British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) SURFACE WATER POLLUTION OF THE BY NEW HARBOR, DELTA, Rasha El Gohary1, Müfit Bahadir2 1Associate Professor, Central Laboratory for Environmental Quality Monitoring, National Water Research Center, NWRC, , Egypt. 2 Professor emeritus, Technische Universität Braunschweig, Institute of Environmental and Sustainable Chemistry, Hagenring 30, 38106 Braunschweig, Germany

ABSTRACT: The Damietta Harbor is situated near the eastern branch of the River Nile estuary, 250 km east of . Marine eutrophication is mainly an inshore problem that affects lagoons, harbors, estuaries and coastal areas adjacent to river mouths. Although the main body of the Mediterranean Sea as a whole is not yet seriously threatened by eutrophication, areas of pronounced eutrophication are expanding in the Mediterranean. The main objective of the study is to characterize water, soil and sediment that will be dredged to determine their suitability for placement in either upland, an offshore disposal site, or at an existing beach for re-nourishment, and to observe the effect of the harbor on surface water pollution of the Mediterranean Sea. The dredging operations in Damietta Port sediment, soil and water investigations were conducted to understand the possible disposal or re-use considerations. The following samples were investigated: • Offshore stations representing existing, proposed and reference stations, • Sediment cores within the port and approach channel, • Sediment grabs within the port and approach channel, and • Soil borings from terminal basin. Also, the water quality of different basins inside the harbor and in the marine waters at the mouth of the harbor was investigated. Water samples were analyzed for parameters indicating the chemical and biological quality of the harbor environment. In general, the water, soil, and sediment quality in the study area were within the permissible levels for physical-chemical parameters of marine water, although some metals were considerably higher than the background levels. In total, the off shore qualities were within the limits in all locations that are not hazardous to the Mediterranean Sea environment. KEYWORDS: Mediterranean Sea Pollution, Water Quality, Environmental Analysis, Dredging Damietta Harbor.

INTRODUCTION The state of the open waters in the Mediterranean Sea is considered to be generally good. In coastal areas, the presence of pollution hotspots, located in semi-enclosed bays, near important harbors, large cities and industrial areas, is probably the major problem. Waters in the open sea are classified among the poorest of the world in terms of nutrients. Marine ecosystem still seems to function well. Current threats such as localized eutrophication, heavy metals, organic and microbial pollution, oil spills, introducing non-indigenous species are mainly the results of pressures from anthropogenic activities. Hence, more attention to their management control is needed. Land-based activities such as urbanization, industry, and agriculture

20 ISSN 2054-6351 (print), ISSN 2054-636X (online) British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) represent the main source of pollution of the Mediterranean Sea. In case of urban and industrialized pollution, the main problem is the rapid population growth where only few legal and economic instruments are applied and inadequate environmental infrastructure investment still customary. Egypt's Mediterranean coastline occupies the south-eastern corner of the Mediterranean Basin. Along the Mediterranean coast of Egypt, there are eight coastal governorates. These are from west to east Matruh, Alexandria, Behaira, Kafr El-Sheikh, Damietta, Daqahliya, , and North Sinai. The maritime transport in the eastern Mediterranean, including oil tankers, commercial and passenger ships, affect the coast to a large extent. The entire beaches are frequently polluted by oil lumps, litter and plastic debris; even in remote areas of the coast, where there are no related activities. Table (1) summarizes and ranks the activities corresponding to the coastal governorates. Table (1): Summary and ranking of activities corresponding to the coastal governorates Tourism & Industry & Ports & Fisheries Agriculture Recreation Energy Constructions Matruh 1 3 1 2 3 Alexandria 1 1 1 2 2 Beheira 3 1 3 1 1 Kafr El 3 3 3 1 1 Sheikh Damietta 3 2 1 1 2 Dakahleya 2 3 2 1 1 Port Said 2 2 2 2 3 North Sinai 2 3 2 2 3 1: High 2: Moderate 3: Low

Table (2): Ranking of contaminants corresponding to the coastal governorates Liquid Solid Air H. Metals , Nutrients & wastes Wastes Pollution Org. Eutrophication Pollution Matruh 3 2 3 3 3 Alexandria 1 1 1 1 1 Beheira 1 2 1 1 1 Kafr El 2 1 2 2 2 Sheikh Damietta 2 2 2 2 1 Dakahleya 2 2 1 1 1 Port Said 2 2 2 2 2 North 3 3 3 3 3 Sinai 1: High 2: Moderate 3: Low

