Cambridge Isotope Laboratories, Inc. www.isotope.com NMR SOLVENTS Deuterated Solvents for NMR • NMR Solvents • NMR Reference Standards • NMR Tubes CambridgeCambridge Isotope Isotope Laboratories, Laboratories, Inc. Inc. www.isotope.comwww.isotope.com NMR Solvents TABLE OF CONTENTS Contact Information.........................1 Shipping Information.......................1 Packaging Information.....................2 NMR Solvents...............................3-16 NMR Tubes.......................................17 NMR Reference Standards.........15,16 NMR Solvent Technical Tips............19 NMR Solvents Data Chart.........20, 21 Chemical Shifts of Solvents............22 tel: 978-749-8000 800-322-1174 (USA) fax: 978-749-2768 [email protected] Cambridge Isotope Laboratories, Inc. www.isotope.com CONTACT INFORMATION CONTACT CIL BY PHONE, FAX OR E-MAIL The CIL Customer Service Department is open Monday-Thursday 8:00 A.M. to 5:30 P.M.; Friday 8:00 A.M. to 5:00 P.M EST. Phone Fax E-mail 1-800-322-1174 (USA) 1-978-749-2768 [email protected] (North America) 1-800-643-7239 (Canada) [email protected] (International) 1-978-749-8000 (International) [email protected] (Environmental Products) 1-800-322-1174 (Environmental) 1-800-ISOTOPE ( US Regional Sales Manager) CONTACT YOUR REGIONAL SALES MANAGER Please contact your local sales representative to request a quote or discuss long term blanket discount orders. Dialing 1-800-ISOTOPE within the US will automatically put you in touch with your local Sales Manager. You may also visit our Web site at www.isotope.com for a list of Regional Sales Managers and the areas they service. CONTACT YOUR CUSTOMER ACCOUNT COORDINATOR In order to provide our loyal customers with seamless customer service, each Regional Sales Manager has a dedicated Customer Account Coordinator assigned to their territory. Your Customer Account Coordinator is available to process your orders and quote requests as well as to confirm the delivery status of your order. Please contact your local Customer Account Coordinator to request a quote or to place an order. For a listing of Domestic and International Customer Account Coordinators and the areas they service, please visit our Web site at www.isotope.com. CONTACT YOUR INTERNATIONAL DISTRIBUTOR In order to provide our international customers with the best service possible, CIL has an established network of independent international distributors. Most of our distributors have worked with CIL for more than ten years. To request a quotation or place an order, please contact your local distributor noted on back cover. Our International Customer Service Department is also available to assist you. SHIPPING INFORMATION Shipments within the United States will be sent via UPS, Federal Express, or truck. Canadian shipments will be sent via Federal Express or truck. • International shipments of non-hazardous materials will be sent via Federal Express or best method. • Hazardous materials will be shipped by air freight, surface vessel or Federal Express where applicable. CIL tries to be as cost effective as possible, but the carrier may place additional charges. • Hazardous substances are identified with the appropriate UN number and transported in compliance with UN recommendations. • We will oblige your shipping instructions whenever it is feasible to do so. CIL reserves the right to change the method of transportation if required to comply with transportation regulations. Such a change would not alter your responsibility for payment of shipping charges. Additional shipping charges may apply. tel: 978-749-8000 800-322-1174 (USA) fax: 978-749-2768 [email protected] 2 Cambridge Isotope Laboratories, Inc. www.isotope.com unit CATALOG LISTINGS INCLUDE New Indicator: NEW Alternative Name Formula Molecular Weight * Compound Name Enrichment Density Unit Dimethyl Sulfoxide-d6 (D,99.9%) (contains 0.05% v/v TMS) (DMSO) CIL Catalog # mw 84.17 DLM-10tb CD3SOCD3 10x0.6 mL CAS # [2206-27-1] d 1.18 10x0.75 mL NMR Solvents 10x1 g 3x(10x1 g) Additional Information 5 g 10 g 10x10 g UN# Hazard Class Storage Information** Structure Shipping Restrictions 3x(10x10 g) 25 g 50 g * Molecular weight is based on 100% enrichment ** Stable if stored under normal conditions, unless other wise noted OUR LABELS INCLUDE