EUROPEAN UNION THE EUROPEAN PARLIAMENT THE COUNCIL Strasbourg, 16 December 2008 (OR. en) 2007/0121 (COD) PE-CONS 3671/08 LEX 958 ADD 9 REV 2 COMPET 306 ENV 538 CHIMIE 49 MI 293 ENT 213 CODEC 1079 REGULATION OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL ON CLASSIFICATION, LABELLING AND PACKAGING OF SUBSTANCES AND MIXTURES, AMENDING AND REPEALING DIRECTIVES 67/548/EEC AND 1999/45/EC, AND AMENDING REGULATION (EC) No 1907/2006 PE-CONS 3671/08 ADD 9 REV 2 EN ANNEX VI Table 3.1 List of harmonised classification and labelling of hazardous substances Index No International Chemical EC No CAS No Classification Labelling Specific Conc. Limits, Notes Identification M-factors Hazard Class and Hazard Pictogram, Hazard Suppl. Hazard Category Code(s) statement Signal Word statement statement Code(s) Code(s) Code(s) Code(s) 606-030-00-6 hexan-2-one; 209-731-1 591-78-6 Flam. Liq. 3 H226 GHS02 H226 methyl butyl ketone; Repr. 2 H361f *** GHS08 H361f *** butyl methyl ketone; STOT RE 1 H372 ** GHS07 H372 ** methyl-n-butyl ketone STOT SE 3 H336 Dgr H336 606-031-00-1 3-propanolide; 200-340-1 57-57-8 Carc. 1B H350 GHS06 H350 1,3-propiolactone Acute Tox. 2 * H330 GHS08 H330 Eye Irrit. 2 H319 Dgr H319 Skin Irrit. 2 H315 H315 606-032-00-7 hexachloroacetone 204-129-5 116-16-5 Acute Tox. 4 * H302 GHS07 H302 Aquatic Chronic 2 H411 GHS09 H411 Wng 606-033-00-2 2-(3,4-dichlorophenyl)-4-methyl- 243-761-6 20354-26-1 Acute Tox. 4 * H312 GHS07 H312 1,2,4-oxadiazolidinedione; Acute Tox. 4 * H302 GHS09 H302 methazole Eye Irrit. 2 H319 Wng H319 Skin Irrit. 2 H315 H315 Aquatic Chronic 2 H411 H411 606-034-00-8 metribuzin (ISO); 244-209-7 21087-64-9 Acute Tox. 4 * H302 GHS07 H302 4-amino-6-tert-butyl-3- Aquatic Acute 1 H400 GHS09 H410 methylthio-1,2,4-triazin-5(4H)- Aquatic Chronic 1 H410 Wng one; 4-amino-4,5-dihydro-6-(1,1- dimethylethyl)-3-methylthio- 1,2,4-triazin-5-one PE-CONS 3671/08 ADD 9 REV 2 1 ANNEX VI EN Index No International Chemical EC No CAS No Classification Labelling Specific Conc. Limits, Notes Identification M-factors Hazard Class and Hazard Pictogram, Hazard Suppl. Hazard Category Code(s) statement Signal Word statement statement Code(s) Code(s) Code(s) Code(s) 606-035-00-3 chloridazon (ISO); 216-920-2 1698-60-8 Skin Sens. 1 H317 GHS07 H317 5-amino-4-chloro-2- Aquatic Acute 1 H400 GHS09 H410 phenylpyridazine-3-(2H)-one; Aquatic Chronic 1 H410 Wng pyrazon 606-036-00-9 quinomethionate; 219-455-3 2439-01-2 Repr. 2 H361f *** GHS08 H361f *** chinomethionat (ISO); Acute Tox. 4 * H332 GHS07 H332 6-methyl-1,3-dithiolo(4,5- Acute Tox. 4 * H312 GHS09 H312 b)quinoxalin-2-one Acute Tox. 4 * H302 Wng H302 STOT RE 2 * H373 ** H373 ** Eye Irrit. 