Ehrenfest's Theorem Revisited

Ehrenfest's Theorem Revisited

EHRENFEST’S THEOREM REVISITED1 by H. Arod´z2 Jagiellonian University, Cracow, Poland Abstract Historically, Ehrenfest’s theorem (1927) is the first one which shows that classical physics can emerge from quantum physics as a kind of approximation. We recall the theorem in its original form. Next, we highlight its generalizations to the relativistic Dirac particle, and to a particle with spin and izospin. We argue that apparent classicality of the macroscopic world can probably be explained within the framework of standard quantum mechanics. 1 Introduction The principal aim of both classical and quantum mechanics is to describe motions of certain physical objects. Both theories can be very successfully applied to va- rious physical objects, but the sets of these objects do not coincide. As is well known, classical mechanics gives wrong predictions when applied to microsco- pic objects such as atoms. On the other hand, it seems that quantum mechanics is capable to correctly describe motions of the elementary particles as well as motions of macroscopic bodies, hence it has a wider range of applicability. Ne- vertheless, there are phenomena description of which requires a theory still more general than quantum mechanics. For example, scattering of elementary partic- les can lead to creation or annihilation of particles – here quantum field theory arXiv:1907.02354v1 [physics.hist-ph] 4 Jul 2019 is needed. Such a generalization of quantum mechanics to quantum field theory is well-known since the middle of 20th century. There are still some problems with it, but the prevailing opinion is that they concern more its mathematical side than foundations. Another departure from standard quantum mechanics seems to 1Article based on talk given at the XXII Kraków Methodological Conference “Emergence of the Classical”. Cracow, October 2018. 2Email: [email protected] 1 be necessary when an elementary particle interacts with a very complex, perhaps even randomly fluctuating or unstable, environment. Understanding of this case is rather poor. To a certain degree the situation is analogous to the well known par- tition of classical electrodynamics into the theory of the electromagnetic field in vacuum and the electrodynamics of continua with constitutive relations and other additional ingredients. An effective quantum mechanics in continua is still under construction. It turns out that classical mechanics can be derived from quantum mechanics as a kind of approximate theory. Such derivations are usually called classical limit of quantum mechanics. There exist several of them, including the discussed be- low Ehrenfest type classical limit, which dates back to 1927 [1], and is likely the oldest one. Its main feature is that it links solutions of the pertinent fundamental evolution equations, which are the Schroedinger wave equation in quantum me- chanics and the Newton equation of motion in classical mechanics. Other kinds of classical limits are carried out on more advanced levels of theory. For instance, one may derive from quantum mechanics the classical Hamilton-Jacobi equation [2], the Lagrange formalism [3], or distributions on phase space, see, for example, [4], [5]. Our main goal here is to recall the seminal paper [1], and to show, using mo- dern examples, how fruitful is the invented by Paul Ehrenfest method for deri- ving classical mechanics from quantum mechanics. It leads to very interesting extended versions of classical mechanics featuring, e. g., a non relativistic par- ticle with spin and izospin, or a relativistic particle with spin, which all emerge from quantum mechanics. Furthermore, Ehrenfest’s theorem provides a tantali- zing suggestion that perhaps whole classical physics can be recovered as certain approximations to quantum theories. Considering wave packets, we find some arguments that corroborate this idea. The present article is addressed to audience wider than just theoretical physici- sts. Nevertheless, certain familiarity with basic equations of classical and quantum mechanics is assumed. The plan of the article is as follows. First, we briefly discuss description of states of a particle in quantum mechanics with emphasis on the so called wave packets. Section 3 is devoted to the original form of Ehrenfest’s theorem. In Sec- tion 4 we sketch a solution of the main problem with the Ehrenfest method: the lack of relativistic covariance. Next, in the 5th Section we discuss certain exten- sion of that theorem, which leads to a less known example of classical mechanics of a point-like particle with spin and izospin. Section 6 contains remarks on appli- cability of quantum mechanics to macroscopic bodies, including a new argument 2 for practical nonexistence of so called Schroedinger’s cats. 2 Quantum states of a particle Classical mechanics and quantum mechanics address the same