21 ISSN 2054-6351 (print), ISSN 2054-636X (online) British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) Therefore, it is important to monitor the impacts of ports as they are important sources of pollution of the Mediterranean Sea. The study area is Damietta Harbor that was constructed in 1982 and is located about 9.7 km west of the Damietta Nile. The harbor basin was dredged inland and is located in the on a narrow strip of land between the Nile and Lake Manzala. It is 210 km northeast of Cairo and 15 km from the Mediterranean with geographical coordinates as Latitude: 31°26' N and Longitude: 31°48' E. The Governorate is bounded by the Mediterranean to the north, by the Manzala Lake to the east and by the Daqahlia Governorate to south and west. Dredging in port areas is usually necessary for nautical reasons (“maintenance dredging”). This kind of dredging is a given fact for port authorities, usually public bodies organizing and funding the dredging activity. The question concerning here is whether this sediment will have an impact on the sea pollution in the future because of European legislation in the field of water quality management, sustainable use of the seas and oceans (1), nature conservation (2), and other relevant regulations (3), thus for environmental purposes (also called clean up dredging). As this concerns sediment of poor or bad quality, the economic impact of it can be considerably. Dredged sediment, which cannot be dumped into the sea or surface water, is a waste and thus should be treated in compliance with the Waste Directive. Therefore, the objective of the study was to characterize water, soil and sediment that will be dredged in future in order to determine their suitability for placement in either upland, an offshore disposal site, or at an existing beach for re-nourishment.

MATERIALS AND METHODS Sampling Strategy and Locations According to the planned dredging operations in Damietta Port, water, sediment and soil investigations were conducted in order to understand the possible disposal or re-use considerations. According to field sampling plan for Damietta port terminal project, the following samples were collected: • Sixteen offshore stations representing existing, proposed and reference stations, • Six sediment cores within the port and approach channel, • Ten sediment grabs within the port and approach channel, and • Three soil borings from the proposed terminal basin. In order to monitor the water quality of different basins inside the harbor and the marine waters at the mouth of the harbor four stations were selected representing the harbor properly, three stations were added to cover the open water just outside the harbors, and an additional station (station five) was selected at the basin situated in the internal canal, which joins the Damietta Branch of the Nile River to the harbor. In total, eight sampling stations were investigated in the course of this study. Water samples were analyzed for parameters indicating the chemical and biological quality of the harbor environment. The purpose of the offshore sampling stations was to study the existing and the proposed dumping sites relative to the surrounding reference stations. The purpose of the sediment cores

22 ISSN 2054-6351 (print), ISSN 2054-636X (online) British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) was to characterize the material down to the full project depth and to delineate any vertical changes in composition. The purpose of the grabs was to better define horizontal changes in surficial sediment composition and to provide large volume samples for toxicity and bioaccumulation bioassays. The sampling locations are provided in Figure 1 (Core Stations), Figure 2 (Grab Stations) and Figure 3 (Offshore Stations).

Figure (1) Core sampling locations inside Damietta Port

Figure (2) Grab sampling locations inside Damietta Port

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3505000 R-S4 R-S5

R-S3 R-S1 P-S1 P-S2 3500000 R-S7 P-S4 G10 P-S3 R-S2 R-S8 E-S2E-S1 R-S6 E-S4E-S3 3495000 G9

C6 3490000

G8

3485000

3480000 370000 375000 380000 385000 390000 395000 400000 405000 410000 Figure (3): Offshore water sampling location plus the rest of Core and Grab sampling location

All equipment designated to support the sampling activities at Damietta Port were pre-checked by the Field Task Leader and the Survey Task Leader during mobilization efforts. This inspection included handling system on-board, the sampling vessel that will be used to deploy/recover gravity core and grab sampler, all sampling equipment (including gravity core and grab sampler), and navigational system. Field Samples for Quality Control and Collection Frequency Data precision and accuracy evaluations were based on blank measurements of equipment rinsings, field and laboratory duplicates, and matrix spiking exercises. These quality control (QC) samples were collected at following frequencies: • One field duplicate for every 20 samples, • One matrix spike sample and matrix spike duplicate per 20 samples, and • One equipment rinsate blank for every 20 samples. The equipment rinsing blank were collected from the soil sampling equipment by rinsing field gear with deionized (DI) water after decontamination and before subsampling commences. The remaining QC samples were taken during the sample collection and homogenization processes performed in the laboratory and are described in the QAPP. At each station the following activities were made: recording of start and end of sampling time, the station number, and the sea conditions. Transparency of the water was measured by lowering a Secchi disc from the lighted side of the vessel and recording its reading. A 5-liter water sample was collected by lowering a Neskin bottle (5 L capacity) at -5 m to collect water samples. The temperature and pH were measured in situ using the multisensory Horiba. The DO was determined using Winkler technique.

