sigma-aldrich.com 595 North Harrison Road, Bellefonte, PA 16823-0048 USA Tel: (800) 247-6628 (814) 359-3441 Fax: (800) 447-3044 (814) 359-3044 Bulletin 925F SPME Applications Guide The SPME Applications Guide is a bibliographic resource of published technical articles about solid phase microextraction. With the continued growth of SPME, and its expansion into environmental, food, forensic, and other fields, we recognize the need for an organized bibliography. This guide should serve a useful purpose in your SPME research and analyses. This guide is for general information only. We have made every attempt to make the information as complete and accurate as possible. Where entries are missing, information was not available at the time of printing. NOTE: Because of copyright restrictions, Supelco cannot provide copies of the articles listed. If you desire copies, please refer to the publications cited. Using This Guide This guide is organized in an easy-to-use format. The references are Table of Contents grouped into application areas (see the Table of Contents) with the Application Area new references placed at the end of each area in bold. The Analyte/ Matrix column identifies the class of analytes and the sample matrix. Books .................................................................... 2 The Literature Reference column provides the title of the article, Foods, Flavors & Fragrances ..................................... 2 journal reference, and authors. The next column describes the SPME fiber and conditions used in the sample extraction. The last column Polymers and Coatings .......................................... 65 indicates the instrument used in the analysis. Natural Products .................................................... 69 Pharmaceuticals .................................................... 87 Key to Abbreviations Biological Matrices ................................................. 90 Abbrev. Description Toxicology ........................................................... 104 AED atomic emission detection Forensics ............................................................. 122 DVB divinylbenzene Environmental ..................................................... 129 ECD electron capture detection FID flame ionization detection Water .......................................................... 134 FPD flame photometric detection Pesticides ..................................................... 176 FTD flame thermonic detection Soil .............................................................. 187 GC gas chromatography HPLC high pressure liquid chromatography Air ............................................................... 195 ICP inductive coupled plasma Theory and Technique ......................................... 202 MS mass spectrometry Supelco SPME Literature ...................................... 221 MSD mass selective detection NPD nitrogen/phosphorus detection SPME Products .................................................... 222 PAD photodiode-array detection PDMS polydimethylsiloxane PICI positive ion chemical ionization SIM selective ion monitoring TCD thermionic-selective detection TED thermal energy detection VIS visible spectrophotometry sigma-aldrich.com SPME Application Guide 7th Edition (New references added to the 7th edition are in bold) SPME Fiber / Analyte / Extraction Matrix Literature Reference Conditions Instrument Books Techniques for Analyzing Food Aroma, Supelco Cat. # 26589-U Marcel Decker ISBN: 0-8247-9788-4, Marsili, R. Solid Phase Microextraction: A Practical Guide Supelco Cat. # 26610-U Edited by SueAnn Scheppers Wercinski Marcel Decker 15BN: 0-8247-7058-7 Solid Phase Microextraction: Theory and Practice Supelco Cat. # 26591-U Edited by Janusz Pawliszyn VCH, New York, 275pp (1997) Applications of Solid Phase Microextraction Supelco Cat. # 26611-U Edited by Janusz Pawliszyn RSC Chromatography Monographs ISBN 0-85404-525-2 Royal Society of Chemistry 1999 Applied SPME, 1999, 364-371 Royal Society of Chemistry, Cambridge, UK Coden: 67TUA8 Talon, R, Montel, M. Foods, Flavors, & Fragrances 601 Aroma compounds Developments in extraction techniques and their Review article GC in food application to analysis of volatiles in foods Trends-Anal-Chem, May 2000, 19(5), 322-329 Sides, S., Robards, K., Helliwell, S. 602 Contaminants Application of SPME in Food Analysis Review article GC, LC, MS in Food J. Chromatogr. A (2000), 880(1+2), 35-62 Kataok, H., Lord, H., Pawliszyn, J. 2593 PAHs in Use of headspace SPME coupled to LC for the analysis of PAHs 60µM PDMS/DVB LC-fluorimetric tea infusion in tea infusions 60 min @ 90 °C J Chromatogr A 1164, #1-2, 10-17 (2007) headspace Vinas, P.; Campillo, N.; Aguinaga, N.; Perez-Canovas, E.; Hernandez-Cordoba, M. 784 Catechins, cafeine