Common Name: CHROMIC ACID CAS Number: 7738-94-5 DOT Number: NA 1463 (Solid) RTK Substance number: 0429 UN 1755 (Solution) Date: September 1996 Revision: July 2002 ------------------------------------------------------------------------- ------------------------------------------------------------------------- HAZARD SUMMARY * Chromic Acid can affect you when breathed in and by * Exposure to hazardous substances should be routinely passing through your skin. evaluated. This may include collecting personal and area * Chromic Acid should be handled as a CARCINOGEN-- air samples. You can obtain copies of sampling results WITH EXTREME CAUTION. from your employer. You have a legal right to this * Chromic Acid can cause reproductive damage. Handle information under OSHA 1910.1020. with extreme caution. * If you think you are experiencing any work-related health * Chromic Acid is a CORROSIVE CHEMICAL and problems, see a doctor trained to recognize occupational contact can severely irritate and burn the skin and eyes diseases. Take this Fact Sheet with you. with possible eye damage. * Breathing Chromic Acid can irritate the nose, throat and WORKPLACE EXPOSURE LIMITS lungs causing coughing, wheezing and/or shortness of The following exposure limits are for Chromic Acid breath. (measured as Chromium VI): * Chromic Acid can cause a sore and/or hole in the “bone” dividing the inner nose, sometimes with bleeding, OSHA: The legal airborne permissible exposure limit discharge or formation of a crust. (PEL) is 0.1 mg/m3, not to be exceeded at any * Chromic Acid may cause a skin allergy. If allergy time. develops, very low future exposure can cause itching and a skin rash. NIOSH: The recommended airborne exposure limit is * High exposure may affect the liver. 0.001 mg/m3, which should not be exceeded at any time. IDENTIFICATION Chromic Acid is a dark, purplish red, odorless, sand-like ACGIH: The recommended airborne exposure limit is 3 solid. It is used in Chromium plating, medicine, ceramic 0.05 mg/m averaged over an 8-hour workshift. glazes and paints. * Chromic Acid may be a CARCINOGEN in humans. REASON FOR CITATION There may be no safe level of exposure to a carcinogen, so * Chromic Acid is on the Hazardous Substance List all contact should be reduced to the lowest possible level. * The above exposure limits are for air levels only. When because it is regulated by OSHA and cited by ACGIH, skin contact also occurs, you may be overexposed, even DOT, NIOSH, DEP, IARC, NFPA and EPA. though air levels are less than the limits listed above. * This chemical is on the Special Health Hazard Substance List because it is a CARCINOGEN and CORROSIVE. * Definitions are provided on page 5. WAYS OF REDUCING EXPOSURE * Enclose operations and use local exhaust ventilation at the HOW TO DETERMINE IF YOU ARE BEING site of chemical release. If local exhaust ventilation or enclosure is not used, respirators should be worn. EXPOSED * Wear protective work clothing. The New Jersey Right to Know Act requires most employers * Wash thoroughly immediately after exposure to Chromic to label chemicals in the workplace and requires public Acid and at the end of the workshift. employers to provide their employees with information and * Post hazard and warning information in the work area. In training concerning chemical hazards and controls. The addition, as part of an ongoing education and training federal OSHA Hazard Communication Standard, 1910.1200, effort, communicate all information on the health and requires private employers to provide similar training and information to their employees. safety hazards of Chromic Acid to potentially exposed workers. CHROMIC ACID page 2 of 6 This Fact Sheet is a summary source of information of all Also, check your skin daily for little bumps or blisters, the first potential and most severe health hazards that may result from sign of “Chrome ulcers.” If not treated early, these can last for exposure. Duration of exposure, concentration of the substance years after exposure. and other factors will affect your susceptibility to any of the potential effects described below. Any evaluation should include a careful history of past and --------------------------------------------------------------------------- present symptoms with an exam. Medical tests that look for damage already done are not a substitute for controlling HEALTH HAZARD INFORMATION exposure. Acute Health Effects Request copies of your medical testing. You have a legal right The following acute (short-term) health effects may occur to this information under OSHA 1910.1020. immediately or shortly after exposure to Chromic Acid: Mixed Exposures * Contact can severely irritate and burn the skin and eyes * Because smoking can cause heart disease, as well as