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Figure (4): Lowering of CTD and plankton nets

The Grab sampler was used to collect sediment samples. Lowering sediment garbs were made twice and three times in order gain sufficient sample volumes. Redox Potential Discontinuity (RPD) layer was measured using plastic scale rule to scrap back surficial sediment and measuring the depth of visual transition. The sample jar for the acid volatile sulfide and simutaneoulsy extracted metals (AVS/SEM) sample was filled without an empty head space by sediments from the top 2 centimeters of the grab sample. The remaining sediments in the grab sampler were homogenized and collected using stainless utensils. Finally, plankton nets were lowered vertically and then towed horizontally at the lowest vessel speed to collect plankton samples. Plankton was collected using a net sampler. Net samples were taken by hauling a phytoplankton net 25 m, 25 cm in diameter and 1 m in length. A 1 liter of subsurface water for quantitative plankton assessment was collected. Zooplankton samples were collected using a net of blotting silk having 50 m and 45 cm mouth diameter. The net samples were preserved in 5% formalin for later investigation in the laboratory. Samples were kept on ice for later examination in the laboratory. All grab and water samples were placed in the ice boxes filled with crushed ice. Quality control samplings were collected at the end of sampling as follows: one field duplicate, one equipment rinsate blank and one matrix spike sample and matrix spike duplicate. Water samples were filtered during night using filtration system and pre-weighed membrane filter papers. Other sediment samples were placed in ice boxes, which were filled with newly bought crushed ice to keep the samples frozen. Sediment core samples were collected using a piston–gravity core (Fig. 5) to a penetration depth of -3 m in the port (C1 through C5) and in the approach channel (C6). Cores were cut in the field into six required depth intervals: 0 to - 0.25 m, -0.25 to -0.5 m, -0.5 to -1.0 m, -1.0 to -1.5 m, -1.5 to -2.0 m, and -2.0 to -3.0 m. The sediment core intervals were placed in ice boxes filled with ice till reaching the lab.

Figure (5): Gravity-Piston core sampler

25 ISSN 2054-6351 (print), ISSN 2054-636X (online) British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) Water Quality Analyses Water quality analyses were carried out after standard methods (ISO ,2006) in terms of (i) Hydrographic parameters (water temperature, salinity, dissolved oxygen, total suspended matter, and pH), (ii) Eutrophication parameters (nitrite, nitrate, dissolved inorganic phosphorus, total nitrogen, and total phosphorous), and (iii) Total Petroleum Hydrocarbons (TPH). RESULTS AND DISCUSSION Hydrographic Parameters of Damietta Harbor Water Temperature: The surface water temperature in Damietta Harbor (DH) during the study was in a very narrow range. Figure 6 shows the locations of sampling stations. The minimum surface water temperature was found at the station 6 (28.8 °C), representing the middle section of the harbor, while the maximum temperature was found at the station 5 (29.5 °C). Surface water temperatures averaged during the present work to 29.2 °C. Generally, in natural water bodies, water temperature is subject to great variation due to several factors, e.g., air temperature, latitude, sun altitude, season, wind, depth, confinement of the water body, waves, and gain or loss of heat, particularly in shallow water loss to land (La Fond, 1962). Temperature influences the rate of photosynthesis by aquatic plants due to the varying oxygen levels with varying temperature, the metabolic rates of aquatic organisms, and the sensitivity of organisms to toxic wastes, parasites and diseases. Figure 7 shows the spatial distribution of surface water temperature (°C) at different stations.

