COMMISSION OF THE EUROPEAN COMMUNITIES ANNEX 1 TO THE COMMISSION STAFF WORKING DOCUMENT Monitoring of Pesticide Residues in Products of Plant Origin in the European Union, Norway, Iceland and Liechtenstein 2006 1 TABLE OF CONTENTS Table A: List of all detectable substances............................................................................... 3 Table B: Overall results of the national (incl. EU co-ordinated) monitoring programmes .... 9 Table C: Fresh (incl. frozen) fruit and vegetables, surveillance sampling: results of the national (incl. EU co-ordinated) monitoring programmes................................................... 10 Table D: Cereals, surveillance sampling: results of the national (incl. EU co-ordinated) monitoring programmes......................................................................................... 11 Table E: Fresh (incl. frozen) fruit and vegetables, enforcement sampling: results of the national (incl. EU co-ordinated) monitoring programmes................................................... 12 Table F: Processed products, surveillance sampling: results of the national (incl. EU co- ordinated) monitoring programmes ....................................................................... 13 Table G: Samples with residues of more than one pesticide in fresh (incl. frozen) fruit, vegetables and cereals, surveillance and enforcement sampling ........................... 14 Table H: Pesticides found most often in the national (incl. EU co-ordinated) monitoring programmes in the European Union, Norway, Iceland and Liechtenstein for a) fruit and vegetables and b) cereals, as reported. ............................................................ 15 Table I: Numbers of samples taken by participating States for each commodity in the EU co- ordinated programme ............................................................................................. 22 Table K: Residues of pesticides in the eight commodities as analysed in the EU Member States and EEA States....................................................................................................... 23 Table L: Results from the EU co-ordinated monitoring programme for pesticide residues for each pesticide analysed for in aubergines, bananas, cauliflower, grapes, orange juice, peas, peppers and wheat......................................................................................... 24 Table M: Presentation of the most important pesticide-commodity combinations where residues were found (in alphabetical order)......................................................................... 27 Table N: Number and origin of the samples taken by country (sum of surveillance and follow- up enforcement samples, sum of fresh (incl. frozen) fruit, vegetables, cereals and processed products ................................................................................................. 30 Table O: Accreditation, participation in proficiency tests and implementation of the EU Quality Control Procedures of the pesticide residue laboratories....................................... 31 2 Table A: List of all detectable substances The table lists all substances analysed for in surveillance samples of fruit and vegetables. It specifies, where they were detected in one to four samples (1-4), or in five or more samples (>4). Substances are listed according to their residue definition in the EC-Directives or, for those not covered by EC-Directives, in the national legislation, e.g. "endosulfan" refers to "α-endosulfan", "β-endosulfan" and "endosulfan-sulphate”. 1,2-dibromoethane amitraz, total 1-4 binapacryl >4 1-naphthylacetic acid 1-4 amitrole (aminotriazol) bioallethrin 2,3,5,6-TCA ancymidol biphenyl >4 2,3,5-trimethacarb anilazine 1-4 bitertanol >4 2,3,6-TBA antraquinone boscalid (nicobifen) >4 2,4,5-T 1-4 aspon bromacil 1-4 2,4,6-tribromanisol asulam bromfenvinphos 2,4-D >4 atraton bromfenvinphos-methyl 2,4-DB atrazine 1-4 bromide, total >4 2,6-dichlorobenzamide azaconazole bromocyclen 2,6-dichloro-cresol azamethiphos bromofenoxim 2-chlorethanol, total azimsulfuron bromophos 1-4 2-phenylphenol azinphos-ethyl 1-4 bromophos-methyl (orthophenylphenol) >4 azinphos-methyl >4 bromopropylate >4 3,4,5-trimethacarb aziprotryne bromoxynil 3-ketocarbofuran azocyclotin bromoxynil octanoate 4-CPA 1-4 azolamide bromoxynil phenol abamectin, sum >4 azoxystrobin >4 bromoxynil-methyl- acephate >4 barban ether acetamiprid >4 beflubutamid bromoxynil-octanoate acetochlor benalaxyl >4 brompyrazon acibenzolar benazolin bromuconazole acibenzolar-S-methyl 1-4 bendiocarb, sum bufencarb acifluorfen benfluralin >4 bupirimate >4 aclonifen >4 benfuracarb buprofenzin >4 acrinathrin >4 benfuresate butocarboxim sulfon alachlor 1-4 benodanil butocarboxim, sum alanycarb bensulfuron