INSTITUTE OF SOLID STATE CHEMISTRY AND MECHANOCHEMISTRY SB RAS NOVOSIBIRSK STATE UNIVERSITY V International Conference «Fundamental Bases of Mechanochemical Technologies» FBMT- 2018 BOOK of ABSTRACTS Novosibirsk 2018 Fundamental Bases of Mechanochemical Technologies. The Book of Abstracts of the V International Conference “Fundamental Bases of Mechanochemical Technologies”. 25-28 June 2018, Novosibirsk, Russia. – Novosibirsk: IPC NSU, 2018. – 234 p. ISBN 978-5-4437-0794-5 Organized by Institute of Solid State Chemistry and Mechanochemistry SB RAS www.solid.nsc.ru Novosibirsk State University www.nsu.ru Acknowledgements: Russian Foundation for Basic Research (project № 18-03-20029) Federal Agency for Scientific Organizations ABEX Co. NOVIC Co. Technical Editors: T.P. Shakhtshneider I.G. Konstanchuk Cover drawing: I.V. Burdukova ISBN 978-5-4437-0794-5 © Institute of Solid State Chemistry and Mechanochemistry SB RAS, 2018 V International Conference “Fundamental Bases of Mechanochemical Technologies” Novosibirsk, June 25-28, 2018 PREFACE Welcome to the FBMT 2018! The V International Conference “Fundamental Bases of Mechanochemical Technologies” (FBMT 2018) will be held on June 25-28, 2018 in Novosibirsk, Russia. It is hosted by the Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the Russian Academy of Sciences and Novosibirsk State University. The Institute of Solid State Chemistry and Mechanochemistry SB RAS has made a significant contribution to the development of new technologies based on mechanochemical reactions and mechanical alloying. The I International Conference on Fundamental Bases of Mechanochemical Technologies organized by the Institute was held in 2001 in Novosibirsk; the II Conference was joint with the VIII International Conference on Sintering and was held in Novosibirsk in 2004. The III Conference in this series was organized by the Institute and held in 2009 in Novosibirsk. The IV FBMT was held in Novosibirsk in 2013. Year after year, the Conference had demonstrated a growing interest from research organizations and industries to the mechanochemical technologies. The participation of Novosibirsk State University in the organization of this Conference guarantees active participation of young scientists in the Conference. The Conference has attracted a total of 230 contributions; 110 are scheduled for oral presentation. The contributions were submitted by scientists from 10 countries throughout the world. The present Book of Abstracts introduces recent advances in mechanical alloying, mechanochemical synthesis and production of new materials by the mechanochemical methods. We thank our sponsors for the financial support of FBMT 2018: - Novosibirsk State University, - Federal Agency for Scientific Organizations, - Russian Foundation for Basic Research, - NOVIC Co., - ABEX Co. Without their help, it would have been impossible to prepare this event successfully. We hope that the Conference will stimulate new research activities and help establish and strengthen international cooperation. N. Z. Lyakhov Chairman of FBMT 2018 3 V International Conference “Fundamental Bases of Mechanochemical Technologies” Novosibirsk, June 25-28, 2018 SCOPE OF THE CONFERENCE The V International Conference “Fundamental Bases of Mechanochemical Technologies” is devoted to all aspects of theory, methods and applications of mechanochemistry. The Conference will provide a forum for chemists, physicists, materials scientists, engineers and industry representatives to discuss the most recent achievements and current challenges of the fascinating field of mechanochemistry. The Conference will offer a lot of opportunities for exchanging ideas and finding new research partners. The contributions are expected to be focused on traditional and novel subjects of mechanochemistry including but not limited to: Theoretical aspects of mechanical activation. Mechanochemical reactions: kinetics and mechanisms. Mechanochemical synthesis. Mechanical alloying. Mechanochemistry of organic systems and plant raw materials. Mechanochemistry for the design of new materials including materials for energetics and additive technologies. New mechanochemical technologies. BACKGROUND OF THE CONFERENCE FBMT-2018 is the latest in the series of FBMT conferences previously held in Novosibirsk, Russia in 2001, 2004, 2009, 2013. These conferences have promoted dissemination of research results in the field of mechanochemistry and facilitated interactions between scientists and industry. INTERNATIONAL ADVISORY COMMITTEE Honorary Chairman Prof. Vladimir Boldyrev T. Akopova (Russia) Gao Hong (China) Rakesh Kumar (India) M. Alymov (Russia) T. Grigoreva (Russia) D. Rybin (Russia) E. Avvakumov (Russia) L. Isupova (Russia) M. Senna (Japan) P. Baláž (Slovakia) E. Ivanov (USA) V. Šepelák (Germany) N. Bazarnova (Russia) S. James (UK) A. Streletskii (Russia) P. Billik (Slovakia) A. M. Jorge Jr. (Brazil) L. Takacs (USA) E. Boldyreva (Russia) S. Kaloshkin (Russia) G. Telysheva (Latvia) G. Cagnetta (Italy) T. Ketegenov (Kazakhstan) Viet H. Nguyen (Vietnam) K. Chattopadhyay (India) B. Kuznetsov (Russia) P. Vitiaz (Belarus) F. Delogu (Italy) F. Lamaty (France) Weike Su (China) D. Dudina (Russia) E. Levashov (Russia) A. Yermakov Russia) F. Emmerling (Germany) O. Lomovsky (Russia) M. Zinigrad (Israel) T. Friščić (Canada) N. Lyakhov (Russia) A. F. Fuentes (Mexico) D. Oleszak (Poland) LOCAL ORGANIZING COMMITTEE Prof. N.Z. Lyakhov - chairman; Institute of Solid State Chemistry and Mechanochemistry SB RAS Prof. O.I. Lomovsky - deputy chairman; Institute of Solid State Chemistry and Mechanochemistry SB RAS Prof. T.P. Shakhtshneider -scientific secretary; Institute of Solid State Chemistry and Mechanochemistry SB RAS Prof. A.P. Nemudry - Institute of Solid State Chemistry and Mechanochemistry SB RAS Prof. E.V. Boldyreva - Institute of Solid State Chemistry and Mechanochemistry SB RAS Prof. N.F. Uvarov - Institute of Solid State Chemistry and Mechanochemistry SB RAS Prof. D.V. Dudina - Lavrentyev Institute of Hydrodynamics SB RAS Dr. I.G. Konstanchuk - Institute of Solid State Chemistry and Mechanochemistry SB RAS Dr. A.L. Bychkov - Institute of Solid State Chemistry and Mechanochemistry SB RAS CONFERENCE SECRETARIAT Irina Bagryantseva, Elizaveta Meteleva, Fedor Gorbunov, Inna Burdukova, Arina Ukhina 4 MILLS AND MECHANOCHEMICAL ACTIVATORS Mills of «CEM», «AGO», «APF» types have been designed at the Institute of Solid State. Chemistry and Mechanochemistry SB RAS and patented. Mills of «CEM» type are successfully used: * to grind and activate brittle substances and natural minerals with hardness up to 8-9 units to prepare construction materials; * in technological lines manufacturing various types of ceramics, pigments, fertilizers, medicines; * in the production of new materials as chemical CEM-7 reactors. TECHNICAL CHARACTERISTICS CEM-7 CEM-20 Operational mode Continuous or discrete Power of the electric motor, kW 5 18 Productivity in continuous mode ( e.g. for sand), kg/hour 20-50 850-1200 The maximum initial size of material particles, mm 3 5 Size of particles after milling, mm 5-20 10-60 Overall dimensions (length/ width/ height), mm: 700/540/420 1910/1225/870 Weight, kg 235 1300 PLANETARY AGO MILLS - ONE OF THE MOST POWERFUL IN THE CLASS Full milling time (up to 1-5 microns) - from 30 sec. (!) up to 5 minutes. The important advantage of these mills is the very intensive water cooling that prevents the milling material from overheating typical for conventional planetary mills. Can be delivered with a touch-screen control panel. Planetary mills are successfully used: * for thin and super-thin crushing of inorganic hard and super- AGO-2 hard materials; * for mechanochemical activation of inorganic materials; * for extraction of poorly soluble components in the environment of a solvent; * for synthesis of new materials, composites, catalysts. AGO-3 Novic Co Kutateladze str., 18, Novosibirsk, 630128. Russia Tel. +7383-335-64-03, E-mail: [email protected]; http://www.novic-mill.ru ABEX is a Russian company, founded in 2012, for the introduction of technologies based on mechanochemical activation of plant raw materials in the production of biologically active additives. Within a short period of time, the company managed to launch a line of parafarmaceuticals "Biocomposite", created on the basis of a unique mechanochemical technology and having no analogues on the pharmaceutical market. The highest bioavailability and effectiveness of drugs is confirmed by certificates of state registration of products. Biocomposite "Immuno" is a modern preparation of immunomodulating action with a high degree of bioavailability. It is created on the basis of mechanochemical technology, which allows to increase the effectiveness of preparations tens of times, increasing their absorption in the intestine. Biocomposite "Super Silicon" is a preparation based on the chelate complex of silicon. It is made from vegetable raw materials, rice husk and green tea. Synthesis is carried out by mechanochemical activation of the components. In the course of mechanochemical synthesis, the reagents and products are in solid form, which allows preventing oxidation and loss of the biologically active components. Biocomposite “Alginat” is a new effective preparation of complex action with a high degree of bioavailability. Mechanochemical technology provides the transition of calcium, magnesium, selenium, manganese, chromium and zinc from the inorganic phase to the water-soluble organic