Station 7

Station 5

Station 6

Station 1

Station 8

Station 4 Station 2 Station 3

Figure 6: Locations of sampling stations

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Figure 7: Spatial distribution of surface water temperature (°C) at different stations

Salinity (S‰): The results of salinity measurements of surface waters of DH during the present work are presented in Figure 8. Likewise the temperature distribution, salinity results ranged in a very narrow range. Minimum salinity was recorded at the station 5 (37.2 ‰), while the maximum value was found at the station 7 (39.4 ‰). The average salinity value calculated during the present work attained 38.4 ‰, which also represents the salinity of the Mediterranean surface water. In fact, these apparently minor variations might be misleading, where minor variations in salinity indicate different density, different water masses, and water movements. Spatial distribution of salinity in DH clearly shows these water movements, where there is an obvious mixing of fresh water entering the harbor via the internal canal, indicated by the minimum salinity recorded at station 5. The isohaline contour map shows (likewise temperature distribution) the effect of this mixing at the station 4 at the mouth of the internal canal in the middle of the harbor; increased salinities were noticed extending from station 4 to all directions. Stations 1, 2 and 3 represent the marine environment just outside the harbor. These stations indicate the effect of the internal drain on the entrance of the harbor; the western station (1) beyond the left-hand jetty indicate the more saline Mediterranean water directed with the long shore current from the west, and mixing with the less saline water at the entrance of the harbor, in which the salinity decrease reached a minimum in the eastward direction (station 3). The southern part of the harbor (represented by the stations 6, 7 and 8) was characterized by higher salinities, again affected by stagnation and higher evaporation at the southern basins. The seawater salinity of the investigated area is affected by various factors, such as the discharge of drainage water, high accelerated evaporation during summer season, and the rain water during winter in the area.

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Figure 8: Spatial distribution of surface water salinity (‰) at different stations.

Hydrogen ion concentration (pH): During the present work, the pH ranged from a minimum of 8.47 at station 6 and a maximum of 8.75 at station 5. Although the pH range in marine waters is about 7.5 - 8.4, the pH values in the present work were slightly higher than the upper limit. This higher pH might be due to the high level of photosynthesis in the harbor. It was found that statistical positive correlation exists between pH and chlorophyll-a biomass (Aboul-Kassim, 1987), indicating that the pH of the environment could be used as a good indicator for its production level. Primary production does not result directly from an elevation of pH, but from a higher level of photosynthesis that increases the pH. PH influences many chemical and biological processes in water. For example, different organisms flourish at different pH ranges. The distribution of pH at different stations of the study area is shown in Figure 9. The pH values during the study varied between 8.05 and 8.16. These values of the existing stations might be related to the high organic load and TSS due to dumping of dredged material in the study area.

Figure 9: Spatial distribution of surface water pH at different stations.

28 ISSN 2054-6351 (print), ISSN 2054-636X (online) British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) The hydrographical parameters in the surface water of the Damietta Harbor are given in Table 3. Table 3: Hydrographical parameters in surface water of the Damietta Harbor

Station DO TSM Salinity pH Temp (°C) No. (mg/L) % (mg/L) (‰) Sat. 1 5.68 114 36 39.1 8.68 29.2 2 5.82 116 33.4 38.0 8.49 28.9 3 6.10 128 27 37.3 8.52 29.4 4 6.53 135 27.6 37.9 8.48 29.3 5 6.81 143 23.4 37.2 8.75 29.5 6 6.81 133 29.2 39.0 8.47 28.8 7 8.23 158 31.2 39.4 8.63 29.0 8 7.24 146 24.8 39.1 8.68 29.2 Minimum 5.68 114 23.4 37.2 8.47 28.8 Maximum 8.23 158 36 39.4 8.75 29.5 Average 6.65 134 29.1 38.4 8.59 29.2 DO: Dissolved Oxygen, % Sat.: Percentage of Oxygen Saturation, TSM: Total Suspended Matter Total Suspended Matter (TSM) concentrations during the present work averaged to 29.1 mg/L, ranging from 23.4 mg/L at station 5 to 36.0 mg/L at station 1.

Figure 10: Spatial distribution of total suspended matter (mg/L) in surface water at different stations

29 ISSN 2054-6351 (print), ISSN 2054-636X (online) British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) The Eutrophication Parameters of the Damietta Harbor Carbon, nitrogen and phosphorus are the most significant micronutrients studied in aquatic ecosystems. There, they are distributed between the water and sediment interface in both dissolved and particulate forms. Bio-available nutrients are taken up and metabolized by aquatic organisms in their life cycle (Murdoch et al., 1998). The bio-available species of nitrogen often occur in dissolved forms in sea water (nitrate, nitrite and ammonium). Accumulation of nutrients in water and sediment can result in eutrophication, which is often accompanied by the depletion of oxygen in water and the decrease of biodiversity in the affected water body (Vollenweider, 1968; Sutcliffe and Jones, 1992). Organic matter produced by phytoplankton in eutrophic shallow lakes settles to the sediment and decomposes by aerobic and anaerobic processes, during which different carbon, nitrogen and phosphorus compounds are produced (Jensen and Anderson, 1992).