butoxycarboxim aldicarb, sum >4 bensulide butralin aldimorph bensultap buturon aldrin 1-4 bentazone butylate allethrin benthiavalicarb- cadusafos >4 allidochlor isopropyl camphechlor (toxaphen) alloxydim-sodium benzoximate captafol >4 alodan benzoylprop captan >4 alpha-cypermethrin benzthiazuron captan/folpet, sum >4 (alphamethrin) >4 beta-cyfluthrin 1-4 carbanolate ametryn beta-cypermethrin carbaryl >4 amidithion bifenazate carbendazim, sum >4 amidosulfuron bifenox carbetamide 1-4 aminocarb bifenthrin >4 carbofuran, sum >4 3 carbophenothion 1-4 cis-nonachlor demeton-S-methyl 1-4 carbosulfan >4 cis-permethrin demeton-S-methyl- carboxin clethodim sulfone carfentrazon-ethyl clethodim-imin-sulfon desethylatrazin carpropamid clethodim-sulfoxid 1-4 desisopropylatrazin cekafix clodinafop-propagyl 1-4 desmedipham 1-4 chinomethionat >4 cloethocarb desmetryn chloranil clofentezine >4 diafenthiuron 1-4 chlorbenside clomazone 1-4 dialifos chlorbenside sulfon clopyralid diallate chlorbenzilate cloquintocet-methyl 1-4 diazinon >4 chlorbromuron 1-4 cloquintocet-mexyl dicamba chlorbufam clothianidin >4 dichlobenil chlordane, sum (a-/g-) 1-4 copper compounds >4 (dichlorbenil) >4 chlordane, sum(a-/g- coumachlor dichlofenthion /oxy-) coumaphos (dichlorfenthion) chlordecone >4 crimidine dichlofluanid >4 chlordene, alpha- crotoxyfos dichlone chlordene, gamma- crufomate dichloran 1-4 chlordimeform cyanazine dichlormid chlorfenapyr >4 cyanofenphos dichlorophenone 1-4 chlorfenethol cyanophos dichlorprop 1-4 chlorfenprop cyazofamid >4 dichlorvos >4 chlorfenson >4 cycloate diclobutrazol 1-4 chlorfenvinphos >4 cycloxydim diclofop chlorfluazuron 1-4 cycluron dicloran >4 chlorflurenol cyflufenamid dicofol >4 chlorflurenol, total cyfluthrin, sum >4 dicrotophos 1-4 chloridazon >4 cyhalofop-butyl dieldrin, sum >4 chlormephos cyhalothrin >4 diethatyl-ethyl chlormequat >4 cyhexatin, sum >4 diethofencarb >4 chloroaniline(3-) cymiazol difenoconazole >4 chlorobenzilate 1-4 cymoxanil >4 difenoxuron chloroneb cypermethrin, total >4 difenzoquat chloropropylate cyphenothrin difenzoquat chlorothalonil >4 cyprazine methylsulfate chloroxuron cyproconazole >4 diflovidazin >4 chlorpropham >4 cyprodinil >4 diflubenzuron >4 chlorpyrifos >4 cyprofuram diflufenican 1-4 chlorpyrifos-methyl >4 cyromazine >4 dikegulac chlorsulfuron cythioate dimefox chlorthal 1-4 dalapon dimefuron chlorthal-dimethyl >4 daled dimethachlor chlorthiamid daminozide, sum 1-4 dimethametryn chlorthion danifos dimethenamid 1-4 chlorthiophos dazomet dimethenamid-p chlorthiophos-sulfone DDMU dimethipin chlortoluron 1-4 DDT, sum >4 dimethirimol chlozolinate 1-4 deltamethrin >4 dimethoate, sum >4 chromafenozide demeton-O dimethomorph >4 cinidon-ethyl 1-4 demeton-O-methyl 1-4 dimethylvinphos (E) cinosulfuron demeton-S dimethylvinphos (Z) 4 dimetilan etoxazole 1-4 fluazifop-p-butyl 1-4 dimoxystrobin etridiazole >4 fluazinam 1-4 diniconazole >4 etrimfos 1-4 fluazolate dinitramine famophos fluazuron dinobuton famoxadone >4 flubenzimine dinocap 1-4 famphur fluchloralin dinoseb, sum fenamidone 1-4 flucycloxuron dinoterb fenamiphos, sum >4 flucythrinate >4 dioxabenzofos fenarimol >4 fludioxonil >4 dioxacarb fenazaflor flufenacet fluthiamid 1-4 dioxathion >4 fenazaquin >4 flufenoxuron >4 diphenamid fenazox flumethrin diphenyl sulfone fenbuconazole >4 flumetralin diphenylamine >4 fenbutatin oxide >4 flumioxazin dipropetryn fenchlorazole fluometuron dipropylisocinchomeron fenchlorphos, sum 1-4 fluorochloridone 1-4 at fenfuram fluorodifen diquat >4 fenhexamid >4 fluoroglycofen disulfoton, sum 1-4 fenitrothion >4 fluotrimazole ditalimfos 1-4 fenobucarb 1-4 fluoxastrobin dithianon >4 fenoprop flupyrsulfuron 1-4 dithofencarb >4 fenothiocarb flupyrsulfuron-methyl diuron >4 fenoxaprop fluquinconazole >4 DMSA fenoxaprop-p flurecol-butyl DNOC fenoxaprop-p-ethyl flurenol dodemorph fenoxycarb >4 flurochloridone dodine >4 fenpiclonil >4 fluroxypyr 1-4 doxacarb fenpropathrin >4 fluroxypyr-meptyl edifenphos 1-4 fenpropidin >4 flurprimidol endosulfan, sum >4 fenpropimorph >4 flurtamone endosulfandiol fenpyroximate >4 flusilazole >4 endothal fenson 1-4 flusulfamide endrin, sum fensulfothion 1-4 flutolanil >4 endrin-aldehyd fenthion, sum >4 flutriafol >4 EPN >4 fentin fluvalinate >4 epoxiconacole >4 fentin acetate folpet >4 EPTC fentin hydroxide fonofos esfenvalerate >4 fenuron forchlorfenuron etacelasil fenvalerate, total >4 formetanate >4 etaconazole fenvalerate/esfenvalerate formothion ethalfluralin RR&SS >4 fosetyl-aluminium ethephon 1-4 fenvalerate/esfenvalerate (phosethyl-aluminium) >4 ethidimuron RS&SR >4 fosmethilan ethiofencarb, sum >4 fipronil >4 fosthiazate ethion >4 flampropisopropyl fuberidazole 1-4 ethiprole flamprop-methyl furalaxyl 1-4 ethirimol >4 flazasulfuron furathiocarb ethoate-methyl flonicamid