SAFETY DATA SHEET Alkanol 6112 Version 3.0 Revision Date 2013/02/20 Document no. 130000023956 This SDS adheres to the standards and regulatory requirements of China and may not meet the regulatory requirements in other countries. Section 1 - Chemical and Enterprise Identification Chinese name : Alkanol 6112 Product name in English : Alkanol 6112 Other names : Alkanol ™ 6112 FabricSurfactant Manufacturer or supplier's details Company : Du Pont China Holding Co., Ltd Street address : China, Shanghai, 399 KeYuan Road, Bldg 11, Zhangjiang Hi-Tech Park, Pudong New District 201203 Telephone : 86 21 3862 2888 Telefax : 86 21 3862 2889 Emergency telephone : 86 532 8388 9090 number Recommended use of the chemical and restriction on use No information available. Section 2 - Hazard Identification GHS Hazard Category Acute toxicity (Inhalation) Category 3 Skin irritation Category 2 Serious eye damage/eye irritation Category 2A Specific target organ toxicity - Category 1 single exposure Aspiration hazard Category 1 Acute aquatic toxicity Category 2 GHS Label Elements Pictogram : Signal word : Danger Hazardous warnings : May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. Toxic if inhaled. Causes damage to organs. (Central nervous system) 1/8 SAFETY DATA SHEET Alkanol 6112 Version 3.0 Revision Date 2013/02/20 Document no. 130000023956 Toxic to aquatic life. Hazardous prevention : Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. measures Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/ eye protection/ face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed: Call a POISON CENTER or doctor/ physician. Specific treatment (see supplemental first aid instructions on this label). Do NOT induce vomiting. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/ container to an approved waste disposal plant. Main Symptom and Emergency Summary After Contact Refer to section 4 of this SDS for information on symptoms, hazards and treatment after contact. Section 3 - Ingredients/Composition Information Chemical nature : Mixture Components Chemical Name CAS-No. Concentration Polyethylene oxide monooctadecyl ether 9005-65-6 <10% Decan-1-ol 112-30-1 45 - 55% Water 7732-18-5 40 - 50% Section 4 - First-aid Measures Inhalation : Move to fresh air. Oxygen or artificial respiration if needed. Call a physician immediately. Skin contact : Wash off immediately with plenty of water. Take off contaminated clothing and shoes immediately. Call a physician immediately. Wash contaminated clothing before re-use. Eye contact : Rinse immediately with plenty of water and seek medical advice. Ingestion : Do NOT induce vomiting. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Call a physician immediately. 2/8 SAFETY DATA SHEET Alkanol 6112 Version 3.0 Revision Date 2013/02/20 Document no. 130000023956 Most important : No information available. symptoms/effects, acute and delayed Protection of first-aiders : No information available. Notes to physician : Do NOT induce vomiting. Note: To prepare activated charcoal slurry, mix thoroughly 50 g of activated charcoal in 400 ml (about 2 cups) water. Section 5 - Fire-fighting Measures Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. media Specific hazards : No information available. Specific fire fighting : Wear self-contained breathing apparatus and protective suit. methods and special protective equipment for fire fighters Section 6 - Leak Emergency Treatment Protective measures, : Use personal protective equipment. devices and emergency treatment procedure for workers Environmental protection : No information available. measures Collection of leaking : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, materials, removal method universal binder, sawdust). Shovel or sweep up. Flush with water. and materials used for disposal Prevention of secondary : No information available. hazards Section 7 - Operation Handling and Storage Operation Handling Technical : Avoid inhalation of vapour or mist. Avoid contact with skin, eyes and clothing. measures/Precautions Wash hands before breaks and immediately after handling the product. Precautions for safe : No information available. handling Hygiene measures : No information available. 