International conference ANALYTICAL CHEMISTRY AND CHEMICAL ANALYSIS (AC&CA-05) devoted to 100 anniversary of Anatoly BABKO Kyiv, Ukraine September 12-18, 2005 Organized by Scientific Council of Analytical Chemistry at Academy of Sciences of Ukraine, Ukrainian Chemical Society, Kyiv Taras Shevchenko National University; under collaboration with European Association for Chemical and Molecular Sciences (EuCheMS) and International Union of Pure and Applied Chemistry (IUPAC) 1 International conference ANALYTICAL CHEMISTRY AND CHEMICAL ANALYSIS (AC&CA-05), devoted to 100 anniversary of Anatoly Babko / Book of abstracts: Kyiv - Ukraine. September 12-18, 2005, 480 p. Editorial board: V.N. Zaitsev, V.P. Antonovich, N.V. Chiviryova, I.V. Stoyanova, V.P. Gorodnyuk Original authors style including interpretation, formulas and names of chemical compounds, schemes, pictures and explanations, is preserved in the abstracts published in this book. This conference has been held with the financial assistance of INTAS 2005 Kyiv Taras Shevchenko National University, Ukraine 2 PREFACE The organizing committee extends a cordial invitation to participate in International conference on Analytical Chemistry and Chemical Analysis (AC&CA-05) which is hold in scenic city of Kyiv, Ukraine, from September 12 to 18, 2005. This conference belongs to the series of Ukrainian conferences in analytical chemistry established in 1970th by Ukrainian chemical society and chemical division of Ukrainian Academy of Sciences. AC&CA-05 is a 7th conference in analytical chemistry in Ukraine and it is dedicated to the centenary of the birth of the outstanding Ukrainian scientist, Anatoly K. Babko for his expertise in analytical chemistry and in the chemistry of complex compounds. The current conference is organised by Analytical Scientific Council at Academy of Sciences of Ukraine under collaboration with European Association for Chemical and Molecular Sciences (EuCheMS) and sponsored by International Union of Pure and Applied Chemistry (IUPAC) and by the International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union (INTAS). Main goals of the conference are to survey a status of modern analytical science in Ukraine against the global one, to renew international collaboration of Ukrainian analytical chemists and educators, and to approach positions of scientists and analytical engineers. The idea of the conference is to demonstrate renaissance of science and analytical practice in Ukraine after it gained independence. Organizing committee meets great help and gets support for realisation of this idea from many international bodies, such as chemical societies of Russia, Japan, Austria, Germany and Great Britain, as well as from scientific web portals: SpectroscopyNOW, ChemWeb.com, etc. As a result of such support AC&CA-05 have about 450 participants from 31 countries. This provided an excellent opportunity for young Ukrainian researchers, teachers and students, and for scientists from neighbouring countries, to meet the representatives of international scientific community and to re-establish links with their European colleagues and thus initiate new collaborative work. All main aspects of analytical and bioanalytical sciences is covered by the conference program. AC&CA-05 consists of 12 invited lectures and seven symposia: General Aspects of Analytical Chemistry, Analytical Methods, Objects of the Analysis, Sensors and Tests, Separation and Pre-concentration, Pharmaceutical and Biomedical Analysis, History and Methodology of Analytical Chemistry. Conference program includes two special symposia: Memorial one, dedicated to Anatoly Babko and Analytical Russian-Germany-Ukrainian symposium (ARGUS-9). It is great that AC&CA-05 took place in 2005. This year Ukraine demonstrates Eurointegration policy and we are in the vanguard of this process. In 2004 Analytical Chemistry Council NAS of Ukraine becomes a member of European Association for Chemical and Molecular Sciences. AC&CA-05 is the next step towards Eurointegration of Ukrainian analytical science. The first steps are always hard to make. We tried to do our best … Thanks all participants for coming to AC&CA-05. The Chairman of organizing committee, Chair of Analytical Chemistry Scientific Council of NASU Prof. Vladimir N. Zaitsev 3 Contents Plenary lectures ................................................................................... 9 GENERAL ASPECTS ......................................................................... 21 Keynote lectures ................................................................................ 21 Oral presentations ............................................................................. 25 Poster presentations .......................................................................... 31 ANALYTICAL METHODS ................................................................. 63 Keynote lectures ................................................................................ 63 Oral presentations ............................................................................. 73 Poster presentations .......................................................................... 89 OBJECTS OF THE ANALYSIS ........................................................ 163 Keynote lectures .............................................................................. 163 Oral presentations ........................................................................... 170 Poster presentations ........................................................................ 181 SEPARATION AND PRE-CONCENTRATION ............................... 242 Keynote lectures .............................................................................. 242 Oral presentations ........................................................................... 249 Poster presentations ........................................................................ 261 SENSORS AND TESTS .................................................................... 294 Keynote lectures .............................................................................. 294 Oral presentations .......................................................................... 301 Poster presentations ....................................................................... 313 PHARMACEUTICAL AND BIOMEDICAL ANALYSIS............... 336 Keynote lectures .............................................................................. 336 Oral presentations .......................................................................... 343 Poster presentations ....................................................................... 355 HISTORY OF ANALYTICAL CHEMISTRY ................................... 398 Keynote lectures .............................................................................. 398 Oral presentations .......................................................................... 401 9th ANALYTICAL RUSSIAN-GERMAN-UKRAINIAN SYMPOSIUM (ARGUS-9) ................................................................ 407 Keynote lectures .............................................................................. 409 Oral presentations .......................................................................... 419 Poster presentations ....................................................................... 434 AUTHOR INDEX .............................................................................. 468 4 CONFERENCE SPONSORS International Union of Pure and Applied Chemistry (IUPAC) Kyiv Taras Shevchenko National University International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union (INTAS) Badische Anilin & Soda Fabrik AG 5 Anatoly Kirillovich BABKO (15.10.1905 - 7.01.1968) A Short Biography In October, 2005 the Ukrainian scientific community will celebrate the centenary of the birth of the outstanding Ukrainian scientist, Anatoly K. Babko for his expertise in analytical chemistry and in the chemistry of complex compounds. The scientific work of Anatoly K. Babko was conducted mainly at the Kyiv State University where he chaired the Department of Analytical Chemistry as from 1944 to 1960, after when during 1960 to 1968 he retained the title of Professor. His scientific duties were performed primarily at the Institute of General and Inorganic Chemistry of the Ukrainian Academy of Sciences, where he headed the Department of Analytical Chemistry from 1941 to 1968. The scientific interests of Anatoly K. Babko ranged widely, especially in regard to fundamental aspects of analytical chemistry, applications of organic reagents in inorganic analysis, chemistry of complex compounds (including heteropolyacids), analytical applications of complex compounds in photometry, luminescence and chemiluminescence, ion chromatography, and liquid-liquid extraction. A significant achievement of Anatoly K. Babko was in the area of systematic physicochemical research of complex compounds in solution based on their photometric properties. Anatoly K. Babko showed the stability constants of complexes to be highly important, and demonstrated the relevance of the step- wise character of the dissociation of complex compounds. In developing theoretical problems he always thought about practical uses of results in the national economy. His theoretical and experimental results were applied to developing numerous methods of analytical determination of elements in complex