SAFETY DATA SEEET 1. Identification Product identifier Tyme™-1 Cold Parts Cleaner Other means of identification Product Code Item# 1750566 Recommended use Parts cleaning solvent for use in cold cleaner / dip tank Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold byc Company name CRC Canada Co. Address 83 Galaxy Blvd Unit 35 - 37 Toronto, ON M9W 5X6 Canada Telephone General Information 416-847-7750 24-Eour Emergency 800-424-9300 (Canada) (CEEMTREC) Website www.crc-canada.ca E-mail [email protected] 2. Eazard identification Physical hazards Not classified. Eealth hazards Skin corrosion/irritation Category 1C Serious eye damage/eye irritation Category 1 Sensitization, skin Category 1B Carcinogenicity Category 1B Specific target organ toxicity, single exposure Category 3 narcotic effects Environmental hazards Hazardous to the aquatic environment, acute Category 2 hazard Hazardous to the aquatic environment, Category 2 long-term hazard Label elements Signal word Danger Eazard statement Causes severe skin burns and eye damage. May cause an allergic skin reaction. Causes serious eye damage. May cause drowsiness or dizziness. May cause cancer. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Material name: Tyme™-1 Cold Parts Cleaner SDS CANADA Item# 1750566 Version #: 02 Revision date: 11-16-2018 Issue date: 06-25-2018 1 / 9 Response IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. If skin irritation or rash occurs: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. Collect spillage. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Other hazards None known. Supplemental information When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen chloride and possibly phosgene. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % tetrachloroethylene perchloroethylene 127-18-4 45 - 70 water 7732-18-5 15 - 40 cyclohexanol 108-93-0 7 - 13 tall oil 8002-26-4 1 - 5 ethoxylated nonylphenol, branched 68412-54-4 0.1 - 1 The exact percentage (concentration) of composition has been withheld as a trade secret. All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important May cause drowsiness and dizziness. Headache. Nausea, vomiting. Burning pain and severe symptoms/effectsl acute and corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, delayed redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Indication of immediate Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an treatment needed ambulance. Continue flushing during transport to hospital. Keep victim under observation. Symptoms may be delayed. General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed. When exposed to extreme heat or hot the chemical surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen chloride and possibly phosgene. Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. Material name: Tyme™-1 Cold Parts Cleaner SDS CANADA Item# 1750566 Version #: 02 Revision date: 11-16-2018 Issue date: 06-25-2018 2 / 9 r. Accidental release measures Personal precautionsl Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear protective equipment and appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do emergency procedures not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for This product is miscible in water. Prevent product from entering drains. containment and cleaning up Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. Put material in suitable, covered, labeled containers. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. 7. Eandling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Should be handled in closed systems, if possible. Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Conditions for safe storagel Store in a dry, cool and well-ventilated place. Keep container tightly closed. Store away from including any incompatibilities incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. ACGIE Threshold Limit Values Components Type Value cyclohexanol (CAS TWA 50 ppm 108-93-0) tetrachloroethylene (CAS STEL 100 ppm 127-18-4) TWA 25 ppm Canada. Alberta OELs (Occupational Eealth & Safety Codel Schedule 1l Table 2) Components Type Value cyclohexanol (CAS TWA 205 mg/m3 108-93-0) 50 ppm tetrachloroethylene (CAS STEL 678 mg/m3 127-18-4) 100 ppm TWA 170 mg/m3 25 ppm Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substancesl Occupational Eealth and Safety Regulation 29r/97l as amended) Components Type Value cyclohexanol (CAS TWA 50 ppm 108-93-0) tetrachloroethylene (CAS STEL 100 ppm 127-18-4) TWA 25 ppm Canada. Manitoba OELs (Reg. 217/200rl The Workplace Safety And Eealth Act) Components Type Value cyclohexanol (CAS TWA 50 ppm 108-93-0) Material name: Tyme™-1 Cold Parts Cleaner SDS CANADA Item# 1750566 Version #: 02 Revision date: 11-16-2018 Issue date: 06-25-2018 3 / 9 Canada. Manitoba OELs (Reg. 217/200rl The Workplace Safety And Eealth Act) Components Type Value tetrachloroethylene (CAS STEL 100 ppm 127-18-4) TWA 25 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Components Type Value cyclohexanol (CAS TWA 50 ppm 108-93-0) tetrachloroethylene (CAS STEL 100 ppm 127-18-4) TWA 25 ppm Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety) Components Type Value cyclohexanol (CAS TWA 206 mg/m3 108-93-0) 50 ppm tetrachloroethylene (CAS STEL 685 mg/m3 127-18-4) 100 ppm TWA 170 mg/m3 25 ppm Biological limit values ACGIE Biological Exposure Indices Components