Automated in-tube solid phase microextraction coupled polypyrrole capillary LC-ES-MS in tes with HPLC-ES-MS for the determination of catechins and caffeine in tea Analyst (Cambridge, U. K.) (2000) 125(12), 2216-2222 Wu, J. C.; Xie, W.; Pawliszyn, J. 2557 Sorbic, benzoic Simultaneous determination of sorbic and benzoic acids in food 85µm polyacrylate GC-FID acids in food dressing by headspace SPME and gas chromatography headspace dressing J. Chromatogr., A 1117, #1, 109-114 (2006-06-02) Dong, C. Z.; Mei, Y.; Chen, L. 2199 Sorbic, benzoic Headspace SPME applied to the simultaneous determination of 65µm PDMS-DVB GC-FID acids in sorbic and benzoic acids in beverages headspace beverages Anal. Chim. Acta (2006) 562. #1, 23-29 Dong, Chunzhou; Wang, Wenfang 834 Caffeine Caffeine determination in beverages by SPME and GC-MS in beverages Ind. Bevande (2000) 29(170) 595-597, 605 Guidotti, Maurizio; Panzironi, Laura 8 Caffeine and flavors Solventless Determination of Caffeine in uncoated fiber GC-MS in coffee/tea/cola Beverages Using SPME with Fused Silica Fibers 5 min J. Chromatogr. 603: 185-191 (1992) Hawthorne, S., Miller, D., Arthur, C., Pawliszyn, J. 2461 Phthalic acid esters Headspace SPME of phthalic acid esters from vegetable oil 100µm PDMS GC/ECD Ambient temperature, unless otherwise indicated. 2 in vegetable oil employing solvent based matrix modification headspace Anal. Chim. Acta 582, #1,24-33 (1-16-2007) Holadova, K.; Prokupkova, G.; Hajslova, J.; Poustka, Jan 2751 Volatiles from free Headspace-(HS-SPME) analysis of oxidized volatiles from free headspace GC Fatty acids fatty acids (FFA) and application for measuring hydrogen donating antioxidant activity FOOD CHEM. 105, #1, 414-420 (2007) JaeMin Lee; Dong-Hwan Kim; Pahn-Shick Chang; JaeHwan Lee 2875 Alcohol Reaction design for evaluation of the substrate range of hydrolases headspace GC-MS hydrolases Biocatalysis and Biotransformation 26, #3, 228-234 (2008) Antoniotti, Sylvain; Fernandez, Xavier; Dunach, Elisabet 2471 Fatty acids Physicochemical and volatiles characterization of trans-free solid headspace GC in solid fats fats produced by lipase-catalyzed interesterification. J Food Sci 72, #6, E368-74 (2007 Aug) Lee, J H; Akoh, C C; Lee, K-T 2209 Volatiles in Identification of volatile degradants in formulations containing sesame headspace GC-MS Sesame oil oil using SPME/GC/MS J. PHARM. BIOMED. ANAL. 44, #2, 450-455 (28 JUN 2007) Chen, W.; Zhou, P.; Wong-Moon, K. C.; Cauchon, N. S. 2671 Off-flavours SPME-GC and sensors as rapid methods for monitoring headspace GC-FID in nuts lipid oxidation in nuts. Food Additives and Contaminants 24, #11, 1219-1225 (2007) Pastorelli, S; Torri, L; Rodriguez, A; Valzacchi, S; Limbo, S; Simoneau, C. 2726 Flavors in Endogenous biophenol, fatty acid and volatile profiles of selected oils headspace GC camellia oil FOOD CHEM. 100, #4, 1544-1551 (2007) Haiyan, Z.; Bedgood, Jr D. R.; Bishop, A. G.; Prenzler, P. D.; Robards, K. 2275 Flavors in Sensory evaluation of butterfat-vegetable oil blend spread prepared headspace canola oil and with structured lipid containing canola oil and caprylic acid caprylic acid J Food Science 70 #7, S406-S412 (2005) Kim, B.; Shewfelt, Robert L.; Lee, Hyoungil; Akoh, Casimir C. 2158 Volatile oxidative Evaluation of oxidative stability of canola oils by headspace analysis headspace GC products of JAOC, 82, #12, 869-874 (2005) canola oil Richards, Amy; Wijesundera, Chakra; Salisbury, Phil 2157 Volatile flavors Sensory and oxidative quality of screw-pressed flaxseed oil headspace GC in flaxseed oil JAOC, 82, #12, 887-892 (2005) Wiesenborn, D.; Kangas, N.; Tostenson, K.; Hall, C.; Chang, K. 2305 Volatiles in Analysis of volatile compounds and triglycerides of seed oils DVB/Car 50/30µm GC/MS Poppy seed oil extracted from different poppy varieties (Papaver somniferum L.) headspace J Ag Food Chem 53, #21, 8310-8316 (2005) Krist, S.; Stuebiger, G.; Unterweger, H.; Bandion, F.; Buchbauer, G. 2693 Hexanal & pentane A headspace SPME method of use in monitoring hexanal and pentane headspace GC/MS in liquid during storage: Applications to liquid infant foods and powdered infant foods infant formulas. Food Chem. 101, #3, 1078-1086 (2007) Garcia-Llatas, G.; Lagarda, M. J.; Romero, F.; Abellan, P.; Farre, R. 32 Flavors in Solid Phase Microextraction for Flavor Analysis 100µm PDMS GC/GC-MS coffee/fruit juice/ J. Agric. Food Chem, 42: 1925-1930 (1994) 10 min vegetable oil Peppard, T., Yang, X. 603 Volatiles Analysis of volatile contaminants in vegetable oils by 75µm Carboxen/PDMS GC-MS in vegetable oil headspace SPME with Carboxen-based fibers. 30-45 min @ 100°C J. Chromatogr. 873 (2000): 79-94 headspace Page, B., Lacroix, G. 39 Halogenated volatiles Application of SPME to the Headspace GC Analysis of GC in food Halogenated