Recent Reviews Covers Principally the Middle Part of the 2013 Literature

Number 112

compiled by Veronica M. Cornel

Department of Chemistry, Reedley College, 995 Reed Avenue, Reedley, California 93654

Reviews are listed in order of appearance in the sources indicated. In multidisciplinary review journals, only those reviews which fall within the scope of this Journal are included. Sources are listed alphabetically in three categories: regularly issued review journals and series volumes, contributed volumes, and other monographs. Titles are numbered serially, and these numbers are used for reference in the index.

Major English-language sources of critical reviews are covered. Encyclopedic treatises, annual surveys such as Specialist Periodical Reports, and compilations of symposia proceedings are omitted.

This installment of Recent Reviews covers principally the middle part of the 2013 literature. Previous installment: J. Org. Chem. 2014, 79(1).

Additional Information Available: A file containing this Recent Review compilation in Microsoft Word and the data in plain text that can be imported into Endnote (using Refer style) and Reference Manager databases.

Regularly Issued Journals and Series Volumes

Accounts of Chemical Research Hydrogenation of Terminal 1,1-Diaryl Alkenes. 2013, 52(34), 8795–7. 1. Winkler, M.; Sander, W. Triradicals. 2014, 47(1), 8. Beutner, G. L.; Denmark, S. E. Lewis Base 31–44. Catalysis of the Mukaiyama Directed Aldol Reaction: 2. Montchamp, J.-L. Phosphinate Chemistry in the 40 Years of Inspiration and Advances. 2013, 52(35), 21st Century: A Viable Alternative to the Use of Phos- 9086–96. phorus Trichloride in Organophosphorus Synthesis. 9. Kan, S. B. J.; Ng, K. K. H.; Paterson, I. The 2014, 47(1), 77–87. Impact of the Mukaiyama Aldol Reaction in Total 3. Sole, D.; Fernandez, I. Controlling the Ambi- Synthesis. 2013, 52(35), 9097–108. philic Nature of σ-Arylpalladium Intermediates in 10. Zhao, D.; Glorius, F. Enantioselective Hydro- Intramolecular Cyclization Reactions. 2014, 47(1), 168– genation of Isoquinolines. 2013, 52(37), 9616–8. 79. 11. Corbet, M.; De Campo, F. 8-Aminoquinoline: A 4. Costentin, C.; Robert, M.; Saveant, J.-M.; Tard, Powerful Directing Group in Metal-Catalyzed Direct C. Breaking Bonds with Electrons and Protons. Models Functionalization of C–H Bonds. 2013, 52(38), 9896–8. and Examples. 2014, 47(1), 271–80. 12. Brooner, R. E. M.; Widenhoefer, R. A. Cationic, Two-Coordinate Gold π Complexes. 2013, 52(45), Angewandte Chemie, International Edition in 11714–24. English 13. Renny, J. S.; Tomasevich, L. L.; Tallmadge, E. H.; Collum, D. B. Method of Continuous Variations: 5. Vlaar, T.; Maes, B. U. W.; Ruijter, E.; Orru, R. V. Applications of Job Plots to the Study of Molecular A. Palladium-Catalyzed Migratory Insertion of Isocyan- Associations in Organometallic Chemistry. 2013, ides: An Emerging Platform in Cross-Coupling Chem- 52(46), 11998–2013. istry. 2013, 52(28), 7084–97. 14. Hopf, H. Pentalenes – From Highly Reactive 6. Liang, T.; Neumann, C. N.; Ritter, T. Introduc- Antiaromatics to Substrates for Material Science. 2013, tion of Fluorine and Fluorine-Containing Functional 52(47), 12224–6. Groups. 2013, 52(32), 8214–64. 15. Suarez, A. I. O.; Lyaskovskyy, V.; Reek, J. N. 7. Besset, T.; Gramage-Doria, R.; Reek, J. N. H. H.; van der Vlugt, J. I.; de Bruin, B. Complexes with Remotely Controlled Iridium-Catalyzed Asymmetric Nitrogen-Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic 33. Barata-Vallejo, S.; Postigo, A. Metal–Mediated Applications. 2013, 52(48), 12510–29. Radical Perfluoroalkylation of Organic Compounds. 16. Boudhar, A.; Charpenay, M.; Blond, G.; 2013, 257(21–22), 3051–69. Suffert, J. Fenestranes in Synthesis: Unique and 34. Jain, L.; Jain, V. K.; Kushwah, N.; Pal, M. K.; Highly Inspiring Scaffolds. 2013, 52(49), 12786–98. Wadawale, A. P.; Bregadze, V. I.; Glazun, S. A. Chalco- 17. Kratsch, J.; Roesky, P. W. Rare-Earth-Metal genocarboranes: A Family of Multifaceted Sterically Methylidene Complexes. 2014, 53(2), 376–83. Demanding Ligands. 2014, 258–9, 72–118.

