Risk Characterization of Contaminants in Passaic River Sediments, New Jersey
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Middle States Geographer, 2006, 39:13-25 RISK CHARACTERIZATION OF CONTAMINANTS IN PASSAIC RIVER SEDIMENTS, NEW JERSEY Victor Onwueme and Huan Feng* Department of Earth and Environmental Studies Montclair State University Montclair, New Jersey 07043 ABSTRACT: Sediment data from the Passaic River collected in 1991, 1993, 1995, and 1999 were analyzed for selected metals (Cr, Pb, Hg, Ni, and Zn) and organic contaminants (TCDDs and total DDTs). In this study, we compared the concentrations of these selected contaminants with different sediment quality benchmark below which adverse effects are unlikely, to determine the hazard quotients (HQ) of the chemicals of concern. It was found that the contribution of TCDDs to the potential toxic risk in the Passaic River was over 99% in all the years and average concentrations ranging from 0.007 to 0.02 µg g-1. For all the metals, Pb and Hg posses the highest risk, with HQ > 268 for Pb and HQ > 58 for Hg based on the sample analysis from the 1995 sampling. The degree and spatial extent of contaminant “hot spots” in this study is correlated well with proximity to anthropogenic sources, suggesting localized point source inputs. In this study, Harrison Reach is identified as the river segment posing the greatest potential risk for all chemicals analyzed while TCDDs and Hg are identified as the primary drivers of potential risk in all reaches along the lower Passaic River. Although a variety of chemicals of concern contaminated the Passaic River, we found good spatial correlations of TCDDs contamination with other chemical contaminations. Therefore, remediation of TCDDs contaminated sediments could address the issue to a great extent. Information derived from this study in identifying “hot spots” and localized areas of contamination are important for environmental remediation and restoration. Keywords: Contaminated sediments, Passaic River INTRODUCTION industrial expansion in Newark, which accompanied both World War I and World War II, led to the rapid growth of many industries, including chemicals, paint The Passaic River System is part of the New and pigment, metal refining, ship building, textiles and York-New Jersey Harbor Estuary System. The lower leather, rubber, rope, paper products, plastics, reach of the Passaic River consists of a 10 km (6 mile) perfumes, wood treatment, petroleum transport, and stretch primarily located in Newark, New Jersey. The more recently, hazardous waste handling. These area has five navigational reaches, as defined by the continue to operate in the region (Myers, 1945; United States Army Corps of Engineers (USACE), Cunningham, 1954, 1966; Halle, 1984; MacRae’s, including (upriver from mouth) Point No Point Reach, 1986). The attendant urbanization and industrial Harrison Reach, Newark Reach, Kearny Reach, and development has drastically altered the shorelines of Arlington Reach. The Passaic River was once a great the Passaic River. The river has narrowed river with numerous ecological systems, supporting considerably due to shoreline development to create enormous biological diversity, and providing the additional land for industrial sites. Bulkheading and native people with critical environmental and riprapping the riverbank and wetland reclamation human-use services. But like many urban rivers in the have caused a drastic change in the natural, land-shore world’s civilization history, urban expansion and interface (Iannuzzi et al., 2002). Along the lower 10 industrial development have adversely impacted the km of the Passaic River, at least 90% of the original Passaic River since the early nineteenth century wetland habitat no longer exists, and it has been (Cunningham, 1954; Brydon, 1974). Water quality replaced by landfills, bulkheads, and shoreline riprap. deteriorated throughout the nineteenth century as raw These wetlands were reclaimed with as much as 4 m sewage and industrial chemicals were discharged of fill materials on the original marsh surface directly into the river through sewers, industrial (Iannuzzi et al., 2002; Squires, 1992). Waste disposal, outfalls, and surface run-off (Cunningham, 1966; atmospheric deposition, industrial sewage, and toxic Brydon, 1974; Galishoff, 1988). In 1894, as much as chemicals spills have greatly contaminated the Passaic one-third of the total flow of the Passaic River was River aquatic system including water and sediments. estimated to be raw sewage (Brydon, 1974). The In 1970, the United States Environmental Protection 13 Risk Characterization of Contaminants Agency (USEPA) declared the Passaic River the downstream of the 10 kilometer (6 mile) study “second most polluted river in America”. boundary (Figure 1). The dataset