SAFETY DATA SHEET Revision Date 10-Feb-2021 Revision Number 2 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Description: Cadmium selenide Cat No. : 11057 CAS-No 1306-24-7 Molecular Formula CdSe 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Thermo Fisher (Kandel) GmbH . Erlenbachweg 2 76870 Kandel Germany Tel: +49 (0) 721 84007 280 Fax: +49 (0) 721 84007 300 E-mail address [email protected] www.alfa.com Product safety Tel + +049 (0) 7275 988687-0 1.4. Emergency telephone number Carechem 24: +44 (0) 1235 239 670 (Multi-language emergency number) Poison Information Center Mainz www.giftinfo.uni-mainz.de Telephone: +49(0)6131/19240 Exclusively for customers in Austria: Poison Information Center (VIZ) Emergency call 0-24 clock: +43 1 406 43 43 Office hours: Monday to Friday, 8am to 4pm, tel: +43 1 406 68 98 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Based on available data, the classification criteria are not met ______________________________________________________________________________________________ ALFAA11057 Page 1 / 11 SAFETY DATA SHEET Cadmium selenide Revision Date 10-Feb-2021 ______________________________________________________________________________________________ Health hazards Acute oral toxicity Category 3 (H301) Acute Inhalation Toxicity - Dusts and Mists Category 3 (H331) Specific target organ toxicity - (repeated exposure) Category 2 (H373) Environmental hazards Acute aquatic toxicity Category 1 (H400) Chronic aquatic toxicity Category 1 (H410) Full text of Hazard Statements: see section 16 2.2. Label elements Signal Word Danger Hazard Statements H373 - May cause damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects H301 + H331 - Toxic if swallowed or if inhaled Precautionary Statements P264 - Wash face, hands and any exposed skin thoroughly after handling P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P311 - Call a POISON CENTER or doctor/physician P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P260 - Do not breathe dust/fume/gas/mist/vapors/spray 2.3. Other hazards Toxic to terrestrial vertebrates SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No 1272/2008 Cadmium selenide 1306-24-7 EEC No. 215-148-3 <=100 Acute Tox. 3 (H301) Acute Tox. 3 (H331) STOT RE 2 (H373) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) ______________________________________________________________________________________________ ALFAA11057 Page 2 / 11 SAFETY DATA SHEET Cadmium selenide Revision Date 10-Feb-2021 ______________________________________________________________________________________________ Component Concentration limits M-Factor Component notes Cadmium selenide - 10 (acute) Note 1 1 (Chronic) Note Note 1: The concentration stated or, in the absence of such concentrations, the generic concentrations of this Regulation (Table 3.1) or the generic concentrations of Directive 1999/45/EC (Table 3.2), are the percentages by weight of the metallic element calculated with reference to the total weight of the mixture Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. Eye Contact In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required. Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately. Inhalation Remove to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed None reasonably foreseeable. 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Not combustible. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture Do not allow run-off from fire-fighting to enter drains or water courses. ______________________________________________________________________________________________ ALFAA11057 Page 3 / 11 SAFETY DATA SHEET Cadmium selenide Revision Date 10-Feb-2021 ______________________________________________________________________________________________ Hazardous Combustion Products Selenium oxide, Hydrogen selenide, Cadmium oxide. 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Should not be released into the environment. 6.3. Methods and material for containment and cleaning up Sweep up and shovel into suitable containers for disposal. Avoid dust formation. 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid dust formation. Use only under a chemical fume hood. Do not breathe (dust, vapor, mist, gas). Do not ingest. If swallowed then seek immediate medical assistance. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work. 7.2. Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. Technical Rules for Hazardous Substances (TRGS) 510 Storage Class (LGK) Storage Class/LGK 6.1D (Germany) 7.3. Specific end use(s) Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters ______________________________________________________________________________________________ ALFAA11057 Page 4 / 11 SAFETY DATA SHEET Cadmium selenide Revision Date 10-Feb-2021 ______________________________________________________________________________________________ Exposure limits List source(s): UK - EH40/2005 Work Exposure Limits, Third edition. Published 2018. Component European Union The United Kingdom France Belgium Spain Cadmium selenide STEL: 0.075 mg/m3 15 TWA / VME: 0.004 TWA / VLA-ED: 0.01 min mg/m3 (8 heures). mg/m3 (8 horas) TWA: 0.025 mg/m3 8 hr indicative limit TWA / VLA-ED: 0.002 STEL: 0.3 mg/m3 15 min mg/m3 (8 horas) TWA / TWA: 0.1 mg/m3 8 hr VLA-ED: 0.1 mg/m3 (8 horas) Component Italy Germany Portugal The Netherlands Finland Cadmium selenide TWA: 0.05 mg/m3 (8 TWA: 0.002 mg/m3 8 Stunden). AGW - horas TWA: 0.2 mg/m3 8 exposure factor 1 horas TWA: 0.001 TWA: 0.02 mg/m3 (8 mg/m3 8 horas Stunden). MAK TWA: 0.004 mg/m3 8 Höhepunkt: 0.16 mg/m3 horas Haut Component Austria Denmark Switzerland Poland Norway Cadmium selenide MAK-KZW: 0.3 mg/m3 Haut/Peau TWA: 0.05 mg/m3 8 15 Minuten STEL: 0.16 mg/m3 15 timer MAK-TMW: 0.1 mg/m3 8 Minuten Stunden TWA: 0.015 mg/m3 8 Stunden TWA: 0.004 mg/m3 8 Stunden TWA: 0.02 mg/m3 8 Stunden Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust MDHS10/2 Cadmium and inorganic compounds of cadmium in air Laboratory method using flame atomic absorption spectrometry