Chemical Reviews Current Organic Chemistry

18. Rouden, J.; Lasne, M.-C.; Blanchet, J.; 35. Mirfeizi, L.; Campbell-Verduyn, L.; Dierckx, R. Baudoux, J. (–)-Cytisine and Derivatives: Synthesis, A.; Feringa, B. L.; Elsinga, P. H. Application of Click Reactivity, and Applications. 2014, 114(1), 712–78. Chemistry for PET. 2013, 17(19), 2108–18. 19. Kiss, L.; Fulop, F. Synthesis of Carbocyclic and 36. Popkov, A.; Elsinga, P. H. Asymmetric Heterocyclic β-Aminocarboxylic Acids. 2014, 114(2), Synthesis of Carbon-11 Labeled α-Amino Acids for PET. 1116–69. 2013, 17(19), 2127–37. 20. Tilly, D.; Chevallier, F.; Mongin, F.; Gros, P. C. 37. Way, J.; Bouvet, V.; Wuest, F. Synthesis of 4- Bimetallic Combinations for Dehalogenative Metalation [18F]Fluorohalobenzenes and Palladium-Mediated Involving Organic Compounds. 2014, 114(2), 1207–57. Cross-Coupling Reactions for the Synthesis of 18F- 21. Chinchilla, R.; Najera, C. Chemicals from Labeled Radiotracers. 2013, 17(19), 2138–52. Alkynes with Palladium Catalysts. 2014, 114(3), 1783– 38. Heravi, M. M.; Hashemi, E.; Ghobadi, N. 826. Development of Recent Total Syntheses Based on the Heck Reaction. 2013, 17(19), 2192–224. Chemical Society Reviews 39. Joshi, S. D.; More, U. A.; Kulkarni, V. H.; Aminabhavi, T. M. Pyrrole: Chemical Synthesis, 22. Zhang, H.-J.; Priebbenow, D. L.; Bolm, C. Microwave Assisted Synthesis, Reactions and Appli- Acylsilanes: Valuable Organosilicon Reagents in cations: A Review. 2013, 17(20), 2279–304. Organic Synthesis. 2013, 42(21), 8540–71. 40. Vorontsov, A. V.; Arsentyev, A. V. Preparation 23. Rachwalski, M.; Vermue, N.; Rutjes, F. P. J. T. of Organic Compounds Using Photocatalytic Reactions. Recent Advances in Enzymatic and Chemical Deracem- 2013, 17(21), 2459–81. isation of Racemic Compounds. 2013, 42(24), 9268–82. 41. Queval, P.; Jahier, C.; Basle, O.; Mauduit, M. 24. Bariwal, J.; Van der Eycken, E. C–N Bond Cationic Ruthenium Complexes in Olefin Metathesis. Forming Cross-Coupling Reactions: An Overview. 2013, 2013, 17(22), 2560–74. 42(24), 9283–303. 42. Schanz, H.-J. Stimuli-Responsive Olefin Meta- 25. Etienne, M.; Weller, A. S. Intramolecular C–C thesis Catalysts. 2013, 17(22), 2575–91. Agostic Complexes: C–C Sigma Interactions by Another 43. Dassonneville, B.; Delaude, L.; Demonceau, A.; Name. 2014, 43(1), 242–59. Dragutan, I.; Dragutan, V.; Etse, K. S.; Hans, M. 26. Lennox, A. J. J.; Lloyd-Jones, G. C. Selection of Selected Recent Advances in the Synthesis of Bioactive Boron Reagents for Suzuki–Miyaura Coupling. 2014, Compounds Using Olefin Metathesis as a Key Step. 43(1), 412–43. 2013, 17(22), 2609–53. 44. Bassetti, M.; D'Annibale, A. Formation of Five- Chemistry - A European Journal and Six-Membered α,β-Unsaturated Lactones through Ring-Closing Metathesis of Functionalized Acrylates. 27. Szaloki, G.; Pozzo, J.-L. Synthesis of Sym- Applications to Synthesis of Natural Products. 2013, metrical and Nonsymmetrical Bisthienylcyclopentenes. 17(22), 2654–77. 2013, 19(34), 11124–32. 45. Dragutan, I.; Dragutan, V.; Demonceau, A.; 28. Wilson, D. J. D.; Dutton, J. L. Recent Advances Delaude, L. Enabling Access to Diverse Bioactive in the Field of Main-Group Mono- and Diatomic Molecules through Enyne Metathesis Concepts. 2013, “Allotropes” Stabilized by Neutral Ligands. 2013, 17(22), 2678–720. 19(41), 13626–37. 46. Dragutan, I.; Dragutan, V.; Demonceau, A.; 29. Scheffler, U.; Mahrwald, R. Recent Advances Vosloo, H. C. M. Synthesis of Castanospermine and in Organocatalytic Methods for Asymmetric C–C Bond Epimers by Metathesis Routes. 2013, 17(22), 2721–39. Formation. 2013, 19(43), 14346–96. 30. Chan, T. L.; Wu, Y.; Choy, P. Y.; Kwong, F. Y. Current Organic Synthesis A Radical Process Towards the Development of Trans- ition-Metal-Free Aromatic Carbon–Carbon Bond-Form- 47. Dadiboyena, S. Construction of Structurally ing Reactions. 2013, 19(47), 15802–14. Inspiring Spiroisoxazolines. 2013, 10(5), 661–82. 31. Zhang, H.; Zhao, Y. Pillararene-Based Assem- 48. Huang, S.; Xie, Y.; Wu, S.; Jia, M.; Wang, J.; blies: Design Principle, Preparation and Applications. Xu, W.; Fang, H. Alkylboronate Synthesis Based on 2013, 19(50), 16862–79. Transition Metal-Catalyzed Hydroboration. 2013, 10(5), 683–96. Coordination Chemistry Reviews 49. Govender, T.; Maguire, G. E. M.; Kruger, H.

G.; Shiri, M. A Review of Cyanoacetyl Indoles (CAIs): 32. Chelucci, G. Metal-Complexes of Optically Versatile Starting Materials in Organic Synthesis. Active Amino- and Imino-Based Pyridine Ligands in 2013, 10(5), 737–50. Asymmetric Catalysis. 2013, 257(11–12), 1887–932. 50. Zhang, Q.; Liu, X.; Feng, X. Recent Advances 67. Reddy, V. P.; Vadapalli, A.; Sinn, E.; Hosmane, in Enantioselective Synthesis of γ-Substituted Buten- N. N-Heterocyclic Carbenes in Organofluorine Chem- olides via the Catalytic Asymmetric Vinylogous Reac- istry. 2013, 747, 43–50. tions. 2013, 10(5), 764–85. 68. Suss-Fink, G. Water-Soluble Arene Ruthenium Complexes: From Serendipity to Catalysis and Drug European Journal of Organic Chemistry Design. 2014, 751, 2–19. 69. Caseri, W. Initial Organotin Chemistry. 2014, 51. Lohoelter, C.; Weckbecker, M.; Waldvogel, S. 751, 20–4. R. (–)-Isosteviol as a Versatile Ex-Chiral-Pool Building 70. Huber, S.; Cokoja, M.; Kuehn, F. E. Historical Block for Organic Chemistry. 2013, (25), 5539–54. Landmarks of the Application of Molecular Transition 52. Perez, D.; Pena, D.; Guitian, E. Aryne Cyclo- Metal Catalysts for Olefin Epoxidation. 2014, 751, 25– addition Reactions in the Synthesis of Large Polycyclic 32. Aromatic Compounds. 2013, (27), 5981–6013. 71. Chisholm, M. H. Comments on the Use of 53. Xie, P.; Huang, Y. Domino Cyclization Alkoxides and Related π-Donors in Organotransition Initiated by Cross-Rauhut–Currier Reactions. 2013, Metal Chemistry as Illustrated by M2(OR)6 Compounds (28), 6213–26. (M = Mo or W). 2014, 751, 55-9. 54. Pagliaro, M.; Ciriminna, R.; Pandarus, V.; 72. Gervasio, G.; Sappa, E.; Secco, A. Advances in Beland, F. Platinum-Based Heterogeneously Catalyzed the Chemistry of Alkyne-Substituted Homo- and Hydrosilylation. 2013, (28), 6227–35. Heterometallic Carbonyl Clusters of the Iron, Cobalt 55. Ragoussi, M.-E.; Ince, M.; Torres, T. Recent and Nickel Triads. An Update. 2014, 751, 111–52. Advances in Phthalocyanine-Based Sensitizers for Dye- 73. Crabtree, R. H. The Stability of Organo- Sensitized Solar Cells. 2013, (29), 6475–89. metallic Ligands in Oxidation Catalysis. 2014, 751, 56. Xuan, J.; Lu, L.-Q.; Chen, J.-R.; Xiao, W.-J. 174–80. Visible-Light-Driven Photoredox Catalysis in the 74. Timofeev, S. V.; Sivaev, I. B.; Prikaznova, E. Construction of Carbocyclic and Heterocyclic Ring A.; Bregadze, V. I. Transition Metal Complexes with Systems. 2013, (30), 6755–70. Charge-Compensated Dicarbollide Ligands. 