Publications 543. Mugridge, J.S.; Bergman, R.G.; Raymond, K.N. “Equilibrium Isotope Effects on Noncovalent Interactions in a Supramolecular Host−Guest System” J. Am. Chem. Soc. 2012, 134, 2057-2066. 542. Tauchert, M.E.; Incarvito, C.D.; Rheingold, A.L.; Bergman, R.G.; Ellman, J.A. “Mechanism of the Rhodium(III)-Catalyzed Arylation of Imines via C–H Bond Functionalization: Inhibition by Substrate” J. Am. Chem. Soc. 2012, 134, 1482-1485. 541. Gianetti, T.L; Tomson, N.C.; Arnold, J.; Bergman, R.G. “Z-selective Catalytic Internal- Alkyne Semi-Hydrogenation under H2:CO Mixtures by a Niobium(III) Imido Complex” J. Am. Chem. Soc. 2011, 133, 14904-14907. 540. Tomson, N.C.; Crimmin, M.R.; Petrenko, T.; Rosebrugh, L.E.; Sproules, S.; Boyd, W.C.; Bergman, R.G.; DeBeer, S.; Toste, F.D.; Wieghardt, K. “A Step beyond the Feltham_Enemark Notation: Spectroscopic and Correlated ab Initio Computational Support for an Antiferromagnetically Coupled M(II) ̶ (NO)¯ Description of Tp*M(NO)(M = Co, Ni)” J. Am. Chem. Soc. 2011, 133, 18785-18801. 539. Crimmin, M.R.; Rosebrugh, L.E.; Tomson, N.C., Weyhermüller, T.; Bergman, R.G.; Toste, F.D.; Wieghardt, K. “[(TMEDA)Co(NO)2][BPh4]: A Versatile Synthetic Entry Point to Four and Five Coordinate {Co(NO)2}10 Complexes” J. Organometallic Chem. 2011, 696, 3974-3981. 538. Brown, C.J.; Miller, G.M.; Johnson, M.W.; Bergman, R.G.; Raymond, K.N. “High- Turnover Supramolecular Catalysis by a Protected Ruthenium(II) Complex in Aqueous Solution” J. Am. Chem. Soc. 2011, 133, 11964-11966. 537. Zhao, C.; Bergman, R.G.; Toste, F.D. “Direct Michael Addition of Alkenes via a Cobalt-Dinitrosyl Mediated Vinylic C-H Functionalization Reaction” J. Am. Chem. Soc. 2011, 133, 10787-10789. 536. Hesp, K.D.; Bergman, R.G.; Ellman, J.A. “Expedient Synthesis of N-Acyl Anthranilamides and β-Enamine Amides by the Rh(III)-Catalyzed Amidation of Aryl and Vinyl C-H Bonds with Isocyanates” J. Am. Chem. Soc. 2011, 133, 11430-11433. 535. Tomson, N.C.; Bergman, R.G.; Arnold, J. “Synthesis and Reactivity of Cationic Niobium and Tantalum Methyl Complexes Supported by Imido and Diketiminato Ligands” Dalton Trans. 2011, 40, 7718-7729. 534. Razgon, A.; Anstey, M.R.; Yakelis, N.A.; Bergman, R.G.; Sukenik, C.N. “Surface Immobilization of an Organo-Iridium Complex through a Carbon-Metal Bond” Inorganica Chimica Acta 2011, 375, 305-307. 533. Wang, Z.J.; Brown, C.J.; Bergman, R.G.; Raymond, K.A.; Toste, F.D. “Hydroalkoxylation Catalyzed by a Gold(I) Complex Encapsulated in a Supramolecular Host” J. Am. Chem. Soc. 2011, 133, 7358-7360. 532. Koller, J; Bergman, R.G. “Highly Efficient Aluminum-Catalyzed Ring-Opening Polymerization of Cyclic Carbonates, Lactones, and Lactides, Including a Unique Crystallographic Snapshot of an Intermediate” Organometallics 2011, 30, 3217-3224. 531. Crimmin, M.R.; Bergman, R.G.; Toste, F.D. “Synthesis of [RuCl2(NO)2(THF)] and its double C-N bond forming reactions with alkenes” Angew. Chem. 2011, 50, 4484-4487. 530. Brasse, M.; Ellman, J.A.; Bergman, R.G. “A Facile, Metal- and Solvent Free, Autoxidative Coupling of Quinolines with Indoles and Pyrroles” Chem. Comm. 2011, 47, 5019-5021. 