Sara Karimibehzad Ezzatollah Najafi1 Mostafa M. Amini Azadehtadjarodi Ali Dehghani
Supporting Information
Synthesis and characterization of lead(II) coordination polymers for fabrication of an organic light-emitting diode (OLED) and photoluminescence property of the nanosize lead oxide core of polymer
Sara KarimiBehzad · Ezzatollah Najafi1 · Mostafa M. Amini · AzadehTadjarodi · Ali Dehghani · BehrouzNotash
S.K. Behzad · E. Najafi · B. Notash · M. M. Amini ()
Department of Chemistry, ShahidBeheshti University, Tehran 1983963113, Iran E-mail: (M.M. Amini).
A. Dehghani · A.Tadjarodi() Faculty of Chemistry, Iran University of Science & Technology (IUST), Tehran, 16846, Iran
E-mail address: tajarodi@ iust.ac.ir (A.Tadjarodi).
Table S1Selected bond lengths (Å) and angles (˚) for compound [(Pb(4-bpdb)(NO3)(PhN2O2))2]n
Pb(1)-O(10) / 2.321(5) / Pb(2)-O(8) / 2.344(5)Pb(1)-O(9) / 2.453(5) / Pb(2)-O(7) / 2.410(5)
Pb(1)-O(1) / 2.645(5) / Pb(2)-N(5) / 2.613(6)
Pb(1)-N(4)#1 / 2.663(6) / Pb(2)-O(9) / 2.715(5)
Pb(1)-O(2) / 2.670(5) / Pb(2)-N(8)#2 / 2.765(6)
Pb(1)-N(1) / 2.676(6) / O(2)-Pb(1)-N(1) / 122.95(16)
O(10)-Pb(1)-O(9) / 64.26(16) / O(8)-Pb(2)-O(7) / 65.74(17)
O(10)-Pb(1)-O(1) / 76.90(16) / O(8)-Pb(2)-N(5) / 84.37(18)
O(9)-Pb(1)-O(1) / 131.14(16) / O(8)-Pb(2)-O(9) / 144.70(16)
O(10)-Pb(1)-N(4)#1 / 84.1(2) / O(7)-Pb(2)-O(9) / 83.57(16)
O(9)-Pb(1)-N(4)#1 / 81.91(19) / N(5)-Pb(2)-N(8)#2 / 156.33(18)
O(1)-Pb(1)-N(4)#1 / 123.68(17) / O(9)-Pb(2)-N(8)#2 / 108.92(18)
Symmetry codes:#1: x+1,y+1,z; #2: x-1,y-1,z
Table S2Geometrical parameters of hydrogen bonds in [(Pb(4-bpdb)(NO3)(PhN2O2))2]n
D–H…A / D–H/Å / H…A/Å / ∠DHA/˚ / D…A/ÅC(3)-H(3A)...O(1)#3 / 0.95 / 2.52 / 3.304(8) / 139.5
C(6)-H(6A)...O(8)#4 / 0.95 / 2.46 / 3.361(8) / 158.6
C(9)-H(9)...O(3)#5 / 0.95 / 2.50 / 3.311(9) / 143.8
C(11)-H(11)...O(4)#2 / 0.95 / 2.55 / 3.490(9) / 172.2
C(13)-H(13)...O(5)#6 / 0.95 / 2.36 / 3.123(9) / 136.6
C(14)-H(14)...O(7) / 0.95 / 2.49 / 3.160(9) / 127.7
C(19)-H(19)...O(3)#7 / 0.95 / 2.55 / 3.446(9) / 156.5
C(23)-H(23)...O(4)#8 / 0.95 / 2.33 / 3.160(10) / 146.2
Symmetry codes: 1: x+1,y+1,z; #2: x-1,y-1,z: #3: -x+1,-y+1,-z+1;
#4: x-1,y,z; #5: x,y-1,z; #6: -x+2,-y+1,-z+1; #7: x+1,y,z;
#8 -x+3,-y+2,-z+1.
Fig. S1. Perspective view of the coordination sphere around (A) Pb1 and (B) Pb2 atoms in [(Pb(4-bpdb)(NO3)(PhN2O2))2]n coordination polymer.
Fig. S2. A perspective view of (A) - and (B) C-H-interactionsto form the larger3D supramolecular network.
Fig. S3. Cyclic voltammograms of the lead complexes.
Fig. S4. TG-DTA of single crystal of [(Pb(4-bpdb)(NO3)(PhN2O2))2]n.
Fig. S5. Luminescence–voltage characteristic of 2 based device.