2014, 751, 57. Herrmann, J. M.; Koenig, B. Reductive Deoxy- 221–50. genation of Alcohols: Catalytic Methods Beyond Barton- 75. Fliedel, C.; Braunstein, P. Recent Advances in McCombie Deoxygenation. 2013, (31), 7017–27. S-Functionalized N-Heterocyclic Carbene Ligands: 58. Fernandez-Ibanez, M. A.; Macia, B.; Alonso, D. From the Synthesis of Azolium Salts and Metal Com- A.; Pastor, I. M. Recent Advances in the Catalytic plexes to Applications. 2014, 751, 286–300. Enantioselective Reformatsky Reaction. 2013, (31), 7028–34. Natural Product Reports 59. Gomez, A. M.; Lobo, F.; Uriel, C.; Lopez, J. C. Recent Developments in the Ferrier Rearrangement. 76. Yu, M. J.; Zheng, W.; Seletsky, B. M. From 2013, (32), 7221–62. Micrograms to Grams. Scale-up Synthesis of Eribulin 60. Lanigan, R. M.; Sheppard, T. D. Recent Mesylate. 2013, 30(9), 1158–64. Developments in Amide Synthesis: Direct Amidation of 77. Amara, Z.; Caron, J.; Joseph, D. Recent Carboxylic Acids and Transamidation Reactions. 2013, Contributions from the Asymmetric Aza-Michael (33), 7453–65. Reaction to Alkaloids Total Synthesis. 2013, 30(9), 1211–25. Heterocycles 78. Fraga, B. M. Natural Sesquiterpenoids. 2013, 30(9), 1226–64. 61. Pradipta, A. R.; Tanaka, K. Synthesis of 3,7,9- 79. Evano, G.; Theunissen, C.; Pradal, A. Impact of and 2,6,9-Triazabicyclo[3.3.1]nonane Derivatives. 2013, Copper-Catalyzed Cross-Coupling Reactions in Natural 87(10), 2001–14. Product Synthesis: The Emergence of New Retrosynth- 62. Katoh, T. Total Synthesis of Decahydrobenzo- etic Paradigms. 2013, 30(12), 1467–89. [D]Xanthene Sesquiterpenoids Aureol, Strongylin A, 80. Marcos, I. S.; Moro, R. F.; Costales, I.; Basabe, and Stachyflin. Development of a New Strategy for the P.; Diez, D. Sesquiterpenyl Indoles. 2013, 30(12), 1509– Construction of a Common Tetracyclic Core Structure. 26. 2013, 87(11), 2199–224. 63. Makabe, H. Recent Syntheses of Proantho- Organometallics cyanidins. 2013, 87(11), 2225–48. 64. Yamamoto, Y. Syntheses of Heterocycles via 81. Jia, G. Our Journey to the Chemistry of Alkyne Cycloadditions Catalyzed by Cyclopentadienyl- Metallabenzynes. 2013, 32(23), 6852–66. ruthenium-Type Complexes. 2013, 87(12), 2459–93. 82. Waterman, R. σ-Bond Metathesis: A 30-Year 65. Nakano, H.; Okuyama, Y.; Kwon, E. Chiral Retrospective. 2013, 32(24), 7249–63. Oxazolidine Catalyst for Asymmetric Synthesis. 2014, 89(1), 1–26. Russian Chemical Reviews