529. Bowring, M.A.; Bergman, R.G.; Tilley, T.D. “Disambiguation of Metal and Brønsted Acid Catalyzed Pathways for Hydroarylation with Pt(II) Catalysts” Organometallics 2011, 30, 1295-1298. 528. Tsai, A.S.; Tauchert, M.E.; Bergman, R.G.; Ellman, J.A. “Rhodium(III) Catalyzed Arylation of Boc-Imines via C–H Bond Functionalization” J. Am. Chem. Soc. 2011, 133, 1248-1250. 527. Crimmin, M.R.; Colby, D.A.; Ellman, J.A.; Bergman, R.G. “Synthesis and Coordination Chemistry of Tri-Substituted Benzamidrazones” Dalton Trans. 2011, 40, 514-522. 526. Koller, J.; Bergman, R.G. “Highly Efficient Aluminum-Catalyzed Hydro-Amination/- Hydrazination of Carbodiimides” Organometallics 2010, 29, 5946-5952. 525. Berman, A.M.; Bergman, R.G.; Ellman, J.A. “Rh(I)-Catalyzed Direct Arylation of Azines” J. Org. Chem. 2010, 75, 7863-7868. 524. Boyd, W.C.; Crimmin, M.R.; Rosebrugh, L.E.; Schomaker, J.M.; Toste, F.D.; Bergman, R.G. “Cobalt-Mediated, Enantioselective Synthesis of C2 and C1 Dienes” J. Am. Chem. Soc. 2010, 132, 16365-16367. 523. Mugridge, J.S.; Szigethy, G.; Bergman, R.G.; Raymond, K.N. “Encapsulated Guest- Host Dynamics: Guest Rotational Barriers and Tumbling as a Probe of Host Interior Cavity Space” J. Am. Chem. Soc. 2010, 132, 16256-16264. 522. Calladine, J.A.; Torres, O.; Anstey, M.; Ball, G.E.; Bergman, R.G.; Curley, J.; Duckett, S.B.; George, M.W.; Gilson, A.I.; Lawes, D.J.; Perutz, R.N.; Sun, X.; Vollhardt, K.P.C. “Photoinduced N2 Loss as a Route to Long-lived Organometallic Alkane Complexes: A Time-resolved IR and NMR Study” Chem. Sci. 2010, 1, 622-630. 521. Nichols, J.M.; Bishop, L.M.; Bergman, R.G.; Ellman, J.A. “Catalytic C-O Bond Cleavage of 2-Aryloxy-1-arylethanols and its Application to the Depolymerization of Lignin Related Polymers” J. Am. Chem. Soc. 2010, 132, 12554-12555. 520. Arceo, E.; Ellman, J.A.; Bergman, R.G. “Rhenium-Catalyzed Didehydroxylation of Vicinal Diols to Alkenes Using a Simple Alcohol as a Reducing Agent” J. Am. Chem. Soc. 2010, 132, 11408-11409. 519. Koller, J.; Bergman, R.G. “Synthesis, Characterization, and Reactivity of Aluminum Alkyl/Amide Complexes Supported by Guanidinate and Monoanionic OCO-Pincer Ligands” Organometallics 2010, 29, 3350-3356. 518. Tomson, N.C.; Arnold, J.; Bergman, R.G. “Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)Nb(III) Imido Complexes” Organometallics 2010, 29, 5010- 5025. 517. Arceo, E.; Ellman, J.A.; Bergman, R.G. “A Direct, Biomass-Based Synthesis of Benzoic Acid: Formic Acid-Mediated Deoxygenation of the Glucose-Derived Materials Quinic Acid and Shikimic Acid” ChemSusChem. 2010, 3, 811-813. 516. Koller, J.; Bergman, R.G. “Aluminum-Catalyzed Intramolecular Hydroamination of Aminoalkenes” Chem. Comm. 2010, 46, 4577-4579. 515. Tomson, N.C.; Arnold, J.; Bergman, R.G. “Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the β–Diketiminato Ligand” Organometallics 2010, 29, 2926-2942. 514. Bishop, L.; Roberson, R.E.; Bergman, R.G.; Trauner, D. “On the Development of Catalytic Carba-6π Electrocyclizations” SYNLETT 2010, 13, 2233-2244. 513. Hastings, C.J.; Pluth, M.D.; Bergman, R.G.; Raymond, K.N. “Enzymelike Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation” J. Am. Soc. Chem. 2010, 132, 6938-6940. 