Pt. 414, App. A 40 CFR Ch. I (7±1±98 Edition) PSES and PSNS 1 n-Propyl alcohol/Hydrogenation of propionaldehyde, Oxo process Maximum SAN resin/Suspension polymerization Effluent characteristics Maximum for any for any Styrene/Dehydrogenation of ethylbenzene one day monthly average Styrene/Dehydration of methyl benzyl alco- hol (coproduct of propylene oxide) 1,3-Dichloropropylene ........................ 794 196 Diethyl phthalate ................................ 113 46 1-Tetralol, 1-Tetralone mix/Oxidation of Dimethyl phthalate ............................. 47 19 tetralin (1,2,3,4-Tetrahydronaphthalene) 4,6-Dinitro-o-cresol ............................. 277 78 3,3,3-Trifluoropropene/Catalyzed hydrogen Ethylbenzene ..................................... 380 142 fluoride exchange with chlorinated pro- Fluoranthene ...................................... 54 22 pane Fluorene ............................................. 47 19 Vinyl toluene/Dehydrogenation (thermal) of Hexachlorobenzene ........................... 794 196 Hexachlorobutadiene ......................... 380 142 ethyltoluene Hexachloroethane .............................. 794 196 Methyl Chloride .................................. 295 110 Copper Methylene Chloride ............................ 170 36 Methylhydroabietate/Esterification of Naphthalene ....................................... 47 19 Nitrobenzene ...................................... 6,402 2,237 hydroabietic acid (rosin) with methanol 2-Nitrophenol ...................................... 231 65 Acetaldehyde/Oxidation of ethylene with cu- 4-Nitrophenol ...................................... 576 162 pric chloride catalyst Phenanthrene ..................................... 47 19 Acetic acid/Catalytic oxidation of butane Pyrene ................................................ 48 20 Acetone/Dehydrogenation of isopropanol Tetrachloroethylene ........................... 164 52 Toluene .............................................. 74 28 Acrylamide/Catalytic hydration of acrylo- Total Cyanide ..................................... 1,200 420 nitrile Total Lead .......................................... 690 320 Acrylic acid/Oxidation of propylene via acro- Total Zinc 2 ......................................... 2,610 1,050 lein 1,2,4-Trichlorobenzene ...................... 794 196 Acrylonitrile/Propylene ammoxidation 1,1,1-Trichloroethane ......................... 59 22 Adipic acid/Oxidation of cyclohexanol- 1,1,2-Trichloroethane ......................... 127 32 Trichloroethylene ................................ 69 26 cyclohexanone mixture Vinyl Chloride ..................................... 172 97 Adipic acid/Oxidation of cyclohexane via cyclohexanol-cyclohexanone mixture 1 All units are micrograms per liter. 2 Total Zinc for Rayon Fiber Manufacture that uses the vis- Allynitrile/Allychloride + sodium cyanide cose process and Acrylic Fiber Manufacture that uses the zinc Aniline/Hydrogenation of nitrobenzene chloride/solvent process is 6,796 µg/l and 3,325 µg/l for maxi- Benzofurans, 2,3-Dihydro-2,2-dimethyl-7- mum for any one day and maximum for monthly average, respectively. benzofuranol/ from o-Nitrophenol + Meth- allyl chloride APPENDIX A TO PART 414ÐNON- n-Butyl alcohol/Hydrogenation of n- COMPLEXED METAL-BEARING WASTE Butyraldehyde, Oxo process 1,4-Butanediol/Hydrogenation of 1,4- STREAMS AND CYANIDE-BEARING butynediol WASTE STREAMS Butryolactone/Dehydrogenation of 1,4- Chromium butanediol Caprolactam/From cyclohexane via Methylhydroabietate/Esterification of cyclohexanone and its oxime hydroabietic acid (rosin) with methanol Lilian (hydroxydihydrocitronellal)/Hydra- Acrylic acid/Oxidation of propylene via acro- tion and oxidation of citronellol lein 1,2-Dichloroethane/Oxyhydrochlorination of N-butyl alcohol/Hydrogenation of n- ethylene Butyraldehyde, Oxo process Dialkyldithiocarbamates, metal salts/ Cyclohexanone/From phenol via Dialkylamines + carbon disulfide cyclohexanol by hydrogenation-dehydro- 2-Ethylhexanol/from n-Butyraldehyde by genation Aldo condensation and hydrogenation Fatty amines/Hydrogenation of fatty nitriles Fatty amines/Hydrogenation of fatty nitriles (batch) (batch) Helioptropin/Oxidation of isosafrole, chro- Geraniol/B-Myrcene + Hydrogen chloride, mium catalyst esterification of geranyl chloride, hydroly- Isobutanol/Hydrogenation of sis of geranyl acetate isobutyraldehyde, Oxo process Furfuryl alcohol/Hydrogenation of furfural Cyclohexyl Mercaptan/Cyclohexanol + Hy- Geranial (Citral)/Oxidation of geraniol (cop- drogen sulfide per catalyst) Ethyl Mercaptan/Ethanol + Hydrogen sulfide Glyoxal/Oxidation of ethylene glycol Methanol/H.P. Synthesis from natural gas Isobutanol/Hydrogenation of via synthetic gas isobutyraldehyde, Oxo process Oxo Alcohols, C7±C11/Carbonation & hydro- Isopropanol/Catalytic