- Nitrate (NO3 ): From the obtained data, it is obvious that the nitrate values in the surface water were low (ranging from 0.12 mg/L at station 7 to 15.03 mg/L at station 3). This might be attributed to the increase of nitrate uptake by the blooming phytoplankton developed in the area during the warm seasons (Zentara and Kamykowski, 1977). The average of nitrate concentration in surface waters during the present work attained 5.58 mg/L. It is obvious that areas suffering from high photosynthetic activities (the southern part of the harbor) are accompanied by low concentration of the bioavailable nutrient salts, and vice versa. According to the spatial distribution of nitrate, illustrated in Figure 11, the contour map indicated the presence of high concentration patch just outside the harbor; the concentration was decreased gradually in the southward direction, reaching a minimum at the south most zones of the harbor. The correlation analysis indicated a negative correlation of nitrate to DO, which also reflects the exhaustion of nitrate due to the high photosynthesis rate and thereby production of DO.

Figure 11: Spatial distribution of nitrate (mg/L) in surface water at different stations

- Nitrite (NO2 ): Very low nitrite concentrations were found during the study, ranging from a minimum of 0.045 mg/L at station 7 to a maximum of 1.23 mg/L at station 1. The average value was found to be 0.362 mg/L. However, it is customary to obtain such nitrite values in

30 ISSN 2054-6351 (print), ISSN 2054-636X (online) British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) the marine environment, since nitrite exists in a moderate oxidizing state, where it is converted to ammonium under reducing conditions, and into nitrate under oxidizing ones. Nitrite seems to be assimilated in a similar rate as nitrate (Figure 12) with a similar correlation with DO. Likewise nitrate distribution, the nitrite concentration decreased in the southward direction, reaching a minimum at the south most zones of the harbor. In addition to its negative correlation with DO, nitrite is directly correlated with nitrate and TSM concentrations.

Figure 12: Spatial distribution of nitrite (mg/L) in surface water at different stations.

Total Nitrogen (TN): The minimum TN contents of surface waters were detected at the station 5 (48.6 mg/L), while the maximum concentration was found at the station 1 (187 mg/L) with an average concentration of 89.7 mg/L. Although the concentration of dissolved inorganic nitrogen (nitrite and nitrate) during the present work constituted only a minor fraction of TN, these forms were found exerting an influence on the spatial distribution of TN. By reviewing the data, illustrated in Figure 13, the maximum concentrations of TN were always present in surface waters belonging to the stations located outside the harbor. This pattern was reflected by the previously discussed dissolved inorganic forms of N with high concentration patches in the same area. There was a decrease of TN as directing in the southward direction till the southern end of the harbor. According to the obtained results from the correlation analysis, TN was found in direct significant correlation with the nitrate concentrations, while a poor correlation was obtained with nitrite. Accordingly, nitrate might be always representing an almost fixed fraction of TN. Indeed, there was a similarity in the spatial distribution of TN and nitrate, represented by the presence of a high concentration patch on the northwest part of the contour map. The positive significant correlation of TN with TSM might suggest the dominance of the nitrogenous nature in the suspended particles.

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Figure 13: Spatial distribution of total nitrogen (mg/L) in surface water at different stations

Total Phosphorous (TP): Total phosphorous during the present work ranged from a minimum of 1.23 mg/L at the station 4 to a maximum of 11.8 mg/L at the station 7. The average concentration attained at 5.07 mg/l (Figure 14). These results might indicate that TP can be considered biologically inert.

Figure 14: Spatial distribution of total phosphorous (mg/L) at surface water at different stations High TP concentrations were recognized in the northwest part of the study area in open waters, and found decreases in both directions to the east and south, reaching a minimum at the center of the harbor. The concentration was found to increase again reaching a maximum in the south most basins of the harbor. TP was found in significant positive correlation for each of DO, salinity and pH, while a significant negative correlation with nitrate was established. Reactive Phosphorous (dissolved inorganic phosphorous, DIP): The natural abundance of nutrients is in the order of carbon > nitrogen > phosphorus. Due to this sequence, phosphorus

32 ISSN 2054-6351 (print), ISSN 2054-636X (online) British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) is often considered to be the limiting nutrient in the ecological cycle. In the marine environment, phosphorus is one of the nutrient elements and is essential for life. It is one of the most important factors controlling the growth and reproduction of phytoplankton (Riley and Chester, 1971). However, phosphorus causes eutrophication and might be considered as a potential pollutant, when it is present in high concentrations in seawater.

