Version March 2020 CLASSIFICATION & LABELLING SUMMARY (C&L Summary) Environment Hazards .............................................. 2 Physical chemical Hazards ....................................... 8 Health Hazards ..................................................... 14 Disclaimer The information contained in this paper is intended for guidance only and whilst the information is provided in utmost good faith and has been based on the best information currently available, is to be relied upon at the user’s own risk. No representations or warranties are made with regards to its completeness or accuracy and no liability will be accepted by the Hydrocarbon Solvents Producers Association (HSPA) - Cefic nor any company participating in HSPA for damages of any nature whatsoever resulting from the use of or reliance on the information. This document does not necessarily represent the views of any company participating in HSPA - Cefic. Users are reminded that the text of the REACH Regulation is the only authentic legal reference and that the information in this paper cannot serve as substitute for legal advice and each company must decide the strategy to follow. 1 Version March 2020 Environment Hazards Substance Name CLP classification GHS classification Category 1 : C9 Aromatics Hydrocarbons, C9, aromatics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C9-C10, aromatics > 1% naphthalene Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Category 2 : C10-C12 Aromatics Hydrocarbons, C10, aromatics, >1% naphthalene Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C10, aromatics, <1% naphthalene Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C10-C13, aromatics, <1% naphthalene Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C10-C13, aromatics, >1% naphthalene Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Category 3 : C9-C14 Aliphatics (2-25% Aromatics) Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 aromatics (2-25%) Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 aromatics (2-25%) Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, Aquatic Chronic cat 3 : H412 Aquatic acute cat 3, Chronic cat 3 : H402, H412 aromatics (2-25%) Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, Aquatic Chronic cat 3 : H412 Aquatic acute cat 3, Chronic cat 3 : H402, H412 aromatics (2-25%) Hydrocarbons, C12-C16, n-alkanes, isoalkanes, cyclics, Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 aromatics (2-25%) Category 4 : C14-C20 Aliphatics (2-25% Aromatics) Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, Not classified Not classified aromatics (2-30 %) Hydrocarbons, C16-C20, n-alkanes, isoalkanes, cyclics, Aquatic chronic cat 4 : H413 Aquatic chronic cat 4 : H413 aromatics (2-30 %) Category 5 : C5 Aliphatics Normal-Pentane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2 : H401 2 Version March 2020 Environment Hazards Substance Name CLP classification GHS classification Iso-Pentane (2-methylbutane) Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2 : H401 Cyclopentane Aquatic Chronic Cat 3 : H412 Aquatic Acute cat 2 : H401 Hydrocarbons, C5, n-alkanes, isoalkanes Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2 : H401 Category 6 : 6 Aliphatics n-Hexane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C6, isoalkanes, <5% n-hexane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 3, Chronic cat 2 : H402, H411 Hydrocarbons, C6, n-alkanes, isoalkanes, cyclics, n-hexane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 rich Hydrocarbons, C5-C7, n-alkanes, isoalkanes, <5% n-hexane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C5-C7, n-alkanes, isoalkanes, n-hexane rich Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 3, Chronic cat 2 : H402, H411 2-Méthyl-pentane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 3, Chronic cat 2 : H402, H411 2,2 Diméthyl-butane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 3, Chronic cat 2 : H402, H411 2,3 Diméthyl-butane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 3, Chronic cat 2 : H402, H411 Category 7 : C7-C9 Aliphatics Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, >5% Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 