Mineralization Halos and Diagenesis in Water-Laid Tuff of the Thomas Range, Utah GEOLOGICAL SURVEY PROFESSIONAL PAPER 818-B Mineralization Halos and Diagenesis in Water-Laid Tuff of the Thomas Range, Utah By DAVID A. LINDSEY BERYLLIUM-BEARING TUFFS IN WESTERN UTAH GEOLOGICAL SURVEY PROFESSIONAL PAPER 818-B A statistical study of the petrogenesis of water-laid tuff adjacent to the Spar Mountain beryllium and fluorspar district UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON: 1975 UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY V. E. McKelvey, Director Library of Congress Cataloging in Publication Data Lindsey, David A. Mineralization halos and diagenesis in water-laid tuff of the Thomas Range, Utah. (Beryllium-bearing tuffs in western Utah) (Geological Survey Professional Paper 818-B) Bibliography: p. Supt. of Docs. no.: I 19.16:818-B 1. Volcanic ash, tuff, etc.-Utah-Thomas Range. 2. Ore-deposits-Utah-Thomas Range. 3. Diagenesis-Utah-Thomas Range. I. Title. II. Series. III. Series: United States Geological Survey Professional Paper 818-B. QE46l.L624 552'.2 75-619026 For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 Stock Number 024-001-02706-2 CONTENTS Page Page Abstract ______________________________ _ B1 Petrogenesis ____ ------------------------ B12 Introduction ___________________________ _ 1 Problems in petrogenetic interpretation _ _ _ _ _ _ _ _ _ _ 12 Geographic and geologic setting ________________ _ 3 A petrogenetic model -------------------- 12 Methods of study _____ -------------------- 3 R-mode factor analysis ____ _ _ ____ ___ _ _ __ _ _ 13 Sampling plan ____ -----------________ _ 3 Factor analysis of water-laid tuff data _ _ _ _ _ _ _ _ _ _ 13 Laboratory procedure -----------________ _ 3 Interpretation of stratigraphic and geographic anomalies 16 Composition of the water-laid tuff ______________ _ 5 Conclusions _____ ------------------------ 17 Lithology and petrography ----------------- 5 Mineralization halos _ -------------------- 17 Abundance of mineral and chemical components ___ _ 7 Sources of variation ____________________ _ 9 Diagenesis ___ ------------------------ 17 Geographic variation ________ -~-- ________ _ 11 References cited ________________ ---------- 18 ILLUSTRATIONS Page FIGURE 1. Map showing location of the Thomas Range study area and mineral occurrences in the western Utah beryllium ~h----------------------------------------------------------B2 2. Map showing geographic features, distribution of beryllium, fluorspar, and uranium deposits, and distribution of water-laid tuff in the southern part of the Thomas Range -------------------------- 4 3. Photographs of water-laid tuff of the younger volcanic rocks _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 6 4. Map and sections showing classification of water-laid tuff into vitric, zeolitic, and feldspathic facies _ _ _ _ _ 9 5-12. Histograms showing frequency distribution and maps showing mean values at each collection station in water- laid tuff in the Thomas Range for the following: 5. Bulk density ____________________________________ ~ _ _ _ _ _ _ _ _ _ _ _ 23 6. Powder density _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 24 7. Porosity __ ---------------------------------------_________ 25 8. Clinoptilolite content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 26 9. Quartz content -------------------------------------_________ 27 10. a-cristobalite content___________________________________________ 28 11. Potassium feldspar content ----------____ -------------____________ 29 12. Glass content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 30 13. Map showing occurrence of calcite in water-laid tuff in the Thomas Range _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 31 14. Map showing occurrence of fluorite and halite in water-laid tuff of the Thomas Range _ _ _ _ _ _ _ _ _ _ _ _ _ 32 15-40. Histograms showing frequency distribution and maps showing mean values at each collection station in water- laid tuff in the Thomas Range for the following: 15. Silica content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 33 16. Alumina content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 34 17. Total iron content (as Fe20a) -------------------------------------- 35 18. Magnesium oxide content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 36 19. Calcium oxide content------------------------------------------ 37 20. Sodium oxide content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 38 21. Potassium oxide content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 39 22. Carbon dioxide content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 40 23. Water-soluble chlorine content ------------------------------------- 41 24. Fluorine content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 42 25. Cesium content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 43 26. Lithium content __ ------------------------------------------- 44 27. Rubidium content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 45 28. Equivalent uranium content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 46 29. Barium content ---------------------------________ ----------- 47 30. Beryllium content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 48 31. Chromium content ---------------------________ ____ _______ ____ 49 III IV FIGURE 15-40. Histograms and maps - Continued. Page 32. Gallium content ___________________________________________ --- B50 33. Lanthanum content -------------------------------________ ---- 51 34. Manganese content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 52 35. Niobium content -----------------------------------------____ 53 36. Strontium content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 54 37. Titanium content _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 55 38. Vanadium C·)ntent _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 56 39. Yttrium content ___________ --------------_____________________ 57 40. Zirconium content ____ __________ _____ ______ ___ __________ __ _ ___ 58 41. Graph showing eigenvalues and cumulative proportion of total variance explained by the first 10 principal com- pon~~ ------------------------------------------------------- ~ TABLES Page TABLE 1. Stratigraphic section in the southern part of the Thomas Range and Spor Mountain _ _ _ _ _ _ _ _ _ _ _ _ _ _ B3 2. Summary statistics for physical properties, mineral composition, and chemical composition of 160 samples of water-laid tuff from the Thomas Range------------------------------------- 7 3.