hydrogenation of ace- genation of C6±C10 Olefins tone Polyoxypropylene diamine/Polypropylene 2-Mercaptobenzothiazoles, copper salt/2- glycol + Ammonia Mercaptobenzothiazole + copper salt 232 VerDate 27<AUG>98 10:07 Aug 28, 1998 Jkt 179160 PO 00000 Frm 00228 Fmt 8010 Sfmt 8010 Y:\SGML\179160T.XXX pfrm01 PsN: 179160T Environmental Protection Agency Pt. 414, App. A Methanol/High pressure synthesis from natu- Nickel ral gas via synthetic gas Acetates, 7,11-Hexadecadien-1-ol Methanol/Low pressure synthesis from natu- (gossyplure)/Coupling reactions, low pres- ral gas via synthetic gas sure hydrogenation, esterification Methyl ethyl ketone/Dehydrogenation of sec- Acetates, 9-dodecen-1-ol (pheromone)/Cou- Butanol pling reactions, low pressure hydro- Oxo alcohols, C7±C11/Carbonation & hydro- genation, esterification genation of C6±C10 olefins Acrylic acid/oxidation of propylene via acro- Phenol/Liquid phase oxidation of benzoic lein acid Acrylonitrile/Propylene ammoxidation Polyoxyalkylene amines/Polyoxyalkylene n-Alkanes/Hydrogenation of C6-C22 alpha glycol + ammonia olefins (ethylene oligomers) Polyphenylene oxide/Solution polymeriza- Adiponitrile/Direct cyanation of butadiene tion of 2,6-xylenol by oxidative coupling Alkyl amines/Amination of alcohols (cuprous salt catalyst) 4-Aminoacetanilide/Hydrogenation of 4- Polyoxypropylene diamine/Polypropylene Nitroacetanilide glycol + Ammonia BTX/Hydrogenation of olefins (cyclohexenes) Quinaldine (dye intermediate)/Skraup reac- Terphenyls, hydrogenated/Nickel catalyst, tion of aniline + crotonaldehyde hydrogenation of terphenyl Silicones, silicone fluids/Hydrolysis and con- Bisphenol-A, hydrogenated densation of chlorosilanes (Biscyclohexanol-A)/Hydrogenation of Silicones, silicone rubbers/Hydrolysis and Bisphenol-A condensation of chlorosilanes Butadiene (1,3)/Extractive distillation of C±4 pyrolyzates Silicones, silicone specialties (grease, disper- n-Butanol/Hydrogenation of n- sion agents, defoamers & other products) Butyraldehyde, Oxo process Silicones: Silicone resins/Hydrolysis & con- 1,3-Butylene glycol/Hydrogenation of densation of methyl, phenyl & vinyl acetaldol chlorosilanes 1,4-Butanediol/Hydrogenation of 1,4- Silicones: Silicone fluids/Hydrolysis of butynediol chlorosilanes to acyclic & cyclic Butylenes (mixed)/Distillation pf C4 organosiloxanes pyrolyzates Styrene/Dehydration of a-Methylbenzyl alco- 4-Chloro-2-aminophenol/Hydrogenation of 4- hol (coproduct of propylene oxide) Chloro-2-nitrophenol Tetrachloroethylene (perchloroethylene)/ Lilial (hydroxydihydrocitronellal)/Hydration Oxyhydrochlorination of tetrachloroethane and oxidation of citronellol Tris(anilino)s-triazine/Cyanuric chloride + Cycloparaffins/Catalytic hydrogenation of aniline + cogeners aromatics in kerosene solvent Trichloroethylene/Oxyhydrochlorination of Cyclohexanol/Hydrogenation of phenol, dis- tetrachloroethane tillation Unsaturated polyester resin/Reaction of ma- Cyclohexanone/From phenol via leic anhydride + phthalic anhydride + pro- cyclohexanol by hydrogenation-dehydro- pylene glycol polyester with styrene or genation methyl methacrylate Dialkyldithiocarbamates, metal salts/ Dialkylamines + carbon disulfide Lead Ethylamine/Reductive amination of ethanol Ethylamines (mono, di, tri)/Reductive Alkyd resin/Condensation polymerization ammination (ammonia + hydrogen) of eth- Alkyd resins/Condensation polymerization of anol phthalic anhydride + glycerin + vegetable Isoeugenol, high % trans/Separation of oil esters mixed cis & trans isoeugenols Dialkydithiocarbamates, metal salts/ 2-Ethylhexanol/from n-Butyraldehyde by Dialkylamines + carbon disulfide Aldol condensation and hydrogenation Thiuram (dimethyldithiocarbamate) Fatty acids, hydrogenated/tallow & coco hexasulfide/Dimethyldithiocarbamate + acids + Hydrogen sulfur Fatty amines/Hydrogenation of fatty nitriles Triphenylmethane dyes (methyl violet)/Con- (batch) densation of Formaldehyde + N- Fatty amines/Hydrogenation of tallow & Methylaniline + N,N-dimethylaniline, oxi- coco nitriles dation of reaction product Glyoxal-urea formaldehyde textile resin/con- 4,4′-Bis-(N,N-dimethylaniline) carbinol, densation to N-bis(hydroxymethyl) ureas & Michler's hydrol/Oxidation of 4,4′-Methyl- N,N′-(dihydroxyethyl) ureas ene-bis(N,N-dimethylaniline) with lead 11-hexadecenal/Coupling rxns, low pressure oxide hydrogenation Naphthenic acid salts Hexahydrophthalic anhydride/Condensation Stearic acid, metal salts/Neutralization with of butadiene & maleic anhydride (Diels- a metallic base Alder reaction) + hydrogenation 233 VerDate 27<AUG>98 10:07 Aug 28, 1998 Jkt 179160 PO 00000 Frm 00229 Fmt 8010 Sfmt 8010 Y:\SGML\179160T.XXX pfrm01 PsN: 179160T Pt. 414, App. A 40 CFR Ch. I (7±1±98 Edition) Isobutanol/Hydrogenation of Acrylic fibers (85% polyacrylonitrile)