* . 1111111111111111111111111111111'1111111111111111111~~~~~~~~~~~~II~IIIIIlBlIDI111 111 111111liiII PLO201 787 S- 105 ~~~~~~~ S 0 . 3 3/i5 0 I A LW - DA fcB ANNUAL REPORT 2001 INSTITUTE OF NUCLEAR CHEMISTRY AND TECHNOLOGY EDITORS Wiktor Smulek, Ph.D. Ewa Godlewska-Para,M.Sc. PRINTING Sylwester Wojtas ©C Copyright by the Institute of Nuclear Chemistry and Technology, Warszawa 2002 All rights reserved CONTENTS GENERAL INFORMATION 9 MANAGEMENT OF THE INSTITUTE 11 MANAGING STAFF OF THE INSTITUTE 11 HEADS OF THE INCT DEPARTMENTS 11 SCIENTIFIC COUNCIL (1999-2003) 11 SCIENTIFIC STAFF 14 PROFESSORS 14 ASSOCIATE PROFESSORS 14 SENIOR SCIENTISTS (Ph.D.) 15 RADIATION CHEMISTRY AND PHYSICS, RADIATION TECHNOLOGIES 17 SPECTRAL AND KINETIC STUDIES OF RADICAL CATIONS DERIVED FROM AROMATIC CARBOXYLIC ACIDS CONTAINING THIOETHER GROUP A. Korzeniowska-Sobczuk, G.L. Hug, K. Bobrowski 19 SULFUR- AND CARBON-CENTERED RADICALS DERIVED FROM THIOETHERS CONTAINING ACETYL GROUP G. Strzelczak, K. Bobrowski, N. Varmenot, J. Berges, Z. Abedinzadeh 21 SHORT-LIVED OXIDATION PRODUCTS DERIVED FROM ENKEPHALINES G. Kciuk, J. Mirkowski, K. Bobrowski 23 COMPUTATIONAL CHARACTERIZATION OF SULFUR-OXYGEN BONDED SULFURANYL RADICALS DERIVED FROM TERT-BUTYL 2-(METHYLTHIO) PEROXYBENZOATE: EVIDENCE FOR a' -TYPE RADICALS D. Pogocki, Ch. Schoneich 24 MODIFICATION OF DNA RADIOLYSIS BY IRON(III) IONS AT ROOM TEMPERATURE H.B. Ambroi, T.J. Kemp, E.M. Kornacka, G. Przybytniak 27 INFLUENCE OF IRON(III) IONS ON DNA CONFORMATION H.B. Ambroi, T.J. Kemp, G. Przybytniak 28 EPR STUDY ON RADIATION-INDUCED METHYL RADICALS IN Na-A ZEOLITE M. Danilazuk, J. Sadlo, J. Michalik 29 HEXAMERIC SILVER IN SODALITES J. Michalik, J. Perlifiska, J. Sadlo, H. Yamada, T. Wqsowicz, T. Kodaira 31 COMPARATIVE X- AND Q-BAND EPR STUDY OF RADIATION-INDUCED RADICALS IN TOOTH ENAMEL BLOCKS J. Sadio, G.C.A.M. Vanhaelewyn, P.F.A.E. Matthys, F.J. Callens, J. Michalik, W. Stachowicz 34 ANGULAR DEPENDENCE OF POST-IMPLANTATION DAMAGE RECOVERY UNDER 1 MeV ELECTRON IRRADIATION IN GaAs S. Warchol, H. Rzewuski, J. Krynicki, R. Groetzschel 37 APPLIED ASPECTS OF SOLID STATE RADIATION CHEMISTRY: RADIATION RESISTANCE OF CONCRETE Z.P. Zag6rski, A. Rafalski 39 DETECTION OF IRRADIATION IN DRIED MUSHROOMS BY THERMOLUMINESCENCE AND EPR SPECTROSCOPY W. Stachowicz, G. Strzelczak, K. Malec-Czechowska 41 STUDIES OF GELATINIZATION OCCURRING IN NON-IRRADIATED AND IN GAMMA IRRADIATED WHEAT AND POTATO STARCH AND THE INTERACTION OF POTATO STARCH POLYSACCHARIDES WITH 1-MONO-LAUROYL GLYCEROL BY LIGHT MICROSCOPY, RHEOMETRY AND DIFFERENTIAL SCANNING CALORIMETRY K Ciesla, A.