Stillwellite-(Ce) (Ce, La, Ca)Bsio

Stillwellite-(Ce) (Ce, La, Ca)Bsio

Stillwellite-(Ce) (Ce; La; Ca)BSiO5 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Hexagonal. Point Group: 3: As °at rhombohedral crystals, to 4 cm, and massive. Twinning: Observed about [100]. Physical Properties: Cleavage: One imperfect. Fracture: Conchoidal. Hardness = 6.5 D(meas.) = 4.57{4.60 D(calc.) = 4.67 » Optical Properties: Transparent to translucent. Color: Red-brown to pale pink; colorless in thin section. Streak: White. Optical Class: Uniaxial (+) to biaxial (+). ! = 1.765{1.784 ² = 1.780{1.787 2V(meas.) = 0±{6± Cell Data: Space Group: P 31: a = 6.841{6.844 c = 6.700{6.702 Z = 3 X-ray Powder Pattern: Mary Kathleen mine, Australia. 3.43 (s), 2.96 (s), 2.13 (ms), 4.44 (m), 1.864 (m), 2.71 (mw), 2.24 (mw) Chemistry: (1) (2) (1) (2) (1) (2) SiO2 22.40 22.06 La2O3 27.95 19.12 MgO 0.06 UO2 0.22 Ce2O3 33.15 30.82 CaO 0.95 0.34 ThO2 5.41 Pr2O3 1.82 F 0.30 + B2O3 12.23 [13.46] Nd2O3 5.36 H2O 0.85 Al2O3 0.42 Sm2O3 0.34 H2O¡ 0.10 Y2O3 0.74 0.28 Fe2O3 0.18 P2O5 0.67 Total [100.00] [99.26] (1) Mary Kathleen mine, Australia; recalculated to 100.00% after removal of very small amounts of uraninite and apatite determined by separate analysis. (2) Vico volcano, near Vetralla, Italy; by electron microprobe, B2O3 calculated from stoichiometry, original total given as 99.23%; corresponds to (Ce0:50La0:31Nd0:08Th0:05Pr0:03Ca0:02Sm0:01)§=1:00B1:02Si0:97O5: Occurrence: Locally abundant as a metasomatic replacement of metamorphosed calcareous sediments (Mary Kathleen mine, Australia); in alkalic pegmatites in syenite in an alkalic massif (Dara-i-Pioz massif, Tajikistan). Association: Allanite, garnet, uraninite (Mary Kathleen mine, Australia); calcite, monazite, bastnÄasite, thorite, uranothorite, thorianite (Desmont mine, Canada); pyrochlore, tienshanite, sogdianite, thorite, cesium kupletskite, reedmergnerite, steacyite, pectolite, quartz (Dara-i-Pioz massif, Tajikistan). Distribution: In the Mary Kathleen mine, about 55 km east of Mt. Isa, Queensland, Australia. At the Desmont mine, near Wilberforce, Ontario, and at Mont Saint-Hilaire, Quebec, Canada. From Mineville, Essex Co., New York, USA. Large crystals in the Dara-i-Pioz massif, Alai Range, Tien Shan, Tajikistan. From the Inagli massif, 30 km west of Aldan, Yakutia, Russia. Found around the Langesundsfjord, Norway. In the Il¶³maussaq intrusion, southern Greenland. At Bassano Romano and on the Vico volcano, near Vetralla, Lazio, Italy. Name: For Dr. Frank Leslie Stillwell (1888{1963), Australian ore mineralogist, and its predominant cerium content. Type Material: National Museum of Natural History, Washington, D.C., USA, 113038. References: (1) McAndrew, J. and T.R. Scott (1955) Stillwellite, a new rare-earth mineral from Queensland. Nature, 176, 509{510. (2) (1956) Amer. Mineral., 41, 370 (abs. ref. 1). (3) Gay, P. (1957) An X-ray investigation of some rare-earth silicates: cerite, lessingite, beckelite, britholite, and stillwellite. Mineral. Mag., 31, 455{468. (4) Dusmatov, V.D., A.F. E¯mov, and Y.I. Semenov (1963) First discoveries of stillwellite in the USSR. Doklady Acad. Nauk SSSR, 153, 913{915 (in Russian). (5) Dusmatov, V.D. (1964) First discovery of stillwellite in USSR. Dokl. Akad. Nauk Tadzh. SSR, 7, 33{35. (6) Callegari, A., G. Giuseppetti, F. Mazzi, and C. Tadini (1992) The re¯nement of the crystal structure of stillwellite: RE[BSiO5]: Neues Jahrb. Mineral., Monatsh., 49{57. (7) Burns, P.C., F.C. Hawthorne, D.J. MacDonald, G.D. Ventura, and G.C. Parodi (1993) The crystal structure of stillwellite. Can. Mineral., 31, 147{152. All rights reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise without the prior written permission of Mineral Data Publishing..

View Full Text

Details

  • File Type
    pdf
  • Upload Time
    -
  • Content Languages
    English
  • Upload User
    Anonymous/Not logged-in
  • File Pages
    1 Page
  • File Size
    -

Download

Channel Download Status
Express Download Enable

Copyright

We respect the copyrights and intellectual property rights of all users. All uploaded documents are either original works of the uploader or authorized works of the rightful owners.

  • Not to be reproduced or distributed without explicit permission.
  • Not used for commercial purposes outside of approved use cases.
  • Not used to infringe on the rights of the original creators.
  • If you believe any content infringes your copyright, please contact us immediately.

Support

For help with questions, suggestions, or problems, please contact us