Journal of Organometallic Chemistry 83. Vasilyev, A. V. Electrophilic Activation of Acetylene Compounds in Bronsted Superacids. 66. Stibr, B. Carbon Insertion into Borane Reactions of Vinyl Type Cations. 2013, 82(3), 187–204. Clusters via Nucleophilic Addition Reactions of Borane 84. Magdesieva, T. V. New Types of 'Combined' and Carborane Anions. 2013, 747, 16–24. Pericyclic Reactions. 2013, 82(3), 228–47. 85. Sitnikov, N. S.; Fedorov, A. Y. Synthesis of 100. Kawaguchi, S.-i.; Ogawa, A. Highly Selective Allocolchicinoids. A 50 Year Journey. 2013, 82(5), 393– Addition of Phosphorus-Containing Interelement 411. Compounds to Alkynes. 2013, 24(17), 2199–215. 86. Shirinian, V. Z.; Lonshakov, D. V.; Lvov, A. G.; 101. Balmond, E. I.; Galan, M. C.; McGarrigle, E. Krayushkin, M. M. Fluorescent Photochromes of M. Recent Developments in the Application of Org- Diarylethene Series: Synthesis and Properties. 2013, anocatalysis to Glycosylations. 2013, 24(18), 2335–9. 82(6), 511–37. 102. Arseniyadis, S.; Fournier, J.; Thangavelu, S.; 87. Lipunova, G. N.; Fedorchenko, T. G.; Lozano, O.; Prevost, S.; Archambeau, A.; Menozzi, C.; Chupakhin, O. N. Verdazyls: Synthesis, Properties, Cossy, J. Palladium-Catalyzed Allylic Alkylation of Application. 2013, 82(8), 701–34. Allyl Dienol Carbonates. Reactivity, Regioselectivity, 88. Yu Mikhaylov, D.; Budnikova, Y. H. Fluoro- Enantioselectivity, and Synthetic Applications. 2013, alkylation of Organic Compounds. 2013, 82(9), 835–64. 24(18), 2350–64. 103. Liu, G.; Xu, G.; Luo, R.; Tang, W. Search for Science Ideal P-Chiral Phosphorus Ligands for Practical Asymmetric Hydrogenation and Asymmetric Suzuki– 89. Taatjes, C. A.; Welz, O.; Eskola, A. J.; Savee, J. Miyaura Coupling. 2013, 24(19), 2465-71. D.; Scheer, A. M.; Shallcross, D. E.; Rotavera, B.; Lee, 104. Rao, Y. Pd-catalyzed sp2 C–H Hydroxylation E. P. F.; Dyke, J. M.; Mok, D. K. W.; Osborn, D. L.; with TFA/TFAA via Weak Coordinations. 2013, 24(19), Percival, C. J. Direct Measurements of Conformer- 2472–6. Dependent Reactivity of the Criegee Intermediate 105. Boultadakis-Arapinis, M.; Lescot, C.; Micouin, CH3CHOO. 2013, 340(6129), 177–80. L.; Lecourt, T. Functionalization of the Anomeric C–H 90. Krautwald, S.; Sarlah, D.; Schafroth, M. A.; Bond of Carbohydrates. Old Strategies and New Oppor- Carreira, E. M. Enantio- and Diastereodivergent Dual tunities. 2013, 24(19), 2477–91. Catalysis: α-Allylation of Branched Aldehydes. 2013, 106. Koike, T.; Akita, M. Visible-light-induced 340(6136), 1065–8. Photoredox Catalysis. An Easy Access to Green Radical 91. Kornecki, K. P.; Briones, J. F.; Boyarskikh, V.; Chemistry. 