Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) as amended Material Name: Carbon Dioxide (DX) Gas Purifier Media SDS ID: 0048 (EU) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Material Name Carbon Dioxide (DX) Gas Purifier Media Product Code 8008786 Product Description The media contained in this product, when used as designed, under normal operating conditions, and installed and maintained according to product literature, is not expected to be hazardous. Classifications and hazards represented on this Safety Data Sheet are only applicable in the unlikely event that the purifier media is liberated from the purifier housing. The purifier has sieves internal to the housing to prevent the media from escaping during intended use. Caution: Some units are provided with a fill port, which is factory sealed with a VCR® fitting and plug, covered with red shrink wrap. This port must never be opened by the end user, since it will potentially result in a release of the media. Registration status REACH compliance status of the substance is currently under investigation. 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses For removal of volatile acids and bases, refractory compounds, condensable organics, non-condensable organics and moisture from carbon dioxide gas Uses advised against Use only with gases listed in Identified Uses. 1.3 Details of the supplier of the safety data sheet Entegris GmbH Hugo-Junkers-Ring 5, Gebäude 107/W, 01109 Dresden, Germany Telephone Number: +49 (0) 351 795 97 0 Fax Number: +49 (0) 351 795 97 499 Only Representative Tetra Tech International, Inc. Fuchsstrasse 1, 67688 Rodenbach, Germany [email protected] Entegris, Inc. 129 Concord Road Building 2 Billerica, MA 01821 USA Telephone Number: +1-952-556-4181 Telephone Number: +1-800-394-4083 (toll free within North America) E-mail: [email protected] 1.4 Emergency telephone number +1-703-527-3887 (24 hours) - CHEMTREC - International SECTION 2: Hazards identification 2.1 Classification of the substance or mixture ____________________________________________________________ Page 1 of 16 Issue date: 2019-03-21 Revision 2.0 Print date: 2019-03-21 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) as amended Material Name: Carbon Dioxide (DX) Gas Purifier Media SDS ID: 0048 (EU) Classification according to Regulation (EC) No 1272/2008 [CLP] Serious Eye Damage/Eye Irritation - Category 2 Skin Sensitization - Category 1 Carcinogenicity - Category 1A Specific Target Organ Toxicity - Single Exposure - Category 3 ( respiratory system ) Specific Target Organ Toxicity - Repeated Exposure - Category 1 ( respiratory system , immune system , kidneys ) Hazardous to the Aquatic Environment - Chronic - Category 4 2.2 Label elements Labeling according to Regulation (EC) No. 1272/2008 [CLP] Hazard symbols Signal word Danger Hazard statements H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H350 May cause cancer. H335 May cause respiratory irritation. H372 Causes damage to organs through prolonged or repeated exposure. （respiratory system , immune system , kidneys ） H413 May cause long lasting harmful effects to aquatic life. Precautionary statements Prevention P260 Do not breathe gas. P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P272 Contaminated work clothing should not be allowed out of the workplace. P270 Do not eat, drink or smoke when using this product. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. Response P308+P313 IF exposed or concerned: Get medical advice/attention. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal ____________________________________________________________ Page 2 of 16 Issue date: 2019-03-21 Revision 2.0 Print date: 2019-03-21 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) as amended Material Name: Carbon Dioxide (DX) Gas Purifier Media SDS ID: 0048 (EU) P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Statement(s) of Unknown Aquatic Toxicity 50% of the mixture consists of ingredient(s) of unknown chronic aquatic toxicity. 2.3 Other hazards May form combustible dust concentrations in air (during handling or processing). In normal use, as installed and maintained according to product literature, this material in its final form is not expected to be hazardous. SECTION 3: Composition / information on ingredients 3.2 MIXTURE CAS Component Name 1272/2008 (CLP) Percent EC No Synonyms Registration No Annex VI, Table 3: 1313-99-1 Skin Sens. 1 - H317 215-215-7 Nickel monoxide Carc. 1A - H350 30-50 -- STOT RE 1 - H372 Aquatic Chronic 4 - H413 7440-44-0 231-153-3 Carbon -- 10-30 -- 12736-96-8 Silicic acid, aluminium potassium 235-787-1 -- 10-30 sodium salt -- Self-Classified: 7631-86-9 Eye Irrit. 2 - H319 231-545-4 Silicon dioxide 10-20 Carc. 1A - H350 -- STOT SE 3 - H335 STOT RE 1 - H372 1309-48-4 Self-Classified: 215-171-9 Magnesium oxide 5-10 Eye Irrit. 2 - H319 -- STOT SE 3 - H335 Full text of H- and EUH-statements: see section 16. SECTION 4: First aid measures 4.1 Description of first aid measures Inhalation First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. Skin ____________________________________________________________ Page 3 of 16 Issue date: 2019-03-21 Revision 2.0 Print date: 2019-03-21 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) as amended Material Name: Carbon Dioxide (DX) Gas Purifier Media SDS ID: 0048 (EU) First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. Eyes First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Then get immediate medical attention. Ingestion First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. If swallowed, get medical attention. 4.2 Most Important Symptoms/Effects Acute eye irritation, respiratory tract irritation, allergic reactions Delayed allergic reactions, cancer, respiratory system damage, immune system damage, kidney damage 4.3 Indication of Immediate Medical Attention and Special Treatment No data available. Note to Physicians Treat symptomatically and supportively. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Use extinguishing agents appropriate for surrounding fire. Unsuitable Extinguishing Media None known. 5.2 Special hazards arising from the substance or mixture Negligible fire hazard. Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. 5.3 Advice for firefighters Negligible fire hazard. Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Fire Fighting Measures This product will remain stable when housed in the filter body. Protective Equipment and Precautions for Firefighters Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against possible exposure. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Wear personal protective clothing and equipment. In normal use, as installed and maintained according to product literature, this material in its final form is not expected to be hazardous. Classifications and hazards represented on this Safety Data Sheet are only applicable in the unlikely event that the purifier media is liberated from the purifier housing. The purifier has sieves internal to the housing to prevent the media from escaping during intended use. 6.2 Environmental precautions Avoid release to the environment. 6.3 Methods and Materials for Containment and Cleaning Up Keep unnecessary people away, isolate hazard area and deny entry. Collect spill using a vacuum cleaner with a HEPA filter or wet and scoop up dry spills. Avoid accumulation of airborne dusts. Avoid sweeping spilled ____________________________________________________________