rare ; Large volume refuse common . General appearance along the No refuse visible ; Small refuse visible ; Small volume refuse banks common ; Large volume refuse (tires, carts) rare ; Large volume refuse common . Water Clarity Clear ; Milky ; Light brown ; Dark brown , Oily sheen ; Greenish ; Other______Water odor None ; Sewage ; Chlorine ; Fishy ; Rotten eggs ; Other______Appearance at water’s edge No evidence of salt crusts ; White crusty deposits rare ; Numerous (check one) white crusty deposits ; Banks covered with white crusty deposits . Fish presence (check one) Absent ; Rare ; Common . Crayfish presence Absent ; Rare ; Common . Sunfish presence Absent ; Rare ; Common . Bull frog presence Not Observed ; Observed Leopard frog presence Not Observed ; Number observed alive ______; Dead______Floating leaves or other organic matter (not algae) (check all that Absent ; Rare ; Common . apply) Leaves or other organic matter Absent ; Rare ; Common . on streambed % Algae cover in the wetted width of the stream 10 meters above and below sample point % % Macrophytes cover in the wetted width of the stream 10 m above and below sample point %

1.8 E. COLI Collection Time Incubation Time Enumeration Time Coliliert 18 (incubation time = 18 to 22 hours) Reagent Used? Colilert (incubation time = 24 to 28 hours) Flag (Incubation/Holding Time Exceeded?) Holding time is 6 hours from collection. Incubation Period is 18 hours for Colilert technique COLILERT RESULTS Regular/ Duplicate/ Number Large Wells Number Small Wells Most Probable Blank Positive Positive Number (from Table)

Form Checked by Page 2 of 5 ADEQ – AMBIENT STREAM MONITORING FIELD FORM REVISED JULY 2018 1.9 EVENTS THIS TABLE INCLUDES FIELD RELATED EVENT CODES YOU WILL ENTER INTO THE WQDB. CHECK THE BOX NEXT TO ALL APPLICABLE EVENTS. USE THE EVENT FLAGS (F1, F2, ETC.) IF YOU WANT TO INCLUDE A COMMENT FOR A PARTICULAR ITEM THAT YOU CIRCLED. INCLUDE FLAG COMMENTS IN SPACE PROVIDED BELOW. IT IS VERY IMPORTANT THAT RECENT OR CURRENT FLOODING BE FLAGGED.

* = FILL OUT EVERY TIME. YOU MUST FLAG AND EXPLAIN IF THESE ARE NOT CHECKED. Check Description Flag * Baseflow Conditions * General – Precipitation at sample time.

None ; Light ; Moderate ; Heavy ; Cloud Cover (%) = * Weather – Significant rain during past 48 hours may affect results Flow – Low D.O. / high pH attributed to ponding or evaporation of stream Flow – Stream dry at time of visit Flow – Evidence of recent flooding. Fresh debris line in channel , Grasses Laid Over ; Fresh debris line in bushes/trees

; Recent flood event greater than baseflow but less than bankfull ; Riparian vegetation scoured away ; •Flood Width______meters. Flow – Flood event in progress at time of visit Low DO value attributed to groundwater upwelling Flow – Measurement from USGS gauge/records or 3rd party Low Flow (FQ1): Flow segments disconnected/spatially intermittent Low Flow (FQ2): Surface water present, but no/little visible flow Low Flow (FQ3): Standing water/pools/ponded water only Low Flow (FQ4): Flow only interstitial Flow- Regulated flow Flow- stream dry at time of visit Flood > Bankfull occurred recently or in the past season Fire (recent) in the watershed is affecting the study reach Nearby spring influencing samples Algal bloom Indication of toxic algae Abundant macrophytes Abundant waterfowl Fish kill observed Fish kill attributed to low DO, high pH or algal toxicity SOP – Deviation from standard operating procedures (indicate in ‘Field Notes’) Equipment problems associated with visit Incomplete sampling event – Missing parameter(s) or reports Limited sampling event – Selected parameters only QC Equipment blank associated with visit QA/QC or duplicate sample collected at time of visit Flag 1 Flag 2 Flag 3

Form Checked by Page 3 of 5 ADEQ – AMBIENT STREAM MONITORING FIELD FORM REVISED JULY 2018 1.10 FLOW MEASUREMENTS

Measurement from Run , Riffle, , Pool ; Comments:______Station Distance from Depth, ft Velocity, ft/s Comments Initial Point 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Attach separate sheet or the “Discharge” Excel spreadsheet to calculate discharge.

Form Checked by Page 4 of 5 ADEQ – AMBIENT STREAM MONITORING FIELD FORM REVISED JULY 2018 1.11 FLOAT METHOD DISCHARGE MEASUREMENT (COLLECT 3-5 TIMED VELOCITY MEASUREMENTS AND RECORD DISTANCE TO CALC VELOCITY (FT/S) Distance: Times: 1) 2) 3) 4) 5) = avg time Velocity (ft/s):

______Width, ft x ______Depth, ft x ______Velocity, ft/s x 0.85 corr.factor = cfs

1.12 FIELD NOTES INCLUDE: CURRENT FLOW CONDITIONS, WATER APPEARANCE, RECENT PRECIP, NON-POINT SOURCES AFFECTING THE REACH, BANK EROSION/EXCESS SEDIMENT IN CHANNEL, DEVIATIONS FROM SOP, SUCH AS HOLDING TIME EXCEEDED.