2013, 24(19), 2492–505. Fullilove, F.; Autschbach, J.; Schrote, K. E.; Lancaster, 107. Ishikawa, T.; Harwood, L. M. Organic Super- K. M.; Davies, H. M. L.; Berry, J. F. Direct Spectro- bases: The Concept at a Glance. 2013, 24(19), 2507-9. scopic Characterization of a Transitory Dirhodium Donor–Acceptor Carbene Complex. 2013, 342(6156), Synthesis―Stuttgart 351–4. 92. Brimioulle, R.; Bach, T. Enantioselective Lewis 108. Aitken, L. S.; Arezki, N. R.; Dell'Isola, A.; Acid Catalysis of Intramolecular Enone [2+2] Photo- Cobb, A. J. A. Asymmetric Organocatalysis and the cycloaddition Reactions. 2013, 342(6160), 840–3. Nitro Group Functionality. 2013, 45(19), 2627–48. 93. Fier, P. S.; Hartwig, J. F. Selective C–H 109. Karimi, B.; Enders, D.; Jafari, E. Recent Fluorination of Pyridines and Diazines Inspired by a Advances in Metal-Catalyzed Asymmetric Mannich Classic Amination Reaction. 2013, 342(6161), 956–60. Reactions. 2013, 45(20), 2769–812. 94. Herwig, P.; Zawatzky, K.; Grieser, M.; Heber, 110. Eckermann, R.; Gaich, T. The Akuammiline O.; Jordon-Thaden, B.; Krantz, C.; Novotny, O.; Alkaloids; Origin and Synthesis. 2013, 45(20), 2813–23. Repnow, R.; Schurig, V.; Schwalm, D.; Vager, Z.; Wolf, 111. Chen, P.; Liu, G. Recent Advances in Trans- A.; Trapp, O.; Kreckel, H. Imaging the Absolute ition-Metal-Catalyzed Trifluoromethylation and Re- Configuration of a Chiral Epoxide in the Gas Phase. lated Transformations. 2013, 45(21), 2919–39. 2013, 342(6162), 1084–6. 112. Vitale, P.; Scilimati, A. Functional 3-Aryl- 95. Wang, P.; Dong, S.; Shieh, J.-H.; Peguero, E.; isoxazoles and 3-Aryl-2-Isoxazolines from Reaction of Hendrickson, R.; Moore, M. A. S.; Danishefsky, S. J. Aryl Nitrile Oxides and Enolates: Synthesis and Erythropoietin Derived by Chemical Synthesis. 2013, Reactivity. 2013, 45(21), 2940–8. 342(6164), 1357–60. 113. Silva, E. M. P.; Varandas, P. A. M. M.; Silva, 96. Jat, J. L.; Paudyal, M. P.; Gao, H.; Xu, Q.-L.; A. M. S. Developments in the Synthesis of 1,2-Dihydro- Yousufuddin, M.; Devarajan, D.; Ess, D. H.; Kuerti, L.; pyridines. 2013, 45(22), 3053–89. Falck, J. R. Direct Stereospecific Synthesis of Unpro- 114. Li, H.; Zhang, Y.; Wang, J. Reaction of Diazo tected N-H and N-Me Aziridines from Olefins. 2014, Compounds with Organoboron Compounds. 2013, 343(6166), 61–5. 45(22), 3090–8. 115. Oliver, S.; Evans, P. A. Transition-Metal- Synlett Catalyzed Allylic Substitution Reactions: Stereo- selective Construction of α- and β-Substituted Carbonyl 97. Sui, X.; Zhu, R.; Gu, Z. Palladium-Catalyzed Compounds. 2013, 45(23), 3179–98. Chemoselective Catellani Ortho-Arylation Reactions 116. Nithiy, N.; Rosa, D.; Orellana, A. Carbon– and Their Applications in Natural Products Synthesis. Carbon Bond Formation Through Palladium Homo- 2013, 24(16), 2023–31. enolates. 