EN EN EN COMMISSION OF THE EUROPEAN COMMUNITIES Brussels, 17.10.2007 SEC(2007) 1411 PART II – ANNEX 1 COMMISSION STAFF WORKING DOCUMENT Monitoring of Pesticide Residues in Products of Plant Origin in the European Union, Norway, Iceland and Liechtenstein 2005 1 EN EN TABLE OF CONTENTS Table A: List of all detectable substances ............................................................................... 3 Table B: Overall results of the national monitoring programmes........................................... 8 Table C: Fresh (incl. frozen) fruit and vegetables, surveillance sampling: results of the national monitoring programmes ............................................................................. 9 Table D: Cereals, surveillance sampling: results of the national monitoring programmes... 10 Table E: Fresh (incl. frozen) fruit and vegetables, enforcement sampling: results of the national monitoring programmes ........................................................................... 11 Table F: Processed products, surveillance sampling: results of the national monitoring programmes............................................................................................................ 12 Table G: Samples with residues of more than one pesticide in fresh (incl. frozen) fruit, vegetables and cereals, surveillance and enforcement sampling ........................... 13 Table H: Pesticides found most often in the national (incl. co-ordinated) monitoring programmes in the European Union, Norway, Iceland and Liechtenstein for a) fruit and vegetables and b) cereals, as reported ............................................................. 14 Table I: Numbers of samples taken by participating States for each commodity in the EU co-ordinated programme ........................................................................................ 21 Table K: Residues of pesticides in the nine commodities as analysed in the EU Member States and EEA States ............................................................................................ 22 Table L: Results from the EU co-ordinated monitoring programme for pesticide residues for each pesticide analysed for in pears, beans, potatoes, carrots, oranges, mandarins, spinach, rice and cucumber. ................................................................................... 23 Table M: Presentation of the most important pesticide-commodity combinations where residues were found (in alphabetical order) ........................................................... 26 Table N: Number and origin of the samples taken by country (sum of surveillance and follow-up enforcement samples, sum of fresh (incl. frozen) fruit, vegetables, cereals and processed products............................................................................... 30 Table O: Accreditation, participation in proficiency tests and implementation of the EU Quality Control Procedures of the pesticide residue laboratories .......................... 31 2 EN EN Table A: List of all detectable substances The table lists all substances analysed for in surveillance samples of fruit and vegetables. It specifies, where they were detected in one to four samples (1-4), or in five or more samples (>4). Substances are listed according to their residue definition in the EC-Directives or, for those not covered by EC-Directives, in the national legislation, e.g. "endosulfan" refers to "α- endosulfan", "β-endosulfan" and "endosulfan-sulphate”. 1-naphthylacetic acid 1-4 azamethiphos ether 2,3,5,6-TCA, azinphos-ethyl >4 bromoxynil-octanoate 2,3,5-trimethacarb azinphos-methyl >4 brompyrazon 2,4,5-T 1-4 aziprotryne bromuconazole 1-4 2,4-D >4 azocyclotin bufencarb 2,4-DB azolamide bupirimate >4 2,4-dimethylaniline 1-4 azoxystrobin >4 buprofenzin >4 2,6-dichlorobenzamide barban 1-4 butocarboxim sulfon 2-chlorethanol, total >4 beflubutamid butocarboxim, sum 1-4 3,4,5-trimethacarb 1-4 benalaxyl >4 butoxycarboxim 3,4-dichloranilin, total 1-4 benazolin butralin 3-ketocarbofuran bendiocarb, sum 1-4 buturon 4,4-dibrombenzophenon benfluralin 1-4 butylate 4,4-dichlorbenzophenon benfuracarb 1-4 cadusafos 1-4 4-CPA 1-4 benodanil captafol >4 abamectin, sum >4 bensulfuron-methyl captan >4 acephate >4 bensultap captan/folpet, sum >4 acetamiprid >4 bentazone 1-4 carbanolate acibenzolar benthiavalicarb carbaryl >4 acibenzolar-S-methyl benzoximate 1-4 carbendazim, sum >4 aclonifen >4 benzoylprop-ethyl carbetamide acrinathrin >4 benzthiazuron carbofuran, sum >4 alachlor 1-4 beta-cyfluthrin carbon tetrachloride aldicarb, sum >4 bifenazate 1-4 carbophenothion 1-4 aldimorph bifenox carbosulfan 1-4 aldrin >4 bifenthrin >4 carboxin 1-4 allethrin binapacryl >4 carfentrazon-ethyl 1-4 allidochlor bioallethrin cartap (hydrochoride) alpha-cypermethrin >4 biphenyl >4 cekafix alphamethrin 1-4 bitertanol >4 chinomethionat 1-4 ametryn 1-4 boscalid (nicobifen) >4 chloanil amidithion brofenprox chlorbenside amidosulfuron bromacil 1-4 chlorbenside sulfon aminocarb bromfenvinphos chlorbromuron aminotriazol bromfenvinphos-methyl chlorbufam amitraz, total >4 bromide, total >4 chlordane, sum (a-/g-) anilazine 1-4 bromocyclen chlordane, sum (a-/g- antraquinone bromofenoxim /oxy-) aspon bromophos-ethyl >4 chlordecone >4 asulam bromophos-methyl 1-4 chlordene, alpha- atraton bromopropylate >4 chlordene, gamma- atrazine bromoxynil chlordimeform azaconazole 1-4 bromoxynil-methyl- chlorfenapyr >4 3 EN EN chlorfenethol cycluron dimefuron chlorfenprop-methyl cyflufenamid dimethachlor chlorfenson 1-4 cyfluthrin, sum >4 dimethametryn chlorfenvinphos >4 cyhalofop-butyl 1-4 dimethenamid chlorfluazuron 1-4 cyhalothrin >4 dimethenamid-p chlorflurenol cyhexatin, sum >4 dimethipin chlorflurenol, total cymoxanil >4 dimethirimol chloridazon 1-4 cypermethrin, total >4 dimethoate, sum >4 chlormephos cyproconazole >4 dimethomorph >4 chlormequat >4 cyprodinil >4 dimethylvinphos (E) chloroaniline(3-) 1-4 cyprofuram dimethylvinphos (Z) chlorobenzilate cyromazine >4 dimoxystrobin chloroneb daled diniconazole >4 chlorothalonil >4 daminozide, sum 1-4 dinitramine 1-4 chloroxuron DDMU dinobuton chlorpropham >4 DDT, sum >4 dinocap chlorpropylate DEF 6 dinoseb, sum chlorpyrifos-ethyl >4 deltamethrin >4 dinoterb 1-4 chlorpyrifos-methyl >4 demeton-O dioxabenzofos chlorsulfuron demeton-S-methyl 1-4 dioxacarb chlorthal demeton-S-methyl- dioxathion 1-4 chlorthal-dimethyl >4 sulfone >4 diphenamid chlorthiamid desethylatrazin diphenyl sulfone chlorthion desisopropylatrazin diphenylamine >4 chlorthiophos 1-4 desmedipham dipropetryn chlortoluron desmetryn dipropyliso- chlozolinate 1-4 diafenthiuron cinchomeronat cinidon-ethyl dialifos diquat >4 cinosulfuron diallate disulfoton, sum cis-nonachlor diazinon >4 ditalimfos 1-4 cis-permethrin dicamba dithianon >4 clethodim dichlofluanid >4 dithofencarb >4 clodinafop-propagyl dichlone diuron >4 cloethocarb dichlorbenil >4 DMSA 1-4 clofentezine >4 dichlorfenthion DMST >4 clomazone 1-4 dichlorprop >4 DNOC clopyralid 1-4 dichlorvos >4 dodemorph 1-4 cloquintocet-methyl diclobutrazol dodine >4 cloquintocet-mexyl diclofop-methyl edifenphos clothianidin >4 dicloran >4 endosulfan, sum >4 copper compounds >4 dicofol >4 endosulfanalkohol coumaphos dicrotophos >4 endrin, sum >4 crimidine dieldrin, sum >4 endrin-aldehyd crotoxyfos diethatyl-ethyl EPN >4 crufomate 1-4 diethofencarb >4 epoxiconacole >4 cyanazine difenoconazole >4 EPTC cyanofenphos difenoxuron esfenvalerate >4 cyanophos diflovidazin etacelasil cyazofamid >4 diflubenzuron >4 etaconazole cycloate diflufenican 1-4 ethalfluralin cycloxydim dimefox ethephon >4 4 EN EN ethidimuron fipronil >4 genite 1-4 ethiofencarb, sum 1-4 fipronil-sulfon glufosinate-ammonium >4 ethion >4 flampropisopropyl glyphosate 1-4 ethiprole 1-4 flamprop-methyl glyphosate-trimesium 1-4 ethirimol >4 flazasulfuron halacrinate ethoate-methyl florasulam halfenprox ethofumesate 1-4 fluazifop after halofenozide 1-4 ethoprophos >4 hydrolysis >4 haloxyfop >4 ethoxyquin >4 fluazifop, total 1-4 haloxyfop methyl ester ethylene oxide 1-4 fluazifop-p-butyl 1-4 haloxyfop-etotyl 1-4 etofenprox >4 fluazinam 1-4 haloxyfop-R, total etoxazole 1-4 fluazolate HCH, sum (a-/b-/d-/e-) >4 etridiazole >4 fluazuron heptachlor, sum >4 etrimfos 1-4 flubenzimine heptachloroepoxide >4 famophos fluchloralin heptenophos 1-4 famoxadone >4 flucycloxuron 1-4 hexachlorobenzene >4 fenamidone >4 flucythrinate 1-4 hexaconazole >4 fenamiphos, sum 1-4 fludioxonil >4 hexaflumuron 1-4 fenarimol >4 flufenacet fluthiamid hexazinone fenazaflor flufenoxuron >4 hexythiazox >4 fenazaquin >4 flumethrin hydrocyanic acid 1-4 fenazox flumetralin hydrogen phosphide >4 fenbuconazole >4 flumioxazin hymexazol fenbutatin oxide >4 fluometuron imazalil >4 fenchlorazole fluorochloridone 1-4 imazamethabenz-methyl fenchlorim fluorodifen imazamox fenchlorphos, sum 1-4 fluoroglycofen-ethyl imazapyr fenfuram fluotrimazole imazaquin 1-4 fenhexamid >4 fluquinconazole >4 imazethapyr fenitrothion >4 flurecol-butyl imazethapyr fenobucarb flurenol imibenconazol fenoprop flurochloridone imidacloprid >4 fenothiocarb fluroxypyr indoxacarb >4 fenoxaprop flurprimidol iodofenphos fenoxaprop-p flurtamone ioxynil 1-4 fenoxycarb >4 flusilazole >4 ioxynil octanoate fenpiclonil 1-4 flusulfamide iprobenfos fenpropathrin >4 flutolanil 1-4 iprodione >4 fenpropidin 1-4 flutriafol >4 iprovalicarb >4 fenpropimorph >4 fluvalinate >4 isazofos fenpyroximate >4 folpet >4 isobenzan fenson fonofos 1-4 isocarbamid fensulfothion 1-4 forchlorfenuron isodrin fenthion, sum >4 formetanate 1-4 isofenphos, sum 1-4 fentin 1-4 formothion isomethiozin