Contribution of HIRES to cometary science Philippe Rousselot UTINAM Institute/OSU THETA, Besançon Emmanuel Jehin STAR Institute, Univ. of Liège Back to basics for comets... Nucleus ~ 10 km Coma ~ 10 000 – 100 000 km Dust tail Plasma tail ~ a few millions km ~ a few millions km 2/11 Chemical composition known by spectroscopic investigation with ground- based facilities / space mission and in situ analysis. Spectroscopic observation with ground-based facilities : Comet = gas + dust Sun Earth : emision spectrum (gas) + solar continuum (dust) 3/11 The spectrum observed in a cometary coma includes two elements : → a continuum coming from the solar lights scattered by the dust grains (Mie scattering that creates a reddening) → some emission lines created by the fluorescence mechanism of chemical species in the coma. 4/11 Parent molecules visible with ground based facilities ( % / eau) : water H O 100 IR, radio 2 carbon monoxide CO 0,2-23 radio, IR, UV carbon dioxide CO 2.5-30 IR 2 Hydrocarbons ( ≈ 2%) : methane CH 0.12-1.5 IR 4 acetylene C2H2 0.04-1.5 IR ethane C2H6 0.14-2 IR CHO-bearing molecules ( ≈ 4%) : methanol CH3OH 0.6-6.2 radio, IR formaldehyde H2CO 0.13-1.4 radio, IR ethylene glycol HOCH2CH2OH 0.07-0.35 radio formic acid HCOOH 0.028-0.18 radio ethanal CH3CHO 0.047-0.08 radio methyl formate HCOOCH3 0.07-0.08 radio ethanol C2H5OH 0.12 radio glycolaldehyde CH2OHCHO 0.016 radio Nitrogen-bearing molecules ( ≈ 1%) : ammonia NH3 0.3-0.7 radio, IR + dissociation hydrogen cyanide HCN 0.085-0.25 radio, IR products / ions hydrogen isocyanide HNC 0.002-0.035 radio (ex : CN, C , C , acetonitrile CH CN 0.008-0.035 radio 2 3 3 NH , NH, CH, methyl cyanide HC3N 0.002-0.068 radio 2 + + isocyanic acid HNCO 0.009-0.08 radio CO , N2 …) + formamide NH CHO 0.008-0.021 radio 2 isotopologs Sulfur-bearing molecules ( ≈ 1,5 %) : + Na, Ca+ hydrogen sulfide H2S 0.13-1.5 radio sulfur monoxide SO 0.04-0.3 radio sulfur dioxide SO2 0.2 radio carbonyl sulfide OCS 0.03-0.4 radio, IR disulfure de carbone CS2 0.2 UV, radio thioformaldehyde H2CS 0.009-0.09 radio disulfur S2 0.001-0.25 UV 5/11 HIRES: → Wavelength range (0.35-1.8 mm) adapted mainly to dissociation products or ions (CN, C2, C3, NH2, NH, CH, CO+, N2+…). → Measurement of absolute and relative abundancies, even for low abundancies (e.g N2+ for most of the comets). → Measurement of isotopic ratios in dissociation products. Detection of species with low abundance: → Important for interstellar comets coming inside the solar system: case of 2I/ Borisov, 2 such comets expected to be detected / year with LSST, most of them will probably be faint and with a short period of visibility. Unique opportunity to have information about the composition of other planetary systems. → Important for Main Belt Comets to detect gazeous species and infer their composition. → Important for distant comets: source of activity ? 6/11 Isotopic ratios: The following isotopic ratios have now been measured in comets: D/H, 12C/13C, 14N/15N, 16O/18O,16O/17O, 32S/34S, 32S/33S Among them 12C/13C, 14N/15N, 16O/18O can be measured in radicals having emission lines in the spectral range covered by HIRES: NH2 → 14N/15N C2 → 12C/13C CN → 12C/13C and 14N/15N N2+ → 14N/15N CO+ → 12C/13C and 16O/18O 7/11 Case of 14N/15N: → Terrestrial value = 272 → Measurements done in comets with : → HCN (sub-mm range) → CN (388 nm with UVES at VLT) → NH2 (570 nm with UVES at VLT) Rousselot et al. (2014) → Attempts to measure it with N2+ in comet C/2016 R2 with UVES at VLT. → Rosetta (ROSINA in situ mass spectrometer) in comet 67P: NH3 and N2 (results announced for paper in preparation, not so obvious to measure because of some other species with similar mass). → Dust grains with Stardust. 8/11 → At least 3 isotopic reservoirs in the solar system: → PSN poor in 15N (14N/15N=441) → inner solar system (planets + bulk meteorites) enriched by a factor of 1.6 / PSN (14N/15N=272) → cometary ices enriched by a factor of 3 / PSN (14N/15N~140) → ratios ≈ consistent with an increase of 15N with heliocentric distance (qualitative agreement with D/H) Füri (2015) 9/11 What HIRES could do: → Gain for S/N ~ 5 / VLT (UVES) Example with 13CO+ emission lines simulated from an UVES spectrum of comet C/2016 R2: UVES spectrum with (very weak ! Simulated spectrum with the same 13 + 13CO+ emission lines) CO emission lines with S/N x 5 → Measurement of 14N/15N in N2+ (not enough S/N with UVES even with C/2016 R2) → Reduce error bars to detect 14N/15N variations in NH or CN with the 2 type of comet (not yet detected but large errorbars). → Measurements of isotopic ratios in interstellar comets (2I/Borisov with NH2 emission lines) 10/11 … and, maybe, measurement of relative abundances in exocomets: → Absorption lines (Ca II and Na I) due to exocomets detected in b Pic and more than 20 other stars. → Ca II K absorption lines observed at 393.4 nm around b Pic by HARPS: → Doppler shift allows dynamical studies (for b Pic : two families of comets, one of them being in MMR with a massive planet and the other one being fragments of one of a few Kiefer et al. (2014) parent bodies). → First « exocomet transit » observed by TESS on b Pictoris: Zieba et al. (2019) 11/11 Thanks for your attention ! 12/11 Credit: Jean-Paul Rémy-Martin .