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Printed in GERMANY – ISSN 1018-4619 © by PSP Volume 24 – No 5b. 2015 Fresenius Environmental Bulletin FEB - EDITORIAL BOARD Environmental Toxicology: Prof. Dr. H. Greim Chief Editor: Senatskomm. d. DFG z. Prüfung gesundheitsschädl. Arbeitsstoffe TU München, 85350 Freising-Weihenstephan, Germany Prof. Dr. H. Parlar Institut für Lebensmitteltechnologie und Analytische Chemie Prof. Dr. A. Kettrup TU München - 85350 Freising-Weihenstephan, Germany Institut für Lebensmitteltechnologie und Analytische Chemie e-mail: [email protected] TU München - 85350 Freising-Weihenstephan, Germany FEB - ADVISORY BOARD Co-Editors: Environmental Analytical Chemistry: Environmental Analytical Chemistry: K. Ballschmitter, D - K. Bester, D - K. Fischer, D - R. Kallenborn, N Dr. D. Kotzias D.C.G. Muir, CAN - R. Niessner, D - W. Vetter, D – R. Spaccini, I Via Germania 29 21027 Barza (Va) ITALY Environmental Proteomic and Biology: D. Adelung, D - G.I. Kvesitadze, GEOR A. Reichlmayr-Lais, D - C. Steinberg, D Environmental Proteomic and Biology: Environmental Chemistry: Prof. Dr. A. Görg Fachgebiet Proteomik J.P. Lay, D - J. Burhenne, D - S. Nitz, D - R. Kreuzig, D TU München - 85350 Freising-Weihenstephan, Germany D. L. Swackhammer, U.S.A. - R. Zepp, U.S.A. – T. Alpay, TR V. Librando; I Prof. Dr. A. Piccolo Università di Napoli “Frederico II”, Environmental Management: Dipto. Di Scienze Chimico-Agrarie Via Università 100, 80055 Portici (Napoli), Italy L.O. Ruzo, U.S.A - U. Schlottmann, D Prof. Dr. G. Schüürmann UFZ-Umweltforschungszentrum, Environmental Toxicology: Sektion Chemische Ökotoxikologie Leipzig-Halle GmbH, K.-W. Schramm, D - H. Frank, D - D. Schulz-Jander, U.S.A. - Permoserstr.15, 04318 Leipzig, Germany H.U. Wolf, D – M. McLachlan, S Environmental Chemistry: Prof. Dr. M. Bahadir Managing Editor: Institut für Ökologische Chemie und Abfallanalytik TU Braunschweig Dr. G. Leupold Hagenring 30, 38106 Braunschweig, Germany Editorial Chief-Officer: Prof. Dr. M. Spiteller Selma Parlar Institut für Umweltforschung Universität Dortmund PSP- Parlar Scientific Publications Otto-Hahn-Str. 6, 44221 Dortmund, Germany Angerstr.12, 85354 Freising, Germany e-mail: [email protected] - www.psp-parlar.de Prof. Dr. Ivan Holoubek RECETOX_TOCOEN Marketing Chief Manager: Kamenice 126/3, 62500 Brno, Czech Republic Max-Josef Kirchmaier MASELL-Agency for Marketing & Communication, Public-Rela- tions Environmental Management: Angerstr.12, 85354 Freising, Germany Dr. H. Schlesing e-mail: [email protected] - www.masell.com Secretary General, EARTO, Rue de Luxembourg,3, 1000 Brussels, Belgium Prof. Dr. F. Vosniakos T.E.I. of Thessaloniki, Applied Physics Lab. Abstracted/ indexed in: Biology & Environmental Sciences, P.O. Box 14561, 54101 Thessaloniki, Greece BIOSIS, C.A.B. International, Cambridge Scientific Abstracts, Chemical Abstracts, Current Awareness, Current Contents/ Agricul- Dr. K.I. Nikolaou ture, CSA Civil Engineering Abstracts, CSA Mechanical & Trans- Organization of the Master Plan & portation Engineering, IBIDS database, Information Ventures, NISC, Environmental Protection of Thessaloniki (OMPEPT) Research Alert, Science Citation Index Expanded (SCI Expanded), 54636 Thessaloniki, Greece SciSearch, Selected Water Resources Abstracts 0 © by PSP Volume 24 – No 5b. 2015 Fresenius Environmental Bulletin CONTENTS ORIGINAL PAPERS SORPTION AND DESORPTION OF Pb2+ AND Cu2+ IN DIFFERENT TUNISIAN SOILS 1909 Hamdi Sahraoui, María Luisa Andrade, Mohamed Hachicha, Luis Felipe Silva Oliveira and Flora Alonso Vega EFFECTS OF TWO FUNGICIDES, CYPRODINIL AND FLUDIOXONIL, 1920 ON GENOTOXICITY IN DROSOPHILA SMART ASSAY AND ON PROLIFERATION AND VIABILITY OF HEK293 CELLS FROM THE PERSPECTIVE OF CARCINOGENESIS Asuman Karadeniz, Bülent Kaya, Burhan Savaş and Ş. Fatih Topcuoğlu INFLUENCE OF WEAK MAGNETIC FIELD ON HEAVY 1926 METAL CATIONS REMOVAL BY ZERO VALENT IRON Chao Wang, Zhongjin Xiao, Lei Wang and Junlian Qiao CONTRIBUTIONS TO THE INSECT FAUNA OF 1932 BURDUR PROVINCE (TURKEY) IN TERMS OF HYDROPHILIDAE, HELOPHORIDAE AND CHRYSOMELIDAE (COLEOPTERA) WITH CHOROTYPE ANALYSES Baran Aslan, Ayçin Yılmaz, Fatma Bayram and Ebru G. Aslan EFFECTS OF ELECTRODE MATERIAL ON THE ELECTROKINETIC 1940 REMEDIATION OF CADMIUM-CONTAMINATED SOIL NEAR A MINE TAILING Zongping Cai, Jeremiah Van Doren, Mengqing Xu, Dongrui Chen, Weishan