SAFETY DATA SHEET 1. Identification Product identifier Spray Tank Cleaner Other means of identification Product code 06002 Recommended use Agricultural/ Horticultural Use- Equipment Cleaner- Refer to product label. Recommended restrictions Refer to product label. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Lawn and Garden Products, Inc. Address PO Box 35000 Fresno, CA 93745 Telephone Emergency Contact Number 1-559-994-9144 Website www.montereylawngarden.com E-mail [email protected] Emergency phone number CHEMTREC (24 hours): USA, Canada, Puerto Rico 1-800-424-9300 Virgin Islands 1-800-424-9300 International Maritime +1 (703) 527-3887 2. Hazard(s) identification Physical hazards Not classified. Health hazards Acute toxicity, oral Category 4 Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Environmental hazards Hazardous to the aquatic environment, acute Category 2 hazard Hazardous to the aquatic environment, Category 2 long-term hazard OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary statement Prevention Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Wear eye/face protection. Response If swallowed: Call a poison center/doctor if you feel unwell. If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment (see this label). Wash contaminated clothing before reuse. Collect spillage. Storage Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC) Material name: Spray Tank Cleaner SDS US 456 Version #: 01 Issue date: 01-14-2016 1 / 9 Supplemental information 3.51% of the mixture consists of component(s) of unknown acute oral toxicity. 9.66% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 9.66% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Potassium Hydroxide (Caustic 1310-58-3 5 - < 10* Potash) Sodium Nitrite (Nitrous acid) 7632-00-0 3 - < 5* Phosphoric Acid 7664-38-2 < 0.1* Other components below reportable levels 80 - < 90 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Take off immediately all contaminated clothing. Wash off with soap and water. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell. Most important Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and symptoms/effects, acute and blurred vision. Burning pain and severe corrosive skin damage. Severe eye irritation. Permanent delayed eye damage including blindness could result. Indication of immediate Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an treatment needed ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire-fighting Move containers from fire area if you can do so without risk. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe emergency procedures mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Material name: Spray Tank Cleaner SDS US 456 Version #: 01 Issue date: 01-14-2016 2 / 9 Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is containment and cleaning up possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. Prevent entry into waterways, sewer, basements or confined areas. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Do not breathe mist or vapor. Do not get this material in contact with eyes. Do not get in eyes, on skin, or on clothing. Do not taste or swallow. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. Conditions for safe storage, Store locked up. Store in original tightly closed container. Keep container tightly closed. Store including any incompatibilities away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Phosphoric Acid (CAS PEL 1 mg/m3 7664-38-2) US. ACGIH Threshold Limit Values Components Type Value Phosphoric Acid (CAS STEL 3 mg/m3 7664-38-2) TWA 1 mg/m3 Potassium Hydroxide Ceiling 2 mg/m3 (Caustic Potash) (CAS 1310-58-3) US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Phosphoric Acid (CAS STEL 3 mg/m3 7664-38-2) TWA 1 mg/m3 Potassium Hydroxide TWA 2 mg/m3 (Caustic Potash) (CAS 1310-58-3) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Skin protection Hand protection Wear appropriate chemical resistant gloves. Other Wear appropriate chemical resistant clothing. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Respiratory protection not required. Thermal hazards Wear appropriate thermal protective clothing, when necessary. Material name: Spray Tank Cleaner SDS US 456 Version #: 01 Issue date: 01-14-2016 3 / 9 General hygiene Keep away from food and drink. Always observe