lung with possible eye damage. cancer, emphysema, and other respiratory problems, it may * Breathing Chromic Acid can irritate the nose, throat and worsen respiratory conditions caused by chemical exposure. lungs causing coughing, wheezing and/or shortness of Even if you have smoked for a long time, stopping now will breath. reduce your risk of developing health problems. * Because more than light alcohol consumption can cause Chronic Health Effects liver damage, drinking alcohol may increase the liver The following chronic (long-term) health effects can occur at damage caused by Chromic Acid. some time after exposure to Chromic Acid and can last for months or years: Conditions Made Worse By Exposure * Persons with a history of skin allergy to Chromium Cancer Hazard compounds can have a severe rash with skin exposure to * Chromic Acid may be a CARCINOGEN in humans since Chromic Acid. it has been shown to cause lung cancer in animals. * Many scientists believe there is no safe level of exposure to WORKPLACE CONTROLS AND PRACTICES a carcinogen. Unless a less toxic chemical can be substituted for a hazardous Reproductive Hazard substance, ENGINEERING CONTROLS are the most * Chromic Acid may damage the developing fetus. effective way of reducing exposure. The best protection is to enclose operations and/or provide local exhaust ventilation at Other Long-Term Effects the site of chemical release. Isolating operations can also * Chromic Acid can cause a sore and/or hole in the “bone” reduce exposure. Using respirators or protective equipment is dividing the inner nose, sometimes with bleeding, less effective than the controls mentioned above, but is discharge, or formation of a crust. sometimes necessary. * Chromic Acid may cause a skin allergy. If allergy develops, very low future exposure can cause itching and a In evaluating the controls present in your workplace, consider: skin rash. (1) how hazardous the substance is, (2) how much of the * High exposure may affect the liver. substance is released into the workplace and (3) whether harmful skin or eye contact could occur. Special controls MEDICAL should be in place for highly toxic chemicals or when significant skin, eye, or breathing exposures are possible. Medical Testing In addition, the following control is recommended: For those with frequent or potentially high exposure (half the TLV or greater), the following is (are) recommended before * Where possible, automatically transfer Chromic Acid or beginning work and at regular times after that: pump liquid Chromic Acid from drums or other storage containers to process containers. * Lung function tests. Good WORK PRACTICES can help to reduce hazardous If symptoms develop or overexposure is suspected, the exposures. The following work practices are recommended: following are recommended: * Workers whose clothing has been contaminated by * Liver function tests. Chromic Acid should change into clean clothing promptly. * Evaluation by a qualified allergist, including careful * Do not take contaminated work clothes home. Family exposure history and special testing, may help diagnose members could be exposed. skin allergy. CHROMIC ACID page 3 of 6 * Contaminated work clothes should be laundered by Respiratory Protection individuals who have been informed of the hazards of IMPROPER USE OF RESPIRATORS IS DANGEROUS. exposure to Chromic Acid. Such equipment should only be used if the employer has a * Eye wash fountains should be provided in the immediate written program that takes into account workplace conditions, work area for emergency use. requirements for worker training, respirator fit testing and * If there is the possibility of skin exposure, emergency medical exams, as described in OSHA 1910.134. shower facilities should be provided. * On skin contact with Chromic Acid, immediately wash or * Where the potential exists for exposure over shower to remove the chemical. At the end of the 0.001 mg/m3 (as Chromium VI), use a MSHA/NIOSH workshift, wash any areas of the body that may have approved supplied-air respirator with a full facepiece contacted Chromic Acid, whether or not known skin operated in a pressure-demand or other positive-pressure contact has occurred. mode. For increased protection use in combination with an * Do not eat, smoke, or drink where Chromic Acid is auxiliary self-contained breathing apparatus operated in a handled, processed, or stored, since the chemical can be pressure-demand or other positive-pressure mode. swallowed. Wash hands carefully before eating, drinking, * Exposure to 15 mg/m3 (as Chromium VI) is immediately applying cosmetics, smoking, or using the toilet. dangerous to life and health. If the possibility of exposure * For solid Chromic Acid use a vacuum or a wet method to above 15