2013, 45(23), 3199–210. 98. Martin, S. E. S.; Watson, D. A. Silyl-Heck Reactions for the Preparation of Unsaturated Tetrahedron Organosilanes. 2013, 24(17), 2177–82. 99. Han, J.-W.; Chen, J.-X.; Li, X.; Peng, X.-S.; 117. Tsakos, M.; Kokotos, C. G. Primary and Wong, H. N. C. Recent Developments and Applications Secondary Amine-(Thio)Ureas and Squaramides and of Chiral Tetraphenylenes. 2013, 24(17), 2188–98. Their Applications in Asymmetric Organocatalysis. 125. Drusan, M.; Sebesta, R. Enantioselective C–C 2013, 69(48), 10199–222. and C–Heteroatom Bond Forming Reactions Using 118. Hristova, Y. R.; Kemper, B.; Besenius, P. Chiral Ferrocene Catalysts. 2014, 70(4), 759–86. Water-soluble Au(I) Complexes, Their Synthesis and 126. Yang, Y.; Yu, B. Recent Advances in the Applications. 2013, 69(49), 10525–33. Synthesis of Chitooligosaccharides and Congeners. 119. Ramig, K. Stereodynamic Properties of 2014, 70(5), 1023–46. Medium-Ring Benzo-Fused Nitrogenous Heterocycles: Benzodiazepines, Benzazepines, Benzazocines, and Tetrahedron: Asymmetry Benzazonines. 2013, 69(51), 10783–95. 120. Zhang, C.-P.; Chen, Q.-Y.; Guo, Y.; Xiao, J.-C. 127. Kolodiazhnyi, O. I. Recent Developments in Bifunctional Fluoroalkylation Reagents. An Intro- the Asymmetric Synthesis of P-Chiral Phosphorus duction to Halo-Substituted 3-Oxa-Perfluoroalkane- Compounds. 2012, 23(1), 1–46. sulfonyl Fluorides. 2013, 69(51), 10955–89. 128. Chauhan, P.; Chimni, S. S. Organocatalytic 121. David, E.; Couve-Bonnaire, S.; Jubault, P.; Asymmetric Synthesis of 3-Amino-2-Oxindole Deriv- Pannecoucke, X. Ethyl Dibromofluoroacetate: A atives Bearing a Tetra-Substituted Stereocenter. 2013, Versatile Reagent for the Synthesis of Fluorinated 24(7), 343–56. Molecules. 2013, 69(52), 11039–55. 129. Heravi, M. M.; Zadsirjan, V. Oxazolidinones as 122. Heravi, M. M.; Hashemi, E.; Azimian, F. Chiral Auxiliaries in Asymmetric Aldol Reactions Recent Developments of the Stille Reaction as a Applied to Total Synthesis. 2013, 24(19), 1149–88. Revolutionized Method in Total Synthesis. 2014, 70(1), 130. Sutar, R. L.; Joshi, N. N. Base-catalyzed 7–21. Mukaiyama-type Aldol Additions, A Continued Quest 123. Kataev, E. A.; Mueller, C. Recent Advances in for Stereoselectivity. 2013, 24(21–22), 1345–63. Molecular Recognition in Water: Artificial Receptors 131. Chatterjee, B.; Bera, S.; Mondal, D. Julia-Kocienski and Supramolecular Catalysis. 2014, 70(2), 137–67. Olefination. A Key Reaction for the Synthesis of Macrolides. 124. Voskressensky, L. G.; Festa, A. A.; Varlamov, 2014, 25(1), 1–55. A. V. Domino Reactions Based on Knoevenagel Con- densation in the Synthesis of Heterocyclic Compounds. Recent Advances. 2014, 70(3), 551–72.

