WOBELEA PTY LTD T/AS YM-FAB POST HARVEST CHEMICALS 18 EMBREY COURT, PAKENHAM VICTORIA 3810 PH: 61 3 5940 1077 FAX: 61 3 5940 2599 EMAIL: [email protected] ABN: 60 005 363 833 SAFETY DATA SHEET - YM-FAB NYLATE Issue Date: 4/11/2016 Version No: 1 .1 Reviewed 08/02/2017 Safety Data Sheet according to WHS and ADG requirements Revision 3/11/2021 SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name YM-FAB NYLATE, YM-FAB NYLATE G980, YMFAB NYLATE P, YMFAB ANYLATE P Chemical Name 3-bromo-1-chloro-5,5-dimethylhydantoin Proper shipping name OXIDIZING SOLID, CORROSIVE N.O.S. (contains 3-bromo-1-chloro-5,5-dimethylhydantoin) Chemical formula C5-H6-Br-Cl-N2-O2 Other means of YM-FAB NYLATE, BROMINE identification CAS number 126-06-7 OR 32718-18-6 Recommended Use: A microbiological disinfectant for cooling towers, irrigation lines, and cut flower holding water. For control of plant and human pathogens in wash water for fruit and vegetables in recirculated or single pass systems. Details of the supplier of the safety data sheet Registered company WOBELEA PT LTD YMFAB CHEMICALS LIMITED name Address 18 Embrey Court, Pakenham Vic 3810 C/- Level 2, 123 Carlton Gore Road, Newmarket Auckland 1023 NZ Telephone 03 5940 1077 61 + 3 5940 1077 or New Zealand on 09 571 0712 Fax 03 5940 2599 61 + 3 5940 2599 Website www.nylate.com.au www.nylate.com.au Email [email protected] Emergency telephone number Association / Poisons Information Centre Organisation Emergency telephone 131126 – Poisons Information Australia. numbers Other emergency 0800 764 766 - Poisons Information New Zealand telephone numbers WOBELEA EMERGENCY RESPONSE Primary Number Alternative Number 1 Alternative Number 2 03 5997 1690 AH 61 + 0427 367 561 Not Available Continued... Page 2 of 18 Version No: 1 Issue Date: 04/11/2016 3-BROMO-1-CHLORO-5,5-DIMETHYLHYDANTOIN – YM-FAB NYLATE SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations, ADG Code and GHS system. WOBELEA HAZARD RATINGS Min Max 0 = Minimum 1 = Low 2 = Moderate 3 = High Chronic 0 4 = Extreme NFPA Ratings (Scale 0-4) Health = 3, Fire = 0, Reactivity = 1, Special Hazard Warning: OXIDIZER Hazard Classification – New Zealand 5.1.1B, 6.1B, 6.5B, 8.2C, 8.3A, 9.1A, 9.3C Approved Handler and Tracking Apply. This product must be under the personal control of an approved handler or secured location and movement of this product must be recorded at each stage of its life cycle. Poisons Schedule 6 Oxidizing Solid Category 2, Metal Corrosion Category 1, Acute Toxicity (Oral) Category 4, Acute Toxicity (Dermal) Category [2] Classification 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 1A, Serious Eye Damage Category 1, Acute Aquatic Hazard Category 1 1. Classification from Wobelea Pty Ltd, 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive Legend: 1272/2008 - Annex VI Label elements Hazard statement(s) H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H401 Toxic to aquatic life Supplementary statement(s) Not Applicable Precautionary statement(s) Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from other combustible chemicals and other combustible organic materials, organic and inorganic compounds, fertilizers and other pesticides. P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment P220 Take all precaution to keep/store away and avoid mixing with all chemicals in P210. Precautionary statement(s) Response P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370 & P378 In case of fire use water, dry powder or carbon dioxide. Continued... Page 3 of 18 Issue Date: 04/11/2016 Version No: 1 3-BROMO-1-CHLORO-5,5-DIMETHYLHYDANTOIN – YM-FAB NYLATE IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue P305+P351+P338 rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P363 Wash contaminated clothing before reuse P304 & P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P321 Specific treatment (see First Aid Measures on Safety Data Sheet). Precautionary statement(s) Storage P405 Store locked up. Precautionary statement(s) Disposal P501 National Transport Commission (Australia) - Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code) Dangerous Goods Classification – Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code) AND "New Zealand NZS5433: Transport of Dangerous Goods on Land". SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances CAS No %[weight] Name 126-06-7 >98 3-bromo-1-chloro-5,5-dimethylhydantoin may contain 16079-88-2 1-bromo-3-chloro-5,5-dimethylhydantoin decomposes on contact with water to produce 7790-92-3 hypochlorous acid 13517-11-8 hypobromous acid 7782-50-5 chlorine 7726-95-6 bromine Mixtures See section above for composition of Substances Substances MAY BE MADE UP OF:- CAS No % weight Name 32718-18-6 >98 Bromo-chloro-5, 5 dimethyl hydantoin Continued... Page 4 of 18 Version No: 1 Issue Date: 04/11/2016 3-BROMO-1-CHLORO-5,5-DIMETHYLHYDANTOIN – YM-FAB NYLATE SECTION 4 FIRST AID MEASURES Description of first aid measures If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally Eye Contact lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 20 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Quickly remove all contaminated clothing, including footwear. Skin Contact Immediately flush body and clothes with large amounts of water, using safety shower if available for at least 15-20 minutes. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. TransportIf fumes or to combustion hospital, or productsdoctor. are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor. Inhalation Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested. Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered. This must definitely be left to a doctor or person authorised by him/her. (ICSC13719) For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and Ingestion prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay. Indication of any immediate medical attention and special treatment needed First Aid Facilities: an eye wash fountain, safety shower and a general washing facility should be available immediately adjacent to the work area. Excellent warning properties force rapid escape of personnel from chlorine vapour thus most inhalations are mild to moderate. If escape is not possible, Continued... Page 5 of 18 Version No: 1 Issue Date: 04/11/2016 3-BROMO-1-CHLORO-5,5-DIMETHYLHYDANTOIN – YM-FAB NYLATE exposure to high concentrations for a very short time can result in dyspnea, haemophysis and cyanosis with later complications being tracheobroncho- pneumonitis and pulmonary oedema. Oxygen, intermittent positive pressure breathing apparatus and aerosolysed bronchodilators are of therapeutic value where chlorine inhalation has been light to moderate. Severe inhalation should result in hospitalisation and treatment for a respiratory emergency. Any chlorine inhalation in an individual with compromised pulmonary function (COPD) should be regarded as a severe inhalation and a respiratory emergency. [CCINFO, Dow 1988] Effects from exposure to chlorine gas include pulmonary oedema which may be delayed. Observation in hospital for 48 hours is recommended Diagnosed asthmatics and those people suffering from certain types of chronic bronchitis should receive medical approval before being employed in occupations involving chlorine exposure. If burn is present, treat as any thermal burn, after decontamination. For acute or short term repeated exposures to strong acids: Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially. Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.