Australasia 20 Cambridge Street, Epping NSW 2121 MATERIAL SAFETY DATA SHEET 486 Jackson Street Petone New Zealand

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER SUNSILK SHAMPOOS

Product Name/s: Variant/s Manufacturer’s Product Codes Sunsilk Shampoo Addictive Brilliant Shine 61061795 - 50mL 61062800 - 6x6x200mL 61062788 - 4x6x400mL 61062835 - 4x3x750mL Sunsilk Shampoo Damaged Hair Reconstruction 61062799 - 6x6x200mL 61062787 - 4x6x400mL 61062836 - 4x3x750mL Sunsilk Shampoo Frizz Defence 61062803 - 6x6x200mL 61062790 - 4x6x400mL Sunsilk Shampoo Longer and Stronger 61062802 - 6x6x200mL 61062790 - 4x6x400mL 20213024 - 4x3x750mL Sunsilk Shampoo Vibrant Colour Protection 61062798 - 6x6x200mL 61062786 - 4x6x400mL Sunsilk Shampoo Perfect Straight 61062801 - 6x6x200mL 61062789 - 4x6x400mL Sunsilk Shampoo Total Care 2 in 1 21111461 - 6x6x200mL 21111352 - 4x6x400mL Sunsilk Shampoo Detox for Men 61062807 - 6x6x200mL 61062794 - 4x6x400mL 21111348 - 4x3x750mL

Page 1 of 7 20 Cambridge Street, Epping NSW 2121 MATERIAL SAFETY DATA SHEET Australia 486 Jackson Street Petone New Zealand

Recommended Use: Cosmetic hair cleansing products. Supplier: Unilever Australasia Limited 20 Cambridge Street, Epping NSW 2121 Australia Level 4, 103 Carlton Gore Road, Newmarket Auckland 1023 Telephone: 1800 888 449 (Australia) 0800 900 029 (New Zealand)

Poisons Information Centre 131126 (Australia) 0800 764 766 (New Zealand) (24 Hours): Website: www.unilever.com.au www.unilever.co.nz

2. HAZARDS IDENTIFICATION

Hazard Classification: Not classified as hazardous according to the criteria of the NOHSC. Not classified as dangerous according to the Australian Dangerous Goods Code Risk Phrase(s): None allocated Safety Phrase(s): S25: Avoid contact with eyes.

3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical identity of ingredients

Ingredient CAS No. Proportion % Water 7732-18-5 >60 Sodium C12-13 Pareth Sulfate 1110392-50-2 10-<30 Cocamidopropyl Betaine 61789-40-0 <10 Fragrance - <10 DMDM Hydantoin 6440-58-0 <10 Mehtylchloroisothiazolinone & 55865-84-9 <10 Methylisothiazolinone

Other ingredients determined not to be to 100 hazardous

Page 2 of 7 Unilever Australasia 20 Cambridge Street, Epping NSW 2121 MATERIAL SAFETY DATA SHEET Australia 486 Jackson Street Petone New Zealand

4. FIRST AID MEASURES General Advice: If poisoning occurs contact a doctor or Poisons Information Centre. Phone 131126 from anywhere in Australia or 0800 764 766 in New Zealand.

Ingestion: If swallowed rinse mouth with water. Drink 1 to 2 glasses of water or milk. If large amounts swallowed, or if symptoms develop obtain medical attention.

Eye Contact: If in contact with eyes, rinse abundantly under flowing water for at least 15 minutes. If irritation develops seek medical attention.

Skin Contact: In case of skin contact, if irritation develops immediately wash off with plenty of water for at least 15 minutes. If irritation persists seek medical attention immediately.

Inhalation: If symptoms are experienced, remove source of contamination and move victim to fresh air immediately. If symptoms persist, seek medical attention.

Advice to Doctor: Treat symptomatically.

5. FIREFIGHTING MEASURES Suitable Extinguishing In case of fire, all extinguishing media are suitable. For safety Media: reasons do not use strong water jets.

Hazards from Combustion Thermal decomposition or combustion may release carbon oxides Products and other toxic gases or vapours

Precautions for Fire If in the event of fire wear self-contained breathing apparatus. Use Fighters and Special personal protective equipment. Remove containers if possible. Protective Equipment: Otherwise keep containers cool with water spray.

Hazchem Code: Not Applicable.

6. ACCIDENTAL RELEASE MEASURES Emergency Procedures: Wear appropriate protective equipment. Avoid contact with eyes. Spills will be slippery.

Methods and Materials for Remove possible leaking containers. Remove all sources and Containment and Clean Up ventilate area. Absorb small spills in inert material (sand or Procedures: vermiculate). Dyke large spills for later disposal. Dispose of material in compliance with federal, state and local regulations.

