SAFETY DATA SHEET 1. IDENTIFICATION OF THE PRODUCT/COMPANY UNDERTAKING 1.1 Product Identifiers Product Name CLEANTECHS HAND DISINFECTANT CLEANTECHS HAND DISINFECTANT 1.2 Relevant Identified Uses/Uses Advised Against Identified Uses Hand sanitizer Uses Advised No specific uses advised against are identified. Against 1.3 Details of the Supplier of the Safety Data Sheet Supplier Company CLEANTECHS Address YeniBosna Merkez Mah.Çınar cad.No:8 Bahçelievler - İstanbul Telephone +90 212 671 65 66 Fax +90 212 671 47 48 SDS No: 131099 E-mail Address [email protected] Person responsible for the safety data sheet Version: 01 Name Adem Ademoğlu Telephone +90 0 543 598 82 10 Date of Issue: 11.05.2020 E-mail [email protected] Revision Date: First issue Manufacturer Company CLEANTECHS Address YeniBosna Merkez Mah.Çınar cad.No:8 Bahçelievler - İstanbul Telephone +90 212 671 65 66 Fax +90 212 671 47 48 E-mail Address [email protected] According to Regulation No 1907/2006/EC (REACH), Annex 1.4 Emergency Telephone Numbers II, as amended by Commission Supplier Company Emergency +90 0 543 598 82 10 Regulation (EU) 2015/830 and Regulation No 1272/2008/EC (CLP) Page: 1/11 SAFETY DATA SHEET According to Regulation No 1907/2006/EC (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 and Regulation No 1272/2008/EC (CLP) SDS No: 131099 Version: 01 Date of Issue: 11.05.2020 Revision Date: First issue 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended) Flammable liquids, Category 2; H225 Eye irritation, Category 2; H319 NOTE: See Section 4.2 for symptoms and Section 11 for more detailed information on health effects. 2.2 Label elements 2.2.1 Labeling according CLP regulation (Regulation (EC) No. 1272/2008, as amended) Hazard symbols DANGER Hazard statements H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. Precautionary statements P102 Keep out of reach of children. P210 Keep away from heat/sparks/open flames/hot surfaces – No smoking. P240 Ground/bond container and receiving equipment. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/protective clothing/eye protection/face protection. P337+P313 If eye irritation persists: Get medical advice/attention. P403+P235 Store in a well ventilated place. Keep cool. Product/container must be disposed of in accordance with local and national regulations. Dispose of P501 container only when totally empty. 2.3 Other hazards No additional hazards are known except those derived from the labeling. Hazard-determining components of labeling: Ethanol This mixture does not meet the PBT and vPvB criteria of REACH Regulation, Annex XIII. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Not applicable, product is a mixture. 3.2 Mixtures INGREDIENT IDENTIFIERS % CLASSIFICATION EINECS1 NO: 200-578-6 CAS2 NO: 64-17-5 Ethanol (96%) INDEX NO3: 603-002-00-5 70 DANGER REACH REGIST. NO: Flammable liquids, Cat. 2; H225 1-2119457610-43-XXXX Eye irritation, Cat. 2; H319 EINECS NO: 231-791-2 CAS NO: 7732-18-5 Not classified as hazardous according to the EC Regulation Deionized water 28,55 INDEX NO: - 1272/2008/EC REACH REGIST. NO: - CLEANTECHS HAND DISINFECTANT Page: 2/11 SAFETY DATA SHEET According to Regulation No 1907/2006/EC (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 and Regulation No 1272/2008/EC (CLP) SDS No: 131099 Version: 01 Date of Issue: 11.05.2020 Revision Date: First issue EINECS NO: 200-289-5 CAS NO: 56-81-5 Not classified as hazardous according to the EC Regulation Glycerol (98%) INDEX NO: - 1,45 1272/2008/EC REACH REGIST. NO: 01-2119471987-18-XXXX NOTE: Any impurities required to be classified or that affect the classification of the product: None See Section 16 for the full text of the H statements declared above. 4. FIRST AID MEASURES 4.1 Description of first aid measures Following inhalation Remove from contaminated area, lay patient down, keep warm and rested. Obtain medical attention. In case of skin contact Wash with plenty of water and soap. If irritation occurs, continues and/or worsens, stop using the product, consult a physician. In case of eye contact Wash out immediately with fresh running water for several minutes. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids, seek medical attention if irritation occurs. If swallowed Do not induce vomiting, if the person is conscious, wash out mouth thoroughly with water. Immediately make victim drink water (two glasses at most). Never give anything to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Inhalation May be harmful when inhaled, may cause irritation of the respiratory tract. Ethanol [CAS# 64-17-5]: At concentrations above 50% may cause local mucosal wounds due to dehydration and precipitation of albumin. Rhinitis (nasal membrane inflammation) may occur. Cough, headache, fatigue may be seen. Skin No adverse effects expected. Repeated or prolonged exposure to ethanol may cause skin irritation and dermatitis, due to degreasing properties of the substance. Eyes Causes serious eye irritation. Burning sensation, increased lacrimation and redness may be seen. Ingestion May be harmful if swallowed. May cause irritation in the gastrointestinal tract. Nausea, vomiting and diarrhea may also be seen. 4.3 Indication of any immediate medical attention and special treatment needed Central nervous system depression, narcosis, nausea, vomiting may be seen when swallowed. Thoroughly observe the patient and treat symptomatically. 5. FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing Use alcohol resistant foam, carbon dioxide (CO2), dry chemical and water spray. media Unsuitable extinguishing Do not use water jet since it may expand the fire. media 5.2 Special hazards arising from the substance or mixture Hazardous combustion Upon burning toxic fumes of carbon monoxide (CO), carbon dioxide (CO2) and various products hydrocarbons may be emitted. CLEANTECHS HAND DISINFECTANT Page: 3/11 SAFETY DATA SHEET According to Regulation No 1907/2006/EC (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 and Regulation No 1272/2008/EC (CLP) SDS No: 131099 Version: 01 Date of Issue: 11.05.2020 Revision Date: First issue Unusual fire & explosion Vapours may travel long distances toward sources of ignition (flash back). hazards Closed containers may rupture violently and suddenly when exposed to fire or excessive heat for a sufficient period of time. 5.3 Advice for firefighters Special firefighting Do not approach containers suspected to be hot. procedures Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Water used to extinguish fire should not enter drainage systems, soil, or stretches of water. Contaminated fire-extinguishing water must be disposed of in accordance with the regulations issued by the appropriate local authorities. Special protective Use self-contained breathing apparatus, and full protective clothing in case of fire. equipment for firefighting 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures 6.1.1 For non-emergency personnel Ensure adequate ventilation, avoid inhalation of vapors/fumes and contact with eyes. Remove all sources of ignition. Prevent further leakage or spillage if safe to do so, keep away from incompatible products. Evacuate the area. 6.1.2 For emergency responders Evacuate personnel to safe areas. Remove all sources of ignition. Ensure adequate ventilation, avoid inhalation of vapors/fumes and contact with eyes. Consider exposure limits and use personal protective equipment referred in Section 8. 6.2 Environmental precautions Try to prevent the material from entering drains or water courses. Spillages or uncontrolled discharges into watercourses must be alerted to the Environmental Agency or other appropriate regulatory body. 6.3 Methods and materials for containment and cleaning up Remove with an inert non-combustible absorbent (like vermiculite, sand, cat litter) and dispose of absorbent as hazardous waste. Wash the contaminated surface with water. Dispose of waste material according to local, state and federal regulations. 6.4 Reference to other sections See Section 7 for safe handling. See Section 8 for exposure controls and personal protection. See Section 13 for disposal considerations. 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Use ex-proof equipment when handling. Ethanol vapors may form explosive mixtures with air (Lower Explosion Limit 3,1% v/v, Upper Explosion Limit 27,7% v/v), do not work in confined spaces and fume hoods with unknown performance. The product is flammable; do not spray directly on fire or hot surfaces. Handle in accordance with the general rules of occupational hygiene and safety. Avoid inhalation of vapours, wear protective clothing when risk of exposure occurs, ensure adequate ventilation. Do not eat, drink or smoke in areas where the material is used, wash thoroughly after handling the material. Remove contaminated clothing and protective equipment before entering eating areas. CLEANTECHS HAND DISINFECTANT Page: 4/11 SAFETY DATA SHEET According to Regulation No 1907/2006/EC (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 and Regulation No 1272/2008/EC (CLP) SDS No: 131099 Version: 01 Date of Issue: 11.05.2020 Revision Date: First issue 7.2 Conditions for safe storage including any incompatibilities Store in a cool, dry, well-ventilated area protected from environmental extremes. Protect from heat, flames and sparks, extremes of temperature and direct sunlight. Store away from food, drink and animal feeding stuffs and foodstuff containers. Containers which are opened must be carefully resealed and kept upright to prevent leakage.