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Cupric Carbonate ID: C1-178 Safety Data Sheet Material Name: Cupric Carbonate ID: C1-178 * * * Section 1 - Identification * * * Chemical Name: Light or Dense Powder Product Use: For Commercial Use NOT TO BE USED AS A PESTICIDE. THIS PRODUCT IS NOT TO BE USED IN VIOLATION OF ANY PATENTS. CHEM ONE LTD. DISCLAIMS ANY AND ALL WARRANTIES, EITHER EXPRESSED OR IMPLIED, INCLUDING THE WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR APPLICATION. IN NO EVENT SHALL CHEM ONE LTD. OR ITS SUPPLIERS BE LIABLE FOR ANY DAMAGES WHATSOEVER INCLUDING DIRECT, INDIRECT, INCIDENTAL, CONSEQUENTIAL, LOSS OF BUSINESS PROFITS OR SPECIAL DAMAGES, EVEN IF CHEM ONE LTD. OR ITS SUPPLIERS HAVE BEEN ADVISED OF THE POSSIBILITY OF SUCH DAMAGES. SOME STATES DO NOT ALLOW THE EXCLUSION OF LIMITATION OF LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES SO THE FOREGOING LIMITATION MAY NOT APPLY. Supplier Information Chem One Ltd. Phone: (713) 896-9966 14140 Westfair East Drive Fax: (713) 896-7540 Houston, Texas 77041-1104 Emergency # (800) 424-9300 or +1- (703) 527-3887 General Comments NOTE: Emergency telephone numbers are to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure, or accident involving chemicals. All non-emergency questions should be directed to customer service. * * * Section 2 – Hazard(s) Identification * * * GHS HAZARD Hazard Classes Hazard Categories Acute toxicity, Oral Category 4 Acute toxicity, Inhalation Category 4 Eye irritation Category 2A Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 1 Signal Word: Warning Pictograms: PHYSICAL HAZARDS: None HEALTH HAZARDS: H302: Harmful if swallowed H315: Causes skin irritation. H332: Harmful if inhaled ENVIRONMENTAL HAZARDS: H410: Very toxic to aquatic life with long lasting effects PRECAUTIONARY STATEMENTS: P102: Keep out of reach of children P202: Do not handle until all safety precautions have been read and understood P261: Avoid breathing dust/fume/gas/mist/vapors/spray. ____________________________________________________________ Issue Date : 4/27/99 08:45:30 CLW Page 1 of 10 Revision Date:06/17/2019 Safety Data Sheet Material Name: Cupric Carbonate ID: C1-178 P264: Wash hands thoroughly after handling P270: Do not eat, drink or smoke when using this product P271: Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment P280: Wear eye protection/face protection. RESPONSE STATEMENTS: P301+P312+P330: IF SWALLOWED: Call a POISON CENTER /doctor if you feel unwell (USA National POISON CENTER 800-222- 1222). Rinse mouth. P304+P340+P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER /doctor if you feel unwell (USA National POISON CENTER 800-222-1222). P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P391: Collect spillage STORAGE STATEMENTS: None DISPOSAL STATEMENTS: P501: Dispose of content and/or container in accordance with local, regional, national or international regulations Hazards not otherwise classified (HNOC): No data available * * * Section 3 – Composition/information on Ingredients * * * CAS # Component Percent 12069-69-1 Copper(II) carbonate hydroxide, 70% (as CuO2, Dry) 70 Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Copper (7440-50-8). Synonyms: Basic Copper Carbonate, Copper (II) Carbonate, Copper (II) Carbonate Hydroxide * * * Section 4 - First Aid Measures * * * Emergency Overview Product is a green solid existing as a fine powder. Use methods suitable for surrounding fire. Avoid breathing dusts. May cause irritation to the nose, throat, and upper respiratory tract. This product is irritating to the eyes and skin. Harmful or fatal if swallowed. Firefighters should wear full protective equipment and clothing when fighting a fire involving this material. High concentration of airborne dust may pose an explosion hazard. Potential Health Effects: Eyes This product is irritating to the eyes. Exposure may result in irritation, pain, swelling, tearing, or photophobia. Copper salts may produce conjunctivitis or even ulceration and clouding of the cornea. Potential Health Effects: Skin Copper salts are irritating to the skin, and may produce itching, redness, and rash. This product may cause skin discoloration. Potential Health Effects: Ingestion High-level acute ingestion of copper salts may produce nausea, vomiting and epigastric burning pain, followed by hemolysis, anemia, and liver and kidney damage secondary to hemolysis. Vomitus is characteristically greenish-blue. Mucosal erosion, a