Form Checked by Page 5 of 5 Exhibit D - FY19 Site Verification Form

Instructions: The ‘Site Verification Form’ must be filled out for every visited site, which includes sites that could not be sampled. Samples should be taken from the latitude and longitude in the FY19 Sampling Plan. For data gap, reference and nutrient sites, the sampling point may be moved (dry or access issues) so long as the sample is taken in the same reach (same water body identification code) and the land use does not change. Do not slide impaired reaches without permission.

SiteID: Date: Site Name: Field crew:

Was the Sample Site Moved from the location indicated in the FY19 SAP?

No, Yes

If yes indicate why.

Latitude / Longitude of sample location (NAD 83 in Decimal Degrees).

General Comments:

Directions to Site (include driving directions, any restrictions/permissions, hiking directions):

Was the Stream Samplable? Check yes/no and check why. YES NO Wadeable, >50% wadeable Dry – visited Wadeable interrupted at original site – moved site to Wetland- no definable channel avoid dry segments Altered – stream channel present, but differs from map Impounded / >50% Not wadeable Spatially intermittent – alternating wet/dry segments (FQ1) Pools only – no flow between pools (FQ3) Access permission denied Interstitial flow- rivulets between cobbles at head or tail of pools (FQ4) Temporarily inaccessible – Fire, other reason Permanently inaccessible- unsafe Map error

Exhibit E – Ambient Water Quality Data QC Checklist for Contractors (see SOP Manual -Chapter 10 Data management for detailed instructions) SiteID: Date/Time sampled:

Trip/Dataset #s: Sample #: AB______

Manage Sites - Update site information:

 Elevation, drainage area, site access directions, current site type (ref, nonref, stressed) if known, biocriteria exemption (eg. intermittent or edw), GIS slope, Stream order, Flow Regime (P, I, E or Edw). Upload Sample/Result Data:

 Upload edi dataset for Test America test results Sample/Result Data Entry – Header tab:

 Fill in all Sample information fields possible; collection date & time must match labels on sample collection bottles.  Select correct “sample purpose” and “Sample type” to match the sample types collected  Crew chief must be filled out (Lead sampler on the trip)  Select appropriate Flow Condition in the “Sample Taken?” field (This is a requirement for Assessments)  Select collection equipment and Method (eg. Chem-01 is the standard one for water chemistry samples, ADEQ Riffle bugs for perennial stream bug samples)  Enter field notes under “notes” section  Enter “ADEQ” for Reporting agency, and your code for “collecting agency”

Sample/Result Data Entry – Field Chem tab:

 Enter all field data using ‘Stream-field measurements’ test plan  Double check field data entry records for 100% correct entry  For E.coli dups – Click Edit button for E.coli parameter, enter new result, place “DUP” in comments box, then “Save as New” to add a 2nd Ecoli value  To add “Event conditions” for weather, algae blooms, equipment problems, QC samples collected: add a parameter for each Event. Click New result, substance=Event condition, Protocol=water, Lookup result= parameter, then click save. Do not add an Event for flow conditions; this is captured on the Header Tab.

Sample/Result Data Entry – Lab Chem tab:

 Is Dataset complete? Must have every parameter listed in the current FY19 SAP  Spot check that uploaded lab values are correct & matching pdf lab report  Splits/Dups within Limits for water chemistry analytes (RPD<20% where results are >2x MRL)? (If not, Request rerun and/or Flag parameter for all samples on the run)  E.coli Dups are within limits (Confidence intervals overlap using IDEXX calculator)?  Field/Lab ratios calculated and qualifiers applied? (run “QA Flagging” procedure in “Schedule trips” page). Check that ADEQ qualifiers are correctly applied.  Lab qualifiers correctly applied? o Check that all flags in Lab report pdf copy are listed for test results in Lab Chem tab o Scan Lab Report –QC Sample Results for any dilutions or qualifiers that apply to your sample & ensure those data are applied to test results. o Reruns: follow WQDB Chapter 10 guidance for entering qualifier RR1, RR2, or RR3

Sample/Result Data Entry – Exceedances?

 Check for standard exceedances: Field pH, DO, E.coli & Lab metals, nutrients (if site-specific standard applies), and SSC (double check that database did not miss any exceedances and that identified exceedances are correct – see http://static.azdeq.gov/swq/Inorganic SWQ Exceedance Calc_IT.xls) List Here: ______ Notify ADEQ liaison of any Human health Standards exceedances (eg. for domestic water source, fish consumption or FBC/PBC designated uses & criteria)

Date Lab data uploaded

Due date for Approval in AZWQDB (+30 days)

Comments:

Exhibit F – Completed Sampling Event Checklist

Instructions: All items in the checklist must be completed for each sampled site. Review invoice and then check each item below to verify completion. Sign and give to business operations team. Site ID Sample Date Crew Chief Trip # Sample #

1. Field data from sample plan in WQDB 2. Lab data from sample plan in WQDB 3. Site locational data up to date in WQDB 4. Data approved in WQDB 5. Site tracking spreadsheet updated daily on Google Drive 6. Sample file packet sent which includes printed copies of a. Completed field forms (Ambient Stream Field Form) b. Labeled Photos (up and down stream) c. Completed Chain of Custody from each lab d. Completed discharge spreadsheet e. Site verification form f. Copies of calibration logs for equipment used to measure pH, dissolved oxygen, and conductivity g. “Water Quality Data QC Checklist” completed. Data credible and usable. ADEQ must be notified of any identified exceedances.

Sign here for indicate OK to Pay

______Water Quality Program Lead Date