SPECIMEN LABEL – SPECIMEN LABEL – SPECIMEN LABEL – SPECIMEN LABEL – SPECIMEN LABEL – SPECIMEN 2,4-D QUINCLORAC GROUP 4 HERBICIDE User Safety Recommendations DICAMBA • Users should wash hands thoroughly with soap and water before SULFENTRAZONE GROUP 14 HERBICIDE eating, drinking, chewing gum, using tobacco, or using the toilet. • Users should remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. If pesticide gets on skin, wash immediately with soap and water. • Users should remove PPE immediately after handling this product. Wash the outside of gloves before removing . As soon as possible, wash thoroughly and change into clean clothing. First Aid If in eyes: • Hold eye open and rinse slowly and gently with water for 15-20 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye . • Call a poison control center or doctor for treat- For use in New York State by spot treatment only. ment advice . Not for sale, distribution, or use in Nassau or If swallowed: • Call a poison control center or doctor immedi- Suffolk Counties in New York State. ately for treatment advice . • Have person sip a glass of water if able to swallow. ACTIVE INGREDIENTS: • Do not induce vomiting unless told to do so by a Quinclorac . 8 .43% poison control center or doctor . Sulfentrazone . 0 .69% • Do not give anything by mouth to an uncon- 2,4-D, dimethylamine salt . 11 .81% scious person . Dicamba, dimethylamine salt . 1 .49% OTHER INGREDIENTS: . 77 .58% If on skin or • Take off contaminated clothing . TOTAL 100 .00% on clothing: • Rinse skin immediately with plenty of water for THIS PRODUCT CONTAINS: 15-20 minutes . 0 .75 lb . 3,7-dichloro-8-quinolinecarboxylic acid per gallon or 8 .43% . • Call a poison control center or doctor for treat- 0.06 lb. N-[2,4-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl- ment advice . 5-oxo-1H-1,2,4-triazol-1-yl] phenyl]methanesulfonamide per gallon or 0 .69% . 0 .88 lb . 2,4-dichlorophenoxyacetic acid equivalent per gallon or 9 .81% . Have the product container or label with you when calling a 0 .10 lb . 3,6-dichloro-o-anisic acid equivalent per gallon or 1 .24% . poison control center or doctor or going for treatment . You may Isomer Specific By AOAC Methods. also contact 1-877-800-5556 for emergency medical treatment information . CAS Registry Numbers: Quinclorac (84087-01-4), Sulfentrazone (122836-35-5), Dicamba, dimethylamine salt (2300-66-5), 2,4-D, dimethylamine salt (2008-39-1). Environmental Hazards This pesticide may be toxic to fish and aquatic invertebrates. Do not apply directly to water, to areas where surface water is present, or to KEEP OUT OF REACH OF CHILDREN intertidal areas below the mean high water mark. Drift and runoff may be hazardous to plants, and to aquatic organisms in water adjacent to CAUTION treated areas. Do not contaminate water when disposing of equipment Si Usted no entiende la etiqueta, busque a alguien para que se la wash waters or rinsate. explique a Usted en detalle. (If you do not understand the label, find This chemical has properties and characteristics associated with some one to explain it to you in detail.) chemicals detected in groundwater. The use of this chemical in areas where soils are permeable, particularly where the water table is shallow, may result in groundwater contamination. Application around a cistern or well may result in contamination of drinking water or groundwater. Physical and Chemical Hazards READ THE ENTIRE LABEL FIRST. Combustible. Do not use or store near heat or open flame. OBSERVE ALL PRECAUTIONS AND FOLLOW DIRECTIONS CAREFULLY. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner incon- PRECAUTIONARY STATEMENTS sistent with its labeling. Hazards to Humans and Domestic Animals Do not apply this product in a way that will contact workers or other CAUTION: Causes moderate eye irritation. Avoid contact with eyes or persons, either directly or through drift . Only protected handlers may clothing. Harmful if swallowed. be in the area during application . Personal Protective Equipment (PPE) For any requirements specific to your State or Tribe, consult the All mixers, loaders, applicators, and other handlers must wear*: agency responsible for pesticide regulation . • long-sleeved shirt and long pants, • protective eyewear (such as goggles, face shield, or safety glasses), Agricultural Use Requirements • shoes and socks, Use this product only in accordance with its labeling and with the • chemical-resistant gloves made of barrier laminate, butyl rubber, Worker Protection Standard, 40 CFR part 170. nitrile rubber, neoprene rubber, natural rubber, polyethylene, poly- This standard contains requirements for the protection of agricul- vinyl chloride, or viton (except for applicators