3- The biologically available form of phosphorous is orthophosphate (PO4 ), which can be considered the vital form of phosphorous that limits the flora in the marine environment. In the present work, very low concentration of DIP was detected, ranging from 0.02 mg/L at station 3 to 0.09 mg/L at station 1. The average concentration of DIP during the present work attained 0.052 mg/L (Figure15). This very low concentration indicates that phosphate is the limiting factor that controls the phytoplankton activity in the study area. Spatial distribution of DIP during the present work is shown in Figure 15. In this figure, the high concentration of DIP was dominant at the northwest part of the map representing the marine environment. These high values were found decreasing in the eastward and southward directions, reaching a minimum at the southern parts of the harbor.

Figure15: Spatial distribution of dissolved inorganic phosphate (mg/L) in surface water at different stations

Summary of the Water Quality at the Study Area Table 4 summarizes the data for the different bio-limiting factors and compares them with the permissible levels after Egyptian guidelines. It is obvious that the bio-limiting parameters are very low compared with the limit values therein. One can clearly recognize from this table that the water quality in the study area is within the permissible levels for the physical-chemical parameters of marine water.

33 ISSN 2054-6351 (print), ISSN 2054-636X (online) British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) Table 4: Summary of physical-chemical parameters for marine waters

Paramete DO TSM (mg/L) S‰ pH Temperature (ºC) r (mg/L) Damietta 5.68 – 23.4 – 36.0 37.2 – 39.4 8.47 – 8.75 28.8 – 29.5 Harbor 8.23 (29.1) (38.4) (8.59) (29.2) (6.65) EEAA1 4 mg/L 60 mg/L ----- 6 - 9 ø 5 ºC above the at all time mean annual Canada2 > 8.0 max increase 25 < 10% 7.0 – 8.7 Not to exceed ± 1 mg/L mg/L from Fluctuation and should not ºC background levels vary by more for any short-term than 0.2 from (>24 h); ;max the natural pH increases 5 mg/L expected at for long term (>1 that time to 130 d) World ------50 mg/L ------6 – 9 < 3 ºC increase Bank/IF C3 1. EEAA = Criteria and specifications for the parameters when discharged into marine environments. 2. Canadian Water Quality Guidelines for the Protection of Aquatic Life, 1999, updated 2001. 3. World Bank: Pollution Prevention and Abatement Handbook, World Bank Group, Effective July 1998.

CONCLUSIONS From the outcomes of the study it is concluded that in general the water, sediment, and soil quality in the study area were within the permissible levels for the physical-chemical parameters of marine waters. However, these values exceed the limits inside the harbor for some parameters especially through the dredging phase. The off-shore quality were within the limits in all location for the physical-chemical parameters of marine water, sediment, and soil that show New Demiatta harbor prevents the Mediterranean Sea from pollution especially during dredging. But, the Egyptian Law No. 4 from 1994 on the Environment does not include any provisions with respect to regional and cadastral planning that aimed to introduce sustainable development, to safeguard the environment and to prevent conflicts between different coastal zone applications. This should be taken into account while reviewing the environmental laws for an amendment. Recommendations The authors draw from this study the following measures to be taken in order to improve the harbor and coastal quality of the Damietta Port and neighborhood:

34 ISSN 2054-6351 (print), ISSN 2054-636X (online) British Journal of Environmental Sciences Vol.6, No.3, pp. 20- 37, October 2018 ___Published by European Centre for Research Training and Development UK (www.eajournals.org) 1. Some state actions are recommended in terms of environmental monitoring and developing a better National Land Use Plan in order to improve the water and habitat quality in the neighborhood of the Nile Harbors and the Mediterranean Sea. 2. Regularly monitoring the following parameters:

. Water quality in the basin and the open sea (DO, TSS, TP, Nitrate, BOD, and Chlorophyll) should be monitored monthly in order to check, if it is within the acceptable limits of the international standers. Monitoring and management plan should also keep records of significant environmental matters, including monitoring data, water quality, shoreline changes, accidents and occupational illnesses, spills, fires, and other emergencies should be documented. 3. Encouraging solid waste sorting and separation at the origin (glass, plastics, cardboard and paper, organic waste, and metals). 4. Reviewing, enforcing and implementing all legislation and regulations related to coastal activities and their control. 5. Providing financial and technical support to all relevant governmental agencies such as the Ministry of Tourism to facilitate compliance with the laws and regulations set by Egyptian Environmental Affairs Agency (EEAA).

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