Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 18 SDS No. : 41762 V004.0 Tangit PVC-U Special Adhesive (formerly known as Tangit ALL Revision: 22.02.2018 PRESSURE) printing date: 17.05.2018 Replaces version from: 04.04.2017 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Tangit PVC-U Special Adhesive (formerly known as Tangit ALL PRESSURE) Contains: Tetrahydrofuran Butanone Cyclohexanone 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Pipe adhesive 1.3. Details of the supplier of the safety data sheet Henkel Ltd Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: +44 1442 278000 Fax-no.: +44 1442 278071 [email protected] 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 0 8701 906777 - For further general health & safety, technical and practical advice on this product, please call +44 (0) 1606 593933 or write to: Technical Services; Henkel Limited; Road 5; Winsford Industrial Estate; Winsford; Cheshire; CW7 3QY- Email: [email protected] SDS No.: 41762 V004.0 Tangit PVC-U Special Adhesive (formerly known as Tangit ALL Page 2 of 18 PRESSURE) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (CLP): Flammable liquids Category 2 H225 Highly flammable liquid and vapor. Skin irritation Category 2 H315 Causes skin irritation. Serious eye damage Category 1 H318 Causes serious eye damage. Carcinogenicity Category 2 H351 Suspected of causing cancer. Specific target organ toxicity - single exposure Category 3 H336 May cause drowsiness or dizziness. Target organ: Central Nervous System Specific target organ toxicity - single exposure Category 3 H335 May cause respiratory irritation. Target organ: respiratory tract irritation 2.2. Label elements Label elements (CLP): Hazard pictogram: Signal word: Danger Hazard statement: H225 Highly flammable liquid and vapor. H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. Precautionary statement: P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe mist/vapours. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/eye protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor. P501 Dispose of contents/container in accordance with national regulation. 2.3. Other hazards Solvents contained in the product evaporate during processing and their vapors can form explosive/highly inflammable air/vapor mixtures. Pregnant women should absolutely avoid inhalation and skin contact. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. SDS No.: 41762 V004.0 Tangit PVC-U Special Adhesive (formerly known as Tangit ALL Page 3 of 18 PRESSURE) SECTION 3: Composition/information on ingredients 3.2. Mixtures General chemical description: Adhesive solution Base substances of preparation: Non-plasticized PVC in a mixture of organic solvents Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components EC Number content Classification CAS-No. REACH-Reg No. Butanone 201-159-0 20- 40 % STOT SE 3 78-93-3 01-2119457290-43 H336 Eye Irrit. 2 H319 Flam. Liq. 2 H225 Tetrahydrofuran 203-726-8 25- 30 % STOT SE 3 109-99-9 01-2119444314-46 H336 Flam. Liq. 2 H225 STOT SE 3 H335 Eye Irrit. 2 H319 Carc. 2 H351 Acute Tox. 4; Oral H302 Cyclohexanone 203-631-1 10- < 25 % Flam. Liq. 3 108-94-1 01-2119453616-35 H226 Acute Tox. 4; Oral H302 Acute Tox. 4; Dermal H312 Acute Tox. 4 H332 Eye Dam. 1 H318 Skin Irrit. 2 H315 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. SECTION 4: First aid measures 4.1. Description of first aid measures General information: In case of adverse health effects seek medical advice. Inhalation: Move to fresh air, consult doctor if complaint persists. Skin contact: Rinse with running water and soap. Skin care. Remove contaminated clothes immediately. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, do not induce vomiting, consult a doctor. SDS No.: 41762 V004.0 Tangit PVC-U Special Adhesive (formerly known as Tangit ALL Page 4 of 18 PRESSURE) 4.2. Most important symptoms and effects, both acute and delayed Vapors may cause drowsiness and dizziness. After eye contact: Corrosive, may cause permanent damage to eyes (impairment of vision). SKIN: Redness, inflammation. RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released. 5.3. Advice for firefighters Wear protective equipment. Wear self-contained breathing apparatus. Additional information: Cool endangered containers with water spray jet. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Avoid contact with skin and eyes. Wear protective equipment. Danger of slipping on spilled product. 6.2. Environmental precautions Do not empty into drains / surface water / ground water. 6.3. Methods and material for containment and cleaning up Remove with liquid-absorbing material (sand, peat, sawdust). Dispose of contaminated material as waste according to Section 13. 6.4. Reference to other sections See advice in section 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Do not empty waste into waste water drains. During processing and drying after adhesion, ventilate well. Avoid all sources of fire such as stoves and ovens. Switch off all electrical devices such as parabolic heaters, hot plates, storage heaters etc. in good time for them to have cooled down before commencing work. Avoid all sparks, including those occurring at electrical switches and devices. Avoid skin and eye contact. Hygiene measures: Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. SDS No.: 41762 V004.0 Tangit PVC-U Special Adhesive (formerly known as Tangit ALL Page 5 of 18 PRESSURE) 7.2. Conditions for safe storage, including any incompatibilities Store in sealed original container. Observe rules and measures for storage of flammable liquids. Temperatures between + 5 °C and + 35 °C Store in a cool place in closed original container. Do not store together with food or other consumables (coffee, tea, tobacco, etc.). 7.3. Specific end use(s) Pipe adhesive SDS No.: 41762 V004.0 Tangit PVC-U Special Adhesive (formerly known as Tangit ALL Page 6 of 18 PRESSURE) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list category / Remarks Tetrahydrofuran 100 300 Short Term Exposure EH40 WEL 109-99-9 Limit (STEL): [TETRAHYDROFURAN] Tetrahydrofuran Skin designation: Can be absorbed through the EH40 WEL 109-99-9 skin. [TETRAHYDROFURAN] Tetrahydrofuran 50 150 Time Weighted Average EH40 WEL 109-99-9 (TWA): [TETRAHYDROFURAN] Tetrahydrofuran 50 150 Time Weighted Average Indicative ECTLV 109-99-9 (TWA): [TETRAHYDROFURAN] Tetrahydrofuran 100 300 Short Term Exposure Indicative ECTLV 109-99-9 Limit (STEL): [TETRAHYDROFURAN] Butanone 300 899 Short Term Exposure EH40 WEL 78-93-3 Limit (STEL): [BUTAN-2-ONE (METHYL ETHYL KETONE)] Butanone Skin designation: Can be absorbed through the EH40 WEL 78-93-3 skin. [BUTAN-2-ONE (METHYL ETHYL KETONE)] Butanone 200 600 Time Weighted Average EH40 WEL 78-93-3 (TWA): [BUTAN-2-ONE (METHYL ETHYL KETONE)] Butanone 200 600 Time Weighted Average Indicative ECTLV 78-93-3 (TWA): [BUTANONE] Butanone 300 900 Short Term Exposure Indicative ECTLV 78-93-3 Limit (STEL): [BUTANONE] Cyclohexanone Skin designation: Can be absorbed through the ECTLV 108-94-1 skin. [CYCLOHEXANONE] Cyclohexanone Skin designation: Can be absorbed through the EH40 WEL 108-94-1 skin. [CYCLOHEXANONE] Cyclohexanone 20 82 Short Term Exposure EH40 WEL 108-94-1 Limit (STEL): [CYCLOHEXANONE] Cyclohexanone 10 41 Time Weighted Average EH40 WEL 108-94-1 (TWA): [CYCLOHEXANONE] Cyclohexanone 10 40,8 Time Weighted Average Indicative ECTLV 108-94-1 (TWA): [CYCLOHEXANONE] Cyclohexanone 20 81,6 Short Term Exposure Indicative ECTLV 108-94-1 Limit (STEL): [CYCLOHEXANONE] Polyvinyl chloride 10 Time Weighted Average EH40 WEL 9002-86-2 (TWA): [POLYVINYL CHLORIDE, INHALABLE DUST] Polyvinyl chloride 4 Time Weighted Average EH40 WEL 9002-86-2 (TWA):