compiled for this Previous studies carried out to characterize research includes sediment surface data from the 1995 and assess chemical contaminants in the Passaic River remedial investigation sampling program and other and Newark Bay have shown that sediments in the sediment sampling data collected by government Passaic River contain elevated concentrations of agencies, Tierra Solutions Inc., industries and numerous toxic substances including, but not limited academia and compiled by Tierra Solutions Inc. from to, arsenic (As), cadmium (Cd), chromium (Cr), 1990-2000. There are 21 sampling events occurring copper (Cu), lead (Pb), mercury (Hg), nickel (Ni), zinc between 1990 and 2000 with approximately 3,000 (Zn), dichlorodiphenyltrichloroethane (DDT), samples. The sampling dataset is stored as a petroleum hydrocarbons, TCDDs/PCDFs, and non-relational database (i.e. all data in one table) in pesticides (Bonnevie et al., 1992, 1993, 1994; Gillis et Microsoft® Access, where it can be queried to extract al., 1993, 1995; Gunster et al., 1993; Huntley et al., specific sets of data to be analyzed and used. Data for 1993, 1995, 1997; Iannuzzi et al., 1995, 1997; some chemicals of concern (Cr, Pb, Hg, Zn, TCDDs, Iannuzzi and Wenning, 1995; Wenning et al., 1993a, and Total DDTs), which historically have been 1993b, 1994). The present study is part of the discharged into the Passaic River and are known to be ongoing effort to characterize, assess, and remediate toxic, were queried and analyzed for this study. chemical contaminants in Passaic River. In this paper, we focus on the risk assessment of persistent chemical contaminants in the lower Passaic River using Geographic Information System (GIS). In 1991, the USEPA developed a guide for risk assessors, site engineers, and others in using risk information at Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) sites to both evaluate remedial alternatives during the feasibility study and to evaluate ecological and human health risk associated with the selected remedial alternative during and after its implementation (USEPA, 1991). Also, deciding on the best management alternatives for dredged contaminated sediments is challenging for managers, as they must evaluate the human and ecological risks associated with the remediation project. This study will provide an understanding of the temporal and spatial variation, to a certain extent, of the potential risk posed by multiple chemical contaminants in the lower Passaic River, which is imperative in the establishment of preliminary remediation goals and alternatives for the Passaic River. MATERIALS AND METHODS Figure 1. Map showing the study area in the lower Passaic River and locations of some associated industrial facilities along the Passaic River. Our study area is within the 10 km section of the lower Passaic River in New Jersey, which was A variety of different types of sediment under USEPA intensive investigation from 1990 to guidelines from multiple sources (e.g., Environment 2000 (Figure 1). For example, the USEPA conducted Canada, 1995; Ingersoll et al., 1996) were used in this a remedial investigation of the lower Passaic River in study and are presented in Table 1. The Ingersoll et al. 1995 to determine the horizontal and vertical (1996) guidelines identify four levels of protection. distributions and concentrations of chemical These guidelines provide sediment concentrations contaminants in the river sediment. The study where there is a low likelihood of effects (Effects included taking 78 sediment core borings comprising Range Low [ERL] and Threshold Effect Levels of three borings taken along 26 equally spaced [TEL]) as well as concentrations where effects are transects about 360 meters (1200 ft) apart, extending more likely to occur (Effects Range Median [ERM] 14 Middle States Geographer, 2006, 39:13-25 and Probable Effect Levels [PEL]). When a sediment 1991 and 1993 data sets had fewer and unevenly concentration falls below ERL and TEL values, spread-sampling locations but also included the effects are rarely observed. In contrast, the probability collection of core samples. None of the sediment data of effects is more frequent (generally greater than from these different studies were combined in the 50%) when concentrations exceed ERM and PEL effect characterization, since they were temporally values (Ingersoll et al., 1996; Long et al., 1998a). It and spatially different (i.e., collected at different times should be noted that an exceedance of any one of these and from a variety of different depths). In this study, sediment guidelines does not necessarily mean that we defined that sediment composited over a depth of aquatic or human life are at risk. This is because the 0-15 cm was considered as upper layer sediment, sediment guidelines are not site-specific,