Product Selector Coatings, Civil Engineering and Fibers & Textiles EPI-REZ™ Resins and EPIKURE™ Curing Agents for Waterborne Epoxy Applications Our Products for Hexion takes an integrated approach Americas to sustainability with the ultimate goal of creating long-term stakeholder value through environmental and product stewardship, safety and compliance. Our sustainability initiative is driven by product innovation, operational excellence and outstanding corporate citizenship. EPI-REZ Waterborne Resins and EPIKURE Curing Agents can be used in applications, such as protective coatings, flooring, adhesives, anticorrosive primers Hexion Inc. (Hexion) offers one of and textile binders, to reduce or eliminate solvent content without sacrificing the broadest lines of waterborne performance. products in the industry. Our EPI-REZ Waterborne Resins are also EPI-REZ Waterborne Epoxy Resins used to coat engineering fibers in order to and their corresponding EPIKURE provide superior matrix adhesion in high- performing fiber-reinforced composite Curing Agents constitute unique applications. systems that enable the formulator Hexion pursues waterborne technology to develop optimally performing platforms for coating systems because Hexion believes in the protection of our waterborne end-products. environment and the advancement of health and safety for our customers. TABLE 1. Waterborne Epoxy Resins for Coatings and Civil Engineering Applications Product Remarks [ % ] [ µm ] [ g/eq ] [ g/eq ] Solvent Solvent [ mPa·s ] Heat cure Heat as supplied supplied as as supplied supplied as [ mmol/kg ] [ mmol/kg ] Ambient cureAmbient Dv (vol. mean) Solids content content Solids Marine coatingMarine Weight on solids Particle size, CI, Civil engineeringCivil Epoxy Equivalent Epoxy Viscosity at 25 °C Protective coating Protective Epoxy Group Content Group Epoxy Transportation coating Transportation Epoxy Equivalent Weight Weight Equivalent Epoxy Packaging & Coil coating Coil & Packaging Epoxy Group Content on solids Bisphenol A Epoxy Resins EPI-REZ WD-510 – – 190 - 190 - 8000 - 100 – – Water dispersible bisphenol A 205 205 12000 • • epoxy resin. EPI-REZ WD-512 – – 195 - 195 - 15000 - 100 – – Water dispersible bisphenol A 210 210 60000 • • epoxy resin. EPI-REZ 3520-WY-55 – – 485 - 882 - 7000 - 55 – water / Waterborne dispersion of a 555 1009 17000 2-propoxy- semi-solid Bisphenol A epoxy ethanol • • resin (EPON 1001-type) with an organic co-solvent. EPI-REZ 3540-WY-55 500 - 273 - 1600 - 2933 - 7000 - 53.5 - 0.35 - water / Waterborne dispersion of a solid 625 341 2000 3663 17000 55.5 0.85* 2-propoxy- Bisphenol A epoxy resin (EPON ethanol • • 1007-type) with an organic co-solvent. EPI-REZ 3546-WH-53 454 - 241 - 1900 - 3585 - 1000 - 52.0 - 0.5 - 2.0 water / Waterborne dispersion of a 526 279 2200 4510 15000 54.0 1-methoxy- solid Bisphenol A epoxy resin 2-propanol • • (EPON 1007-type) with a non HAPS co-solvent. EPI-REZ 3547-WY-57 500 - 285 - 1600 - 2807 - <10000 56.0 - 0.4 - 1.5 water / Nonionic dispersion of a high 625 356 2000 3509 58.0 2-propoxy- molecular weight BPA epoxy resin ethanol • • in water and 2-propoxyethanol (EGMPE). EPI-REZ 6520-WH-53 1667 - 888 - 500 - 939 - 