Cambridge Isotope • Product name and description Laboratories, Inc. • Health and safety information 50 Frontage Road Andover, MA 01810 USA • Lot specific number 978-749-8000 • Package size DIMETHYL SULFOXIDE-D6 10 X 0.75MILLILITERS • Pictograms for hazard recognition (D, 99.9%) DLM-10-10X0.75 CAS 2206-27-1 LOT# 9C-999 • CAS numbers Irritant. Combustible. Hygroscopic. Maybe harmful if inhaled, • Storage information swallowed, or absorbed through skin. • Packaging number Store at room temperature away from light and moisture. • Catalog number For research use only - not for diagnostic purposes TECH INFO: Each batch of CIL solvent is routinely tested for chemical and HAzARDoUS ICoNS isotopic purity after initial purification, before packaging, and after packaging. Biohazard Corrosive Environmental Explosive Flammable Harmful Irritant Oxidizing Toxic Danger Compounds listed in this catalog are considered non-hazardous unless otherwise noted. 3 tel: 978-749-8000 800-322-1174 (USA) fax: 978-749-2768 [email protected] Cambridge Isotope Laboratories, Inc. www.isotope.com unit Acetic Acid-d4 (D,99.5%) mw 64.08 DLM-12 CD3COOD 10 g [1186-52-3] d 1.12 25 g UN# 2789 50 g Acetic Acid-d4 “100%” (D,99.93%) mw 64.08 DLM-41 CD3COOD 10x0.75 mL [1186-52-3] d 1.12 5 mL UN# 2789 NMR Solvents Acetone-d6 (D,99.9%) mw 64.12 DLM-9 CD3COCD3 10x0.6 mL [666-52-4] d 0.87 10x0.75 mL UN# 1090 5x3 mL 1 L 10x1 g 3x(10x1 g) 10 g 10x10 g 3x(10x10 g) 25 g Acetone-d6 (D,99.9%) (contains 1% v/v TMS) mw 64.12 DLM-9ta CD3COCD3 10x1 g [666-52-4] d 0.87 3x(10x1 g) UN# 1090 10 g 10x10 g 3x(10x10 g) 25 g Acetone-d6 (D,99.9%) (contains 0.05% v/v TMS) mw 64.12 DLM-9tb CD3COCD3 10x1 g [666-52-4] d 0.87 3x(10x1 g) UN# 1090 10 g 10x10 g 3x(10x10 g) 25 g Acetone-d6 “100%” (D,99.96%) mw 64.12 DLM-38 CD3COCD3 5x0.5 mL [666-52-4] d 0.87 10x0.5 mL UN# 1090 10x0.6 mL 5x0.75 mL 10x0.75 mL 5 mL Acetone-d6 “100%” (D,99.96%) (contains 0.03% v/v TMS) mw 64.12 DLM-38tc CD3COCD3 10x0.75 mL [666-52-4] d 0.87 UN# 1090 Acetonitrile-d3 HPLC grade (D,96-97%) (contains approximately 15-20% D O) mw 44.07 DLM-20 2 CD3C≡N 1 L [2206-26-0] d 0.84 UN# 1648 tel: 978-749-8000 800-322-1174 (USA) fax: 978-749-2768 [email protected] 4 Cambridge Isotope Laboratories, Inc. www.isotope.com unit Acetonitrile-d3 (D,96-97%) mw 44.07 DLM-22 CD3C≡N 1 L [2206-26-0] d 0.84 UN# 1648 Acetonitrile-d3 (D,99.8%) mw 44.07 DLM-21 CD3C≡N 10x0.6 mL [2206-26-0] d 0.84 10x0.75 mL UN# 1648 1 L 10x1 g 3x(10x1 g) NMR Solvents 10 g 25 g 50 g Acetonitrile-d3 (D,99.8%) (contains 0.05% v/v TMS) mw 44.07 DLM-21tb CD3C≡N 10x0.6 mL [2206-26-0] d 0.84 UN# 1648 Acetonitrile-d3 “100%” (D,99.96%) mw 44.07 DLM-53 CD3C≡N 10x0.5 mL [2206-26-0] d 0.84 10x0.6 mL UN# 1648 5x0.75 mL 10x0.75 mL 5 mL Benzene-d6 (D,99.5%) mw 84.15 DLM-1 C6D6 10x0.6 mL [1076-43-3] d 0.95 10x0.75 mL UN# 1114 10x1 g 3x(10x1 g) 5 g 10 g 10x10 g 25 g 50 g 100 g Benzene-d6 (D,99.5%) (contains 0.05% v/v TMS) mw 84.15 DLM-1tb C6D6 10x0.6 mL [1076-43-3] d 0.95 NEW 10 g UN# 1114 Benzene-d6 “100%” (D,99.96%) mw 84.15 DLM-40 C6D6 5x0.5 mL [1076-43-3] d 0.95 10x0.5 mL UN# 1114 5x0.75 mL NEW 10x0.6 10x0.75 mL 5 mL Benzene-d6 “100%” (D,99.96%) (contains 0.03% v/v TMS) mw 84.15 DLM-40tc C6D6 10x0.75 mL [1076-43-3] d 1.52 UN# 1114 5 tel: 978-749-8000 800-322-1174 (USA) fax: 978-749-2768 [email protected] Cambridge Isotope Laboratories, Inc. www.isotope.com unit Bromobenzene-d5 (D,99%) mw 162.04 DLM-398 C6D5Br 5 g [4165-57-5] d 1.52 10 g UN# 2514 25 g Chlorobenzene-d5 (D,99%) mw 117.59 DLM-263 C6D5Cl 1 g [3114-55-4] d 1.16 5 g UN# 1134 NMR Solvents Chloroform-d (D,99.8%) No stabilizers are used in this product. mw 120.38 DLM-7 CDCl3 10x0.6 mL [865-49-6] d 1.50 10x0.75 mL UN# 1888 10x1 g 3x(10x1 g) 50 g 100 g 10x100 g 3x(10x100 g) Chloroform-d (D,99.8% stabilized with silver foil) mw 120.38 DLM-7-50S CDCl3 50 g DLM-7-100S d 1.50 100 g [865-49-6] Chloroform-d (D,99.8%) (contains 1% v/v TMS) No stabilizers are used in this product. mw 120.38 DLM-7ta CDCl3 10x1 g [865-49-6] d 1.50 3x(10x1 g) UN# 1888 50 g 100 g 10x100 g 3x(10x100 g) Chloroform-d (D,99.8%) (contains 0.05% v/v TMS) No stabilizers are used in this product. mw 120.38 DLM-7tb CDCl3 10x1 g [865-49-6] d 1.50 3x(10x1 g) UN# 1888 50 g 100 g 10x100 g 3x(10x100 g) Chloroform-d “100%” (D,99.96%) No stabilizers are used in this product.