issue: description of motions of a set of particles. Such set could consists of just one particle, or a finite number of them. The restriction to finite number of particles is impor- tant, because otherwise one would have to use a field theory which is regarded as different from mechanics for several important reasons. Classical and quantum mechanics are structurally similar to each other in the sense that in both theories we introduce a space of states of the particle and we postulate an equation of mo- tion. They differ in the form of equation of motion: in classical mechanics this can be, for example, the Newton equation, while in quantum mechanics the Schro- edinger equation. Also the spaces of states are very different. For instance, for the simplest single, point-like particle it is six dimensional phase space in classical mechanics, and infinite dimensional Hilbert space in quantum mechanics. The different equations of motion, and different sets of measurable properties (called observables) for the same set of particles are possible because the spaces of states in classical and quantum mechanics are not identical. Therefore, we regard this latter difference as the most important one. In this article we consider the simplest particles, which we describe as ele- mentary. Particles which possess constituents, for example, hadrons, nuclei, or atoms, are excluded. Physical incarnations of the elementary particles are, e. g., electrons, photons, quarks, or the Higgs particle. The term ‘point-like particle‘ used above is well justified only in classical mechanics. It refers to the fact that in the simplest case the state of a single particle at fixed time t is given by the position and velocity of the particle. The position is represented by a point in the R3 space. In quantum mechanics the complete description of the state of the particle at a given time t is provided by a smooth wave function ψ(~x, t) defined on the R3 space 3. There is no reason to relate such a quantum particle with a material point moving in the space. Rather, it should better be pictured as a cloud of matter of a very special kind, which is present at all points where the wave function does not vanish. In particular, it does not have any constant shape or size. The most peculiar feature of the elementary quantum particle is that it can not be destroyed or created in parts in spite of its spatial 3For simplicity, we consider here only so called pure states, omitting more general mixed states. 3 extension, while, for example, a drop of water can be divided into parts, and one part evaporated without disturbing the remaining parts. Physical processes always involve whole elementary quantum particles, which are single indivisible entities, albeit spatially extended 4. With such picture of the quantum particle, the often discussed and experimentally verified nonlocality of quantum mechanics is natural and rather obvious feature. We shall return to the question what is the best intuitive picture of the quantum particle in the last Section. Certain special clouds of quantum matter are called wave packets. Roughly speaking, a wave packet is compact and it consists of a single bit, as opposed to more general quantum states of the particle which, for example, can consist of several non-overlapping compact bits. Change in time of any state is described by the Schrödinger equation. It turns out that in the case of particle in empty space typical wave packet expands. For example, the width l(t) of a three dimensional (spherical Gaussian) wave packet for a particle at rest is given by the formula [6] 2 2 2 h¯ t l(t)= vl0 + 2 2 , u m l0 u t where l0 is the initial width at t =0, m is the mass of the particle, h¯ is the Planck constant. This formula implies that the velocity of the expansion monotonically increases to the asymptotic value h¯ v0 = . ml0 −27 cm2 The value of Planck’s constant is h¯ =1.0545 10 g sec , and the masses of ·−28 −24 electron and proton are, respectively, me =9.1 10 g, mp =1.67 10 g. We would like to draw attention of the reader to the· exceedingly small values· of these masses. The hydrogen atom H – one proton plus one electron, and the hydrogen molecule H2 – two hydrogen atoms, also are very very light. If we would like to 5 have hand-picked one milligram of hydrogen gas , adding one molecule H2 per second, it would take about 1013 years, while the estimated age of our Universe is about 1.4 1010 years. One should be very cautious when extrapolating our picture of macroscopic· particles to such tiny objects. It is instructive to compute the asymptotic velocity v0 for various masses and −8 initial widths. Let us first take as the initial width l0 = 10 cm, which is the 4In literature this feature is often referred to as the unitarity. 5About 11 ccm at 0oC and the normal pressure. 4 km typical atomic size.

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