Page 3 of 7 Unilever Australasia 20 Cambridge Street, Epping NSW 2121 MATERIAL SAFETY DATA SHEET Australia 486 Jackson Street Petone New Zealand

7. HANDLING AND STORAGE Precautions for Safe Avoid contact with eyes. If eye contact occurs rinse well with Handling: water without delay.

In general the use of safety glasses is recommended. If the material is to be handled in a manner where splashing may occur, the use of goggles is recommended. If contact occurs, rinse thoroughly with water. If vapours are present shut off all sources of ignition. Keep away from heat, flame or ignition source. Do not eat, drink or smoke in handling areas. Remove contaminated clothing and wash hands before eating.

Conditions for Safe Store product upright in a cool place and out of direct sunlight. Storage: Store away from alkalis, corrosive and oxidising products. Use good personal hygiene practices.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Occupational No exposure standards allocated. Exposure Standards:

Biological Limit Values: No biological limit allocated. Engineering Controls: Use in a well ventilated area. Install safety showers and eyewash stations.

Personal protection Eye protection in the form of safety glasses should be worn. Avoid equipment: contact with eyes.

9. PHYSICAL AND CHEMICAL PROPERTIES Form/Colour: Transparent opaque liquid.

Odour: Characteristic odour. pH (20oC): 6.0 - 6.5

Vapour Pressure: Not Determined

Boiling Point (oC): >100

Melting Point (oC): Not Determined.

Solubility in Water (mg/L): Soluble

Specific Gravity (20oC) : 1025 - 1045 kg/m3

Flash Point (oC): >100

Upper and Lower Not Determined.

Page 4 of 7 Unilever Australasia 20 Cambridge Street, Epping NSW 2121 MATERIAL SAFETY DATA SHEET Australia 486 Jackson Street Petone New Zealand

Flammability Limits in Air (%): Autoignition Temp (oC): Not Determined.

Viscosity mPs (30oC): 4,000 – 6,000

10. STABILITY AND REACTIVITY Chemical Stability: Stable under normal conditions of handling, use and transportation.

Conditions to Avoid: Avoid heat and sources of ignition. Avoid moisture and protect from heat and frost, Protect from freezing.

Incompatible Materials: Keep away from strong oxidising agents, alkalis and corrosive substances.

Hazardous Decomposition Decomposition will not occur. Products:

Hazardous Reactions: None known

11. TOXICOLOGICAL INFORMATION Acute Oral Toxicity: Not Available. No particular hazards.

Acute Dermal Toxicity: Not Available.

Skin Irritation: Not Available.

Skin Sensitisation: Unlikely to cause skin sensitisation.

Eye Irritation: May cause mild irritation to eyes.

Inhalation: Not Available.

12. ECOLOGICAL INFORMATION Ecotoxicity: Not Available.

Persistence and Not Available. Degradability:

Mobility: Not Available:

Page 5 of 7 Unilever Australasia 20 Cambridge Street, Epping NSW 2121 MATERIAL SAFETY DATA SHEET Australia 486 Jackson Street Petone New Zealand

13. DISPOSAL CONSIDERATIONS Disposal Methods: Recover product if possible and dispose in accordance with local, state and federal government. Containers may be washed with water and recycled.

Special Requirements for No special requirements for landfill or incineration. Landfill or Incineration:

14. TRANSPORT INFORMATION

UN Number: Not Applicable. Proper shipping name: Not Applicable. Class: Not Applicable. Subsidiary Risks: Not Applicable. Packing group: Not Applicable. Hazchem code: Not Applicable. EPG: Not Applicable. Segregation Dangerous Not Applicable. Goods: Marine Transport: Not Applicable. Air Transport: Not Applicable.

15. REGULATORY INFORMATION AUSTRALIA

SUSDP Poisons Schedule: Not Applicable.

Prohibition/Licensing Cosmetic ingredients must be labelled on the primary pack. Requirements:

Industrial Chemicals Ingredients are in the Australian Inventory of Chemical (Notifications and Substances or are covered by certificates, permits or exemptions Assessment) Act 1989: in compliance with the Industrial Chemicals (Notification and Assessment) Act 1989.

Page 6 of 7 Unilever Australasia 20 Cambridge Street, Epping NSW 2121 MATERIAL SAFETY DATA SHEET Australia 486 Jackson Street Petone New Zealand

NEW ZEALAND Group Standard: None allocated

HSNO Approval Number: None allocated

HSNO Class: None allocated

HSNO Regulations: Not applicable

16. OTHER INFORMATION Date of Issue: 10 January 2014 Date of Last Revision: 29 March 2012 Version number: 6

DISCLAIMER This information is based on our current knowledge and is intended to describe the product for the purpose of health, safety and environmental requirements only. Since Unilever Australasia cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review this MSDS in the context of how the user intends to handle and use the product.

END OF MSDS

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