Index

Acetylenes, electrophilic homolytic substitution, 30 Complexes, p-block, zero oxidation activation, 83 Aryl nitrile oxides, with enolates, state, 28 with Bronsted superacids, 83 112 Criegee intermediates, 89 Acylsilanes, 22 Arylethene, fluorescent, 86 Cross coupling, Cu catalyzed, 79 Alcohols, reductive deoxygenation, Arylpalladium intermediate, 3 Cross-Rauhut–Currier reactions, 57 Aryne cycloaddition, 52 53 Aldehydes, branched, allylation, Aziridines, from olefins, 96 Cyanoacetylindoles, 49 90 Benzazepines, 119 Cyclopentadienylruthenium Alkaloids, akuammiline, 110 Benzazocines, 119 complex, 64 via aza-Michael reaction, 77 Benzazonines, 119 Cytisine, 18 molybdenum complexes, 71 Benzodiazepines, 119 Deracemization, 23 tungsten complexes, 71 Benzoxanthene sesquiterpenoids, Diarylalkenes, hydrogenation, 7 Alkylboronates, synthesis, 48 synthesis, 62 Diazines, fluorination, 93 Alkynes, carbonyl clusters, 72 Biaryl cross coupling, 30 Dibromofluoroacetate, 121 diphosphine addition, 100 Bisthienylcyclopentenes, 27 Dicarbollide ligands, 74 reactivity, Pd, 21 Bond breaking, 4 Dihydropyridines, 113 Allocolchicinoids, synthesis, 85 Borane clusters, with carboranes, Dirhodium carbene complex, 91 Allotropes, p-block, ligand 66 Domino reactions, Knoevenagel stabilized, 28 Butenolides, enantioselective condensation, 124 Allyl dienol carbonates, alkylation, synthesis, 50 Enones, photocycloaddition, 92 102 Carbocycle preparation, domino Enyne metathesis, 45 Allylic substitution, transition process, 53 Epoxides, chiral, imaging, 94 metals, 115 Carbocyclic aminocarboxylic acids, Eribulin mesylate synthesis, 76 Amides, from carboxylic acids, 60 19 Erythropoietin synthesis, 95 Amine (thio)ureas, 117 Carbohydrates, C-H bond Fenestranes, 16 Amino acids, preparation, 19 activation, 105 Ferrier rearrangement, glycals, 59 radiolabeled, 36 Catellani ortho arylation, 97 Ferrocenes, chiral, 125 Amino pyridine ligands, 32 C–C bond formation, Pd Fluorination, 6 Aminooxindoles, asymmetric homoenolates, 116 Fluoroalkylation, 88 synthesis, 128 C–C metal agostic complexes, 25 bifunctional, 120 Aminoquinolines, 11 C–H bond functionalization, 11 Fluorohalobenzene, radiolabeled, Aqueous molecular recognition, Chalcogenocarboranes, 34 37 123 Chitooligosaccharides, 126 Glycosylation, organocatalysis, Arene Ru complex, 68 Click chemistry, PET, 35 101 Aromatics, C–C bond formation, C–N bond formation, cross Gold complex, aqueous, 118 30 coupling, 24 Gold, carbenes, 12 Gold, π complexes, 12 N-Heterocyclic carbenes, ligands, Photoredox catalysis, visible light, Heck reaction, 38 75 106 Heteroarylethenes, fluorescent, 86 Olefin epoxidation, 70 Photoreduction, visible light, 56 Heterocycles, N-, synthesis, 61 Olefin metathesis catalyst, 42 Phthalocyanine, solar cells, 55 via alkyne cycloaddition, 64 bioactive compounds, 43 Pillararenes, 31 Heterocyclics, aminocarboxylic Organic superbases, 107 Proanthocyanidin synthesis, 63 acids, 19 Organoboron, diazo coupling, 114 Pyridines, fluorination, 93 via photoredox catalysis, 56 Organocatalysis, C–C bond Pyrroles, 39 Hydroboration, 48 formation, 29 Reformatsky reaction, 58 Hydrosilylation, Pt, 54 Michael addition, 29 Ring-closing metathesis, acrylates, Indolizidine alkaloids, via olefin nitro group, 108 44 metathesis, 46 Organometallic ligands, oxidation dienynes, 45 Isocyanide,migratory insertion, catalysis, 73 Ruthenium complex, olefin Pd, 5 Organosilanes, silyl Heck reaction, metathesis, 41 Isoquinolines, hydrogenation, 10 98 Sesquiterpenoids, 78 Isosteviol, 51 Organosilicon, 22 Sesquiterpenyl indoles, 80 Isoxazolines, 112 Organostannanes, 69 Sigma bond metathesis, 82 Job plots, organometallics, 13 Oxazolidine catalyst, chiral, 65 Signaling glycoprotein, 95 Lactones, via ring closing Oxazolidinones, aldol reactions, Spiroisoxazolines, 47 metathesis, 44 129 Squaramides, 117 Ligands, N-centered radicals, 15 Pentalenes, 14 Stille reaction, 122 Lupinine, synthesis, 92 Perfluoroalkylation, 120 Supramolecules, aqueous, 123 Macrolides, via Julia Kocienski with metals, 33 Suzuki Miyaura coupling, boron, olefination, 131 Pericyclic reactions, 84 26 Mannich reactions, metal Phenols, functionalization, 104 Tetraphenylenes, chiral, 99 catalyzed, 109 trifluoroacetic acid, 104 Thermopsine, synthesis, 92 Metalation, dehalogenative, 20 Phosphinates, 2 Triazabicyclononanes, 61 Metallabenzynes, 81 Phosphorus compounds, Trifluoromethylation, 111 Methylidene, rare earth metal asymmetric synthesis, 127 Triradicals, 1 complex, 17 Phosphorus ligands, chiral, 103 Verdazyls, 87 Mukaiyama aldol addition, 8,9,130 Photocatalysis, 40