TRICALCIUM PHOSPHATE CONSOLIDATED CHEMICAL CO Chemwatch Hazard Alert Code: 1 Chemwatch: 17420 Issue Date: 01/01/2013 Version No: 4.1.1.1 Print Date: 05/09/2016 Safety Data Sheet according to WHS and ADG requirements S.GHS.AUS.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name TRICALCIUM PHOSPHATE Chemical Name calcium orthophosphate Chemical formula Ca.2/3H3O4P Other means of TRICALCIUM PHOSPHATE, 1147 identification CAS number 7758-87-4 Relevant identified uses of the substance or mixture and uses advised against Relevant identified Laboratory reagent, minor food additive. Major component of bone ash. Food additive 542 Bone Phosphate uses Details of the supplier of the safety data sheet Registered company CONSOLIDATED CHEMICAL CO name Address 52-62 Waterview Close 3175 Australia Telephone 03 9799 7555 Fax 03/9799 7666 Website Not Available Email Not Available Emergency telephone number Association / Not Available Organisation Emergency telephone 1800 839 984 numbers Other emergency Not Available telephone numbers CHEMWATCH EMERGENCY RESPONSE Primary Number Alternative Number 1 Alternative Number 2 1800 039 008 1800 039 008 +612 9186 1132 Once connected and if the message is not in your prefered language then please dial 01 SECTION 2 HAZARDS IDENTIFICATION Continued... Chemwatch: 17420 Page 2 of 9 Issue Date: 01/01/2013 Version No: 4.1.1.1 TRICALCIUM PHOSPHATE Print Date: 05/09/2016 Classification of the substance or mixture NON-HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code. CHEMWATCH HAZARD RATINGS Min Max Flammability 0 Toxicity 1 0 = Minimum Body Contact 0 1 = Low Reactivity 0 2 = Moderate 3 = High Chronic 0 4 = Extreme Poisons Schedule Not Applicable Classification [1] Chronic Aquatic Hazard Category 4 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex Legend: VI Label elements GHS label elements Not Applicable SIGNAL WORD NOT APPLICABLE Hazard statement(s) H413 May cause long lasting harmful effects to aquatic life. Supplementary statement(s) Not Applicable Precautionary statement(s) Prevention P273 Avoid release to the environment. Precautionary statement(s) Response Not Applicable Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal P501 Dispose of contents/container in accordance with local regulations. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances CAS No %[weight] Name 7758-87-4 100 calcium orthophosphate Mixtures See section above for composition of Substances SECTION 4 FIRST AID MEASURES Description of first aid measures If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally Eye Contact lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. Continued... Chemwatch: 17420 Page 3 of 9 Issue Date: 01/01/2013 Version No: 4.1.1.1 TRICALCIUM PHOSPHATE Print Date: 05/09/2016 If dust is inhaled, remove from contaminated area. Inhalation Encourage patient to blow nose to ensure clear passage of breathing. If irritation or discomfort persists seek medical attention. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Ingestion Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 FIREFIGHTING MEASURES Extinguishing media There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area. Special hazards arising from the substrate or mixture Fire Incompatibility None known. Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Fire Fighting Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. Non combustible. Not considered a significant fire risk, however containers may burn. Fire/Explosion Hazard Decomposition may produce toxic fumes of:, phosphorus oxides (POx), metal oxides May emit poisonous fumes.|No fire or explosion hazards associated with this product. HAZCHEM Not Applicable SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Remove all ignition sources. Clean up all spills immediately. Minor Spills Avoid contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Moderate hazard. CAUTION: Advise personnel in area. Major Spills Alert Emergency Services and tell them location and nature of hazard. Control personal contact by wearing protective clothing. Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 HANDLING AND STORAGE Precautions for safe handling Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Safe handling Use in a well-ventilated area. Prevent concentration in hollows and sumps. Continued... Chemwatch: 17420 Page 4 of 9 Issue Date: 01/01/2013 Version No: 4.1.1.1 TRICALCIUM PHOSPHATE Print Date: 05/09/2016 Store in original containers. Keep containers securely sealed. Other information Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Conditions for safe storage, including any incompatibilities Polyethylene or polypropylene container. Suitable container Check all containers are clearly labelled and free from leaks. Metals and their oxides or salts may react violently with chlorine trifluoride and bromine trifluoride. These trifluorides are hypergolic oxidisers. They ignites on contact (without external source of heat or ignition) with recognised fuels - contact with these materials, following an ambient or slightly elevated temperature, is often violent and may produce ignition. Storage The state of subdivision may affect the results. incompatibility Phosphates are incompatible with oxidising and reducing agents. Phosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation of phosphates by oxidizing agents may result in the release of toxic phosphorus oxides. + + + + + + + X — Must not be stored together 0 — May be stored together with specific preventions + — May be stored together SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes Australia Exposure calcium Fume (thermally generated) 2 Not Not Not Standards orthophosphate (respirable dust) mg/m3 Available Available Available EMERGENCY LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 calcium orthophosphate Particulate material (PNOS) 30 mg/m3 330 mg/m3 2000 mg/m3 Ingredient Original IDLH Revised IDLH calcium orthophosphate Not Available Not Available Exposure controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. Appropriate The basic types of engineering controls are: engineering controls Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Personal protection Safety glasses with side shields Chemical goggles. Eye and face Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy protection document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Skin protection See Hand protection below Continued... Chemwatch: 17420 Page 5 of 9 Issue Date: 01/01/2013 Version No: 4.1.1.1 TRICALCIUM PHOSPHATE Print Date: 05/09/2016 The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through