3/8 SAFETY DATA SHEET Alkanol 6112 Version 3.0 Revision Date 2013/02/20 Document no. 130000023956 Storage Suitable storage : Keep tightly closed. Perishable if frozen. conditions Section 8 - Exposure Control and Personal Protection Engineering controls : Ensure adequate ventilation. Occupational Exposure Limits No information available. Biological occupational : No information available. exposure limits Personal protective equipment Respiratory protection : No information available. Hand protection : Material: Impervious gloves Eye protection : Safety glasses, Tightly fitting safety goggles Skin protection : Long sleeved clothing, Apron Section 9 - Physical and Chemical Properties Appearance (Physical state, form, colour, etc.) Physical state : liquid Form : liquid Colour : milky, white Odour : like soap pH (specifed concentration) : 5 - 8 Melting point/freezing point no data available Boiling point, initial boiling point and boiling range Boiling point/boiling range : 100 °C (1,013 hPa) Flash point : 113 °C Method: Pensky-Martens closed cup - PMCC Decomposition temperature : no data available 4/8 SAFETY DATA SHEET Alkanol 6112 Version 3.0 Revision Date 2013/02/20 Document no. 130000023956 Auto -ignition temperature : no data available Explosion limits Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Vapour density : no data available Density Relative density : 0.91 (25 °C) Solubility(ies) Water solubility : dispersible Solubility in other solvents : no data available Partition coefficient: n - : no data available octanol/water Section 10 - Stability and Reactivity Stability : Stable Possible hazardous : No information available. reactions under specific conditions Conditions to avoid : No information available. Materials to avoid : No information available. Hazardous decomposition : No information available. products Section 11 - Toxicological Information 5/8 SAFETY DATA SHEET Alkanol 6112 Version 3.0 Revision Date 2013/02/20 Document no. 130000023956 Acute toxicity : Polyethylene oxide monooctadecyl ether: Oral: LD50/rat : > 38,000 mg/kg Decan-1-ol: Oral: LD50/rat : 4,720 mg/kg Inhalation: LC50/2 h/mouse : 4 mg/l Central nervous system depression Dermal: LD50/rabbit : 3,560 mg/kg Skin corrosion/irritation : Polyethylene oxide monooctadecyl ether: Species: rabbit Classification: Not classified as irritant Result: Slight or no skin irritation Decan-1-ol: Species: rabbit irritant Eye irritation/corrosion : Polyethylene oxide monooctadecyl ether: Species: rabbit Classification: Not classified as irritant Result: Slight or no eye irritation Decan-1-ol: Species: rabbit irritant Respiratory or skin : Polyethylene oxide monooctadecyl ether: sensitisation Species: guinea pig Classification: Not a skin sensitizer. Result: Did not cause sensitisation on laboratory animals. Decan-1-ol: Species: human Patch test on human volunteers did not demonstrate sensitisation properties. Germ cell mutagenicity : Polyethylene oxide monooctadecyl ether: Did not cause genetic damage in animals. Did not cause genetic damage in cultured mammalian cells. Did not cause genetic damage in cultured bacterial cells. 6/8 SAFETY DATA SHEET Alkanol 6112 Version 3.0 Revision Date 2013/02/20 Document no. 130000023956 Decan-1-ol: Evidence suggests this substance does not cause genetic damage in animals. Carcinogenicity : Polyethylene oxide monooctadecyl ether: Overall weight of evidence indicates that the substance is not carcinogenic. Decan-1-ol: Overall weight of evidence indicates that the substance is not carcinogenic. Toxicity for reproduction : Polyethylene oxide monooctadecyl ether: Animal testing showed no reproductive toxicity. Animal testing showed no developmental toxicity. Decan-1-ol: Evidence suggests the substance is not a reproductive toxin in animals. Evidence suggests the substance is not a developmental toxin in animals. Specific Target Organs : no data available Toxicity (Single/Repeated) Aspiration hazard : no data available Other : Polyethylene oxide monooctadecyl ether: Repeated dose toxicity: Oral - feed , multiple species No toxicologically significant effects were found. No adverse effects expected., Information given is based on data obtained from similar substances. Section 12 - Ecological Information Ecotoxicity effects Toxicity to fish : Decan-1-ol: LC50/96 h/Pimephales promelas (fathead minnow): 2.3 mg/l Other : Decan-1-ol: EC50/48 h/Daphnia magna (Water flea): 3 mg/l Persistence and : no data available degradation 7/8