SAFETY DATA SHEET Product Number 708 Section 1. Identification GHS product identifier : Rubber Solvent Synonyms : Petroleum hydrocarbon solvent Product Name : Gasoline Stove & Lantern Fuel : MSDS # Supplier's details : Sunnyside Corporation 225 Carpenter Ave. Wheeling, IL 60090 800-323-8611 [email protected] Emergency telephone : Technical Contact: (847) 541-5700 number (8am - 4pm CT M-F) CHEMTREC Emergency: (800) 424-9300 (United States Only) Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : FLAMMABLE LIQUIDS - Category 2 substance or mixture SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B TOXIC TO REPRODUCTION: INHALATION [Fertility] - Category 2 TOXIC TO REPRODUCTION [Unborn child] - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Narcotic effects] - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Highly flammable liquid and vapor. Causes skin and eye irritation. Suspected of damaging fertility if inhaled. Suspected of damaging the unborn child. May be fatal if swallowed and enters airways. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure. Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling. Date of issue/Date of revision : 2/20/2015. Version : 1 1/15 Gasoline Stove & Lantern Fuel Section 2. Hazards identification Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Store in a well-ventilated place. Keep cool. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise : None known. classified Section 3. Composition/information on ingredients Substance/mixture : Substance Other means of : Petroleum hydrocarbon solvent; CITGO® Material Code: 19336 identification CAS number/other identifiers CAS number : Solution Ingredient name % CAS number n-hexane 10 - 30 110-54-3 Hexane, other isomers 10 - 30 * C7-C8 Alkanes 10 - 30 ** Heptane 7 - 13 142-82-5 Methylcyclopentane 7 - 13 96-37-7 Toluene 3 - 7 108-88-3 C9-C15 Alkanes 1 - 5 ** C7-C8 Cycloalkanes 1 - 5 ** Cyclohexane 1 - 5 110-82-7 C9-C15 Cycloalkanes 1 - 5 ** * = Various ** = Mixture *** = Proprietary Any concentration shown as a range is to protect confidentiality or is due to process variation. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that gas or vapor is still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Date of issue/Date of revision : 2/20/2015. Version : 1 2/15 Gasoline Stove & Lantern Fuel Section 4. First aid measures Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute Potential acute health effects Eye contact : Causes eye irritation. Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. Breathing high concentrations can cause irregular heartbeats which can be fatal. Skin contact : Causes skin irritation. Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Inhalation : Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Breathing high concentrations can cause irregular heartbeats which can be fatal. Skin contact : Adverse symptoms may include the following: irritation redness Ingestion : Adverse symptoms may include the following: nausea or vomiting Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : This material (or a component) may sensitize the heart to the effects of sympathomimetic amines. Epinephrine and other sympathomimetic drugs may initiate cardiac arrthymias in individuals exposed to this material. If ingested, this material presents a significant aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal intubation or by placement of the body in a Trendelenburg and left lateral decubitus position. Specific treatments : Treat symptomatically and supportively. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that gas or vapor is still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Date of issue/Date of revision : 2/20/2015. Version : 1 3/15 Gasoline Stove & Lantern Fuel Section 5. Fire-fighting measures Specific hazards arising : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur from the chemical and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Extinguishing media Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam. media Unsuitable extinguishing : Do not use water jet. media Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable