minerals Article Post-Depositional Alteration of Calcium Carbonate Phases in Archaeological Ceramics: Depletion and Redistribution Effects William D. Gilstrap 1,*, Jennifer L. Meanwell 1 , Elizabeth H. Paris 2 , Roberto López Bravo 3 and Peter M. Day 4,5 1 Center for Materials Research in Archaeology and Ethnology, Massachusetts Institute of Technology, Cambridge, MA 02139, USA;
[email protected] 2 Department of Anthropology and Archaeology, University of Calgary, Calgary, AB T2N 1N4, Canada;
[email protected] 3 Escuela de Arqueología, Universidad de Ciencias y Artes de Chiapas, Tuxtla Gutiérrez 29039, Mexico;
[email protected] 4 Institute for Nanoscience and Nanotechnology, N.C.S.R Demokritos, Agia Paraskevi, 153 41 Athens, Greece; p.m.day@sheffield.ac.uk 5 Department of Archaeology, University of Sheffield, Sheffield S1 3NJ, UK * Correspondence:
[email protected] Abstract: The final stage in the life history of prehistoric pottery prior to archaeological recovery is usually the longest, and frequently the most dynamic. The remains of archaeological ceramics spend hundreds to thousands of years deposited within the upper layers of the earth’s crust where they encounter the same diagenetic environmental processes as the surrounding natural materials. Harsh conditions of subterranean environments induce physical stresses and chemical reactions, causing alterations of ceramic structure and composition. This is especially true of carbonate-rich ceramics, as carbonate phases are soluble when deposited within acidic environments. This paper Citation: Gilstrap, W.D.; Meanwell, examines common carbonate depletion and accretion effects of post-depositional environments on J.L.; Paris, E.H.; López Bravo, R.; Day, ancient ceramics from two rather different geological and archaeological contexts: Mesoamerica and P.M.