SODIUM TRIMETAPHOSPHATE Bisley International LLC Chemwatch Hazard Alert Code: 1 Chemwatch: 182705 Issue Date: 27/06/2017 Version No: 4.1.4.8 Print Date: 07/07/2021 Safety Data Sheet according to OSHA HazCom Standard (2012) requirements S.GHS.USA.EN SECTION 1 Identification Product Identifier Product name SODIUM TRIMETAPHOSPHATE Chemical Name trisodium trimetaphosphate H3-O9-P3.3Na; metaphosphoric acid (H3P3O9) trisodium salt; sodium metaphosphate Na3(P3O9) (NaPO3)3; sodium trimetaphosphate; Synonyms trisodium cyclotriphosphate; trisodium metaphosphate; T5508 Chemical formula H3O9P3.3Na Other means of identification Not Available CAS number 7785-84-4 Recommended use of the chemical and restrictions on use Relevant identified uses Cleaning/degreasing preparation ingredient. Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party Registered company name Bisley International LLC Address 1790 Hughes Landing Boulevard Suite 400 The Woodlands TX 77380 United States Telephone +1 (844) 424 7539 Fax Not Available Website www.bisley.biz Email [email protected] Emergency phone number Association / Organisation Bisley International LLC CHEMWATCH EMERGENCY RESPONSE Emergency telephone +1 855 237 5573 +61 2 9186 1132 numbers Other emergency telephone +61 2 9186 1132 +1 855-237-5573 numbers Once connected and if the message is not in your prefered language then please dial 01 Una vez conectado y si el mensaje no está en su idioma preferido, por favor marque 02 SECTION 2 Hazard(s) identification Classification of the substance or mixture Considered a Hazardous Substance by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Not classified as Dangerous Goods for transport purposes. NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this SDSs are NOT to be used to fill in the NFPA 704 diamond. Blue = Health Red = Fire Yellow = Reactivity White = Special (Oxidizer or water reactive substances) Classification Eye Irritation Category 2B, Chronic Aquatic Hazard Category 4 Label elements Hazard pictogram(s) Not Applicable Signal word Warning Hazard statement(s) H320 Causes eye irritation. H413 May cause long lasting harmful effects to aquatic life. Page 1 continued... Chemwatch: 182705 Page 2 of 8 Issue Date: 27/06/2017 Version No: 4.1.4.8 SODIUM TRIMETAPHOSPHATE Print Date: 07/07/2021 Hazard(s) not otherwise classified Not Applicable Precautionary statement(s) Prevention P273 Avoid release to the environment. P264 Wash all exposed external body areas thoroughly after handling. Precautionary statement(s) Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. SECTION 3 Composition / information on ingredients Substances CAS No %[weight] Name 7785-84-4 100 trisodium trimetaphosphate Mixtures See section above for composition of Substances SECTION 4 First-aid measures Description of first aid measures If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper Eye Contact and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Inhalation Other measures are usually unnecessary. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Ingestion Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice. Most important symptoms and effects, both acute and delayed See Section 11 Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Fire-fighting measures Extinguishing media There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area. Special hazards arising from the substrate or mixture Fire Incompatibility None known. Special protective equipment and precautions for fire-fighters Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Fire Fighting Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. Non combustible. Fire/Explosion Hazard Not considered a significant fire risk, however containers may burn. Decomposition may produce toxic fumes of: Continued... Chemwatch: 182705 Page 3 of 8 Issue Date: 27/06/2017 Version No: 4.1.4.8 SODIUM TRIMETAPHOSPHATE Print Date: 07/07/2021 phosphorus oxides (POx) metal oxides May emit poisonous fumes. May emit corrosive fumes. SECTION 6 Accidental release measures Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Remove all ignition sources. Clean up all spills immediately. Minor Spills Avoid contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Moderate hazard. CAUTION: Advise personnel in area. Major Spills Alert Emergency Services and tell them location and nature of hazard. Control personal contact by wearing protective clothing. Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 Handling and storage Precautions for safe handling Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Safe handling Use in a well-ventilated area. Prevent concentration in hollows and sumps. Store in original containers. Keep containers securely sealed. Other information Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Conditions for safe storage, including any incompatibilities Glass container is suitable for laboratory quantities Suitable container Polyethylene or polypropylene container. Check all containers are clearly labelled and free from leaks. Metals and their oxides or salts may react violently with chlorine trifluoride and bromine trifluoride. These trifluorides are hypergolic oxidisers. They ignite on contact (without external source of heat or ignition) with recognised fuels - contact with these materials, following an ambient or slightly elevated temperature, is often violent and may produce ignition. The state of subdivision may affect the results. Storage incompatibility Phosphates are incompatible with oxidising and reducing agents. Phosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation of phosphates by oxidizing agents may result in the release of toxic phosphorus oxides. + x + o + + + X — Must not be stored together 0 — May be stored together with specific preventions + — May be stored together Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes of dangerous goods are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly. SECTION 8 Exposure controls / personal protection Control parameters Occupational Exposure Limits (OEL) INGREDIENT DATA Not Available Emergency Limits Ingredient TEEL-1 TEEL-2 TEEL-3 SODIUM Not Available Not Available Not Available TRIMETAPHOSPHATE Ingredient Original IDLH Revised IDLH trisodium trimetaphosphate Not Available Not Available Continued... Chemwatch: 182705 Page 4 of 8 Issue Date: 27/06/2017 Version No: 4.1.4.8 SODIUM TRIMETAPHOSPHATE Print Date: 07/07/2021 Exposure controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. Appropriate engineering The basic types of engineering controls are: controls Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Personal protection Safety glasses with side shields. Chemical goggles. Eye and face protection Contact lenses may pose a special hazard; soft contact lenses