��������������������� UPDATE OF X RAY AND GAMMA RAY DECAY DATA STANDARDS FOR DETECTOR CALIBRATION AND OTHER APPLICATIONS VOLUME 2 The following States are Members of the International Atomic Energy Agency: AFGHANISTAN GREECE NORWAY ALBANIA GUATEMALA PAKISTAN ALGERIA HAITI PALAU ANGOLA HOLY SEE PANAMA ARGENTINA HONDURAS PARAGUAY ARMENIA HUNGARY PERU AUSTRALIA ICELAND PHILIPPINES AUSTRIA INDIA POLAND AZERBAIJAN INDONESIA PORTUGAL BANGLADESH IRAN, ISLAMIC REPUBLIC OF QATAR BELARUS IRAQ REPUBLIC OF MOLDOVA BELGIUM IRELAND ROMANIA BELIZE ISRAEL RUSSIAN FEDERATION BENIN ITALY SAUDI ARABIA BOLIVIA JAMAICA SENEGAL BOSNIA AND HERZEGOVINA JAPAN SERBIA BOTSWANA JORDAN SEYCHELLES BRAZIL KAZAKHSTAN SIERRA LEONE BULGARIA KENYA SINGAPORE BURKINA FASO KOREA, REPUBLIC OF SLOVAKIA CAMEROON KUWAIT SLOVENIA CANADA KYRGYZSTAN SOUTH AFRICA CENTRAL AFRICAN LATVIA SPAIN REPUBLIC LEBANON SRI LANKA CHAD LIBERIA SUDAN CHILE LIBYAN ARAB JAMAHIRIYA SWEDEN CHINA LIECHTENSTEIN SWITZERLAND COLOMBIA LITHUANIA SYRIAN ARAB REPUBLIC COSTA RICA LUXEMBOURG TAJIKISTAN CÔTE D’IVOIRE MADAGASCAR THAILAND CROATIA MALAWI THE FORMER YUGOSLAV CUBA MALAYSIA REPUBLIC OF MACEDONIA CYPRUS MALI TUNISIA CZECH REPUBLIC MALTA TURKEY DEMOCRATIC REPUBLIC MARSHALL ISLANDS UGANDA OF THE CONGO MAURITANIA UKRAINE DENMARK MAURITIUS UNITED ARAB EMIRATES DOMINICAN REPUBLIC MEXICO UNITED KINGDOM OF ECUADOR MONACO GREAT BRITAIN AND EGYPT MONGOLIA NORTHERN IRELAND EL SALVADOR MONTENEGRO UNITED REPUBLIC ERITREA MOROCCO OF TANZANIA ESTONIA MOZAMBIQUE UNITED STATES OF AMERICA ETHIOPIA MYANMAR URUGUAY FINLAND NAMIBIA UZBEKISTAN FRANCE NETHERLANDS VENEZUELA GABON NEW ZEALAND VIETNAM GEORGIA NICARAGUA YEMEN GERMANY NIGER ZAMBIA GHANA NIGERIA ZIMBABWE The Agency’s Statute was approved on 23 October 1956 by the Conference on the Statute of the IAEA held at United Nations Headquarters, New York; it entered into force on 29 July 1957. The Headquarters of the Agency are situated in Vienna. Its principal objective is “to accelerate and enlarge the contribution of atomic energy to peace, health and prosperity throughout the world’’. UPDATE OF X RAY AND GAMMA RAY DECAY DATA STANDARDS FOR DETECTOR CALIBRATION AND OTHER APPLICATIONS In two volumes VOLUME 2 DATA SELECTION, ASSESSMENT AND EVALUATION PROCEDURES INTERNATIONAL ATOMIC ENERGY AGENCY VIENNA, 2007 COPYRIGHT NOTICE All IAEA scientific and technical publications are protected by the terms of the Universal Copyright Convention as adopted in 1952 (Berne) and as revised in 1972 (Paris). The copyright has since been extended by the World Intellectual Property Organization (Geneva) to include electronic and virtual intellectual property. Permission to use whole or parts of texts contained in IAEA publications in printed or electronic form must be obtained and is usually subject to royalty agreements. Proposals for non-commercial reproductions and translations are welcomed and considered on a case-by-case basis. Enquiries should be addressed to the IAEA Publishing Section at: Sales and Promotion, Publishing Section International Atomic Energy Agency Wagramer Strasse 5 P. O. B o x 1 0 0 1400 Vienna, Austria fax: +43 1 2600 29302 tel.: +43 1 2600 22417 email: [email protected] http://www.iaea.org/books © IAEA, 2007 Printed by the IAEA in Austria May 2007 STI/PUB/1287 IAEA Library Cataloguing in Publication Data Update of X Ray and Gamma Ray Decay Data Standards for Detector Calibration and Other Applications. — Vienna : International Atomic Energy Agency, 2007. 2 v. ; 24 cm. STI/PUB/1287 ISBN 92–0–113606–4 Includes bibliographical references. v. 1. - Recommended Decay Data, High Energy Gamma Ray Standards and Angular Correlation Coefficients — v. 2. - Data Selection, Assessment and Evaluation Procedures. 1. Gamma ray Detectors. 2. Radiation — Measurement. 3. Detectors — Calibration — Standards. 4. X-rays — Equipment and supplies — Standards. I. International Atomic Energy Agency. IAEAL 07–00480 FOREWORD Various groups around the world are engaged in the compilation and evaluation of decay data for either all known or specific radionuclides. Many evaluators operate independently and recommend slightly different values for the same parameter. Even small deviations in the recommended data can have a significant impact on the definition of the decay characteristics of radionuclides used as standards in detector efficiency calibrations and subsequent applications (e.g. in nuclear medicine and environmental monitoring). Under such circumstances, these differences can be propagated into the measurements of decay data for other radioactive nuclides and may also bring into question the efficacy of adopting specific radionuclides in diagnostic and therapeutic treatments. High quality decay data are essential for the efficiency calibration of X and