-Ch. Eliasson, T. Wroliska 43 RADIATION DECONTAMINATION OF LYOPHYLIZED MEAT PRODUCTS W. Migdal, H.B. Owczarczyk 47 RADIOLYTIC DEGRADATION OF PESTICIDES 2,4-D AND DICAMBA P. Drzewicz. P. Gchringer. H. Eschweiler, .J. Sawicki, G. Nalecz-Jawecki, S. Solar. R. Zona, P.P. Panta, W. Gluszewski, A. Bojanowska-Czajka. M. Trojanowicz 49 APPLICATION OF ELECTRON BEAM TO THE OBTAINING OF IMPROVED MEDICAL PRESSURE SENSITIVE ADHESIVES P.P. Pania, W. Gluszewski, E.K. Wojtyfiska. A. Wnuk, Z. Zimek 51 84Kr ION FLUENCE MEASUREMENTS BASED ON RADIATION EFFECTS GENERATED IN CTA IFOILS Z. Peimel-Stuglik. V.A. Skuratov 52 AN ALANPOL - EPR-ALANINE DOSIMETER FOR LOW (0.5-10 kGy) TECHNOLOGICAL DOSES I. Peime!-Stuglik. S. Fabisiak, B. Sartowska 53 RADIOCHEMISTRY, STABLE ISOTOPES, NUCLEAR ANALYTICAL METHODS, GENERAL CHEMISTRY 57 A SIMPLE 2 28Ra-228Ac GENERATOR B. Wiodzimirska, A. Bilewicz 59 2 2 4 2 2 SIMULTANEOUS DETERMINATION OF ? 6 .2 2 8 Ra IN ENVIRONMENTAL WATERS BY MEASUREMENT OF EMANATED 2 2 0 ,2 2 2 Rn USING A 4-INCI I SILICON ElPITAXIAL DETECTOR A. Kordyasz. B. Bartok. A. Bilewicz 60 2 2 0 ADSORPTION OF, Rn ON DIOXYGENYL HEXAFLUOROANTIMONATE SURFACE. A MODEL EXPERIMENT ON THE CHEMISTRY OF ELEMENT 112 A. Bilewicz. K. Lyczko 61 HYPERVALENT TROPOLONATES OF 13 GROUP METAL IONS AND THEIR TOPO ADDUCTS. THE DENSITY FUNCTIONAL STUDIES J. Narbutt, M. Czerwiriski 62 '1THESTRUCTURES OF' Bu4 N[MX4 ] SALTS WITH M =A. Ga, In. TI AND X=CI, Br, I K. Rudawska. H. Ptasiewicz-Bak, S. Siekierski 65 CYTOTOXIC EFFECTS OF' PLATINUM(II) AND PALILADIUM(II) CHLORIDES COMPLEXED WITH DIMETHY-SUJLFOXIDE AND METHYL, 3,4-DIAMINE-2.3,4.6-TETRADEOXY-a-L-LYXO-HIEXOPYRANOSII)E STUDIED IN L1210 CELL LINE L. Fuks, M. Kruszewski. H. Lewandowska, W. Lewandowski. W. Priebe, K. Samochocka 65 ELABORATION OF A METHOD OF GROUP SEPARATION OF REF FROM BIOLOGICAL MATERIALS FOR THEIR DETERMINATION BY RNAA B. Danko, R. Dybczyfiski 67 ELABORATION OF A PROCEDURE FOR THE DETERMINATION OF SOME TRANSITION AND ALKALI METALS IN ENVIRONMENTAL SAMPLES BY ION CHIROMATOGRAPHY K. Kulisa, H. Polkowska-Motrenko. R. Dybczyuiski 68 PRECONCENTRATION AND DETERMINATION OF PLATINUJM AND PALLADIUM IN ENVIRONMENTAL SAMPLES BY GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY .1. Chwastowska, W. Skwara, E. Sterliriska, M. Dabrowska, L. Pszonicki 70 RADIONUCLIDE CONCENTRATION MEASUREMENTS IN SOLUTION AND COAL FLY ASH. A SECOND PROFICIENCY TEST J. Kierzek. J. Parus. B. Matoiewska-Bucko, M. Swiderska 71 CHROMATOGRAPHIC INVESTIGATION OF NAlURAL DYES IN ARCHEOLOGICAL