2 H319 H319 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410 606-037-00-4 triadimefon (ISO); 256-103-8 43121-43-3 Acute Tox. 4 * H302 GHS07 H302 1-(4-chlorophenoxy)-3,3- Skin Sens. 1 H317 GHS09 H317 dimethyl-1-(1,2,4-triazol-1- Aquatic Chronic 2 H411 Wng H411 yl)butanone 606-038-00-X diphacinone (ISO); 201-434-5 82-66-6 Acute Tox. 2 * H300 GHS06 H300 2-diphenylacetylindan-1,3-dione STOT RE 1 H372 ** GHS08 H372 ** Dgr 606-039-00-5 5(or 6)-tert-butyl-2'-chloro-6'- 400-680-2 - Acute Tox. 4 * H332 GHS07 H332 ethylamino-3',7'- Aquatic Acute 1 H400 GHS09 H410 dimethylspiro(isobenzofuran- Aquatic Chronic 1 H410 Wng 1(1H),9'-xanthene)-3-one 606-040-00-0 (N-benzyl-N-ethyl)amino-3- 401-840-4 55845-90-4 Eye Dam. 1 H318 GHS05 H318 hydroxyacetophenone Aquatic Chronic 2 H411 GHS09 H411 hydrochloride Dgr PE-CONS 3671/08 ADD 9 REV 2 2 ANNEX VI EN Index No International Chemical EC No CAS No Classification Labelling Specific Conc. Limits, Notes Identification M-factors Hazard Class and Hazard Pictogram, Hazard Suppl. Hazard Category Code(s) statement Signal Word statement statement Code(s) Code(s) Code(s) Code(s) 606-041-00-6 2-methyl-1-(4- 400-600-6 71868-10-5 Acute Tox. 4 * H302 GHS07 H302 methylthiophenyl)-2- Aquatic Chronic 2 H411 GHS09 H411 morpholinopropan-1-one Wng 606-042-00-1 acetophenone 202-708-7 98-86-2 Acute Tox. 4 * H302 GHS07 H302 Eye Irrit. 2 H319 Wng H319 606-043-00-7 2,4-di-tert-butylcyclohexanone 405-340-7 13019-04-0 Skin Irrit. 2 H315 GHS07 H315 Aquatic Chronic 2 H411 GHS09 H411 Wng 606-044-00-2 2,4,6-trimethylbenzophenone 403-150-9 954-16-5 Acute Tox. 4 * H302 GHS07 H302 Eye Irrit. 2 H319 GHS09 H319 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410 606-045-00-8 oxadiazon (ISO); 243-215-7 19666-30-9 Aquatic Acute 1 H400 GHS09 H410 3-[2,4-dichloro-5-(1- Aquatic Chronic 1 H410 Wng methylethoxy)phenyl]-5-(1,1- dimethylethyl)-1,3,4-oxadiazol- 2(3H)-one 606-046-00-3 reaction mass of cis- and trans- 401-700-2 3100-36-5 Aquatic Acute 1 H400 GHS09 H410 cyclohexadec-8-en-1-one Aquatic Chronic 1 H410 Wng 606-047-00-9 2-benzyl-2-dimethylamino-4- 404-360-3 119313-12-1 Aquatic Acute 1 H400 GHS09 H410 morpholinobutyrophenone Aquatic Chronic 1 H410 Wng 606-048-00-4 2'-anilino-3'-methyl-6'- 406-480-1 - Aquatic Chronic 4 H413 - H413 dipentylaminospiro(isobenzofura n-1(1H),9'-xanthen)-3-one 606-049-00-X 4-(trans-4- 406-700-6 78531-61-0 Skin Sens. 1 H317 GHS07 H317 propylcyclohexyl)acetophenone Aquatic Chronic 4 H413 Wng H413 PE-CONS 3671/08 ADD 9 REV 2 3 ANNEX VI EN Index No International Chemical EC No CAS No Classification Labelling Specific Conc. Limits, Notes Identification M-factors Hazard Class and Hazard Pictogram, Hazard Suppl. Hazard Category Code(s) statement Signal Word statement statement Code(s) Code(s) Code(s) Code(s) 606-050-00-5 6-anilino-1-benzoyl-4-(4-tert- 412-480-2 72453-58-8 Aquatic Chronic 2 H411 GHS09 H411 pentylphenoxy)naphto[1,2,3- de]quinoline-2,7-(3H)-dione 606-051-00-0 4-pentylcyclohexanone 406-670-4 61203-83-6 Aquatic Chronic 2 H411 