Chemical Comparison of FLY ASH and PORTLAND CEMENT

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Bulletin 2 Technical Chemical Comparison OF FLY ASH AND PORTLAND CEMENT The table below shows typical compound The major difference between fly ash and analyses for two fly ashes and a natural portland cement is the relative quantity of each pozzolan (Class F fly ash, Class C fly ash and of the different compounds. Portland cement is Class N - Natural) and ordinary portland cement. rich in lime (CaO) while fly ash is low. Fly ash is A glance at the table reveals that the same high in reactive silicates while portland cement compounds exist in fly ash and portland cement. has smaller amounts. Those of fly ash are amorphous (glassy) due to rapid cooling; those of cement are crystalline, The table illustrates the basic chemical formed by slower cooling. difference. Portland cement is manufactured with CaO, some of which is released in a free Typical Chemical Compounds in Pozzolans state during hydration. As much as 20 pounds and Portland Cement of free lime is released during hydration of 100 pounds of cement. This liberated lime forms the Chemical Pozzolan Type Portland Compound Cement necessary ingredient for reaction with fly ash Class F Class C Class N silicates to form strong and durable cementing SiO 54.90 39.90 58.20 22.60 compounds no different from those formed A12O3 25.80 16.70 18.40 4.30 during hydration of ordinary portland cement. Fe2O3 6.90 5.80 9.30 2.40 CaO 8.70 24.30 3.30 64.40 A review of the chemistry of both materials MgO 1.80 4.60 3.90 2.10 makes it apparent that a blend of the two will SO3 0.60 3.30 1.10 2.30 enhance the concrete product and efficiently Na2O & K2O 0.60 1.30 1.10 0.60 utilize the properties of both. The chemical composition of fly ash is very similar to that of portland cement. For more information or answers to questions about the use of fly ash in specific applications, contact your nearest Boral Resources Technical Sales Representative or call 1-770-684-0102 Revision Date: 12.9.17 1 Bulletin 2 Technical Chemical Comparison OF FLY ASH AND PORTLAND CEMENT 2.

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