COPTIC TEXTILES J. Orska-Gawrv", K. Urbaniak-Walczak, 1. Surowiec. J. KehI. 11. Rejniak. M. Trojanowicz 73 SOME OBSERVATIONS ON CRIZZLED GLASS (PRELIMINARY RESULTS OF A SURVEY OF THE 18TH CENTURY CENTRAL EUROPEAN TABLEWARE) J. Kunicki-Goldfinger. J. Kierzek, B. Maltoewska-Budko. A.J. Kasprzak 76 ULTRAVIOLET BLUE FLUORESCENCE OF THE 18TH CENTURY CENTRAL EUROPEAN GLASS: AN AUXILIARY INDICATOR FOR CURATORS AND CONSERVATORS J. Kunicki-Goldfinger, J. Kierzek 78 SURFACE TREATMENT OF SMOOTH POLYMERIC MEMBRANES BY RF PLASMA DISCHARGES W. Starosta, M. Buczkowski, B. Sartowska. T. Z6itowski. D. Wawszczak 79 DETERMINATION OF BURST STRENGTH OF ELECTRON IRRADIATED PARTICLE TRACK-E.TCHEI) MEMBRANES M. Buczkowski, D. Wawszczak, B. Sartowska, W. Starosta 81 TEMPLATE SYNTHESIS OF NANOTUBUl1lES AND KINI-'TICS OFT'FIlS PROCESS D. Wawszczak, W. Starosta, B. Sartowska, M. Buczkowski 82 SOLVENT INFLUENCED MESOSTRUC(TURES IN POLYURETHANE-BASED MEMBRANES OF DIFFERENT TRANSPORT PARAMETERS USING SAXS SYNCHROTRON METHOD H. Grigoriew, A. Wolifiska-Grabczyk, S. Bernstortf 82 KINETICS OF THE STRUCTURAL CHANGES IN POLYURETI IANES SATURA'I'ED Will-H BENZENE DURING DESORPTION PROCESS H. Grigoriew, A. Woliiiska-Grabczyk, M. I'Pusa, S. Bernstorfl 84 REPROCESSING OF Li2 TiO3 BY AN IChTJ VARIANI OF SOL-GEL METHOD A. Deptuia, W. Lada, T. Olczak, B. Sartowska, A.G. Chmielewski. C. Alvani, S. Casadio 86 SYNTI-IESIS OF LiNixCol -x 0 2 POWDERS BY COMPLEX SOL-GEL PROCESS (C'SGP) AND THEIR ELECTROCIHEMICAL CHARACTERIZATION A. Deptula, W. Lada, 'r. Olczak, F. Croce, A. D'Epilanio, A. Di Bartolomeo, A. Brignocchi 88 ASYMMETRIC HYDROGEN BONDS IN CENTROSYMMETRIC ENVIRONMENT. II: NEUTRON STUDY OF VERY SHORT HYDROGEN BONDS IN POTASSIUM HIYDROGEN DICHLOROMALEATE AT 90 AND 170 K I. Olovsson, H. Ptasiewicz-Bak. '. Gusta[sson 92 NEUTRON DIFFRACTION STUDY OF MAGNETIC PROPERTIES OF RRh4 Gc1 o (R='tb, Ho, Er) COMPOUNDS M. Kolenda, M. Hofmann, J. Leciejewicz, B. t'enc, A. Szytula 93 CRYSTAL Cl 1EMIS'I'RY OF COORDINATION COMPOIJNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART XXXVI: THE, CRYSTAL AND MOLECULAR STRICTURE OF A CALCIUM(II) COMPLEX WITH PYRIDINE-3,5-DICARBOXYLATE AND WAlER LIGANDS W. Starosta, H. Ptasiewicz-B4k, J. Lcciejewicz 94 CRYSTAL CHEMISTRY or- COORI)INATION COMPOUNDS WITH HE'I'EROCYCLIC CARBOXYLATE LIGANDS. PART XXXVII: THE CRYSTAL AND MOLECULAR STRUCTURE OF A CALCIUM(II) COMPLEX WITH PYRIDINE-2,6-DICARBOXYl.A1'E, WATER AND NITRATE lIlGANDS W. Starosta, H. Ptasiewicz-Bak, J. Lcciejewicz 95 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART XXXVIII: THE CRYSTAL AND MOI ECUL AR STRUCTURE OF PYRAZINE-2,6-DICARBOXYLIC ACID DIHYDRATE AND ITS MAGNESIUM(ll) SALT 1H. Ptasiewicz-B1k, J. I..cciejewicz 96 -- CRYSTAL CHEMISTRY OF COORDINAlION COMPOUNDS WITH I ITElROCYCLIC CARBOXYLATE l..IGANDS. PART XXXIX: THE CRYSTAL AND MOLECULAR STRUC'I'URE OF A STRONTIUM(II) COMPLEX WITI I PYRAZINE-2,6-DICARBOXYLATE AND WATER LIGANDS H. Ptasiewicz-B4k, J. Leciejewicz 97 RADIOBIOLOGY 99 CHROMOSOMAL. ABERRATIONS AND MICRONUCLEII IN LYMPHOCYTES OF FIVE BREAST CANCER P'ATIENT'S FOLLOWING AN ACCII)DENT DURING RADIOTHERAPY WITH 8 MeV ELECTRONS A. W6jcik, G. Stephan, S. Sommer, 1. Buraczewska, G. Kobialko, J. Pontek 101 MODELLING THE FREQUENCIES OF; CHROMOSOMAL ABERRATIONS IN PERIPHERAL. LYMPHOCY'I'ES OF PATIENTS UNDERGOING RADIOTHERAPY W. Urbanik, P. Kukotowicz, T. Kuszewski, S. G6zdz, A. W6jcik 101 A CYTOGENETIC ANALYSIS OF THE LONG-TERM EFFECT OF URANIUM MINING ON PERIPHERAL LYMPHOCYTES USING THE MICRONUCLEUS-CENTROMERE ASSAY A. Kryscio, W.-J. Muller, A. W6jcik, N. Kotschy, S. Grobelny, Ch. Strefter 102 SCE FORMATION AFTER EXPOSURE OF CH-1O CELLS PRE-ILABELLED WITI I BrdU OR BIO'l'IN-dt)TP TO VARIOUS DNA-DAMAGING AGENTS L. Stoilov, A. W6jcik, E. Bruckmann, A.K. Giri, G. Obe 104 NITRIC OXIDE INDUCED DNA DAMAGE IN 'I'WO MOUSE LYMPHOMA L5178Y CEL.L LINES EVALUATED AT THE SINGLE CEI L LEVEL M. Kruszewski, T. Iwanehiko, B. Sochanowicz, T. Bartlomiejczyk, P. Lipifiski 105 THE IRON CHELATOR SALICYLALI)EI-IY)E ISONICOTINOYL HYDRAZONEI PREVENTS NITRIC OXII)E INDUCED DNA DAMAGE IN MAMMALIAN CEI.LS M. Kruszewski, T. Iwanerko, B. Sochanowicz, 'I'. Bartdomiejczyk, P. Lipinski 105 ElABORATION OFA NONRADIOACTIVE, PFGE-BASED ASSAY OF DNA DOUBLE-STRAND BREAKS IN HUMAN LYMPHOCYTES 1. Gradzka, I. Szumiel 106 REPAIR OF DNA DOUBLE STRAND) BREAKS IN A'AXIATEL.ANGIECT'ASIA HOMO- AND I IETEROZYGOTE CELLS M. Wojew6dzka, A. Jaworska, 1. Buraczewska 108 VALIDATION OF A NEW .MODIFICATION OF THE NEUTRAL COMET ASSAY M. Wojew6dzka. 1. Buraczewska, M. Rasiriska 109 APPLICATION OF THE ANTI-SSDNA ANTIBODY IN THE ALKALINE COMET ASSAY M. Wojew6dzka, M. Kruszewski. T. Iwaneuiko 110 PRE-TREATMENT WITH NOVEL PLATINUM COMPLEXES RADIOSENSITISES CHO CELLS 1. Buraczewska. N. Jarocewicz, 1. Szumiel. J. Kuduk-Jaworska 110 POLY(ADP-RIBOSE) POLYMERS IN 'IWO L5178Y MURINE LYMPHOMA SUBLINES DIFFERENTIALLY SENSITIVE TO DNA-DAMIAGING AGENTS H.E. Kleczkowska, M. Malanga. 1. Szumiel, F.R. Althaus 112 NUCLEAR TECHNOLOGIES AND METHODS 115 PROCESS ENGINEERING 117 APPLICATION OF RTD AND CFD FOR FLUE GAS IRRADIATION REACTOR INVESTIGA'IION A.G.