1000 - 52.0 - – water / NewGen™ Waterborne dispersion 2000 1065 600 1127 6000 54.5 1-methoxy- of a solid Bisphenol A epoxy resin 2-propanol (EPON 1001-type) with a non • • • • HAPS co-solvent. Provides exceptional corrosion protection for metal substrates as primers, DTM and topcoats. EPI-REZ™ 7510-W-60 4650- 2837 - 185 - 303 - 500 - 60.0 - 1.0 - 2.2 water Nonionic Waterborne Emulsion of a 5400 3294 215 352 5000 62.0 liquid BPA epoxy resin. Low or no • • odor, non-flammable and Liquid epoxy performance. EPI-REZ 7520-WD-52 1740 - 905 - 475 - 913 - 1000 - 51.0 - – water / NextGen Epoxy™ Non-ionic 2105 1095 575 1105 6000 54.0 diacetone aqueous dispersion of a modified alcohol/ EPON™ Resin 1001 solid epoxy 1-butoxy- resin. Coatings performance 2-propanol • • • • comparable to solvent-borne systems while meeting stringent Volatile Organic Compounds (VOC) regulations. Modified Bisphenol A Epoxy Resins EPI-REZ 5522-WY-55 1429 - 765 - 550 - 1028 - 8000 - 52.0 - 0.2 - 07* water / Waterborne dispersion of a novolac 1818 973 700 1307 19000 55.0 2-propoxy- modified Bisphenol A epoxy resin ethanol • • • • (EPON 1002-type) with an organic co-solvent. High chemical and corrosion resistance. Epoxy Novolac Resins EPI-REZ 5003-W-55 4651 - 2698 - 195 - 336 - 2000 - 57.0 - 0.6 - 1.2 water Waterborne dispersion of an 5128 2974 215 371 15000 59.0 epoxidized Bisphenol A novolac • • • resin with an average functionality of 3 (EPON SU-3 type). 2 TABLE 2. Amine Curing Agents for Waterborne Coatings and Civil Engineering Applications Product Remarks [ % ] [ g/eq ] [ g/eq ] Solvent Solvent [ mPa·s ] Heat cure Heat Ambient cureAmbient Color GardnerColor Solids content Solids Marine coatingMarine Weight on solids Civil engineeringCivil Viscosity at 25 °C Protective coating Protective Weight as supplied supplied as Weight Hydrogen Equivalent Equivalent Hydrogen Equivalent Hydrogen Transportation coating Transportation Packaging & Coil coating Coil & Packaging Amine Curing Agents EPIKURE 466 124 225 7000 - 54.0 - 56.0 6 max water Used for Epoxy Modified 12000 • • Concrete (ECC) systems. EPIKURE 6870-W-53 225 425 1000 - 51.0 - 54.0 milky-white water NewGen™ curing agent is a 11000 • • • modified polyamide for use with EPI-REZ Resin 6520-WH-53. EPIKURE 8290-Y-60 163 272 Z3 - Z5* 59.0 - 61.0 9 max 2-propoxy- Water reducible, high molecular ethanol / • • • weight amine adduct. acetic acid EPIKURE 8530-W-75 90 120 6000 - 75 5 max water NextGen Epoxy™ curing agent 13000 • • • • designed for use with EPI-REZ Resin 7520-WD-52. EPIKURE 8537-WY-60 174 290 2300 - 60 9 max water / Water reducible amine adduct. 6400 2-propoxy- • • • • ethanol EPIKURE 8538-Y-68 204* 300* 250 - 500 67.0-70.0 7 max 2-propoxy- Modified polyamine adduct ethanol for highly Zinc - filled systems, • • • • in combination with EPI-REZ™ 6520-WH-53. * Typical values Accelerator EPIKURE 3253 – – 180 - 380 100 6 max – Tertiary amine, • • • • • • tris (dimethyl amino-methyl) phenol. 