Li, Zhanqiang Fang and Lidan Xing REMOVAL OF BASIC RED 9 IN WASTEWATER USING GREEN FENTON REACTION 1947 Azize Alayli Gungor, Neslihan Celebi and Hayrunnisa Nadaroglu ANTIOXIDANT DEFENCE SYSTEMS, LIPID PEROXIDATION AND ACETYLCHOLINESTERASE 1958 ACTIVITY OF OREOCHROMIS NILOTICUS EXPOSED TO MERCURY AND MERCURY + SELENIUM Gülbin Firidin, Ferit Kargın, Özge Fırat, Hikmet Y. Çoğun, Özgür Fırat, Beran Firidin and Tüzin A. Yüzereroğlu ASSESSMENT OF HEAVY METAL POLLUTION IN SURFACE SOILS 1966 FROM URBAN PARKS AND SQUARES: A CASE STUDY FROM CHINA Qiang Liu, Jingshuang Liu, Mingying Zou and Yang Wang THE ENZYMATIC ACTIVITY AND PLASTID PIGMENT CONTENT IN 1976 MEDICAGO X VARIA T. MARTYN TREATED WITH AN EXOGENOUS GROWTH REGULATOR Jacek Sosnowski HEAVY METALS CONTENT IN AMANITA PANTHERINA IN A VICINITY OF 1981 THE THERMO-ELECTRIC POWER PLANT OSLOMEJ, REPUBLIC OF MACEDONIA Emri Murati, Slavcho Hristovski, Ljupcho Melovski and Mitko Karadelev HEMATOLOGICAL PARAMETERS IN NILE TILAPIA (Oreochromis niloticus) 1985 EXPOSED TO SUB-LETHAL CONCENTRATIONS OF CADMIUM AND ZINC Özgür Fırat and Ferit Kargin 1907 © by PSP Volume 24 – No 5b. 2015 Fresenius Environmental Bulletin ASSESSMENT OF HEAVY METALS CONTAMINATION IN FEN RIVER CHANNELS 1990 Yu Qi, Jun Ma and Guisheng Fan NOTICE GLOBAL ENVIRONMENTAL INPUT–OUTPUT RESEARCH 1996 TRENDS DURING 1900–2013: A BIBLIOMETRIC ANALYSIS Jingqing Zhou, Zhen Wang, Beibei Niu and Song Hong INDEX 2005 1908 © by PSP Volume 24 – No 5b. 2015 Fresenius Environmental Bulletin SORPTION AND DESORPTION OF Pb2+ AND Cu2+ IN DIFFERENT TUNISIAN SOILS Hamdi Sahraoui1,2,*, María Luisa Andrade1, Emma F. Covelo1, Mohamed Hachicha2, Jamila Tarhouni, Luis Felipe Silva Oliveira4,5 and Flora Alonso Vega1 1Departamento de Bioloxía Vexetal e Ciencia do Solo, Facultade de Bioloxía, Universidade de Vigo, Lagoas, Marcosende, 36310 Vigo, Pontevedra, Spain. 2Institut National de Recherche en Génie Rural Eaux et Forêts. Université de Carthage. Rue Hédi Elkarray, Elmenzah IV, Tunis, Tunisie 3Institut National Agricole de Tunis. 43, Rue Charles Nicole - Cité Mahrajène, Tunis, Tunisie 4Environmental Science and Nanotechnology Department, Catarinense Institute of Environmental Research and Human Development, IPADHC, Capivari de Baixo, Santa Catarina, Mexico 5Centro Universitário UNIVATES, Bairro Universitário, Lajeado, Brazil ABSTRACT cumulation of trace elements in the long term affects the topsoil. Studies of these soils are limited. Sorption and de- Sorption and retention are the major processes for the sorption are the most important processes controlling the accumulation of potentially toxic trace elements and its trace elements mobility on soil. Trace elements are adsorbed study is of great importance to understand the fate of on the surface of colloidal particles in soils, principally on trace elements in soils. Sorption and retention capacities of hydrous oxides, clays and carbonates [1]. Desorption is the five Tunisian soils and the soil mineral influence were release of sorbed metal ions from soil. studied by Pb2+ and Cu2+ batch sorption experiments and As described by [2] sorption of Pb2+ and Cu2+ in soils scanning electron microscope (SEM) analysis. It has been is affected by specific sorption to various solid phases, pre- shown that sorption and retention of Pb2+ are most influ- cipitation of highly stable compounds and formation of rel- enced by cation exchangeable capacity (CECe), clay con- atively stable complexes with soil components. However, tents, Mn oxides and carbonate contents, whereas Cu2+ even researches done have been focused on the understand- sorption and retention are most influenced by the total or- ing of sorption of Pb2+ and Cu2+ in soils, there has been ganic carbon (TOC) and carbonate contents. The alkalinity little research done on their desorption [3]. Sorption and of the majority of soils due to their carbonate contents lead desorption reactions are often not completely reversible to increase of both Pb2+ and Cu2+ precipitation and high and this non singularity or hysteresis has been observed to sorption capacity. The sorption irreversibility is higher in increase with increased aging of trace elements with soil soils of highest alkalinity, TOC, CECe, and clay contents. constituents [4]. Both hysteresis of Pb2+ and Cu2+ have The Energy Dispersive Spectrometer (EDS) semi-quanti- been observed