SAFETY DATA SHEET 1. Identification Product identifier Cocamidopropyl Betaine Other means of identification Recommended use Surfactant. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Company name Chemistry Connection Address 253 Sturgis Rd Conway, AR 72034 Main Telephone Number (501) 470-9689 Website www.chemistryconnection.com E-mail [email protected] Emergency #: 1-888-583-7738 (8:00am-5:00pm Mon-Fri) Emergency #: CHEMTREC 1-800-424-9300 2. Hazard(s) identification Physical hazards Not classified. Health hazards Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Environmental hazards Hazardous to the aquatic environment, acute Category 2 hazard Hazardous to the aquatic environment, Category 3 long-term hazard OSHA defined hazards Not classified. Label elements Signal word Warning Hazard statement Causes skin irritation. Causes serious eye irritation. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Wash thoroughly after handling. Wear eye protection/face protection. Wear protective gloves. Avoid release to the environment. Response If on skin: Wash with plenty of water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Storage Store away from incompatible materials. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Store in accordance with local/regional/national/international regulations. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information 45.24% of the mixture consists of component(s) of unknown acute oral toxicity. 54.29% of the mixture consists of component(s) of unknown acute dermal toxicity. 45.24% of the mixture consists of component(s) of unknown acute inhalation toxicity. SDS US Revised 01/23/2019 1 / 8 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Cocamidopropyl Betaine 61789-40-0 25 - < 60 Sodium Chloride 7647-14-5 < 10 Glycerine 56-81-5 < 5 Other components below reportable levels 35 - < 66 Residuals Chemical name Common name and synonyms CAS number % Dichloroacetic Acid 79-43-6 <= 2 Formaldehyde 50-00-0 <= 2 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. Composition comments Occupational Exposure Limits for residuals are listed in Section 8. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if symptoms occur. Most important Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred symptoms/effects, acute and vision. Skin irritation. May cause redness and pain. delayed Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation. medical attention and special Symptoms may be delayed. treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting Move containers from fire area if you can do so without risk. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers emergency procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Prevent product from entering drains. containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. SDS US Revised 01/23/2019 2 / 8 Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Conditions for safe storage, Store in tightly closed container. Store away from incompatible materials (see Section 10 of the including any incompatibilities SDS). 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Residuals Type Value Formaldehyde (CAS STEL 2 ppm 50-00-0) TWA 0.75 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form Glycerine (CAS 56-81-5) PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. US. ACGIH Threshold Limit Values Residuals Type Value Dichloroacetic Acid (CAS TWA 0.5 ppm 79-43-6) Formaldehyde (CAS STEL 0.3 ppm 50-00-0) TWA 0.1 ppm US. NIOSH: Pocket Guide to Chemical Hazards Residuals Type Value Formaldehyde (CAS Ceiling 0.1 ppm 50-00-0) TWA 0.016 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines US ACGIH Threshold Limit Values: Skin designation Dichloroacetic Acid (CAS 79-43-6) Can be absorbed through the skin. Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station and safety shower. It is recommended that users of this product perform a risk assessment to determine the appropriate PPE. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. Other Wear appropriate chemical resistant clothing. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards Wear appropriate thermal protective clothing, when necessary. SDS US Revised 01/23/2019 3 / 8 General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Colorless to Yellowish Odor Characteristic. Odor threshold Not available. pH 5 - 7 (10% AQ) Melting point/freezing point Not available. Initial boiling point and boiling > 212 °F (> 100 °C) range Flash point > 212.0 °F (> 100.0 °C) Closed Cup Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density 1.05 @ 25°C (approximate) Solubility(ies) Solubility (water) Soluble Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition