AMMONIA BUFFER SOLUTION MSDS CAS-No.: MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture : Product code : 01077 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Use of the substance/mixture : Laboratory chemicals, Manufacture of substances 1.2.2. Uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba 400005 Mumbai - INDIA T +91 22 6663 6663 - F +91 22 6663 6699 [email protected] - www.lobachemie.com 1.4. Emergency telephone number Emergency number : + 91 22 6663 6663 (9:00am - 6:00 pm) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Skin corrosion/irritation, H314 Category 1B Specific target organ H335 toxicity — Single exposure, Category 3, Respiratory tract irritation Hazardous to the aquatic H400 environment — Acute Hazard, Category 1 Full text of hazard classes and H-statements : see section 16 Adverse physicochemical, human health and environmental effects No additional information available www.lobachemie.com 21/04/2016 1/9 AMMONIA BUFFER SOLUTION Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) : GHS05 GHS07 GHS09 Signal word (CLP) : Danger Hazard statements (CLP) : H314 - Causes severe skin burns and eye damage. H335 - May cause respiratory irritation. H400 - Very toxic to aquatic life. Precautionary statements (CLP) : P261 - Avoid breathing vapours, dust, fume, gas. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a doctor. 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Water (CAS-No.) 7732-18-5 75 - 99 Not classified (EC-No.) 231-791-2 Ammonia solution (CAS-No.) 1336-21-6 10 - 15 Skin Corr. 1B, H314 (EC-No.) 215-647-6 Eye Dam. 1, H318 (EC Index-No.) 007-001-01-2 Aquatic Acute 1, H400 Ammonium chloride (CAS-No.) 12125-02-9 5 - 10 Acute Tox. 4 (Oral), H302 (EC-No.) 235-186-4 Eye Irrit. 2, H319 (EC Index-No.) 017-014-00-8 Edetic acid (EDTA) (CAS-No.) 60-00-4 0.01 - 1 Eye Irrit. 2, H319 (EC-No.) 200-449-4 Aquatic Chronic 4, H413 (EC Index-No.) 607-429-00-8 Full text of H-statements: see section 16 www.lobachemie.com 21/04/2016 2/9 AMMONIA BUFFER SOLUTION Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after ingestion : Harmful if swallowed. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Use personal protective equipment as required. Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : On land, sweep or shovel into suitable containers. Collect spillage. 6.4. Reference to other sections No additional information available SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours. Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. www.lobachemie.com 21/04/2016 3/9 AMMONIA BUFFER SOLUTION Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep container tightly closed. Store in original container. Keep container tightly closed. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters No additional information available 8.2. Exposure controls Hand protection : Protective gloves Eye protection : Chemical goggles or face shield Skin and body protection : Wear suitable protective clothing Respiratory protection : [In case of inadequate ventilation] wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Clear Colorless. Odour : ammonical odour. Odour threshold : No data available pH : 10 - 11 Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : No data available Relative vapour density at 20 °C : No data available Relative density : No data available Solubility : Water: Miscible in water www.lobachemie.com 21/04/2016 4/9 AMMONIA BUFFER SOLUTION Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Log Pow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No additional information available 10.4. Conditions to avoid Direct sunlight. Air contact. Moisture. 10.5. Incompatible materials No additional information available 10.6. Hazardous decomposition products Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Skin corrosion/irritation : Causes severe skin burns and eye damage. pH: 10 - 11 Serious eye damage/irritation : Serious eye damage, category 1, implicit pH: 10 - 11 Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified STOT-single exposure : May cause respiratory irritation. STOT-repeated exposure : Not classified www.lobachemie.com 21/04/2016 5/9 AMMONIA BUFFER SOLUTION Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Aspiration hazard : Not classified SECTION 12: Ecological information 12.1. Toxicity No additional information available 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential No additional information available 12.4. Mobility in soil No additional information available 12.5. Results of PBT and vPvB assessment No additional information available 12.6. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Product/Packaging disposal : Dispose of contents/container to hazardous or special waste collection point, in recommendations accordance with local, regional, national and/or international regulation. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No. (ADR)