GHS09 H411 606-052-00-6 4-(N,N-dibutylamino)-2-hydroxy- 410-410-5 54574-82-2 Aquatic Chronic 3 H412 - H412 2'-carboxybenzophenone 606-053-00-1 flurtamone (ISO); - 96525-23-4 Aquatic Acute 1 H400 GHS09 H410 (RS)-5-methylamino-2-phenyl-4- Aquatic Chronic 1 H410 Wng (α,α,α-trifluoro-m-tolyl)furan- 3(2H)-one 606-054-00-7 isoxaflutole (ISO); - 141112-29-0 Repr. 2 H361d *** GHS08 H361d *** 5-cyclopropyl-1,2-oxazol-4-yl Aquatic Acute 1 H400 GHS09 H410 α,α,α-trifluoro-2-mesyl-p-tolyl Aquatic Chronic 1 H410 Wng ketone 606-055-00-2 1-(2,3-dihydro-1,3,3,6- 411-180-9 92836-10-7 Acute Tox. 4 * H302 GHS08 H302 tetramethyl-1-(1-methylethyl)- STOT RE 2 * H373 ** GHS07 H373 ** 1H-inden-5-yl)ethanone Aquatic Chronic 2 H411 GHS09 H411 Wng 606-056-00-8 4-chloro-3',4'- 404-610-1 116412-83-0 Aquatic Acute 1 H400 GHS09 H410 dimethoxybenzophenone Aquatic Chronic 1 H410 Wng 606-057-00-3 4-propylcyclohexanone 406-810-4 40649-36-3 Skin Irrit. 2 H315 GHS07 H315 Aquatic Chronic 3 H412 Wng H412 606-058-00-9 4'-fluoro-2,2- 407-500-1 21983-80-2 Skin Sens. 1 H317 GHS07 H317 dimethoxyacetophenone Aquatic Chronic 3 H412 Wng H412 606-059-00-4 2,4-difluoro-α-(1H-1,2,4-triazol- 412-390-3 86386-75-6 Acute Tox. 4 * H302 GHS05 H302 1-yl)acetophenone hydrochloride Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 Dgr H317 PE-CONS 3671/08 ADD 9 REV 2 4 ANNEX VI EN Index No International Chemical EC No CAS No Classification Labelling Specific Conc. Limits, Notes Identification M-factors Hazard Class and Hazard Pictogram, Hazard Suppl. Hazard Category Code(s) statement Signal Word statement statement Code(s) Code(s) Code(s) Code(s) 606-060-00-X reaction mass of: trans-2,4- 412-950-7 - Aquatic Acute 1 H400 GHS09 H410 dimethyl-2-(5,6,7,8-tetrahydro- Aquatic Chronic 1 H410 Wng 5,5,8,8-tetramethyl-naphthalene- 2-yl)-1,3-dioxolane; cis-2,4-dimethyl-2-(5,6,7,8- tetrahydro-5,5,8,8-tetramethyl- naphthalene-2-yl)-1,3-dioxolane 606-061-00-5 (3-chlorophenyl)-(4-methoxy-3- 423-290-4 66938-41-8 Muta. 2 H341 GHS08 H341 nitrophenyl)methanone Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng 606-062-00-0 tetrahydrothiopyran-3- 407-330-8 61571-06-0 Repr. 1B H360D *** GHS08 H360D carboxaldehyde Eye Dam. 1 H318 GHS05 *** Aquatic Chronic 3 H412 Dgr H318 H412 606-063-00-6 (E)-3-(2-chlorophenyl)-2-(4- 410-980-5 112704-51-5 Eye Irrit. 2 H319 GHS07 H319 fluorophenyl)propenal Skin Sens. 1 H317 Wng H317 606-064-00-1 pregn-5-ene-3,20-dione 407-450-0 7093-55-2 Aquatic Chronic 4 H413 - H413 bis(ethylene ketal) 606-065-00-7 1-(4-morpholinophenyl)butan-1- 413-790-0 - Aquatic Chronic 2 H411 GHS09 H411 one 606-066-00-2 (E)-5[(4- 410-440-9 164058-20-2 Aquatic Chronic 2 H411 GHS09 H411 chlorophenyl)methylene]-2,2- dimethylcyclopentanone PE-CONS 3671/08 ADD 9 REV 2 5 ANNEX VI EN Index No International Chemical EC No CAS No Classification Labelling Specific Conc.