512. Mugridge, J.S.; Bergman, R.G.; Raymond, K.N. “The Steric Isotope Effect in a Supramolecular Host-Guest Exchange Reaction” Angew. Chem. 2010, 49, 3635-3637. 511. Colby, D.A.; Bergman, R.G.; Ellman, J.A. “Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation” Chem. Rev. 2010, 110, 624-655. 510. Mugridge, J.S.; Bergman, R.G.; Raymond, K.N. “High Precision Measurement of Isotope Effects on Noncovalent Host-Guest Interactions” J. Am. Chem. Soc. 2010, 132, 1182- 1183. 509. Brown, C.J.; Bergman, R.G.; Raymond, K.N. “Enantioselective Catalysis of the Aza- Cope Rearrangement by a Chiral Supramolecular Assembly” J. Am. Chem. Soc. 2009, 131, 17530-17531. 508. Pluth, M.D.; Bergman, R.G.; Raymond, K. N. “Proton-Mediated Chemistry and Catalysis in a Self-Assembled Supramolecular Host” Acc. Chem. Res. 2009, 42, 1650-1659. 507. Schomaker, J.M.; Toste, F.D.; Bergman, R.G. “Cobalt-Mediated [3+2]-Annulation Reaction of Alkenes with α,β-Unsaturated Ketones and Imines” Org. Lett. 2009, 11, 3698- 3700. 506. Pluth, M.D.; Fiedler, D.; Mugridge, J.S.; Bergman, R.G.; Raymond, K.N. “Encapsulation and Characterization of Proton-Bound Amine Homodimers in a Water- Soluble, Self-Assembled Supramolecular Host” PNAS 2009, 106, 10438-10443. 505. Tsai, A.S.; Wilson, R.M.; Harada, H.; Bergman, R.G.; Ellman, J.A. “Rhodium Catalyzed Enantioselective Cylization of Substituted Imidazoles via C–H Bond Activation” Chem. Comm. 2009, 26, 3910-3912. 504. Arceo, E.; Marsden, P.; Bergman, R.G.; Ellman, J.A. “An Efficient Didehydroxylation Method for the Biomass-Derived Polyols Glycerol and Erythritol. Mechanistic Studies of a Formic Acid-Mediated Deoxygenation” Chem. Comm. 2009, 23, 3357-3359. 503. Chan, V.S.; Chiu, M.; Bergman, R.G.; Toste, F.D. ”Development of Ruthenium Catalysts for the Enantioselective Synthesis of P-Stereogenic Phosphines via Nucleophilic Phosphido Intermediates” J. Am. Chem. Soc. 2009, 131, 6021-6032. 502. Yotphan, S.; Bergman, R.G.; Ellman, J.A. "Application of Daugulis Copper-Catalyzed Direct Arylation to the Synthesis of 5-Aryl Benzotriazepines" Org. Lett. 2009, 11, 1511- 1514. 501. Pluth, M.D.; Bergman, R.G.; Raymond, K.N. "The Acid Hydrolysis Mechanism of Acetals Catalyzed by a Supramolecular Assembly in Basic Solution" J. Org. Chem. 2009, 74, 58-63. 500. Pluth, M.D.; Johnson, D.W.; Szigethy, G.; Davis, A.V.; Teat, S.J.; Oliver, A.G.; Bergman, R.G.; Raymond, K.N. "Structural Consequences of Anionic Host- Cationic Guest Interactions in a Supramolecular Assembly" Inorg. Chem. 2009, 48, 111-120. 499. Berman, A.; Lewis, J.C.; Bergman, R.G.; Ellman, J.A. "Rh(I)-Catalyzed Direct Arylation of Pyridines and Quinolines" J. Am. Chem. Soc. 2008, 130, 14926-14927. 498. Bishop, L.M.; Barbarow, J.E.; Bergman, R.G.; Trauner, D. "Catalysis of a 6p Electrocyclization" Angew. Chem. Int. Ed. 2008, 47, 8100-8103. 497. Pluth, M.D.; Bergman, R.G.; Raymond, K.N. "Acceleration of Amide Bond Rotation by Encapsulation in the Hydrophobic Interior of a Water-Soluble Supramolecular Assembly" J. Org. Chem. 2008, 73, 7132-7136. 496. Hastings, C.J.; Pluth, M.D.; Biros, S.M.; Bergman, R.G.; Raymond, K.N. "Simultaneously Bound Guests and Chiral Recognition: a Chiral Self-Assembled Supramolecular Host Encapsulates Hydrophobic Guests" Tetrahedron 2008, 64, 8362-8367.