metallic taste in the mouth, and bloody diarrhea may occur. Hypotension, lethargy, and coma are potential CNS effects that may result from ingestion of large quantities of this product. ____________________________________________________________ Issue Date : 4/27/99 08:45:30 CLW Page 2 of 10 Revision Date:06/17/2019 Safety Data Sheet Material Name: Cupric Carbonate ID: C1-178 Potential Health Effects: Inhalation Inhalation of dust and mists of copper salts can result in irritation of nasal mucous membranes, sometimes of the pharynx and, on occasion, ulceration with perforation of the nasal septum. Inhalation of fumes or fine dust may cause metal fume fever with resulting flu-like symptoms involving fever, chills, sweats, muscle aches and pains, cough, and general malaise. First Aid: Eyes Immediately flush eyes with large amounts of room temperature water, occasionally lifting the lower and upper lids, for at least 15 minutes. If symptoms persist after 15 minutes of irrigation, seek medical attention. First Aid: Skin For skin contact, wash immediately with soap and water. Get medical attention if irritation or pain persists. First Aid: Ingestion If the material is swallowed, get immediate medical attention or advice. Do not induce vomiting unless directed to do so by medical personnel. Have victim rinse mouth thoroughly with water, if conscious. Never give anything by mouth to a victim who is unconscious or having convulsions. Emesis is generally rapid and spontaneous in individuals who have ingested copper salts. First Aid: Inhalation Remove source of contamination or move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Get immediate medical attention. First Aid: Notes to Physician Provide general supportive measures and treat symptomatically. Consult nearest Poison Control Center for all exposures except minor instances of inhalation or skin contact. * * * Section 5 - Fire Fighting Measures * * * General Fire Hazards High concentration of airborne dust may pose an explosion hazard. Prevent human exposure to fire, smoke, fumes, or products of combustion. Hazardous Combustion Products When heated to decomposition, this product emits acrid smoke and fumes, including copper oxide fumes. Extinguishing Media Use methods for the surrounding fire and other materials involved in the fire. Dry chemical, foam, carbon dioxide, or water spray are recommended. Fire Fighting Equipment/Instructions Firefighters should wear full protective clothing including self contained breathing apparatus. NFPA Ratings: Health: 2 Fire: 1 Reactivity: 1 Other: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * * * Section 6 - Accidental Release Measures * * * Containment Procedures Stop the flow of material, if this can be done without risk. Contain the discharged material. If sweeping of a contaminated area is necessary use a dust suppressant agent, which does not react with product (see Section 10 for incompatibility information). Clean-Up Procedures Wear appropriate protective equipment and clothing during clean-up. Shovel the material into waste container. Thoroughly wash the area after a spill or leak clean-up. Solutions of the compound can be neutralized with lime or similar compound. Avoid contamination of soil, and prevent spill residue from running to groundwater or storm drains. ____________________________________________________________ Issue Date : 4/27/99 08:45:30 CLW Page 3 of 10 Revision Date:06/17/2019 Safety Data Sheet Material Name: Cupric Carbonate ID: C1-178 Evacuation Procedures Evacuate the area promptly and keep upwind of the spilled material. Isolate the spill area to prevent people from entering. Keep materials that burn away from spilled material. In case of large spills, follow all facility emergency response procedures. Special Procedures Remove soiled clothing and launder before reuse. Avoid all skin contact with the spilled material. Have emergency equipment readily available. * * * Section 7 - Handling and Storage * * * Handling Procedures All employees who handle this material should be trained to handle it safely. Do not breathe dust. Avoid all contact with skin and eyes. Use this product only with adequate ventilation. Wash thoroughly after handling. Storage Procedures Keep container tightly closed when not in use. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Material should be stored in secondary containers or in a diked area, as appropriate.
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