g ray detectors that are used to quantify the radionuclidic content of a sample by determining the intensities of any resulting X and g rays. A major objective of the IAEA nuclear data programme is to promote improvements in the quality of nuclear data used in science and technology. Hence the IAEA established a Coordinated Research Project (CRP) in 1986 on Measurements and Evaluation of X and Gamma Ray Standards for Detector Efficiency Calibration, with the aim of reducing the discrepancies and uncertainties in those decay data parameters judged to be important in such work. This CRP was completed in 1990, and the results of the work were assembled as a database and presented in IAEA-TECDOC-619, X-ray and Gamma-ray Standards for Detector Calibration. Recommended values for the half-lives and photon emission probabilities were given for a selected set of radionuclides that were judged to be suitable for detector efficiency calibration (X rays from 5 to 90 keV, and g rays from 30 to about 3000 keV). Detector efficiency calibrations for higher gamma ray energies were also considered (i.e. prompt emissions up to 14 MeV from specific nuclear reactions). This timely initiative contributed to the development of measurement techniques and an agreed evaluation methodology. The evaluation procedures used to obtain the recommended values and their estimated uncertainties were documented, along with a summary of the remaining discrepancies. Many important experimental studies were catalysed by the demands of this earlier CRP, and a significant fraction of these new data were not published until the 1990s nor included in the original evaluation process. New efforts under the auspices of a further CRP were judged to be necessary in order to incorporate these new data and update the existing database, along with extending these files to encompass the related needs of a number of important applications such as environmental monitoring and nuclear medicine. A Consultants meeting was held in Vienna on 24 and 25 November 1997 to assess the current needs and identify the most suitable radionuclides. The experts at this meeting advised the establishment of a new CRP on Update of X ray and Gamma Ray Decay Data Standards for Detector Calibration and other Applications. The IAEA established this CRP in 1998 and the participants completed an agreed work programme in 2005. All of the results are presented in Volume 1 of this report, while Volume 2 details the data selection, assessment and evaluation processes adopted in order to ensure traceability. Recommended half-lives, and X and g ray emission probabilities are given for a carefully selected set of radionuclides and nuclear reactions that are suitable for detector efficiency calibration and other applications. The evaluation procedures used to obtain the recommended values and their uncertainties are detailed, and comments have been made on the remaining discrepancies. Consideration is also given to the coincidence method of determining absolute g ray detection efficiencies and the statistical correlation of decay data. An appropriate set of suitable X and g ray decay data standards have been derived, with the expectation that the recommended values will be recognized as international reference standards. The IAEA is grateful to members of the Decay Data Evaluation Project and laboratories affiliated with the International Committee for Radionuclide Metrology for their assistance in the work and for support of the CRP meetings. Both O.A.M. Helene and V.R. Vanin wish to thank their State and Federal funding agencies (FAPESP and CNPq) for financial support during the course of their evaluation studies. The IAEA officers responsible for this publication were M. Herman and A.L. Nichols (ex AEA Technology) of the Division of Physical and Chemical Sciences. The participants in this evaluation study dedicate their work and results to the memory of their co-workers: R.G. Helmer (USA), G.L. Molnár (Hungary) and S.A. Woods (UK). CONTRIBUTING AUTHORS M.-M. Bé Laboratoire National Henri Becquerel, France V.P. Chechev V.G. Khlopin Radium Institute, Russian Federation R. Dersch Physikalisch-Technische Bundesanstalt, Germany O.A.M. Helene Universidade de São Paulo, Brazil R.G. Helmer† Idaho National Laboratory, United States of America M. Herman International Atomic Energy Agency S. Hlaváč Slovak Academy of Sciences, Slovakia A. Marcinkowski The Andrzej Soltan Institute for Nuclear Sciences, Poland G.L. Molnár† Institute of Isotope and Surface Chemistry, Hungary A.L. Nichols AEA Technology, United Kingdom E. Schönfeld Physikalisch-Technische Bundesanstalt, Germany V.R. Vanin Universidade de São Paulo, Brazil M.J. Woods National Physical Laboratory, United Kingdom † Deceased EDITORIAL NOTE The