Femtochemistry of Guest-Host Systems

Femtochemistry of Guest-Host Systems

Poster Femtosecond dynamics in Confined Systems A. Douhal*, M.A. Carranza, M. Sanz and J.A. Organero Departamento de Química física, Sección de Químicas, Fac. de Ciencias del Medio Ambiente, Universidad de Castilla-La Mancha, Avda. Carlos III, S.N. 45071 Toledo (Spain). [email protected] Ultrafast dynamics of molecular systems in confined media has large effect on the space and time domain behaviours of nanostructures (1). In this Lecture, we will present and discuss recent results of femtosecond studies of single and double proton transfer reactions in confined media provided by nanocavities of cyclodextrins and micelles. We examined in real time of reactions (proton transfer events) the effect of confinement on the nanostructure dynamics. The results show an ultrafast (less than 100 fs) first step giving birth to an intermediate which shows femtosecond and hundreds of picosecond dynamics leading to the final structure at the excited state. To study the energy barrier and tunnelling on the dynamics in both solution and nanostructures, we have also examined the effects of isotope (H/D) and excess energy of excitation when observing at different wavelengths of the emission spectrum. The results clearly show that confined water in nanostructure has a very slow (ps regime) dynamics. We believe that the obtained data are relevant to understanding the behaviour of nanodevices where confinement plays a key role in their function and stability. References: For recent review see for example: A. Douhal, Ultrafast Dynamics in Cyclodextrin Nanocavities, Chem. Rev. 2004, 104, 1955. Acknowledgements: This work was supported by the Ministry of Science and Technology (MCYT, Spain) and “Consejeria de Ciencia y Tecnologia de la JCCM, Spain” through projects MAT-2002-01829 and PAI-02-004. TNT2004 September 13-17, 2004 Segovia-Spain .

View Full Text

Details

  • File Type
    pdf
  • Upload Time
    -
  • Content Languages
    English
  • Upload User
    Anonymous/Not logged-in
  • File Pages
    1 Page
  • File Size
    -

Download

Channel Download Status
Express Download Enable

Copyright

We respect the copyrights and intellectual property rights of all users. All uploaded documents are either original works of the uploader or authorized works of the rightful owners.

  • Not to be reproduced or distributed without explicit permission.
  • Not used for commercial purposes outside of approved use cases.
  • Not used to infringe on the rights of the original creators.
  • If you believe any content infringes your copyright, please contact us immediately.

Support

For help with questions, suggestions, or problems, please contact us