3 TABLE 3. Waterborne Epoxy Resins for Structural Applications Product 1 2 Remarks [ % ] [ µm ] [ g/eq ] [ g/eq ] Solvent Solvent [ mPa·s ] Heat cure Heat as supplied as as supplied supplied as [ mmol/kg ] [ mmol/kg ] Rubber goods Rubber Solids content content Solids Weight on solids Epoxy Equivalent Epoxy Viscosity at 25 °C Epoxy Group Content Group Epoxy Heat curable binder Heat curable varnish Epoxy Equivalent Weight Weight Equivalent Epoxy Fiber sizing thermoset matrix thermoset sizing Fiber Epoxy Group Content on solids Particle size, CI, Dv (vol. mean) Fiber sizing thermoplastic sizing Fiber matrix Bisphenol A Epoxy Resins EPI-REZ™ 3510-W-60 4651 - 2837 - 185 - 303 - 500 - 60.0 - 1.0 - 2.2 water Waterborne emulsion of a low 5405 3297 215 352 5000 62.0 • • • molecular weight liquid Bisphenol A epoxy resin. EPI-REZ 3514-W-56 4445 - 2489 - 205 - 366 - 1000 - 55.0 - 0.3 - 1.0 water Waterborne dispersion of a liquid 4880 2733 225 402 15000 57.0 • BPA epoxy resin. EPI-REZ 3515-W-60 3636 - 2291 - 225 - 357 - 4000 - 62.0 - 0.5 - 1.3 water Waterborne dispersion of a 4444 2800 275 436 15000 64.0 • • • semi-solid Bisphenol A epoxy resin. EPI-REZ 3522-W-60 1399 - 832 - 615 - 1033 - 8000 - 58.5 - 1.1 - 3.4 water Waterborne dispersion of a solid 1626 968 715 1201 18000 60.5 • • • • Bisphenol A epoxy resin (EPON 1002-type). EPI-REZ 3540-WY-55 500 - 273 - 1600 - 2933 - 7000 - 53.5 - 0.35 - water / Waterborne dispersion of a solid 625 341 2000 3663 17000 55.5 0.85* 2-propoxy- Bisphenol A epoxy resin (EPON ethanol • • • 1007-type) with an organic co-solvent. EPI-REZ 3546-WH-53 454 - 241 - 1900 - 3585 - 1000 - 52.0 - 0.5 - 2.0 water / Waterborne dispersion of a solid 526 279 2200 4150 15000 54.0 1-methoxy- Bisphenol A epoxy resin (EPON 2-propanol • • • 1007-type) with a non HAPS co-solvent. EPI-REZ 3547-WY-57 500 - 285 - 1600 - 2807 - <10000 56.0 - 0.4 - 1.5 water / High molecular weight BPA epoxy 625 356 2000 3509 58.0 2-propoxy- resin dispersion in water and ethanol • • • 2-propoxyethanol (EGMPE). For reinforcement of thermoplastics. Modified Bisphenol A Epoxy Resins EPI-REZ 5520-W-60 1786 - 1054 - 480 - 814 - 2000 - 58.0 - 0.8 - 2.8 water Waterborne dispersion of a 2083 1229 560 949 15000 60.0 • • urethane-modified Bisphenol A solid epoxy resin. Epoxy Novolac Resins EPI-REZ 5003-W-55 4651 - 2698 - 195 - 336 - 2000 - 57.0 - 0.6 - 1.2 water Waterborne dispersion of an 5128 2974 215 371 15000 59.0 epoxidized Bisphenol A novolac • • • • • (aromatic) resin with an average functionality of 3 (EPON SU-3 type). EPI-REZ 5040-W-58 4875 - 2828 - 185 - 319 - 4000 - 56.0 - < 1.0 water Epoxy phenol novolac dispersion, 5405 3135 205 353 18000 60.0 • • • • • average functionality = 3.6 EPI-REZ 5054-W-65 4875 - 3144 - 180 - 279 - <15000 63.0 - < 0.7 water Epoxy phenol novolac dispersion, 5555 3583 205 318 66.0 • • • • • average functionality = 3.6 EPI-REZ 5108-W-60 4000 - 2360 - 210 - 356 - 5000 - 58.0 - < 1.7 water Waterborne dispersion of an 8 4760 2808 250 424 13000 60.0 • • • functionality Bisphenol A epoxy novolac resin. EPI-REZ 6006-W-68 3920 - 2548 - 215 - 392 - 500 - 63.0 - < 2.0 water Waterborne dispersion of an 4650 3022 255 331 2000 67.0 • • • • • epoxidized o-cresylic novolac resin with an average functionality 6. 1 Heat curable binder for non woven, coated abrasives, composites, adhesives, sealers. 2 Heat curable varnishes for plastics, metal, glass, wood, paper, textiles. 4 TABLE 4. Amine Curing