using ground boom tural workers on farms, forests, nurseries, and greenhouses, and equipment) and handlers of agricultural pesticides . It contains requirements for • chemical-resistant apron when mixing or loading, cleaning up spills training, decontamination, notification, and emergency assistance. or equipment, or otherwise exposed to the concentrate. It also contains specific instructions and exceptions pertaining to * Applicators may choose not to wear protective eyewear when dilution the statements on this label about personal protective equipment is with water only and dilution rates are greater (higher) than 5:1 or and restricted-entry interval . The requirements in this box only apply greater (higher) than 5 parts of water to 1 part of product. to uses of this product that are covered by the Worker Protection User Safety Requirements Standard . Follow manufacturer’s instructions for cleaning/maintaining PPE. If no Do not enter or allow worker entry into treated areas during the such instructions for washables exist, use detergent and hot water. restricted entry interval (REI) of 48 hours. Keep and wash PPE separately from other laundry. (cont. on next page) – 1 – SPECIMEN LABEL – SPECIMEN LABEL – SPECIMEN LABEL – SPECIMEN LABEL – SPECIMEN LABEL – SPECIMEN Agricultural Use Requirements (cont.) pest control advisor if you are unsure as to which active ingredient is PPE required for early entry to treated areas that is permitted under currently less prone to resistance . the Worker Protection Standard and that involves contact with • Adopt an integrated weed-management program for herbicide anything that has been treated, such as plants, soil, or water is: use that includes scouting and uses historical information related • coveralls worn over short-sleeved shirt and short pants, to herbicide use, and that considers mechanical control methods, • chemical-resistant footwear plus socks, cultural (e.g., timing to favor the turf and not the weeds), biological • chemical-resistant gloves made of any water-proof material and, (weed-competitive varieties) and other management practices. • protective eyewear • Scout area prior to application to identify the weed species present and their growth stage to determine if the intended application will be effective . Non-Agricultural Use Requirements • Scout after herbicide application to monitor weed populations for The requirements in this box apply to uses of this product that early signs of resistance development . Indicators of possible herbi- are NOT within the scope of the Worker Protection Standard for cide resistance include: 1) failure to control a weed species normally agricultural pesticides (40 CFR Part 170). The WPS applies when controlled by the herbicide at the dose applied, especially if control this product is used to produce agricultural plants on farms, forests, is achieved on adjacent weeds; 2) a spreading patch of non-con- nurseries, or greenhouses . trolled plants of a particular weed species; 3) surviving plants mixed Reentry Statement: Do not enter or allow people (or pets) to enter with controlled individuals of the same species. If resistance is the treated area until sprays have dried . suspected, prevent weed seed production in the affected area by an alternative herbicide from a different group or by a mechanical 1. Product Description method. Prevent movement of resistant weed seeds to other areas 4-in-1 Herbicide by cleaning equipment . Q4® Plus Turf Herbicide for Grassy & Broadleaf Weeds contains • If a weed pest population continues to progress after treatment with 4 active ingredients that broaden the spectrum of weed control. this product, discontinue use of this product, and switch to another Q4 Plus Turf Herbicide for Grassy & Broadleaf Weeds is a versatile management strategy or herbicide with a different mode of action, if herbicide that will control many troublesome grassy and broadleaf available . weeds in established turfgrass when used as directed. • Contact your local extension specialist or pest control advisor • Versatile post-emergent herbicide for turfgrass to control both for additional pesticide resistance-management and/or integrated grassy and broadleaf weeds. weed-management recommendations for specific types of turf and • Q4® Plus Turf Herbicide for Grassy & Broadleaf Weeds is absorbed weed biotypes. by foliage and roots and translocated throughout the plant where it • For further information or to report suspected resistance, call uses multiple modes of action to control both grassy and broadleaf 877-800-5556 . weeds. One mode of action involves an auxin-type herbicidal activity which disrupts plant growth in broadleaf weeds, while another mode 4. Where To