n-hexane Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 n-hexane Hydrocarbons, C7-C8, n-alkanes Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C6-C10, n-alkanes, isoalkanes, >5% n- Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 hexane Hydrocarbons, C7-C8, isoalkanes Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C7-C9, isoalkanes Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C8-C9, isoalkanes Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 3 Version March 2020 Environment Hazards Substance Name CLP classification GHS classification Hydrocarbons, C7-C8, cyclics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Aquatic Acute cat 1, Chronic cat 1 : Aquatic Acute cat 1, Chronic cat 1 : H400, H410 Normal-Heptane H400, H410 M factor : 10 M factor : 10 Aquatic Acute cat 1, Chronic cat 1 : Iso-Heptane Aquatic Acute cat 1, Chronic cat 1 : H400, H410 H400, H410 Aquatic Acute cat 1, Chronic cat 1 : 2,2,3 Triméthylbutane Aquatic Acute cat 1, Chronic cat 1 : H400, H410 H400, H410 Aquatic Acute cat 1, Chronic cat 1 : Normal-Octane Aquatic Acute cat 1, Chronic cat 1 : H400, H410 H400, H410 Aquatic Acute cat 1, Chronic cat 1 : Iso-Octane (2,2,4-triméthylpentane) Aquatic Acute cat 1, Chronic cat 1 : H400, H410 H400, H410 Aquatic Acute cat 1, Chronic cat 1 : Isooctane (UVCB) Aquatic Acute cat 1, Chronic cat 1 : H400, H410 H400, H410 Aquatic Acute cat 1, Chronic cat 1 : Nonane Aquatic Acute cat 1, Chronic cat 1 : H400, H410 H400, H410 Category 8 : C9-C14 Aliphatics (<2% Aromatics) Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% Not classified Not classified aromatics Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% Aquatic Chronic cat 3 : H412 Aquatic acute cat 3, Chronic cat 3 : H402, H412 aromatics Hydrocarbons, C9-C11, isoalkanes, cyclics, <2% aromatics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, Not classified Not classified <2% aromatics Hydrocarbons, C10-C13, isoalkanes, cyclics, <2% aromatics Aquatic Chronic cat 3 : H412 Aquatic Chronic cat 3 : H412 Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, Not classified Not classified <2% aromatics Hydrocarbons, C13-C15, n-alkanes, isoalkanes, cyclics, Not classified Not classified <2% aromatics Hydrocarbons, C12-C15, n-alkanes, isoalkanes, cyclics, Not classified Not classified <2% aromatics Hydrocarbons, C11-C14, isoalkanes, cyclics, <2% aromatics Not classified Not classified 4 Version March 2020 Environment Hazards Substance Name CLP classification GHS classification Hydrocarbons, C10-C12, isoalkanes, <2% aromatics Aquatic chronic cat 2 : H411 Aquatic chronic cat 2 : H411 Hydrocarbons, C11-C12, isoalkanes, <2% aromatics Not classified Not classified Hydrocarbons, C11-C13, isoalkanes, <2% aromatics Not classified Not classified Hydrocarbons, C10-C13, n-alkanes, <2% aromatics Not classified Not classified Hydrocarbons, C11-C14, n-alkanes, <2% aromatics Not classified Not classified Hydrocarbons, C10-C12, n-alkanes, <2% aromatics Not classified Not classified Hydrocarbons, C13-C14, n-alkanes, <2% aromatics Not classified Not classified Hydrocarbons, C9-C11, cyclics, <2% aromatics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411 Decane Not classified Not classified Undecane Not classified Not classified Dodecane Not classified Not classified Tridecane Not classified Not classified Tetradecane Not classified Not classified Isododecane (2,2,4,6,6-pentamethylheptane) Aquatic chronic cat 1 : H410 Aquatic chronic cat 1 : H410 Hydrocarbons, C4, 1,3-butadiene-free polymd, triisobutylene Aquatic chronic cat 4 : H413 Aquatic chronic cat 4 : H413 fraction, hydrogenated Hydrocarbons, C10-C14 (even numbered), n-alkanes, Not classified Not classified isoalkanes, <2% aromatics Hydrocarbons, C12-C16, isoalkanes, cyclics, < 2% Not classified Not classified aromatics Hydrocarbons, C8-C11, n-alkanes, isoalkanes, <2% Not classified Not classified aromatics Hydrocarbons, C9-C11, n-alkanes, isoalkanes, <2% Not classified Not classified aromatics Hydrocarbons, C9-C12, n-alkanes, isoalkanes, <2% Not classified Not classified aromatics Hydrocarbons, C10-C13, n-alkanes, isoalkanes, <2% Not classified Not classified